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At least 1,621 records · Page 90

Composite Piezoelectric Resonator 1D Modeling with Loss

Abstract – Maximizing the benefit of applying piezoelectric materials in composite structures, which are a mix of piezoelectric and elastic elements, requires analytical modeling. In this paper we describe two main classes of resonators and how to model using network equivalent including material losses. These include extensional devices where the layer areas are parallel to the direction of wave travel as found in a variety of thickness or length mode transducers (BC. Stress T1 = T2 at boundary) and transverse mode resonators (BC. Strain S1 = S2 at boundary) where the major layer area is perpendicular to the wave direction as is found in radial mode or length thickness mode composite resonators. In order to illustrate these models we will use Mason’s equivalent circuits with elastic, dielectric and piezoelectric loss. It is noted that in order to maintain consistency with the linear equations of piezoelectricity and the wave equation care is required when applying complex loss coefficients to the models. Although these techniques are applicable to other models we use Mason’s network equivalent circuit because it is intuitive for composite modeling due to the frequency independent turns ratio and the independence of the equations describing the elastic layers from the adjoining layer properties which aids in understanding the boundary conditions to impose on the layer boundaries. We will present network models for a variety of applications with loss and show how to calculate their impedance spectra, interface stress, strain velocity and displacement spectra.

Sherrit, Stewart↗

High Layer Number ( n = 1–6) 2D Ruddlesden–Popper Lead Bromide Perovskites: Nanosheets, Crystal Structure, and Optoelectronic Properties

2D Ruddlesden–Popper (RP) lead halide perovskites have highly tunable structures, compositions, and properties that enable their promising optoelectronic applications. Among various 2D halide perovskites, the materials chemistry and fundamental optoelectronic properties of high layer number (n) lead-bromide RP perovskites, where n refers to the number of inorganic octahedra layers, have been less studied. Here, we report the synthesis of thin nanosheets of (PEA) 2 Cs n–1 Pb n Br 3n+1 (n = 1–6, PEA = phenylethylammonium) perovskites and study the optical properties, assigning photoluminescence emissions of 486, 496, and 505 nm to n = 4–6 phases, respectively, and reporting the photoluminescence lifetimes. Furthermore, the crystal structure of (PEA) 2 Cs 2 Pb 3 Br 10 was determined to reveal minimal octahedral structural distortions. Ultraviolet photoelectron spectroscopy measurements reveal the positioning of the valence and conduction bands for n = 1–3 phases and confirm the type-I band alignment for the (PEA) 2 Cs n–1 Pb n Br 3n+1 series, laying the foundation for rational heterostructure device design in the future.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ceramic susceptor for induction bonding of metals, ceramics, and plastics

A thin (.005) flexible ceramic susceptor (carbon) was discovered. It was developed to join ceramics, plastics, metals, and combinations of these materials using a unique induction heating process. Bonding times for laboratory specimens comparing state of the art technology to induction bonding were cut by a factor of 10 to 100 times. This novel type of carbon susceptor allows for applying heat directly and only to the bondline without heating the entire structure, supports, and fixtures of a bonding assembly. The ceramic (carbon film) susceptor produces molten adhesive or matrix material at the bond interface. This molten material flows through the perforated susceptor producing a fusion between the two parts to be joined, which in many instances has proven to be stronger than the parent material. Bonding can be accomplished in 2 minutes on areas submitted to the inductive heating. Because a carbon susceptor is used in bonding carbon fiber reinforced plastics and ceramics, there is no radar signature or return making it an ideal process for joining advanced aerospace composite structures.

Fox, Robert L.↗

Compositional Evolution of Saturn's Rings Due to Meteoroid Bombardment

In this paper we address the question of compositional evolution in planetary ring systems subsequent to meteoroid bombardment. The huge surface area to mass ratio of planetary rings ensures that this is an important process, even with current uncertainties on the meteoroid flux. We develop a new model which includes both direct deposition of extrinsic meteoritic "pollutants", and ballistic transport of the increasingly polluted ring material as impact ejecta. Our study includes detailed radiative transfer modeling of ring particle spectral reflectivities based on refractive indices of realistic constituents. Voyager data have shown that the lower optical depth regions in Saturn's rings (the C ring and Cassini Division) have darker and less red particles than the optically thicken A and B rings. These coupled structural-compositional groupings have never been explained; we present and explore the hypothesis that global scale color and compositional differences in the main rings of Saturn arise naturally from extrinsic meteoroid bombardment of a ring system which was initially composed primarily, but not entirely, of water ice. We find that the regional color and albedo differences can be understood if all ring material was initially identical (primarily water ice, based on other data, but colored by tiny amounts of intrinsic reddish, plausibly organic, absorber) and then evolved entirely by addition and mixing of extrinsic, nearly neutrally colored. plausibly carbonaceous material. We further demonstrate that the detailed radial profile of color across the abrupt B ring - C ring boundary can.constrain key unknown parameters in the model. Using new alternates of parameter values, we estimate the duration of the exposure to extrinsic meteoroid flux of this part of the rings, at least, to be on the order of 10(exp 8) years. This conclusion is easily extended by inference to the Cassini Division and its surroundings as well. This geologically young "age" is compatible with timescales estimated elsewhere based on the evolution of ring structure due to ballistic transport, and also with other "short timescales" estimated on the grounds of gravitational torques. However, uncertainty in the flux of interplanetary debris and in the ejects yield may preclude ruling out a ring age as old as the solar system at this time.

Cuzzi, J.↗

Structural Analysis of Composite Flywheels: an Integrated NDE and FEM Approach

A structural assessment by integrating finite-element methods (FEM) and a nondestructive evaluation (NDE) of two flywheel rotor assemblies is presented. Composite rotor A is pancake-like with a solid hub design, and composite rotor B is cylindrical with a hollow hub design. Detailed analyses under combined centrifugal and interference-fit loading are performed. Two- and three-dimensional stress analyses and two-dimensional fracture mechanics analyses are conducted. A comparison of the structural analysis results obtained with those extracted via NDE findings is reported. Contact effects due to press-fit conditions are evaluated. Stress results generated from the finite-element analyses were corroborated with the analytical solution. Cracks due to rotational loading up to 48,000 rpm for rotor A and 34,000 rpm for rotor B were successfully imaged with NDE and predicted with FEM and fracture mechanics analyses. A procedure that extends current structural analysis to a life prediction tool is also defined.

Abdul-Aziz, Ali↗

Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis

Oxidative dehydrogenation of propane to propylene can be achieved using conventional, oxygen-assisted dehydrogenation of propane (O 2 –ODHP) or via the use of soft oxidants, such as CO 2 , N 2 O, S-containing compounds, and halogens/halides. The major roles of soft oxidants include inhibiting overoxidation and improving propylene selectivity, which are considered to be current challenges in O 2 -assisted dehydrogenation. For both CO 2 – and N 2 O–ODHP reactions, significant efforts have been devoted to developing redox-active (e.g., chromium, vanadate, iron, etc.), nonredox-type main group metal oxide (e.g., group IIIA, gallium), and other transition metal/metal oxide catalysts (e.g., molybdenum, palladium platinum, rhodium, ruthenium, etc.), as well as zeolite-based catalysts with adjustable acid–base properties, unique pore structures, and topologies. Metal sulfides have shown promising performance in DHP, whereas the development of suitable catalysts has lagged for SO 2 - or S-assisted ODHP. Recently, significant efforts have been focused on homogeneous and heterogeneous ODHP using halogens (e.g., Br 2 , I 2 , Cl 2 , etc.) and hydrogen halides (e.g., HCl and HBr) for the development of facile processes for C 3 H 6 synthesis. This work aims to provide a critical, comprehensive review of recent advances in oxidative dehydrogenation of propane with these soft oxidants, especially highlighting the current state of understanding of the following factors: (i) relationships between composition, structure, and catalytic performance, (ii) effects of the support, acidity, and promoters, (iii) reaction pathway and mechanistic insights, and (iv) the various roles of soft oxidants. Theoretical and computational insights toward understanding reaction mechanisms and catalyst design principles are also covered. Future research opportunities are discussed in terms of catalyst design and synthesis, deactivation and regeneration, reaction mechanisms, and alternative approaches.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

FEA-Based Failure Analysis of Post-Buckled Composite Multi-Hat Stiffened Panel Under Static Compression

The aerospace industry uses composite multi-hat stiffened panels for skins because of their high strength-to-weight and stiffness-to-weight ratios. However, laminated composites with initial flaws are susceptible to delamination under buckling loads. The goal is to ensure damage initiation occurs past the buckled state, only stable damage progression at loads below the ultimate compressive load, and debonding failure past the ultimate compressive load. This approach reduces weight and addresses a potential design review for future aircraft repairs. The need exists to better understand damage initiation and growth mechanisms in composite structures while assisting in the design, analysis, and sustainment methods. Teflon inserts simulate damage defects during manufacturing, while barely visible impact helps capture human error during manufacturing. This work shows the interaction between the skin-stringer and ply-ply separations at the post-buckled state for both defect events using Abaqus Virtual Crack Closure Technique (VCCT). The initial configuration for the Teflon case was to leave the Teflon region unbonded, and the initial impact damage region approximation came from the experimental data and was considered the initial configuration. When compared against the experimental data produced through the NASA Advanced Composites Project (ACP), the present model captured damage transition from skin-hat to ply1-ply2. The model validations were within ~5% of the experimental data.

composite↗

Search for Organic Nanoglobules in Carbonaceous Chondrites Using Microtomography

Primitive solar materials have various organic matters. In recent years, novel organic materials called organic nanoglobules of a few hundred micrometers in typical size were discovered in carbonaceous chondrites, IDPs, and comet 81P/Wild 2. The organic globules are spherical shape and in many cases with hollow structures. Composition of the globules are mainly aromatic carbon. The isotopic anomalies of SD and 6N 15 observed in the globules indicate that they were formed from photochemical reaction to ice particles at very low temperature environment, such as molecular clouds or outer protosolar disk. Aqueous alteration of organic matters and the gamma-ray irradiation to PAH are also suggested as alternative possible formation processes. If the globules are made from organic ice particles, the hollow regions of the globules are suggested to be once filled with volatile H20-rich organic ices, while if they were formed by aqueous alteration, the hollow regions should be filled with a fluid which caused the aqueous alteration. However, fluids in the globules have not been detected so far in the previous studies. If fluids were originally preserved in the hollows, they might be lost during destructive processes of sample separation or preparation for TEM observation. X-ray computed tomography (CT) is a nondestructive method which can determine 3-D internal structures of objects. SR (synchrotron radiation)-based imaging microtomography can give submicron spatial resolution [8] and was applied to micro textures in extraterrestrial materials, such as cometary grains captured by the Stardust mission [9]. If organic globules are observed non-destructively in carbonaceous chondrites by tomography, we can check the presence of fluids in the hollows. If fluids are preserved, we may analyze chemical and isotopic compositions of the fluids. The purpose of this study is to observe organic nanoglobules using imaging tomography for future analysis.

Matsumoto, T.↗

Broadband and Wide Angle Nonreciprocal Thermal Emission from Weyl Semimetal Structures

Nonreciprocal thermal emission is a cutting-edge technology that enables fundamental control over thermal radiation and has exciting applications in thermal energy harvesting. However, so far one of the foremost challenges is making nonreciprocal emission to operate over a broad wavelength range and for multiple angles. In this work, we solve this outstanding problem by proposing three different types of structures always utilizing only one Weyl semimetal (WSM) thin film combined with one or two additional dielectric or metallic layers and terminated by a metallic substrate. First a tradeoff relationship between the magnitude and bandwidth of the thermal nonreciprocity contrast is established based on the thickness of the WSM film. Then, the bandwidth broadening effect is demonstrated via the insertion of a dielectric spacer layer that can also be fine-tuned by varying its thickness. Finally, further control on the resulting strong nonreciprocal thermal radiation is demonstrated by the addition of a thin metallic layer in the proposed few layer designs. The presented composite structures work for a broad frequency range and multiple emission angles, consisting highly advantageous properties to various nonreciprocal thermal radiation applications. Moreover, the proposed designs do not require any patterning and can be experimentally realized by simple deposition fabrication methods. They are expected to aid in the creation of broadband nonreciprocal thermal emitters that can find applications in new energy harvesting devices.

Andrew Butler↗

Physical aging in graphite/epoxy composites

Sub-Tg annealing has been found to affect the properties of graphite/epoxy composites. The network epoxy studied was based on the chemistry of tetraglycidyl 4,4'-diamino-diphenyl methane (TGDDM) crosslinked by 4,4'-diamino-diphenyl sulfone (DDS). Differential scanning calorimetry, thermal mechanical analysis, and solid-state cross-polarized magic-angle-spinning nuclear magnetic resonance spectroscopy have been utilized in order to characterize this process of recovery towards thermodynamic equilibrium. The volume and enthalpy recovery as well as the 'thermoreversibility' aspects of the physical aging are discussed. This nonequilibrium and time-dependent behavior of network epoxies are considered in view of the increasingly wide applications of TGDDM-DDS epoxies as matrix materials of structural composites in the aerospace industry.

Kong, E. S. W.↗

Coaxial carbon plasma gun deposition of amorphous carbon films

A unique plasma gun employing coaxial carbon electrodes was used in an attempt to deposit thin films of amorphous diamond-like carbon. A number of different structural, compositional, and electrical characterization techniques were used to characterize these films. These included scanning electron microscopy, scanning transmission electron microscopy, X ray diffraction and absorption, spectrographic analysis, energy dispersive spectroscopy, and selected area electron diffraction. Optical absorption and electrical resistivity measurements were also performed. The films were determined to be primarily amorphous, with poor adhesion to fused silica substrates. Many inclusions of particulates were found to be present as well. Analysis of these particulates revealed the presence of trace impurities, such as Fe and Cu, which were also found in the graphite electrode material. The electrodes were the source of these impurities. No evidence of diamond-like crystallite structure was found in any of the film samples. Details of the apparatus, experimental procedure, and film characteristics are presented.

Sater, D. M.↗

On the Sensitivity of Piezoceramics and Piezopolymers in Structural Integrity Monitoring of Large Trusses

An analytical assessment has been made of the reliability of using integrated microactuators and sensors in the form of piezoceramics and piezopolymers as joint integrity monitors in trussed systems. The concept is first implemented for a simple structure which consists of two truss members with a 45 deg lift angle joined at the apex. A piezoceramic patch (or piezopolymer film) bonded on the surface of one of the members at a location near the joint is used as a collocated actuator/sensor. The overall structural dynamic response under an excitation was modeled by finite element method. Different degrees of nodal constraints at the joints representing various degrees of joint integrity are employed. The resulting dynamic response showed distinct responses for varying joint stiffnesses. Parallel experimental work on a truss model using a multichannel data acquisition system and a digital signal analyzer confirms the results from analysis. We further studied the sensitivity of the micro-sensors to the behavior of joints of large arch truss structure. Results obtained for large trusses with many degrees of freedom indicate optimum locations of sensors for which the dynamic response signatures are distinct and distinguishable for relatively small changes in joint integrity and/or structural geometry. Computations based on finite element modeling show that locating the single actuator/sensor at the joint corresponding to the first loss of static stability appear optimal. Hence, static stability analysis of complex trusses can give us a good indication of the optimum placement of sensors for maximum response. This observation is important if few distributed sensors and actuators are available for placement in constructed facilities made from large trusses with many degrees of freedom. As an extension of this work a dynamic response signature identification technique to monitor in-service degradation of joints is under development for application to the monitoring of the integrity of adhesive joints in composite structures.

Abatan, A. O.↗

Sustainable chemistry with plasmonic photocatalysts

There is a pressing global need to increase the use of renewable energy sources and limit greenhouse gas emissions. Towards this goal, highly efficient and molecularly selective chemical processes that operate under mild conditions are critical. Plasmonic photocatalysis uses optically resonant metallic nanoparticles and their resulting plasmonic, electronic, and phononic light-matter interactions to drive chemical reactions. The promise of simultaneous high-efficiency and product-selective reactions with plasmon photocatalysis provides a compelling opportunity to rethink how chemistry is achieved. Plasmonic nanoparticles serve as nanoscale ‘antennas’ that enable strong light–matter interactions, surpassing the light-harvesting capabilities one would expect purely from their size. Complex composite structures, combining engineered light harvesters with more chemically active components, are a focal point of current research endeavors. In this review, we provide an overview of recent advances in plasmonic catalysis. We start with a discussion of the relevant mechanisms in photochemical transformations and explain hot-carrier generation and distributions from several ubiquitous plasmonic antennae. Then we highlight three important types of catalytic processes for sustainable chemistry: ammonia synthesis, hydrogen production and CO 2 reduction. To help elucidate the reaction mechanism, both state-of-art electromagnetic calculations and quantum mechanistic calculations are discussed. This review provides insights to better understand the mechanism of plasmonic photocatalysis with a variety of metallic and composite nanostructures toward designing and controlling improved platforms for green chemistry in the future.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rotorcraft research at NASA

An overview of NASA research in rotorcraft technology is presented. Ten percent of the NASA aeronautics program is made up of rotorcraft research. The aeronautics program conducts research in five areas: aerodynamics, propulsion, materials and structures, information sciences and human factors, and flight systems. The key objectives of NASA research are major reduction in external noise and aircraft vibration, reduction of pilot workload for night, adverse weather and NOE flying, increasing power and reducing fuel consumption in small engines, and identifying and exploiting vehicle characteristics and concepts for triple current speed and improved maneuverability and agility. NASA and Army resources are combined to pursue research at three major centers. The Ames research center conducts research in the physics of transition and turbulent flows, using a new improved wind tunnel and the NAS system. At the Langley Research Center, work is done in noise and vibration reduction, finding lighter and more durable composite structures, and aeroelasticity for tilt motors and X-wing configurations. At the NASA Lewis Research Center, researchers are working on improving helicopter propulsion systems.

Burks, John S.↗

Application of finite element substructuring to composite micromechanics

Finite element substructuring is used to predict unidirectional fiber composite hygral (moisture), thermal, and mechanical properties. COSMIC NASTRAN and MSC/NASTRAN are used to perform the finite element analysis. The results obtained from the finite element model are compared with those obtained from the simplified composite micromechanics equations. A unidirectional composite structure made of boron/HM-epoxy, S-glass/IMHS-epoxy and AS/IMHS-epoxy are studied. The finite element analysis is performed using three dimensional isoparametric brick elements and two distinct models. The first model consists of a single cell (one fiber surrounded by matrix) to form a square. The second model uses the single cell and substructuring to form a nine cell square array. To compare computer time and results with the nine cell superelement model, another nine cell model is constructed using conventional mesh generation techniques. An independent computer program consisting of the simplified micromechanics equation is developed to predict the hygral, thermal, and mechanical properties for this comparison. The results indicate that advanced techniques can be used advantageously for fiber composite micromechanics.

Caruso, J. J.↗

Realistic Thermographic Simulation of Impact Damage with Quadrupole Method

Flash thermography has been shown to be an effective method for detection of delaminations in carbon fiber reinforced polymer (CFRP) composite structures. Improved understanding of thelimitations of the technique can be obtained by simulating the inspection process. Time domainfinite difference and finite element methods are well suited for such simulations but can be computationally intensive. An alternate method is to solve the Laplace transform of the heat equation, then invert the Laplace transform to produce a time domain response. Often this is referred to as the thermal quadrupole method and is well suited for simulating flash thermography. The quadrupole method has been used extensively for simulating one-dimensional heat flow in multilayer systems with contact resistances at the interfaces. It is also applicable for three dimensional configurations, in particular for simulation of changes in thermographic response due to delaminations in composites. This presentation discusses three-dimensional simulations with realistic shapes and contact resistances at the interfaces between layers. The results of these simulations are compared to thermography measurements on composites specimens with impact induced delaminations.

Thermography↗

Fragmentation Increases Impact of Wind Disturbance on Forest Structure and Carbon Stocks in a Western Amazonian Landscape

Tropical second-growth forests could help mitigate climate change, but the degree to which their carbon potential is achieved will depend on exposure to disturbance. Wind disturbance is common in tropical forests, shaping structure, composition, and function, and influencing successional trajectories. However, little is known about the impacts of extreme winds in fragmented landscapes, though second-growth forests are often located in mosaics of forest, pasture, cropland, and other land cover types. Though indirect evidence suggests that fragmentation increases risk of wind damage, few studies have found such impacts following severe storms. In this study, we ask whether fragmentation and forest type (old vs. second growth) were associated with variation in wind damage after a severe convective storm in a fragmented production landscape in western Amazonia. We applied linear spectral unmixing to Landsat 8 imagery from before and after the storm, and combined it with field observations of damage to map wind effects on forest structure and biomass (Figure 4, 5). We also used Landsat 8 imagery to map land cover with the goals of identifying old- and second-growth forest and characterizing fragmentation. We used these data to assess variation in wind disturbance across 95,596 hectares of forest, distributed over 6,110 patches. We find that fragmentation is significantly associated with wind damage, with damage severity higher at forest edges and in edgier, more isolated patches (Figure 7). Damage was more severe in old-growth than in second-growth forests, but this effect was weaker than that of fragmentation (Figure 8). These results illustrate the importance of considering spatial configuration and landscape context in planning tropical forest restoration and predicting carbon sequestration in second-growth forests. Future research should address the mechanisms behind these results, to minimize wind damage risk in second-growth forests so their carbon potential can be maximally achieved.

Schwartz, Naomi B.↗