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At least 1,621 records · Page 90

Assessment of Ku- and Ka-band Dual-Frequency Radar for Snow Retrieval

Dual-frequency Ku/Ka-band radar retrievals of snow parameters such as liquid-equivalent snowfall rate (R) and mass-weighted diameter (Dm) have two principal errors, namely, the differences between the assumed particle size distribution (PSD) model from the actual PSD and inadequacies in characterizing the single-scattering properties of snowflakes. Regarding the first issue, this study, based on radar simulations from a large amount of observed PSD data, shows that there exist relatively high correlations between the estimated snow parameters and their true values derived directly from the measured PSD. For PSD data with R greater than 0.1 mm h−1, a gamma PSD model with a fixed shape factor (μ) equal to 0 (or exponential distribution) provides the best estimates of R and Dm. This is despite negative biases of up to −15 % in R and underestimates and overestimates in Dm for small and large Dm, respectively. The μ = 0 assumption, however, produces relatively poor estimates of normalized intercepts of a gamma PSD (Nw), whereas the best estimates are obtained when μ is considered either 3 or 6. However, the use of an inappropriate scattering table increases the errors in snow retrieval. Simple evaluations are made for cases where the scattering databases used for the algorithm input differ from that used for retrieval. The mismatched scattering databases alone could cause at least 30 %-50 % changes in the estimates of snow water content (SWC) and R and could affect the retrievals of Dm and Nw and their dependence on μ.

Liang Liao↗

Modeling betatron radiation using particle-in-cell codes for plasma wakefield accelerator diagnostics

The analysis of plasma wakefield acceleration experimental measurements, particularly in the characterization of photons emitted through the betatron radiation mechanism, requires the development of accurate numerical models. These computational models are crucial for supporting modern instrumentation designed to measure the single-shot, double-differential angular-energy radiation spectra resulting from interactions between beams and plasmas. Motivated by the needs of such applications, this paper presents detailed numerical models of betatron radiation generated in beam-plasma acceleration experiments. These models are based on the integration of the Liénard-Wiechert (LW) potentials, applied to computed particle trajectories. The particle trajectories are generated using three distinct methods: first, by tracking particles through idealized fields in the blowout regime of PWFA; second, by obtaining trajectories using the fast quasistatic particle-in-cell (PIC) code quickpic; and third, obtaining trajectories from the fully self-consistent PIC code osiris. To ensure the accuracy and reliability of these models, the paper includes various benchmark tests using analytical expressions, as well as employing the PIC code epoch, which takes an alternative approach by using a Monte Carlo quantum electrodynamics (QED)-based radiation model. Additionally, the paper presents simulations of the expected experimental betatron radiation spectra, taking into account parameters relevant to PWFA and plasma photocathode experiments at the SLAC FACET-II facility.

Yadav, M. [University of California, Los Angeles, ↗

Revealing particle-scale powder spreading dynamics in powder-bed-based additive manufacturing process by high-speed x-ray imaging

Powder spreading is a key step in the powder-bed-based additive manufacturing process, which determines the quality of the powder bed and, consequently, affects the quality of the manufactured part. However, powder spreading behavior under additive manufacturing condition is still not clear, largely because of the lack of particle-scale experimental study. Here, we studied particle-scale powder dynamics during the powder spreading process by using in-situ high-speed high-energy x-ray imaging. Evolution of the repose angle, slope surface speed, slope surface roughness, and the dynamics of powder clusters at the powder front were revealed and quantified. Interactions of the individual metal powders, with boundaries (substrate and container wall), were characterized, and coefficients of friction between the powders and boundaries were calculated. The effects of particle size on powder flow dynamics were revealed. Here, the particle scale powder spreading dynamics, reported here, are important for a thorough understanding of powder spreading behavior in the powder-bed-based additive manufacturing process, and are critical to the development and validation of models that can more accurately predict powder spreading behavior.

42 ENGINEERING↗

Hydrothermal Preparation, Crystal Chemistry, and Redox Properties of Iron Muscovite Clay

The development of functional materials based on Earthabundant, environmentally benign compositions is critical for ensuring their commercial viability and sustainable production. In this paper we present an investigation into the crystal chemistry and electrochemical properties of the muscovite clay KFe 2.75 Si 3.25 O 10 (OH) 2 . We first report a low-temperature hydrothermal reaction that allows for a significant degree of control over sample crystallinity, particle morphology, and cation distribution through the lattice. A complex sequence of stacking faults is identified and characterized using a combination of Mössbauer spectroscopy and total scattering neutron experiments. We then show the existence of a reversible electrochemical process using galvanostatic cycling with complementary cyclic voltammetry suggesting that the redox activity occurs primarily on the surface of the particles. We conclude by determining that the ability to (de)intercalate Li ions from the material is hindered by the strong negative charge on the transition metal silicate layers, which prevents the displacement of the interlayer K ions. This work calls attention to a hugely Earth-abundant family of minerals that possesses useful electrochemical properties that warrant further exploration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hyper-Spectral Infrared Remote Sensing for Wildfire-Related Research and Air Quality Monitoring

The National Airborne Sounder Testbed-Interferometer (NAST-I) is an airborne FTS remote sensor that nominally flies on NASA high-altitude aircraft to serve as a spaceborne instrument simulator. NAST-I continues to serve as a pathfinder for future satellite FTS systems and the next generation advanced atmospheric sounders in general. NAST-I provides high resolution spectrally resolved infrared radiances. NAST-I retrieval products characterizing the surface (i.e., skin temperature and spectral emissivity), atmosphere (i.e., profiles of temperature, moisture, ozone, carbon monoxide, and other trace species), and clouds (e.g., optical depth, particle size, temperature, and height) can be used to support fire-related monitoring and research. NAST-I provided 3-d characterizations of wildfire-induced plumes of CO during the FIREX-AQ field campaign (conducted during 2019) which showed the intensity and size evolution of wildfire plumes at high spatial and temporal resolutions. Wildfire-induced CO plumes, in conjunction with their evolution, transport, and age have been identified and recently published in scientific journals. Other research applications, such as surface emissivity changes due to fire burning of ground landscape, have been under investigation. These products could be used in support of wildfire management to better inform decision making and operations for pre-, active, and post-fire environments.

remote sensing↗

Mechanism of electrochemical lithiation of a metal-organic framework without redox-active nodes

Metal-organic frameworks (MOFs) have many potential uses for separations, storage, and catalysis, but their use as intercalation hosts for batteries has been scarce. In this article, we examine the mechanism of Li insertion in a MOF to provide guidance to future design efforts in this area. As a model system, we choose UiO-66, a MOF with the formula (Zr{sub 6}O{sub 4}(OH){sub 4}){sub 4}(1,4-benzenedicarboxylate){sub 6}, as an electrode material for lithium-ion batteries; this MOF is of special interest because the zirconium is not redox active. We report both quantum mechanical characterization of the mechanism and experimental studies in which the material is synthesized as nanoparticles to reduce diffusion lengths for lithium ions and increase the contact area with a conductive carbon phase. The calculated changes in the IR spectra of UiO-66 and lithiated UiO-66 are consistent with the experimental FTIR results. We found experimentally that this MOF can maintain a specific discharge capacity of at least 118 mAh/g for 30 lithiation and delithiation cycles at a rate of C/5, exhibiting good cyclability. Density functional electronic structure calculations show that the charge transfer during lithiation is mainly from Li to node oxygens and carboxylate oxygens, that is, it involves anions rather than cations or aromatic rings, and they provide a mechanistic understanding of the potential for increased Li capacity because the theoretical capacity of UiO-66 with Li at the oxygens in the metal oxide nodes and the carboxylate linkers is more than 400 mAh/g. The lithiation process greatly decreases the bandgap of UiO-66, which is expected to increase its electronic conductivity. The electrode material was also characterized by X-ray diffraction and scanning electron microscopy, which were consistent in confirming that smaller particle sizes were obtained in lower-temperature syntheses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Symposium KK, Resonant Optics in Dielectric and Metallic Structures: Fundamentals and Applications

Symposium KK focused on the design, fabrication, characterization of novel nanoscale optical resonators and alternative materials for sub-diffraction scale resonant particles. Contributions discussed all aspects of this field, and the organizers had more than 130 contributing participants to this session alone, spanning North America, Europe, Asia and Australia. Participants discussed cutting edge research results focused on the structure, physical and optical properties, and ultrafast dynamic response of nanoscale resonators such as plasmonic and dielectric nanoparticles. A strong focus on state-of-the-art characterization and fabrication approaches, as well as presentations on novel materials for sub-diffraction resonators took place. As expected, the sessions provided strong interdisciplinary interactions and lively debate among presenters and participants.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Bulk nanocrystalline Al–Mg–Y alloys with amorphous grain boundary complexions display high strength and compressive plasticity

Although nanocrystalline alloys regularly exhibit high strengths, their use in structural applications often face challenges due to sample size limitations, unstable microstructures, and the limited ability to plastically deform. The incorporation of amorphous grain boundary complexions has been proposed to address these issues, by simultaneously stabilizing nanocrystalline grain structures for scale-up processing and improving alloy toughness. In the present study, the mechanical behavior of bulk nanocrystalline Al–Mg–Y is examined with macroscale compression testing, probing a length scale that is relevant to real-world structural applications. Bulk samples were fabricated via a simple powder metallurgy approach, with different hot-pressing temperatures and durations employed for consolidation in order to investigate microstructural and property evolution. All of the specimens contained primary face-centered cubic Al and secondary Al 4 C 3 and Al 3 Y phases, with the Al 3 Y particles exhibiting two populations of small equiaxed and larger elongated particles. Appreciable plasticity was measured along with high ultimate stresses over 800 MPa due to the presence of amorphous grain boundary complexions. Microstructural characterization of fracture surfaces revealed that the area fraction of dimpled regions increased with longer hot-pressing time. Most importantly, the elongated Al 3 Y particles formed regular cellular patterns with increasing hot-pressing time, delaying shear localization and significantly enhancing plasticity. The hierarchy present in the microstructure of the Al–Mg–Y alloy, from amorphous grain boundary complexions to secondary phases, gives rise to excellent bulk mechanical properties, which are attractive for structural applications.

Bulk nanocrystalline alloy↗

Bipartite mutual information in classical many-body dynamics

Information theoretic measures have helped to sharpen our understanding of many-body quantum states. As perhaps the most well-known example, the entanglement entropy (or more generally, the bipartite mutual information) has become a powerful tool for characterizing the dynamical growth of quantum correlations. By contrast, although computable, the bipartite mutual information (MI) is almost never explored in classical many particle systems; this owes in part to the fact that computing the MI requires keeping track of the evolution of the full probability distribution, a feat which is rarely done (or thought to be needed) in classical many-body simulations. Here, we utilize the MI to analyze the spreading of information in 1D elementary cellular automata (CA). Broadly speaking, we find that the behavior of the MI in these dynamical systems exhibits a few different types of scaling that roughly correspond to known CA universality classes. Of particular note is that we observe a set of automata for which the MI converges parametrically slowly to its thermodynamic value. We develop a microscopic understanding of this behavior by analyzing a two-species model of annihilating particles moving in opposite directions. Furthermore, our work suggests the possibility that information theoretic tools such as the MI might enable a more fine-grained characterization of classical many-body states and dynamics.

Cellular automata↗

Hydrodynamics of the interacting Bose gas in the Quantum Newton Cradle setup

Describing and understanding the motion of quantum gases out of equilibrium is one of the most important modern challenges for theorists. In the groundbreaking Quantum Newton Cradle experiment [Kinoshita, Wenger and Weiss, Nature 440, 900 (2006)], quasi-one-dimensional cold atom gases were observed with unprecedented accuracy, providing impetus for many developments on the effects of low dimensionality in out-of-equilibrium physics. But it is only recently that the theory of generalized hydrodynamics has provided the adequate tools for a numerically efficient description. Using it, we give a complete numerical study of the time evolution of an ultracold atomic gas in this setup, in an interacting parameter regime close to that of the original experiment. We evaluate the full evolving phase-space distribution of particles. We simulate oscillations due to the harmonic trap, the collision of clouds without thermalization, and observe a small elongation of the actual oscillation period and cloud deformations due to many-body dephasing. We also analyze the effects of weak anharmonicity. In the experiment, measurements are made after release from the one-dimensional trap. We evaluate the gas density curves after such a release, characterizing the actual time necessary for reaching the asymptotic state where the integrable quasi-particle momentum distribution function emerges.

Caux, Jean-Sébastien↗

Evolution of the Suprathermal Proton Population at Interplanetary Shocks

We investigate the evolution of the suprathermal (ST) proton population as interplanetary shocks cross 1 au. The variability of the ST proton intensities and energy spectra upstream of the shocks is analyzed in terms of the shock parameters, upstream magnetic field configurations, and preexisting upstream populations. Propitious conditions for the observation of ST particles at distances far upstream from the shock occur in parallel shock configurations when particles can easily escape from the shock vicinity. In this situation, ST intensity enhancements show onsets characterized by velocity dispersion effects and energy spectra that develop into a “hump” profile peaking around ∼10 keV just before the arrival of the shock. The observation of field-aligned proton beams at low energies (5–10 keV) is possible under conditions that facilitate the scatter-free propagation of the particles streaming out of the shock. Upstream of perpendicular shocks, ST intensity enhancements are only observed in close proximity to the shock. Power-law proton spectra develop downstream of the shocks. The functional form for the downstream phase-space density proportional to v(exp -5) is observed only over a limited range of ST energies. The absence of ST populations observed far upstream of interplanetary shocks raises questions about whether ST protons contribute as a seed particle population in the processes of particle acceleration at shocks.

Shock waves↗

Orion Exploration Flight Test Post-Flight Inspection and Analysis

The principal mechanism for developing orbital debris environment models, is to make observations of larger pieces of debris in the range of several centimeters and greater using radar and optical techniques. For particles that are smaller than this threshold, breakup and migration models of particles to returned surfaces in lower orbit are relied upon to quantify the flux. This reliance on models to derive spatial densities of particles that are of critical importance to spacecraft make the unique nature of the EFT-1's return surface a valuable metric. To this end detailed post-flight inspections have been performed of the returned EFT-1 backshell, and the inspections identified six candidate impact sites that were not present during the pre-flight inspections. This paper describes the post-flight analysis efforts to characterize the EFT-1 mission craters. This effort included ground based testing to understand small particle impact craters in the thermal protection material, the pre- and post-flight inspection, the crater analysis using optical, X-ray computed tomography (CT) and scanning electron microscope (SEM) techniques, and numerical simulations.

Miller, J. E.↗

The inertial confinement fusion experimental platform and diagnostics for studies of nuclear reactions relevant to nuclear astrophysics

High energy density plasmas generated in laser-driven inertial confinement fusion implosions provide unparalleled laboratory conditions for studying stellar-relevant nuclear reactions: plasma environment; hot and dense; uniquely high achievable neutron flux. These experiments have the potential to address long-standing questions about plasma effects on nuclear reactions hitherto experimentally inaccessible, including nuclear rates with thermally distributed reactants, plasma screening, and reactions involving nuclei in excited states. The National Ignition Facility (NIF) and OMEGA lasers are two primary facilities for executing experiments of this type. Existing and future nuclear diagnostics, along with supporting diagnostics to characterize the platform, enable exploitation of these plasmas for such nuclear astrophysics-relevant experiments. Here, this review describes the nuclear diagnostic capabilities currently available for these types of experiments at the NIF and OMEGA, including neutron time-of-flight spectrometers, charged-particle detectors, gamma detectors and radiochemistry diagnostics, and briefly summarizes other available diagnostic capabilities used for platform characterization. Enabling tools not yet available are also identified, including a rapid radioactive sample retrieval system, a low-energy neutron spectrometer and a high-efficiency gamma spectrometer.

National Ignition Facility↗

Quantifying electron transport in aggregated colloidal suspensions in the strong flow regime

Electron transport in complex fluids, biology, and soft matter is a valuable characteristic in processes ranging from redox reactions to electrochemical energy storage. These processes often employ conductor–insulator composites in which electron transport properties are fundamentally linked to the microstructure and dynamics of the conductive phase. While microstructure and dynamics are well recognized as key determinants of the electrical properties, a unified description of their effect has yet to be determined, especially under flowing conditions. In this work, the conductivity and shear viscosity are measured for conductive colloidal suspensions to build a unified description by exploiting both recent quantification of the effect of flow-induced dynamics on electron transport and well-established relationships between electrical properties, microstructure, and flow. These model suspensions consist of conductive carbon black (CB) particles dispersed in fluids of varying viscosities and dielectric constants. In a stable, well-characterized shear rate regime where all suspensions undergo self-similar agglomerate breakup, competing relationships between conductivity and shear rate were observed. To account for the role of variable agglomerate size, equivalent microstructural states were identified using a dimensionless fluid Mason number, Mn f , which allowed for isolation of the role of dynamics on the flow-induced electron transport rate. At equivalent microstructural states, shear-enhanced particle–particle collisions are found to dominate the electron transport rate. This work rationalizes seemingly contradictory experimental observations in literature concerning the shear-dependent electrical properties of CB suspensions and can be extended to other flowing composite systems.

Science & Technology - Other Topics↗

Effects of auroral-particle anisotropies and mirror forces on high-latitude electric fields

It is noted that, for most of the mechanisms for the strong electric fields that characterize the narrow regions in which there is acceleration and precipitation of ring current and/or plasma-sheet plasma, certain effects must be taken into account in simulations of auroral electric fields. The effects are those of auroral particle anisotropy, of mirror forces due to the inhomogeneous geomagnetic field, of auroral electron backscatter by the atmosphere, and of electron trapping by the combination of magnetic mirroring and electrostatic forces. What is more, the effects of the very strong perpendicular electric field must also be taken into account in a kinetic description of the Poisson equation in order to achieve a unified theory of the auroral electrostatic structure. Progress in these areas during the past few years is reviewed. It is shown that particle anisotropies and mirror forces can account for some basic electrostatic features of the quiet arc, while additional effects may be occurring in strong events in which the parallel potential drop is more than about 10 kV.

Chiu, Y. T.↗

The scientific potential and technological challenges of the High-Luminosity Large Hadron Collider program

Here, we present an overview of the High-Luminosity (HL-LHC) program at the Large Hadron Collider (LHC), its scientific potential and technological challenges for both the accelerator and detectors. The HL-LHC program is expected to start circa 2027 and aims to increase the integrated luminosity delivered by the LHC by an order of magnitude at the collision energy of 14 TeV. This requires upgrades to the injector system, accelerator complex and luminosity levelling. The two experiments, ATLAS and CMS, require substantial upgrades to most of their systems in order to cope with the increased interaction rate, and much higher radiation levels than at the current LHC. We present selected examples based on novel ideas and technologies for applications at a hadron collider. Both experiments will replace their tracking systems. We describe the ATLAS pixel detector upgrade featuring novel tilted modules, and the CMS Outer Tracker upgrade with a new module design enabling use of tracks in the level-1 trigger system. CMS will also install state-of-the-art highly segmented calorimeter endcaps. Finally, we describe new picosecond precision timing detectors of both experiments. In addition, we discuss how the upgrades will enhance the physics performance of the experiments, and solve the computing challenges posed by the expected large data sets. The physics program of the HL-LHC is focused on precision measurements probing the limits of the Standard Model (SM) of particle physics and discovering new physics. We present a selection of studies that have been carried out to motivate the HL-LHC program. A central topic of exploration will be the characterization of the Higgs boson. The large HL-LHC data samples will extend the sensitivity of searches for new particles or new interactions whose existence has been hypothesized in order to explain shortcomings of the SM. Finally, we comment on the nature of large scientific collaborations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) Field Campaign Report

Cumulus convection is an important component in the atmospheric radiation budget and hydrologic cycle over the southern Great Plains and over many regions of the world, particularly during the summertime growing season when intense turbulence induced by surface radiation couples the land surface to clouds. Current convective cloud parameterizations contain uncertainties resulting in part from insufficient coincident data that couples cloud macrophysical and microphysical properties to inhomogeneities in land surface, boundary layer, and aerosol properties. The Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) campaign was designed to provide a detailed set of measurements that are needed to obtain a more complete understanding of the lifecycle of shallow clouds by coupling cloud macrophysical and microphysical properties to land surface properties, ecosystems, and aerosols. Some of the land-atmosphere-cloud interactions that can be studied using HI-SCALE data are shown in Figure 1. HI-SCALE consisted of two 4-week intensive operation periods (IOPs), one in the spring (April 24-May 21) and the other in the late summer (August 28-September 24) of 2016, to take advantage of different stages of the plant lifecycle, the distribution of “greenness” for various types of vegetation in the vicinity of the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site, and aerosol properties that vary during the growing season. As expected, satellite measurements indicated that the Normalized Difference Vegetation Index (NDVI) was much “greener” in the vicinity of the SGP site during the spring IOP than the late summer IOP as a result of winter wheat maturing in the spring and being harvested in the early summer. As shown in Figure 2, temperatures were cooler than average and soil moisture was high during the spring IOP, while temperatures were warmer than average and soil moisture was low during the late summer IOP. These factors likely influence the occurrence and lifecycle of shallow clouds. Most of the instrumentation was deployed on the ARM Aerial Facility (AAF) Gulfstream 1 (G-1) aircraft, including those that measure atmospheric turbulence, cloud water content and drop size distributions, aerosol precursor gases, aerosol chemical composition and size distributions, and cloud condensation nuclei (CCN) concentrations. The specific instrumentation is listed in Table 1. The team of scientists participating in the G-1 flights were from Pacific Northwest National Laboratory (PNNL), Brookhaven National Laboratory (BNL), and the University of Washington. Routine ARM aerosol measurements made at the surface were supplemented with aerosol microphysical properties measurements, with support from the DOE Environmental Molecular Sciences Laboratory (EMSL) User Facility and the Atmospheric System Radiation (ASR) program. This included deploying a scanning mobility particle sizer (SMPS) to measure aerosol size distribution, a proton transfer reaction-mass spectrometer (PTR-MS) to measure volatile organic compounds, an aerosol mass spectrometer (AMS) to measure bulk aerosol composition, and the single-particle laser ablation time-of-flight mass spectrometer (SPLAT II) to measure single-particle aerosol composition at the SGP site Guest Instrumentation Facility. In this way, characterization of aerosol properties at the surface and on the G-1 were consistent. In addition, the HI-SCALE: Nanoparticle Composition and Precursors add-on campaign was conducted during the second IOP in which several state-of-the-science chemical ionization mass spectrometers were deployed to measure nanoparticle composition and precursors. Scientists participating in the surface measurements were from PNNL, BNL, University California–Irvine, Augsberg College, Colorado University, Aerodyne Inc., and Aerosol Dynamics Inc.

54 ENVIRONMENTAL SCIENCES↗

Shielded Heavy-Ion Environment Linear Detector (SHIELD): an experiment for the Radiation and Technology Demonstration (RTD) Mission

Radiological assessment of the many cosmic ion species of widely distributed energies requires the use of theoretical transport models to accurately describe diverse physical processes related to nuclear reactions in spacecraft structures, planetary atmospheres and surfaces, and tissues. Heavy-ion transport models that were designed to characterize shielded radiation fields have been validated through comparison with data from thick-target irradiation experiments at particle accelerators. With the RTD Mission comes a unique opportunity to validate existing radiation transport models and guide the development of tools for shield design. For the first time, transport properties will be measured in free-space to characterize the shielding effectiveness of materials that are likely to be aboard interplanetary space missions. Target materials composed of aluminum, advanced composite spacecraft structure and other shielding materials, helium (a propellant) and tissue equivalent matrices will be evaluated. Large solid state detectors will provide kinetic energy and charge identification for incident heavy-ions and for secondary ions created in the target material. Transport calculations using the HZETRN model suggest that 8 g cm -2 thick targets would be adequate to evaluate the shielding effectiveness during solar minimum activity conditions for a period of 30 days or more.

NASA Center LaRC↗