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At least 1,621 records · Page 90

A Machine Learning Bias Correction on Large–Scale Environment of High–Impact Weather Systems in E3SM Atmosphere Model

Large–scale dynamical and thermodynamical processes are common environmental drivers of high–impact weather systems causing extreme weather events. However, such large–scale environmental conditions often display systematic biases in climate simulations, posing challenges to evaluating high–impact weather systems and extreme weather events. In this paper, a machine learning (ML) approach was employed to bias correct the large–scale wind, temperature, and humidity simulated by the atmospheric component of the Energy Exascale Earth System Model (E3SM) at ~1° resolution. The usefulness of the ML approach for extreme weather analysis was demonstrated with a focus on three high–impact weather systems, including tropical cyclones (TCs), extratropical cyclones (ETCs), and atmospheric rivers (ARs). We show that the ML model can effectively reduce climate bias in large–scale wind, temperature, and humidity while preserving their responses to imposed climate change perturbations. The bias correction is found to directly improve water vapor transport associated with ARs, and representations of thermodynamical flows associated with ETCs. When the bias–corrected large–scale winds are used to drive a synthetic TC track forecast model over the Atlantic basin, the resulting TC track density agrees better with that of the TC track model driven by observed winds. In addition, the ML model insignificantly interferes with the mean climate change signals of large–scale storm environments as well as the occurrence and intensity of three weather systems. This study suggests that the proposed ML approach can be used to improve the downscaling of extreme weather events by providing more realistic large–scale storm environments simulated by low–resolution climate models.

54 ENVIRONMENTAL SCIENCES↗

Imaging mechanism for hyperspectral scanning probe microscopy via Gaussian process modelling

We investigate the ability to reconstruct and derive spatial structure from sparsely sampled 3D piezoresponse force microcopy data, captured using the band-excitation (BE) technique, via Gaussian Process (GP) methods. Even for weakly informative priors, GP methods allow unambiguous determination of the characteristic length scales of the imaging process both in spatial and frequency domains. We further show that BE data set tends to be oversampled in the spatial domains, with ~30% of original data set sufficient for high-quality reconstruction, potentially enabling faster BE imaging. At the same time, reliable reconstruction along the frequency domain requires the resonance peak to be within the measured band. This behavior suggests the optimal strategy for the BE imaging on unknown samples. Finally, we discuss how GP can be used for automated experimentation in SPM, by combining GP regression with non-rectangular scans.

47 OTHER INSTRUMENTATION↗

Plant-based CO 2 drawdown and storage as SiC

Since the 1950's the Earth's natural carbon cycle has not sufficiently sequestrated excess atmospheric CO 2 contributed by human activities. CO 2 levels rose above 400 ppm in 2013 and are forecasted to exceed 500 ppm by 2070, a level last experienced during the Paleogene period 25–65 MYA. While humanity benefits from the extraction and combustion of carbon from Earth's crust, we have overlooked the impact on global climate change. Here, we present a strategy to mine atmospheric carbon to mitigate CO 2 emissions and create economically lucrative green products. We employ an artificial carbon cycle where agricultural plants capture CO 2 and the carbon is transformed into silicon carbide (SiC), a valuable commercial material. By carefully quantifying the process we show that 14% of plant-sequestered carbon is stored as SiC and estimate the scale needed for this process to have a global impact.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Theory review: Line-driven instability and other causes of structure and variability in hot-star winds

The winds of the hot, luminous, OB stars are driven by the line-scattering of the star's continuum radiation flux. Several kinds of observational evidence indicate that such winds are highly structured and variable. This paper will review possible theoretical causes of such wind structure. For relatively small-scale, stochastic variability, I review the role of the strong intrinsic instability of the line-driving process itself. for larger scale structure, I describe recent efforts to examine how disturbances from the underlying, rotating star can be translated outward into propagating features in the wind.

Owocki, Stanley P.↗

SpiderFab: Process for On-Orbit Construction of Kilometer-Scale Apertures

The SpiderFab effort has investigated the value proposition and feasibility of radically changing the way we build and deploy spacecraft by enabling space systems to fabricate and integrate key components on-orbit. In this Phase II effort, we have focused on developing and demonstrating tools and processes to enable robotic systems to manufacture and assemble high performance structural elements that will serve as the support structures for components such as antennas and solar arrays. Through testing of these technologies in the laboratory environment,these efforts have established the technical feasibility of the key capabilities required for in-space manufacture of large apertures such as antennas, solar arrays, and optical systems,maturing prototype technical solutions for these capabilities to TRL-4. The SpiderFab effort has resulted in successful post-NIAC transition of the technology, first to SBIR-funded development of a technology for in-space manufacture (ISM) of truss structures, and then to a NASA/STMD Tipping Point Technologies funded effort to prepare a flight demonstration of ISM of a structure for a GEO communications satellite.

Manufacturing↗

Microwave Remote Sensing and the Cold Land Processes Field Experiment

The Cold Land Processes Field Experiment (CLPX) has been designed to advance our understanding of the terrestrial cryosphere. Developing a more complete understanding of fluxes, storage, and transformations of water and energy in cold land areas is a critical focus of the NASA Earth Science Enterprise Research Strategy, the NASA Global Water and Energy Cycle (GWEC) Initiative, the Global Energy and Water Cycle Experiment (GEWEX), and the GEWEX Americas Prediction Project (GAPP). The movement of water and energy through cold regions in turn plays a large role in ecological activity and biogeochemical cycles. Quantitative understanding of cold land processes over large areas will require synergistic advancements in 1) understanding how cold land processes, most comprehensively understood at local or hillslope scales, extend to larger scales, 2) improved representation of cold land processes in coupled and uncoupled land-surface models, and 3) a breakthrough in large-scale observation of hydrologic properties, including snow characteristics, soil moisture, the extent of frozen soils, and the transition between frozen and thawed soil conditions. The CLPX Plan has been developed through the efforts of over 60 interested scientists that have participated in the NASA Cold Land Processes Working Group (CLPWG). This group is charged with the task of assessing, planning and implementing the required background science, technology, and application infrastructure to support successful land surface hydrology remote sensing space missions. A major product of the experiment will be a comprehensive, legacy data set that will energize many aspects of cold land processes research. The CLPX will focus on developing the quantitative understanding, models, and measurements necessary to extend our local-scale understanding of water fluxes, storage, and transformations to regional and global scales. The experiment will particularly emphasize developing a strong synergism between process-oriented understanding, land surface models and microwave remote sensing. The experimental design is a multi-sensor, multi-scale (1-ha to 160,000 km ^ {2}) approach to providing the comprehensive data set necessary to address several experiment objectives. A description focusing on the microwave remote sensing components (ground, airborne, and spaceborne) of the experiment will be presented.

Kim, Edward J.↗

Solvent-driven aqueous separations for hypersaline brine concentration and resource recovery

Solvent-driven separation processes can extract water and high-value minerals from high salinity or contaminated brines, simultaneously reducing the environmental impact of brine disposal and enabling resource recovery. The efficient dewatering of hypersaline brines is essential for the sustainable minimal and zero liquid discharge processing of industrial wastewaters. Fractional crystallization can selectively extract ions from contaminated waste streams, allowing critical materials to be recycled, including transition and lanthanide metals required for renewable energy generation and storage. Mass transfer in solvent-driven water extraction occurs across a liquid–liquid interface, eliminating the scaling and fouling of membrane and heat exchanger surfaces and limiting the need for extensive pretreatment. Solvent-driven fractional crystallization can leverage sequential treatment and control of process conditions to rapidly recover salts without requiring evaporation of water. Despite promising applications, the principles and potential of solvent-driven aqueous separations remain poorly understood. This critical review explores the opportunities presented by solvent-based aqueous separations from the molecular to process scale, evaluating the chemistry of solvation and system design in the broader context of desalination, resource recovery, water softening, and mineral production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cost-Driven Design of a Large Scale X-Plane

A conceptual design process focused on the development of a low-cost, large scale X-plane was developed as part of an internal research and development effort. One of the concepts considered for this process was the double-bubble configuration recently developed as an advanced single-aisle class commercial transport similar in size to a Boeing 737-800 or Airbus A320. The study objective was to reduce the contractor cost from contract award to first test flight to less than $100 million, and having the first flight within three years of contract award. Methods and strategies for reduced cost are discussed.

Welstead, Jason R.↗

$\mathrm{RADICAL}$-Pilot and $\mathrm{PMIx}$/$\mathrm{PRRTE}$: Executing Heterogeneous Workloads at Large Scale on Partitioned $\mathrm{HPC}$ Resources

Execution of heterogeneous workflows on high-performance computing (HPC) platforms present unprecedented resource management and execution coordination challenges for runtime systems. Task heterogeneity increases the complexity of resource and execution management, limiting the scalability and efficiency of workflow execution. Re-source partitioning and distribution of tasks execution over portioned re-sources promises to address those problems but we lack an experimental evaluation of its performance at scale. Here this paper provides a performance evaluation of the Process Management Interface for Exascale (PMIx) and its reference implementation PRRTE on the leadership-class HPC plat-form Summit, when integrated into a pilot-based runtime system called RADICAL-Pilot. We partition resources across multiple PRRTE Distributed Virtual Machine (DVM) environments, responsible for launching tasks via the PMIx interface. We experimentally measure the work-load execution performance in terms of task scheduling/launching rate and distribution of DVM task placement times, DVM startup and termination overheads on the Summit leadership-class HPC platform. Integrated solution with PMIx/PRRTE enables using an abstracted, standardized set of interfaces for orchestrating the launch process, dynamic process management and monitoring capabilities. It extends scaling capabilities allowing to overcome a limitation of other launching mechanisms (e.g., JSM/LSF). Explored different DVM setup configurations provide insights on DVM performance and a layout to leverage it. Our experimental results show that heterogeneous workload of 65,500 tasks on 2048 nodes, and partitioned across 32 DVMs, runs steady with resource utilization not lower than 52%. While having less concurrently executed tasks resource utilization is able to reach up to 85%, based on results of heterogeneous workload of 8200 tasks on 256 nodes and 2 DVMs.

97 MATHEMATICS AND COMPUTING↗

Fracture toughness of an Al-Li-Cu-In alloy

The crack initiation and growth fracture toughness of select AL-Li-Cu alloy variants are characterized and elucidated. Conventionally processed plates form large DC cast ingots are investigated to eliminate the variation in microstructure associated with laboratory scale and SPF-processed material. Fracture resistance is characterized using the J-integral method to establish crack initiation and growth behavior at 25 and -185 C. It is shown that state-of-the-art 2090-T81 has superior toughness compared to 2090 + In-T6 at both test temperatures, with the low toughness of 2090 + In-T6 associated with intersubgranular fracture attributed to a high density of subboundary precipitates.

Wagner, John A.↗

A Robust Multi-Scale Modeling System for the Study of Cloud and Precipitation Processes

During the past decade, numerical weather and global non-hydrostatic models have started using more complex microphysical schemes originally developed for high resolution cloud resolving models (CRMs) with 1-2 km or less horizontal resolutions. These microphysical schemes affect the dynamic through the release of latent heat (buoyancy loading and pressure gradient) the radiation through the cloud coverage (vertical distribution of cloud species), and surface processes through rainfall (both amount and intensity). Recently, several major improvements of ice microphysical processes (or schemes) have been developed for cloud-resolving model (Goddard Cumulus Ensemble, GCE, model) and regional scale (Weather Research and Forecast, WRF) model. These improvements include an improved 3-ICE (cloud ice, snow and graupel) scheme (Lang et al. 2010); a 4-ICE (cloud ice, snow, graupel and hail) scheme and a spectral bin microphysics scheme and two different two-moment microphysics schemes. The performance of these schemes has been evaluated by using observational data from TRMM and other major field campaigns. In this talk, we will present the high-resolution (1 km) GeE and WRF model simulations and compared the simulated model results with observation from recent field campaigns [i.e., midlatitude continental spring season (MC3E; 2010), high latitude cold-season (C3VP, 2007; GCPEx, 2012), and tropical oceanic (TWP-ICE, 2006)].

Tao, Wei-Kuo↗

DOE Bioenergy Technologies Office (BETO) 2023 Project Peer Review: WBS 2.4.1.100 Bench Scale Research & Development

Bench Scale Integration develops and optimizes fermentation processes to produce bio-based fuels and chemicals for commercial scale-up. The project uses fermentation science to achieve high titers and production rates by, for example, manipulating how the microorganisms are fed biomass sugars and nutrients, modifying fermentation conditions (pH, temperature, aeration) or developing online control strategies for better fermentation operations and high titer, rates, and yield (TRY). For this period of performance, we continued our development of a commercial-ready 2,3-butanediol (BDO) fermentation from biomass sugars utilizing NREL's proprietary Zymomonas mobilis microorganism. The engineered Z. mobilis can use all the main sugars in corn stover biomass, which are glucose, xylose, and arabinose. BDO is a versatile, low-carbon chemical which can be catalytically upgraded to a variety of hydrocarbon fuels and chemicals. The project had three goals during this review period; evaluate the technical feasibility of using whole slurry pretreated corn stover to achieve the techno-economic analysis (TEA) performance goals, continue optimizing a liquor-based fed-batch fermentation process for high titer, and develop strategies to enable scale-up. After evaluating different iterations of a whole slurry fermentation that did not meet the TEA goals, a Go/No-Go decision was made to pivot to liquor-only with new TEA performance targets, the main one being 140 g/L titer. We successfully met this goal, producing 141 g/L BDO at 1 g/L-hr productivity and 84% process yield. This titer and productivity attracted industrial interest to scale the fermentation resulting in a Technology Commercialization Fund project award in 2022. We used an NREL developed near-infra red (NIR) spectroscopy method for rapid analysis which allowed for changes to aeration levels and sugar feeding during the fermentation to maximize BDO production. The NIR analysis can be done using a hand-held spectrometer, essentially taking the analysis on to the plant floor during scale-up and preliminary work shows the feasibility of using an online probe for continuous monitoring and control. The other scale-up tool is mapping oxygen transfer coefficient (kLa) and oxygen transfer rate (OTR) in various vessels to find conditions that match the optimized 500 mL vessels. Showing a correlation to the mapping work, which is done with water and a dissolved oxygen probe, can reduce the risk of failed fermentations during scale-up. Our end-of-project goal is to meet the design target BDO titer (140-150 g/L) from DMR corn stover liquor at 1000L or larger scale to demonstrate BDO process design case and transfer the technology to industrial fermentation stakeholders for commercialization.

2 3-butanediol↗

Toward more mechanistic representations of biogeochemical processes in river networks: Implementation and demonstration of a multiscale model

A recently introduced multiscale model for representing the effects of small-scale hyporheic-zone biogeochemical processes is extended from the reach scale to river network scales. The model uses advection-dispersion-reaction equations for the channel network and one-dimensional advection-reaction subgrid models for the hyporheic zone. We summarize implementation in the integrated surface/subsurface hydrology modeling system Amanzi-ATS. The extension uses topologically defined meshes to represent stream/river networks and associates a hyporheic subgrid model with each channel grid cell. Biogeochemical reaction modeling capability residing in community software is accessed through an application programming interface. The implementation is verified against independent numerical solutions on a single reach. Mesh convergence studies show that commonly used semi-distributed representations can introduce significant spatial discretization error. Denitrification of farm runoff in a subbasin of the Portage River Basin in Ohio, USA is used to demonstrate the general-purpose reactive transport capability.

54 ENVIRONMENTAL SCIENCES↗

Imaging the End-to-End Dynamics of the Global Solar Wind-Magnetosphere Interaction

Much of what we know about the solar wind’s interaction with the Earth’s magnetosphere has been gained from isolated in situ measurements by single or multiple spacecraft. Based on their observations, we know that reconnection, whether on the dayside magnetopause or deep within the Earth’s magnetotail, controls the flow of solar wind energy into and through the global system. We know that nightside activity provides the energized particles that power geomagnetic storms. But by their very nature these isolated in situ measurements cannot provide an instantaneous global view of the entire system or its cross-scale dynamics. As a result, we don’t know which mode of reconnection prevails on the dayside magnetopause or within the magnetotail as a function of solar wind and geomagnetic conditions. We don’t know which mode or modes of nightside activity supply the most energized particles to the ring current. Nor do we know the dominant loss mode for ring current decay: precipitation, magnetopause outflow, or charge exchange with neutrals. Nor do we know how processes deep within the magnetosphere provide feedback to those happening in the outer magnetosphere. The answers to these questions could have an impact far beyond magnetospheric physics, since magnetic reconnection, particle acceleration, and charge-exchange are fundamental plasma processes that operate at other planets and throughout the universe. Comprehensive end-to-end global imaging of the key micro, meso-, and macro-scale plasma structures that comprise the magnetosphere will provide the answers to these questions via observations with a spatial resolution that exceeds anything possible with in situ measurements. Each proposed interaction mechanism generates a diagnostic plasma structure or boundary signature. Global, end-to-end, imaging provides the pathway to understanding the system as a whole, its constituent parts, and its cross-scale processes on a continuous basis, as needed to quantify the flow of solar wind energy through the global magnetospheric system. The significance of each mechanism is the product of its amplitude and occurrence rate. This white paper describes how a comprehensively-instrumented single spacecraft in a high-latitude circular polar orbit can provide the essential observations needed to track and quantify the flow of solar wind energy through the magnetosphere, including the solar wind plasma and magnetic field input, the magnetopause location in soft X-rays, the auroral oval in far ultraviolet, the ring current in energetic neutrals, the plasmasphere in extreme ultraviolet, the exosphere in Lyman-, the microstructure of the nightside auroral oval in ground-based all sky cameras, and the magnetic perturbations of ionospheric current patterns seen by ground-based magnetometers.

D G Sibeck↗

Nonlinear quantum interferometric spectroscopy with entangled photon pairs

Here, we develop closed expressions for a time-resolved photon counting signal induced by an entangled photon pair in an interferometric spectroscopy setup. Superoperator expressions in Liouville-space are derived that can account for relaxation and dephasing induced by coupling to a bath. Interferometric setups mix matter and light variables non-trivially, which complicates their interpretation. We provide an intuitive modular framework for this setup that simplifies its description. Based on the separation between the detection stage and the light–matter interaction processes, we show that the pair entanglement time and the interferometric time-variables control the observed physics time scale. Only a few processes contribute in the limiting case of small entanglement time with respect to the sample response, and specific contributions can be singled out.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advancing Pressure Gain Combustion for Terrestrial Turbine Systems

The principal objectives of this project were to demonstrate the operability of a natural gas - air RDE at gas turbine engine cycle conditions. To achieve these goals, our specific tasks were to 1) characterize the dynamic injection and mixing performance of candidate injectors, 2) assess the engine operability via interrogation of spatio-temporal dynamics of combustor inlet and exit flows, 3) measure the engine emissions, and 4) complete an overall assessment of the pressure gain potential of the device. In order to advance RDE technology to the greatest extent possible, the reactants and experimental conditions were chosen to replicate combustor and injector conditions in a terrestrial power generation system. This path was taken because the scaling of combustion devices is, in general, an immature area given the challenges of interrelated mixing and chemical kinetics processes both of which scale with operating conditions.

03 NATURAL GAS↗

Plains tectonism on Venus: Inferences from canali longitudinal profiles

Canali-type channels on Venus show inverted profile segments; that is, large portions of the channels trend uphill. The original gradients for these channels were not horizontal, but must have progressively trended downhill. Therefore, undulation patterns imposed on the profiles have to be the result of tectonism occurring since channel formation. This implies that some of the uppermost geological units of the plains, which are coincident with canali, experienced significant postemplacement tectonic deformation. The pattern of deformation is hierarchical. Within observational limits, at least two scales of deformation are indicated. The longer scale deformation (thousands of kilometers) corresponds to large-scale basins; the shorter scale deformation (hundreds of kilometers) corresponds to ridge belts or to small-scale domes/basins. The latter features, at scales up to a few hundred kilometers, extensively deform some plain areas. Although not appearing in the topographic profiles because of resolution limitations, deformation scales of tens of kilometers or less, which mostly reflect wrinkle ridges, also overlap the longer deformation scales. The channels probably formed relatively quickly in comparison to the time scale of deformation. Canali formation is closely related to the genesis of plains, and canali profile deformation reflects tectonic processes operating at multiple scales. The lower limit rates of large-scale tectonic warping are comparable to epeirogenetic deformation rates for Earth's intraplate continental interiors.

Komatsu, Goro↗

Dynamic structural views in solar energy materials by femtosecond electron diffraction

Solar materials convert light into other forms of energy through excited state processes occurring on ultrafast time and atomic length scales. Understanding and controlling such nonequilibrium processes is essential for applications ranging from photovoltaics to photocatalysis. These processes are commonly studied by transient optical techniques, which resolve charge carrier dynamics. However, optical spectroscopy does not directly probe the atomic-scale motions that play a central role in the ultimate functionality of these materials. Filling this missing gap, ultrafast electron and x-ray scattering techniques enable monitoring of structural dynamics in materials with femtosecond time resolution. In this work, we focus on the use of ultrafast electron diffraction (UED) techniques to probe photoinduced energy conversion dynamics in solar energy materials. First, we discuss the use of UED as an ultrafast lattice thermometer allowing a direct probe of nonradiative relaxations such as hot carrier cooling and Auger recombination. Second, we present a time-resolved atomic pair distribution function analysis enabled by UED, which uncovers lattice deformations arising from excitation localization in materials. Finally, we provide an outlook looking toward new approaches for resolving in situ energy conversion dynamics and uncovering structure–property relationships in solar energy materials.

36 MATERIALS SCIENCE↗