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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,621 records · Page 90
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

High-Lift OVERFLOW Analysis of the DLR-F11 Wind Tunnel Model

In response to the 2nd AIAA CFD High Lift Prediction Workshop, the DLR-F11 wind tunnel model is analyzed using the Reynolds-averaged Navier-Stokes flow solver OVERFLOW. A series of overset grids for a bracket-off landing configuration is constructed and analyzed as part of a general grid refinement study. This high Reynolds number (15.1 million) analysis is done at multiple angles-of-attack to evaluate grid resolution effects at operational lift levels as well as near stall. A quadratic constitutive relation recently added to OVERFLOW for improved solution accuracy is utilized for side-of-body separation issues at low angles-of-attack and outboard wing separation at stall angles. The outboard wing separation occurs when the slat brackets are added to the landing configuration and is a source of discrepancy between the predictions and experimental data. A detailed flow field analysis is performed at low Reynolds number (1.35 million) after pressure tube bundles are added to the bracket-on medium grid system with the intent of better understanding bracket/bundle wake interaction with the wing's boundary layer. Localized grid refinement behind each slat bracket and pressure tube bundle coupled with a time accurate analysis are exercised in an attempt to improve stall prediction capability. The results are inconclusive and suggest the simulation is missing a key element such as boundary layer transition. The computed lift curve is under-predicted through the linear range and over-predicted near stall, and the solution from the most complete configuration analyzed shows outboard wing separation occurring behind slat bracket 6 where the experiment shows it behind bracket 5. These results are consistent with most other participants of this workshop.

High-lift↗
NASA NTRS2014

Evaluation of the First Transport Rotorcraft Airframe Crash Testbed (TRACT 1) Full-Scale Crash Test

In 2012, the NASA Rotary Wing Crashworthiness Program initiated the Transport Rotorcraft Airframe Crash Testbed (TRACT) research program by obtaining two CH-46E helicopters from the Navy CH-46E Program Office (PMA-226) at the Navy Flight Readiness Center in Cherry Point, North Carolina. Full-scale crash tests were planned to assess dynamic responses of transport-category rotorcraft under combined horizontal and vertical impact loading. The first crash test (TRACT 1) was performed at NASA Langley Research Center's Landing and Impact Research Facility (LandIR), which enables the study of critical interactions between the airframe, seat, and occupant during a controlled crash environment. The CH-46E fuselage is categorized as a medium-lift rotorcraft with fuselage dimensions comparable to a regional jet or business jet. The first TRACT test (TRACT 1) was conducted in August 2013. The primary objectives for TRACT 1 were to: (1) assess improvements to occupant loads and displacement with the use of crashworthy features such as pre-tensioning active restraints and energy absorbing seats, (2) develop novel techniques for photogrammetric data acquisition to measure occupant and airframe kinematics, and (3) provide baseline data for future comparison with a retrofitted airframe configuration. Crash test conditions for TRACT 1 were 33-ft/s forward and 25-ft/s vertical combined velocity onto soft soil, which represent a severe, but potentially survivable impact scenario. The extraordinary value of the TRACT 1 test was reflected by the breadth of meaningful experiments. A total of 8 unique experiments were conducted to evaluate ATD responses, seat and restraint performance, cargo restraint effectiveness, patient litter behavior, and photogrammetric techniques. A combination of Hybrid II, Hybrid III, and ES-2 Anthropomorphic Test Devices (ATDs) were placed in forward and side facing seats and occupant results were compared against injury criteria. Loads from ATDs in energy absorbing seats and restraints were within injury limits. Severe injury was likely for ATDs in forward facing passenger seats, legacy troop bench seats, and a three-tiered patient litter. In addition, two standing ATDs were used to evaluate the benefit of Mobile Aircrew Restraint Systems (MARS) versus a standard gunner's belt. The ATD with the MARS survived the impact, while fatal head blunt trauma occurred for the standing ATD held by the legacy gunner's belt. In addition to occupant loading, the structural response of the airframe was assessed based on accelerometers located throughout the airframe and using three-dimensional photogrammetric techniques. Analysis of the photogrammetric data indicated regions of maximum deflection and permanent deformation.

Annett, Martin S.↗
NASA NTRS1993

Streamwise vorticity generation and mixing enhancement in free jets by 'delta-tabs'

The effect of triangular tabs, placed at the nozzle exit, on the evolution of free jets is investigated. The effect, a large distortion of the jet cross section and a resultant increase in mixing downstream, has been inferred before to be due to a pair of streamwise vortices originating from each tab. In this paper, the generation mechanism of the streamwise vorticity (omega sub x) is considered first. Two sources are postulated. One is the upstream 'pressure hill', produced by the tab, which appears to be the dominant source. Another is due to vortex filaments shed from the sides of the tab and reoriented downstream by the mean shear of the mixing layer. In the case of a 'delta-tab', a triangular tab with its apex leaning downstream, vorticity from the two sources explain the stronger effect in that configuration. Data on the vorticity evolution for the effect of two delta-tabs are presented, up to twelve jet diameters from the exit, which show that the streamwise vortices persist even at the farthest measurement station. The magnitude of omega sub x-maximum decays continually with distance from the nozzle, its ratio to azimuthal vorticity maximum is found to be about 1/5 everywhere. The relative effect of a delta-tab on jets from an axisymmetric nozzle and a 8:1 rectangular nozzle is also studied. The mixing layer distortion is found to be less pronounced in the rectangular case. The jet mixing, as manifested by the mass flux measured at a downstream station, is increased in the axisymmetric jet but it is decreased in the rectangular jet under consideration by the delta-tab.

Zaman, K. B. M. Q.↗
NASA NTRS1993

Streamwise vorticity generation and mixing enhancement in free jets by delta-tabs

The effect of triangular tabs, placed at the nozzle exit, on the evolution of free jets is investigated. The effect, a large distortion of the jet cross section and a resultant increase in mixing downstream, has been inferred before to be due to a pair of streamwise vortices originating from each tab. In this paper, the generation mechanism of the stream wise vorticity (omega sub x) is considered first. Two sources are postulated. One is the upstream 'pressure hill', produced by the tab, which appears to be the dominant source. Another is due to vortex filaments shed from the sides of the tab and reoriented downstream by the mean shear of the mixing layer. In the case of a 'delta-tab', a triangular tab with its apex leaning downstream, vorticity from the two sources explain the stronger effect in that configuration. Data on the vorticity evolution for the effect of two delta-tabs are presented, up to twelve jet diameters from the exit, which show that the streamwise vortices persist even at the farthest measurement station. The magnitude of omega sub x-maximum decays continually with distance from the nozzle, its ratio to azimuthal vorticity maximum is found to be about 1/5 everywhere. The relative effect of a delta-tab on jets from an axisymmetric nozzle and a 8:1 rectangular nozzle is also studied. The mixing layer distortion is found to be less pronounced in the rectangular case. The jet mixing, as manifested by the mass flux measured at a downstream station, is increased in the axisymmetric jet but it is decreased in the rectangular jet under consideration by the delta-tab.

Zaman, K. B. M. Q.↗
NASA NTRS2005

The Effects of Thrust Uncertainty and Attitude Knowledge Errors on the MMS Formation Maintenance Maneuver

The Magnetospheric Multiscale (MMS) Mission will use a formation of four spinning spacecraft to study the Earth s magnetosphere. The science objectives of MMS require a near-regular tetrahedron formation to be maintained with side lengths ranging from ten kilometers to several thousand kilometers at orbit apogee. To reduce spacecraft complexity and cost, the current mission concept assumes MMS can achieve its formation goals through open-loop orbit control from the ground, rather than in-flight, closed-loop formation control that has been the subject of recent study. Significant analysis has been performed to provide optimal reference orbit and relative orbit designs. However, the feasibility of achieving these orbits, and maintaining them for an extended period of time in the presence of real world errors and perturbations has not been investigated. In particular, attitude knowledge and control errors, which may have a negligible effect on orbit control for conventional missions with spinning spacecraft, can contribute significant errors to the MMS orbits. In this work, a 6 degree-of-freedom (DOF) simulation is developed and used to analyze the effects of realistic errors on formation maintenance maneuver accuracy. Several realistic considerations including a finite-burn model, attitude perturbations, and thrust uncertainty are studied. The primary objective is to quantify the effects of realistic attitude and orbit control, knowledge, and actuator errors on the formation geometry by observing representative maneuver errors of a single spacecraft.

Tsai, Dean C.↗
NASA NTRS2005

Ion Temperature Control of the Io Plasma Torus

We report on observational and theoretical studies of ion temperature in the Io plasma torus. Ion temperature is a critical factor for two reasons. First, ions are a major supplier of energy to the torus electrons which power the intense EUV emissions. Second, ion temperature determines the vertical extent of plasma along field lines. Higher temperatures spread plasma out, lowers the density and slows reaction rates. The combined effects can play a controlling role in torus energetics and chemistry. An unexpected tool for the study of ion temperature is the longitudinal structure in the plasma torus which often manifests itself as periodic brightness variations. Opposite sides of the torus (especially magnetic longitudes 20 and 200 degrees) have been observed on numerous occasions to have dramatically different brightness, density, composition, ionization state, electron temperature and ion temperature. These asymmetries must ultimately be driven by different energy flows on the opposite sides, presenting an opportunity to observe key torus processes operating under different conditions. The most comprehensive dataset for the study of longitudinal variations was obtained by the Cassini UVIS instrument during its Jupiter flyby. Steffl (Ph.D. thesis, 2005) identified longitudinal variations in all the quantities listed above wit the exception of ion temperature. We extend his work by undertaking the first search for such variation in the UVIS dataset. We also report on a 'square centimeter' model of the torus which extend the traditional 'cubic centimeter' models by including the controlling effects of ion temperature more completely.

Delamere, P. A.↗
NASA NTRS1951

Investigation at Mach Number 1.88 of Half of a Conical-spike Diffuser Mounted as a Side Inlet with Boundary-layer Control / H. Fred Goelzer and Edgar M. Cortright, Jr

Experimental investigation was conducted at Mach number 1.88 to determine performance characteristics of half a 50 degree-conical-spike inlet mounted on a flat plate. Initial boundary layer was removed up-stream of inlet by a ram-type scoop of variable height. Initial boundary-layer thickness was also varied. With complete removal of initial boundary layer, total-pressure recovery of approximately 70 percent. Several alternative boundary-layer-removal systems were investigated which decreased the adverse effect of operating the ram scoop sub-critically.

BOUNDARY LAYER CONTROL-INTERNAL AERODYNAMICS↗
NASA NTRS1992

Multiple scattering effects on spaceborne lidar

A semianalytic Monte Carlo code originally developed for oceanographic calculations (Poole et al., 1981) has been modified for use in studying multiple scattering of space-based lidar. The approach is very similar to that described by Kunkel and Weinman (1976). The trajectory of each photon is followed from the transmitter through multiple scattering until the photon is either scattered backward out of the atmosphere, scattered forward into the ground and absorbed, or scattered out the sides of the cloud. The probability that the photon will return directly to the detector is computed and summed over all significant scattering events within the field of view of the detector. Multiple scattering of the lidar pulse causes an apparent increase in the transmittance of the medium. Multiple scattering effects for space-based lidar are more significant than for ground-based lidar due to the much larger beam diameter in the atmosphere. These larger diameters are due not only to the greater range between the lidar and the scattering volume, but also the need to maintain relatively large beam divergences to satisfy eye safety restrictions on the laser irradiance at the Earth's surface. The simulations presented here are for a wavelength of 1064 nm and the Deirmendjian C1 phase function, which yields an extinction coefficient of 17.259/km. We have looked at two cases: a space-based lidar at 296 km observing a C1 cloud 293 km from the lidar and, for comparison purposes, a ground-based lidar looking at a C1 cloud with a base height of either 2 km or 5 km. The C1 size distribution roughly approximates that of stratocumulus or altocumulus clouds (aufm Kampe and Weickmann, 1957).

Winker, David M.↗
NASA NTRS1986

Effects of variables upon pyrotechnically induced shock response spectra

Throughout the aerospace industry, large variations of 50 percent (6 dB) or more are continually noted for linear shaped charge (LSC) generated shock response spectra (SRS) from flight data (from the exact same location on different flights) and from plate tests (side by side measurements on the same test). A research program was developed to investigate causes of these large SRS variations. A series of ball drop calibration tests to verify calibration of accelerometers and a series of plate tests to investigate charge and assembly variables were performed. The resulting data were analyzed to determine if and to what degree manufacturing and assembly variables, distance from the shock source, data acquisition instrumentation, and shock energy propagation affect the SRS. LSC variables consisted of coreload, standoff, and apex angle. The assembly variable was the torque on the LSC holder. Other variables were distance from source of accelerometers, accelerometer mounting methods, and joint effects. Results indicated that LSC variables did not affect SRS as long as the plate was severed. Accelerometers mounted on mounting blocks showed significantly lower levels above 5000 Hz. Lap joints did not affect SRS levels. The test plate was mounted in an almost free-free state; therefore, distance from the source did not affect the SRS. Several varieties and brands of accelerometers were used, and all but one demonstrated very large variations in SRS.

Smith, J. L.↗
DOE OSTI2023

Effective Lanthanide Diffusivity through U-Zr Metallic Fuel

Fuel-cladding chemical interaction (FCCI) is one of the main concerns for the performance of U-Zr metallic fuels. Although FCCI results in complex phase transformations and morphological changes in both the fuel and cladding sides of the interface, the formation of a brittle layer in the cladding side of the interface (sometimes referred to as wastage) has one of the most significant impacts on the cladding mechanical integrity. This brittle layer is associated with the formation of intermetallic compounds between the cladding constituents Fe, Cr and the lanthanide fission product species. The formation of this cladding wastage layer has been the focus of recent efforts to develop a mechanistic modeling framework, including production of lanthanides in the fuel, transport through the fuel to the fuel-cladding interface, and phase transformation to form intermetallic phases. To calculate the rate of transport of lanthanides through the fuel, a multi-scale computational approach has been used. Atomistic calculations have been performed to determine the diffusivities of Nd, the most prevalent lanthanide species, through the solid fuel matrix and along pore surfaces. These diffusivities have been used as input parameters for a mesoscale model to determine an effective diffusion coefficient that accounts for the formation of porosity, its interconnection, and infiltration with bond sodium from the fuel-cladding gap. The effective diffusivity has been used in engineering-scale simulations using the BISON fuel performance code, and BISON simulations have been compared to representative validation cases from the EBR-II reactor.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Inhibition of Alkali Metal Reduction of 1-Adamantanol by London Dispersion Effects

Here, a series of alkali metal 1-adamantoxide (OAd 1 ) complexes of formula [M(OAd 1 )(HOAd 1 ) 2 ], where M=Li, Na or K, were synthesised by reduction of 1-adamantanol with excess of the alkali metal. The syntheses indicated that only one out of every three HOAd 1 molecules was reduced. An X-ray diffraction study of the sodium derivative shows that the complex features two unreduced HOAd 1 donors as well as the reduced alkoxide (OAd 1 ), with the Ad 1 fragments clustered together on the same side of the NaO 3 plane, contrary to steric considerations. This is the first example of an alkali metal reduction of an alcohol that is inhibited from completion due to the formation of the [M(OAd 1 )(HOAd 1 ) 2 ] complexes, stabilized by London dispersion effects. NMR spectroscopic studies revealed similar structures for the lithium and potassium derivatives. Computational analyses indicate that decisive London dispersion effects in the molecular structure are a consequence of the many C–H•••H–C interactions between the OAd 1 groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Improving solar panel durability through novel panel designs and advanced manufacturing equipment

Work in the project was spread across 4 main themes:1) Improved Understanding of Why Cracks Form and Cause Degradation in Solar Cells: We developed a finite element model which correlated well with experimental determined deflection vs load profiles and which predicted stress profiles vs load level and temperature. These profiles helped to guide brace designs and showed the high stress levels seen in the silicon near the interconnect wire locations as the temperature is cooled below -30C, likely forming "invisible" microcracks. Experiments showed how for polymer backsheet modules, a brief exposure to such low temperatures made modules extremely sensitive to propagation of these microcracks at relatively low load levels, and how thicker and softer encapsulant helped to reduce this crack sensitivity. We showed for some modules that most cracks that are seen under loading had their origin at short, hard to see, V-cracks from soldering damage, and how the shunting from cells with high densities of cracks reduces energy delivery more than Pmax. 2) Improved Durability Testing Methods With Respect to Cracked Cells: We lobbied the PV community throughout the project that IEC 61215 was insufficient to probe the sensitivity of module Pmax degradation due to cracks in that in did not have a test leg that included a crack creation step (static loading) followed by a crack opening step (cyclic loading and/or thermal cycling). We published extensively on how pre- existing cracks opened up with cyclic loading. The new IEC TS 63209-1 ED1 test sequence now include our recommendations, and this should lead to improved module designs and reduced risk for investors. We also published recommendations for a new "Cold Climate Test" sequence to probe the sensitivity of modules to degradation from short microcracks formed when modules see temperatures below -30C followed by front side loading. We participated in several USTAG meetings related to cracked cells, EL testing, and mechanical load testing and provided input to the group to improve new standards under consideration. We also showed how the act of performing an EL test can affect the test results due to heating from the injected current. 3) New Module Designs and Related Manufacturing Methods & Equipment: We demonstrated reduced crack sensitivity on encapsulated cell coupons the benefits of building protective compressive stress into the cells by laminating them in a bent state and then allowing the coupon to flatten out after lamination. Our attempts to scale this to the module level with a more manufacturable sequence did not demonstrate the same positive effects, but we hope that others will follow up with other variations on this bent lamination or bent cooling concept to make more durable modules. 4) New Module Mounting Designs: We explored a range of bracing concepts which pressed on the backsheet to slightly bow the glass outward and place cells in a state of protective compressive stress and to reduce the deflection under front side loads. These successfully reduced cell cracking and crack opening, but high static loads permanently deformed cost-effective braces, after which they provided little benefit. We settled on an elegant & effective solution – the RailPad, where lightweight bracing elements are placed between the mounting rail(s) and the backsheet, and the existing strength of the rails is used to prevent module deflection under load. New construction and retrofit designs were made, and test sites were implemented in FL and MA. We applied for RailPad patent protection.

14 SOLAR ENERGY↗
DOE OSTI2024

Low Energy Neutron-induced Charged-particle (Z) (LENZ) instrument development with a focus on pulse shape discrimination for low-energy charged particles

To study neutron-induced charged-particle reactions with high precision, the Low Energy Neutron-induced Charged-particle (Z) instrument (LENZ) was developed at the Los Alamos Neutron Science Center. For the interest of measuring (n,p) and (n, α) reactions simultaneously, Pulse Shape Discrimination methods were investigated to identify different charged particles in the energy range of 3 - 20 MeV and improve signal-to-background ratios using Double-sided Silicon Strip Detectors and waveform digitizers. The risetime and pulse shape properties of detected charged particles were characterized for various silicon detector’s thickness with different orientations. During the post-processing of waveforms, we implemented different digital filters for effective particle identifications and improved energy- and timing- resolutions. We validated the optimized digital filters and pulse shape analyses, via measurements with 228 Th and 229 Th calibration sources, proton-induced reactions on a 7 LiF target, and neutron-induced reactions on CH 2 , Ta 2 O 5 , 58 Ni, and 6 LiF/ 59 Ni targets at the time-of-flight facility, LANSCE. In conclusion, the summary of effective thresholds and Figure of Merits on separating different charged particles is reported.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Advancing the understanding of energy-energy correlators in heavy-ion collisions

We investigate the collinear limit of the energy-energy correlator (EEC) in a heavy-ion context. First, we revisit the leading-logarithmic (LL) resummation of this observable in vacuum following a diagrammatic approach. We argue that this route allows to naturally incorporate medium-induced effects into the all-orders structure systematically. As an example, we show how the phase-space constraints imposed by the static medium on vacuum-like emissions can be incorporated into the LL result by modifying the anomalous dimensions. On the fixed-order side, we calculate the $\mathcal{O}$(α s ) expansion of the in-medium EEC for a γ → $q\overline{q}$ splitting with arbitrary kinematics including, for the first time, subleading colour corrections. When comparing this result to previously used approximations in the literature, we find up to $\mathcal{O}$(1) deviations in the regime of interest for jet quenching signatures. Energy loss effects are also quantified and further suppress the EEC at large angles. These semi-analytic studies are complemented with a phenomenological study using the jet quenching Monte Carlo JetMed. Finally, we argue that the imprint of medium-induced effects in energy-energy correlators can be enhanced by using an alternative definition that takes as input Lund primary declusterings instead of particles.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS2002

Effect of Pin Tool Shape on Metal Flow During Friction Stir Welding

It has been shown that metal moves behind the rotating Friction Stir Pin Tool in two separate currents or streams. One current, mostly on the advancing side, enters a zone of material that rotates with the pin tool for one or more revolutions and eventually is abandoned behind the pin tool in crescent-shaped pieces. The other current, largely on the retreating side of the pin tool is moved by a wiping process to the back of the pin tool and fills in between the pieces of the rotational zone that have been shed by the rotational zone. This process was studied by using a faying surface copper trace to clarify the metal flow. Welds were made with pin tools having various thread pitches. Decreasing the thread pitch causes the large scale top-to-bottorn flow to break up into multiple vortices along the pin and an unthreaded pin tool provides insufficient vertical motion for there to be a stable rotational zone and flow of material via the rotational zone is not possible leading to porosity on the advancing side of the weld.

McClure, J. C.↗
DOE OSTI2022

Assessing the Interactive Impacts of Energy Efficiency and Demand Response on Power System Costs and Emissions

Utilities are increasingly interested in integrating energy efficiency (EE) and demand response (DR) measures and technologies (as well as other distributed energy resources) as a strategic approach to improve their cost-effectiveness and performance. However, the specific EE and DR features that may be best integrated, the interplay between changing EE and DR resource potential, and resulting utility system impacts are not well understood. We quantify the impacts of EE and DR in isolation and in combination on bulk power system costs and emissions based on changes in generation expansion, transmission expansion, and dispatch patterns. The study methodology mimics utility resource planning and uses more novel techniques to select least-cost generation and transmission capacity from supply-and demand-side resources, as compared to more commonly used utility approaches that only consider supply-side resources. The results identify key EE and DR characteristics affecting each other’s power system value and the most valuable technologies and strategies that can be jointly deployed. We discuss implications for EE and DR cost-effectiveness frameworks, program design, and integrated resource planning.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Strings, extended objects, and the classical double copy

We extend Shen’s recent formulation (arXiv:1806.07388) of the classical double copy, based on explicit color-kinematic duality, to the case of finite-size sources with non-zero spin. For the case of spinning Yang-Mills sources, the most general consistent double copy consists of gravitating objects which carry pairs of spin degrees of freedom. We find that the couplings of such objects to background fields match those of a classical (i.e. heavy) closed bosonic string, suggesting a string theory interpretation of sources related by color-kinematics duality. As a special case, we identify a limit, corresponding to unoriented strings, in which the 2-form Kalb-Ramond axion field decouples from the gravitational side of the double copy. Finally, we apply the classical double copy to extended objects, described by the addition of finite-size operators to the worldline effective theory. We find that consistency of the color-to-kinematics map requires that the Wilson coefficients of tidal operators obey certain relations, indicating that the extended gravitating objects generated by the double copy of Yang-Mills are not completely generic.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Hierarchical Materials from High Information Content Macromolecular Building Blocks: Construction, Dynamic Interventions, and Prediction

Hierarchical materials that exhibit order over multiple length scales are ubiquitous in nature. Because hierarchy gives rise to unique properties and functions, many have sought inspiration from nature when designing and fabricating hierarchical matter. More and more, however, nature’s own high-information content building blocks, proteins, peptides, and peptidomimetics, are being coopted to build hierarchy because the information that determines structure, function, and interfacial interactions can be readily encoded in these versatile macromolecules. Here, we take stock of recent progress in the rational design and characterization of hierarchical materials produced from high-information content blocks with a focus on stimuli-responsive and “smart” architectures. We also review advances in the use of computational simulations and data-driven predictions to shed light on how the side chain chemistry and conformational flexibility of macromolecular blocks drive the emergence of order and the acquisition of hierarchy and also on how ionic, solvent, and surface effects influence the outcomes of assembly. Furthermore, continued progress in the above areas will ultimately usher in an era where an understanding of designed interactions, surface effects, and solution conditions can be harnessed to achieve predictive materials synthesis across scale and drive emergent phenomena in the self-assembly and reconfiguration of high-information content building blocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗