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At least 1,621 records · Page 90

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DOE OSTI2022

Interfacial water asymmetry at ideal electrochemical interfaces

Controlling electrochemical reactivity requires a detailed understanding of the charging behavior and thermodynamics of the electrochemical interface. Experiments can independently probe the overall charge response of the electrochemical double layer by capacitance measurements and the thermodynamics of the inner layer with potential of maximum entropy measurements. Relating these properties by computational modeling of the electrochemical interface has so far been challenging due to the low accuracy of classical molecular dynamics (MD) for capacitance and the limited time and length scales of ab initio MD. Here, we combine large ensembles of long-time-scale classical MD simulations with charge response from electronic density functional theory to predict the potential-dependent capacitance of a family of ideal aqueous electrochemical interfaces with different peak capacitances. We show that while the potential of maximum capacitance varies, this entire family exhibits an electrode charge of maximum capacitance (CMC) between -2.9 and -2.2 μC/cm 2 , regardless of the details in the electronic response. Simulated heating of the same interfaces reveals that the entropy peaks at a charge of maximum entropy (CME) of -5.1 ± 0.6 μC/cm 2 , in agreement with experimental findings for metallic electrodes. The CME and CMC both indicate asymmetric response of interfacial water that is stronger for negatively charged electrodes, while the difference between CME and CMC illustrates the richness in behavior of even the ideal electrochemical interface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

Selecting Critical Scenarios of DER Adoption in Distribution Grids Using Bayesian Optimization

We develop a new methodology to select scenarios of DER adoption most critical for distribution grids. Anticipating risks of future voltage and line flow violations due to additional PV adopters is central for utility investment planning but continues to rely on deterministic or ad hoc scenario selection. We propose a highly efficient search framework based on multi-objective Bayesian Optimization. We treat underlying grid stress metrics as computationally expensive black-box functions, approximated via Gaussian Process surrogates and design an acquisition function based on probability of scenarios being Pareto-critical across a collection of line- and bus-based violation objectives. Our approach provides a statistical guarantee and offers an order of magnitude speed-up relative to a conservative exhaustive search. Case studies on realistic feeders with 200-400 buses demonstrate the effectiveness and accuracy of our approach.

Mulkin, Olivier↗

DOE OSTI2021

Resolving Anodic Current and Temperature Distributions in a Polymer Electrolyte Membrane Water Electrolysis Cell Using a Pseudo-Two-Phase Computational Fluid Dynamics Model

Expanding upon our prior experimental work, we constructed a three-dimensional model of a polymer electrolyte membrane water electrolyzer using computational fluid dynamics. We applied the assumption of pseudo-two-phase flow, the flow of two phases with equal velocity. Experimental data were used to obtain parameters and to determine the conditions under which this model was valid. Anodic distributions of current density, temperature, liquid saturation, and relative humidity were obtained at various flow rates. The overall current density and temperature difference from inlet to outlet at the anode agreed strongly with experimental measurements under most circumstances. This verification allowed us to further examine the apparent gas coverage calculated from experimental and model temperature data. Results suggested a low liquid saturation and low relative humidity at the anode due to the consumption of liquid water and water vapor. However, we questioned the accuracy of the pseudo-two-phase assumption at low water feed rates. We concluded that the model was applicable to systems with liquid water feed rates greater than 0.6 ml min -1 cm -2 . Therefore, it is a fair screening method that can advise which operating conditions lead to excessive temperatures or drying at the anode, thereby promoting the longevity of the membrane and catalyst.

25 ENERGY STORAGE↗

DOE OSTI2022

Learning Optimal Aerodynamic Designs

This project created a framework for efficient, accurate, and scalable deep neural network representations of design optimization problem solutions. The inputs to these DNN representations are the vector of design requirement parameters, the outputs are the optimal design variables, and the goal is to learn the map from inputs to outputs (i.e., inverse design). The team addressed the problem of the optimal shape design of aerodynamic lifting surfaces—in particular aircraft wings—using a Reynolds-Average Navier Stokes model to govern the CFD-based aerodynamic shape optimization. The inverse design map for such problems is very complex and high-dimensional, involving inputs and outputs on the order of 1000s. To approximate this inverse design map, the team developed algorithms to construct parsimonious DNN architectures, which automatically identify low-dimensional manifolds in which design requirements affect optimal shape parameters, and trained these architectures with multifidelity optimization methods. The resulting methodology accurately and automatically designs optimal aerodynamic lifting surfaces with very high accuracy (99%) at interactive speeds, of the order of milliseconds, resulting in factors of one million or more speedup relative to CFD-based design optimization.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2025

Applying Linear Optics from Closed Orbits Modulation for finding beam-based alignment of harmonic sextupoles

A fast and accurate beam-based alignment (BBA) method for harmonic sextupoles has been devel oped at NSLS-II using Linear Optics from Closed Orbit Modulation (LOCOM). The approach excites the beam with simultaneous sine-wave signals at two fast correctors, chosen with an appropriate phase advance to span the full betatron phase space. This strategy suppresses systematic errors from hysteresis, while additional errors from orbit drift and power-supply calibration are minimized by the short measurement time (a few minutes) and reliance solely on beam-based current-to-field conver sion of the sextupoles, with hysteresis explicitly included. Simulations indicate that Linear Optics from Closed Orbits (LOCO) combined with 0.5 mm local orbit bumps can resolve relative sextupole field offsets (∆k₂) with precision better than 10% of k₂, reflecting to beam-based alignment (BBA) accuracy finer than 50 µm. Moreover, employing machine-learning-optimized local orbit bumps en hances sextupole-induced quadrupole signals in a deterministic manner and maintains orbit stability under large sextupole strength variations (±40%). The proposed method is experimentally validated through proof-of-principle measurements at NSLS-II, demonstrating its potential as a fast, precise, and robust tool for harmonic sextupole alignment.

43 PARTICLE ACCELERATORS↗

DOE OSTI2023

Exploring the Performance Boundaries of a Small Reconfigurable Multi-Mission UAV through Multidisciplinary Analysis

The performance of a small reconfigurable unmanned aerial vehicle (UAV) is evaluated, combining a multidisciplinary approach in the computational analysis of additive manufactured structures, fluid dynamics, and experiments. Reconfigurable UAVs promise cost savings and efficiency, without sacrificing performance, while demonstrating versatility to fulfill different mission profiles. The use of computational fluid dynamics (CFD) in UAV design produces higher accuracy aerodynamic data, which is particularly important for complex aircraft concepts such as blended wing bodies. To address challenges relating to anisotropic materials, the Tsai–Wu failure criterion is applied to the structural analysis, using CFD solutions as load inputs. Aerodynamic performance results show the low-speed variant attains an endurance of 1 h, 48 min, whereas its high-speed counterpart is 29 min at a 66.7% higher cruise speed. Each variant serves different aspects of small UAS deployment, with low speed envisioned for high-endurance surveying, and high speed for long-range or time-critical missions such as delivery. The experimental and simulation results suggest room for design iteration, in wing area and geometry adjustments. Structural simulations demonstrated the need for airframe improvements to the low-speed configuration. This paper highlights the potential of reconfigurable UAVs to be useful across multiple industries, advocating for further research and design improvements.

42 ENGINEERING↗

DOE OSTI2021

Quality Control Methods for Advanced Metering Infrastructure Data

While urban-scale building energy modeling is becoming increasingly common, it currently lacks standards, guidelines, or empirical validation against measured data. Empirical validation necessary to enable best practices is becoming increasingly tractable. The growing prevalence of advanced metering infrastructure has led to significant data regarding the energy consumption within individual buildings, but is something utilities and countries are still struggling to analyze and use wisely. In partnership with the Electric Power Board of Chattanooga, Tennessee, a crude OpenStudio/EnergyPlus model of over 178,000 buildings has been created and used to compare simulated energy against actual, 15-min, whole-building electrical consumption of each building. In this study, classifying building type is treated as a use case for quantifying performance associated with smart meter data. This article attempts to provide guidance for working with advanced metering infrastructure for buildings related to: quality control, pathological data classifications, statistical metrics on performance, a methodology for classifying building types, and assess accuracy. Advanced metering infrastructure was used to collect whole-building electricity consumption for 178,333 buildings, define equations for common data issues (missing values, zeros, and spiking), propose a new method for assigning building type, and empirically validate gaps between real buildings and existing prototypes using industry-standard accuracy metrics.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NASA NTRS1971

The Stanford gyroscope experiment

Gyroscopes in motion about a massive body are found to have two main effects: (1) geodetic effect, solely due to motion of the gyroscope about the earth and (2) motional effect, due to earth rotation. An experiment is proposed to measure the precession rate of one or more gyroscopes, mounted either on earth or in a satellite, with respect to the axis of a telescope pointing at a suitable fixed star. The procedures and apparatus to be used in this experiment are outlined; the error analysis is summarized. The relation of error to size, speed, and mechanical properties of rotor is presented, along with the design requirements for accuracy of 10 to the -16th power rad/s.

Everitt, C. W. F.↗

NASA NTRS1973

The Delta Launch Vehicle Model 2914 Series

The newest Delta launch vehicle configuration, Model 2914 is described for potential users together with recent flight results. A functional description of the vehicle, its performance, flight profile, flight environment, injection accuracy, spacecraft integration requirements, user organizational interfaces, launch operations, costs and reimbursable users payment plan are provided. The versatile, relatively low cost Delta has a flight demonstrated reliability record of 92 percent that has been established in 96 launches over twelve years while concurrently undergoing ten major upratings to keep pace with the ever increasing performance and reliability requirements of its users. At least 40 more launches are scheduled over the next three years from the Eastern and Western Test Ranges.

Gunn, C. R.↗

NASA NTRS1975

High-order numerical solutions using cubic splines

The cubic spline collocation procedure for the numerical solution of partial differential equations was reformulated so that the accuracy of the second-derivative approximation is improved and parallels that previously obtained for lower derivative terms. The final result is a numerical procedure having overall third-order accuracy for a nonuniform mesh and overall fourth-order accuracy for a uniform mesh. Application of the technique was made to the Burger's equation, to the flow around a linear corner, to the potential flow over a circular cylinder, and to boundary layer problems. The results confirmed the higher-order accuracy of the spline method and suggest that accurate solutions for more practical flow problems can be obtained with relatively coarse nonuniform meshes.

Rubin, S. G.↗

NASA NTRS1974

Solar Energy Monitor In Space (SEMIS)

Measurements made at high altitudes from aircraft have resulted in the establishment of standard values of the solar constant and extraterrestrial solar spectral irradiance. These standard values and other solar spectral curves are described. The problem of possible variations of the solar constant and solar spectrum and their influence on the earth-atmosphere system and weather related phenomena is examined. It is shown that the solar energy input parameters should be determined with considerably greater accuracy and precision than has been possible. An instrument package designed as a compact, low weight solar energy monitor in space (SEMIS) is described.

Thekaekara, M. P.↗

NASA NTRS1976

The development of the Poincare-similar elements with true anomaly as the independent variable

In reference 1, the Hamiltonian of the unperturbed two-body problem in extended phase space is established. Depending on the type of time transformation, eight canonical elements were developed with the true anomaly or the eccentric anomaly as the independent variable. These two new sets, DS(phi) and DS(u), however contain singularities for small eccentricities and inclinations. In reference 2, these singularities are removed by a transformation from DS(u) to eight canonical PS(u) elements. In reference 3, the DS(phi) variables are transformed to the PS(phi) elements to remove the singularities. However, no direct relation was established between the eight canonical PS(phi) elements and the Cartesian coordinates. It is the purpose of this report to establish those relations and to develop the perturbed equations of motion in the PS(phi) space. This report also demonstrates the accuracy of this new set when it is applied to numerical orbit prediction problems.

Mueller, A.↗

NASA NTRS1978

Data Management Symposium, Huntsville, Ala., October 18, 19, 1977, Proceedings

The transfer, processing, and use of satellite data are discussed. Topics relating to simulation and processing techniques include computer design assessments through simulation, data system dynamic simulation, and future timing accuracy requirements and procedures for data processing. Subjects relevant to data base management systems and users and their needs include an image-based information system architecture for correlation satellite and topological data base, efficient searching and sorting applications using an associative array processor, analysis of user's needs for a large technical data base, and variable length data formats. The technology development outlook was considered with attention to data systems technology outlook for supporting NASA programs, a user-oriented interactive information extraction system, and flow control and sorting techniques for telemetry packets.

Castelli, A.↗

NASA NTRS1978

A drag-free Lo-Lo satellite system for improved gravity field measurements

At very low altitudes, the effect of atmospheric drag results in drastically reduced orbit lifetimes and considerable uncertainty in satellite motions. The concept suggested herein employs a DISturbance COmpensation System (DISCOS) on each of a pair of satellites at very low altitudes to provide refined measurements of the earth's gravitational field. The DISCOS maintains the satellites in orbit and essentially eliminates motion uncertainties due mostly to drag and to a lesser extent from solar radiation pressure. By a closed-loop measurement of the relative rangerate between the two low satellites, one can determine the earth's gravitational field with a considerably greater accuracy than could be obtained by tracking a single satellite.

Fischell, R. E.↗

NASA NTRS1980

FBI fingerprint identification automation study. AIDS 3 evaluation report. Volume 4: Economic feasibility

The results of the economic analysis of the AIDS 3 system design are presented. AIDS 3 evaluated a set of economic feasibility measures including life cycle cost, implementation cost, annual operating expenditures and annual capital expenditures. The economic feasibility of AIDS 3 was determined by comparing the evaluated measures with the same measures, where applicable, evaluated for the current system. A set of future work load scenarios was constructed using JPL's environmental evaluation study of the fingerprint identification system. AIDS 3 and the current system were evaluated for each of the economic feasibility measures for each of the work load scenarios. They were compared for a set of performance measures, including response time and accuracy, and for a set of cost/benefit ratios, including cost per transaction and cost per technical search. Benefit measures related to the economic feasibility of the system are also presented, including the required number of employees and the required employee skill mix.

Mulhall, B. D. L.↗

NASA NTRS1981

Stochastic models of cover class dynamics

Investigations related to satellite remote sensing of vegetation have been concerned with questions of signature identification and extension, cover inventory accuracy, and change detection and monitoring. Attention is given to models of ecological succession, present directions in successional modeling and analysis, nondynamic spatial models, issues in the analysis of spatial data, and aspects of spatial modeling. Issues in time-series analysis are considered along with dynamic spatial models, and problems of model specification and identification.

Barringer, T. H.↗

NASA NTRS1982

Mathematical enhancement of data from scientific measuring instruments

The accuracy of any physical measurement is limited by the instruments performing it. The proposed activities of this grant are related to the study of and application of mathematical techniques of deconvolution. Two techniques are being investigated: an iterative method and a function continuation Fourier method. This final status report describes the work performed during the period July 1 to December 31, 1982.

Ioup, J. W.↗

NASA NTRS1984

Evaluation of the HARDMAN comparability methodology for manpower, personnel and training

The methodology evaluation and recommendation are part of an effort to improve Hardware versus Manpower (HARDMAN) methodology for projecting manpower, personnel, and training (MPT) to support new acquisition. Several different validity tests are employed to evaluate the methodology. The methodology conforms fairly well with both the MPT user needs and other accepted manpower modeling techniques. Audits of three completed HARDMAN applications reveal only a small number of potential problem areas compared to the total number of issues investigated. The reliability study results conform well with the problem areas uncovered through the audits. The results of the accuracy studies suggest that the manpower life-cycle cost component is only marginally sensitive to changes in other related cost variables. Even with some minor problems, the methodology seem sound and has good near term utility to the Army. Recommendations are provided to firm up the problem areas revealed through the evaluation.

Zimmerman, W.↗