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At least 1,621 records · Page 90

Beyond Chandra - the X-ray Surveyor

Over the past 16 years, NASA's Chandra X-ray Observatory has provided an unparalleled means for exploring the high energy universe with its half-arcsecond angular resolution. Chandra studies have deepened our understanding of galaxy clusters, active galactic nuclei, galaxies, supernova remnants, planets, and solar system objects addressing most, if not all, areas of current interest in astronomy and astrophysics. As we look beyond Chandra, it is clear that comparable or even better angular resolution with greatly increased photon throughput is essential to address even more demanding science questions, such as the formation and subsequent growth of black hole seeds at very high redshift; the emergence of the first galaxy groups; and details of feedback over a large range of scales from galaxies to galaxy clusters. Recently, NASA Marshall Space Flight Center, together with the Smithsonian Astrophysical Observatory, has initiated a concept study for such a mission now named the X-ray Surveyor. This concept study starts with a baseline payload consisting of a high resolution X-ray telescope and an instrument set which may include an X-ray calorimeter, a wide-field imager and a dispersive grating spectrometer and readout. The telescope would consist of highly nested thin shells, for which a number of technical approaches are currently under development, including adjustable X-ray optics, differential deposition, and modern polishing techniques applied to a variety of substrates. In many areas, the mission requirements would be no more stringent than those of Chandra, and the study takes advantage of similar studies for other large area missions carried out over the past two decades. Initial assessments indicate that such an X-ray mission is scientifically compelling, technically feasible, and worthy of a high prioritization by the next American National Academy of Sciences Decadal Survey for Astronomy and Astrophysics.

Beyond Chandra↗

Unmanned Aircraft Systems (UAS) Integration in the National Airspace System (NAS) Project

Over the past 5 years, the UAS integration into the NAS project has worked to reduce technical barriers to integration. A major focus of this work has been in support of RTCA SC-228. This committee has recently published the first UAS integration minimum performance standards (MOPS). This work has spanned detect and avoid (DAA) as well as command and control comm datalinks. I will discuss DAA efforts with focus on the human systems work. I will discuss how automation was discussed and addressed within this context. ICAO stood up a remotely piloted aircraft systems (RPAS) panel in 2014. They have developed an RPAS manual and are now working to revise existing annexes and standards and recommended practices. The Human In The System (HITS) has worked to infuse human factors guidelines into those documents. I will discuss that effort as well as how ICAO has defined and address autonomy. There is a great deal of interest in the control of multiple vehicles by a single operator. The UAS EXCOM Science and Research Panel (SARP) is holding a workshop on this topic in late June. I will discuss research performed on this topic when I worked for the Army and on-going work within the division and a NATO working group on Human-Autonomy Teaming.

Unmanned Aircraft Systems (UAS)↗

$c$-functions in flows across dimensions

We explore the notion of c-functions in renormalization group flows between theories in different spacetime dimensions. We discuss functions connecting central charges of the UV and IR fixed point theories on the one hand, and functions which are monotonic along the flow on the other. First, using the geometric properties of the holographic dual RG flows across dimensions and the constraints from the null energy condition, we construct a monotonic holographic c-function and thereby establish a holographic c-theorem across dimensions. Second, we use entanglement entropies for two different types of entangling regions in a field theory along the RG flow across dimensions to construct candidate c-functions which satisfy one of the two criteria but not both. In due process we also discuss an interesting connection between corner contributions to the entanglement entropy and the topology of the compact internal space. As concrete examples for both approaches, we holographically study twisted compactifications of 4d N =4 SYM and compactifications of 6d N = (2, 0) theories.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Relativity symmetries and Lie algebra contractions

We revisit the notion of possible relativity or kinematic symmetries mutually connected through Lie algebra contractions under a new perspective on what constitutes a relativity symmetry. Contractions of an SO(m,n) symmetry as an isometry on an m+n dimensional geometric arena which generalizes the notion of spacetime are discussed systematically. One of the key results is five different contractions of a Galilean-type symmetry G(m,n) preserving a symmetry of the same type at dimension m+n−1, e.g. a G(m,n−1), together with the coset space representations that correspond to the usual physical picture. Most of the results are explicitly illustrated through the example of symmetries obtained from the contraction of SO(2,4), which is the particular case for our interest on the physics side as the proposed relativity symmetry for “quantum spacetime”. The contractions from G(1,3) may be relevant to real physics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Atmospheric River Tracking Method Intercomparison Project (ARTMIP): Quantifying Uncertainties in Atmospheric River Climatology

Atmospheric rivers (ARs) are now widely known for their association with high-impact weather events and long-term water supply in many regions. Researchers within the scientific community have developed numerous methods to identify and track of ARs—a necessary step for analyses on gridded data sets, and objective attribution of impacts to ARs. These different methods have been developed to answer specific research questions and hence use different criteria (e.g., geometry, threshold values of key variables, and time dependence). Furthermore, these methods are often employed using different reanalysis data sets, time periods, and regions of interest. The goal of the Atmospheric River Tracking Method Intercomparison Project (ARTMIP) is to understand and quantify uncertainties in AR science that arise due to differences in these methods. This paper presents results for key AR-related metrics based on 20+ different AR identification and tracking methods applied to Modern-Era Retrospective Analysis for Research and Applications Version 2 reanalysis data from January 1980 through June 2017. We show that AR frequency, duration, and seasonality exhibit a wide range of results, while the meridional distribution of these metrics along selected coastal (but not interior) transects are quite similar across methods. Furthermore, methods are grouped into criteria-based clusters, within which the range of results is reduced. AR case studies and an evaluation of individual method deviation from an all-method mean highlight advantages/disadvantages of certain approaches. For example, methods with less (more) restrictive criteria identify more (less) ARs and AR-related impacts. Finally, this paper concludes with a discussion and recommendations for those conducting AR-related research to consider.

Rutz, Jonathan J.↗

Shocks and star formation in Stephan's Quintet. I. Gemini spectroscopy of Hα-bright knots

We present a Gemini-GMOS spectroscopic study of Hubble Space Telescope (HST)-selected Hα-emitting regions in Stephan's Quintet (HCG 92), a nearby compact galaxy group, with the aim of disentangling the processes of shock-induced heating and star formation in its intra-group medium. The ≈40 sources are distributed across the system, but most densely concentrated in the ∼kiloparsec-long shock region. Their spectra neatly divide them into narrow- and broad-line emitters, and we decompose the latter into three or more emission peaks corresponding to spatial elements discernible in HST imaging. The emission-line ratios of the two populations of Hα-emitters confirm their nature as H II regions (90% of the sample) or molecular gas heated by a shock front propagating at ≲300 km s{sup –1}. Their redshift distribution reveals interesting three-dimensional structure with respect to gas-phase baryons, with no H II regions associated with shocked gas, no shocked regions in the intruder galaxy NGC 7318B, and a sharp boundary between shocks and star formation. We conclude that star formation is inhibited substantially, if not entirely, in the shock region. Attributing those H II regions projected against the shock to the intruder, we find a lopsided distribution of star formation in this galaxy, reminiscent of pileup regions in models of interacting galaxies. The Hα luminosities imply mass outputs, star formation rates, and efficiencies similar to nearby star-forming regions. Two large knots are an exception to this, being comparable in stellar output to the prolific 30 Doradus region. We also examine Stephan's Quintet in the context of compact galaxy group evolution, as a paradigm for intermittent star formation histories in the presence of a rich, X-ray-emitting intra-group medium. All spectra are provided as supplemental materials.

79 ASTRONOMY AND ASTROPHYSICS↗

Comparative Study of the Effect of Defects on Selective Adsorption of Butanol from Butanol/Water Binary Vapor Mixtures in Silicalite-1 Films

A promising route for sustainable 1-butanol (butanol) production is ABE (acetone, butanol, ethanol) fermentation. However, recovery of the products is challenging because of the low concentrations obtained in the aqueous solution, thus hampering large-scale production of biobutanol. Membrane and adsorbent-based technologies using hydrophobic zeolites are interesting alternatives to traditional separation techniques (e.g., distillation) for energy-efficient separation of butanol from aqueous mixtures. To maximize the butanol over water selectivity of the material, it is important to reduce the number of hydrophilic adsorption sites. This can, for instance, be achieved by reducing the density of lattice defect sites where polar silanol groups are found. The density of silanol defects can be reduced by preparing the zeolite at neutral pH instead of using traditional synthesis solutions with high pH. In this work, binary adsorption of butanol and water in two silicalite-1 films was studied using in situ attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy under equal experimental conditions. One of the films was prepared in fluoride medium, whereas the other one was prepared at high pH using traditional synthesis conditions. The amounts of water and butanol adsorbed from binary vapor mixtures of varying composition were determined at 35 and 50 °C, and the corresponding adsorption selectivities were also obtained. Both samples showed very high selectivities (100–23 000) toward butanol under the conditions studied. The sample having low density of defects, in general, showed ca. a factor 10 times higher butanol selectivity than the sample having a higher density of defects at the same experimental conditions. This difference was due to a much lower adsorption of water in the sample with low density of internal defects. Analysis of molecular simulation trajectories provides insights on the local selectivities in the zeolite channel network and at the film surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

How a Formate Dehydrogenase Responds to Oxygen: Unexpected O 2 Insensitivity of an Enzyme Harboring Tungstopterin, Selenocysteine, and [4Fe–4S] Clusters

The reversible two-electron interconversion of formate and CO 2 is catalyzed by both nonmetallo- and metallo-formate dehydrogenases (FDHs). The latter group comprises molybdenum- or tungsten-containing enzymes with the metal coordinated by two equivalents of a pyranopterin cofactor, a cysteinyl or selenocysteinyl (Sec) ligand supplied by the polypeptide, and a catalytically essential terminal sulfido ligand. In addition, these biocatalysts incorporate one or more [4Fe–4S] clusters for facilitating long-distance electron transfer. However, an interesting dichotomy arises when attempting to understand how the metallo-FDHs react with O 2 . Whereas existing scholarship portrays these enzymes as being unable to perform in air due to extreme O 2 lability of their metal centers, studies dating as far back as the 1930s emphasize that some of these systems exhibit formate oxidase (FOX) activity, coupling formate oxidation to O 2 reduction. Therefore, to reconcile these conflicting views, we explored context-dependent functional linkages between metallo-FDHs and their cognate electron acceptors within the same organism vis-à-vis catalysis under atmospheric O 2 . Here, we report the discovery and characterization of an O 2 -insensitive FDH2 from the sulfate-reducing bacterium Desulfovibrio vulgaris Hildenborough (DvH) that ligates tungsten, Sec, and four [4Fe–4S] clusters. By advancing a robust expression platform for its recombinant production, we eliminate both the requirement of nitrate or azide during purification and reductive activation with thiols and/or formate prior to catalysis. Because the distinctive spectral signatures of formate-reduced DvH-FDH2 remain invariant under anaerobic and aerobic conditions, we benchmarked the enzyme activity in air, identifying CO 2 as the catalytic product. Full reaction progress curve analysis discloses a high catalytic efficiency when probed with a high-potential artificial electron acceptor. Furthermore, we show that DvH-FDH2 enables near-stoichiometric hydrogen peroxide production without superoxide release to achieve O 2 insensitivity. Notably, simultaneous electron transfer to cytochrome c and O 2 reveals that metal-based electron bifurcation is operational in this system. Taken together, our work proves the co-occurrence of redox bifurcated FDH and FOX activities within a metalloenzyme scaffold. These findings set the stage for uncovering previously unknown O 2 -insensitive flavin-based electron bifurcation mechanisms, as well as for developing authentic formate/air biofuel cells, engineering O 2 -stable FDHs and biohybrid metallocatalysts, and discerning formate bioenergetics of gut microbiota.

13C NMR↗

Self-optimizing, highly surface-active layered metal dichalcogenide catalysts for hydrogen evolution [Surface-active metal dichalcogenide electrocatalysts with self-improving performance for hydrogen evolution]

Low-cost, layered transition-metal dichalcogenides (MX 2 ) based on molybdenum and tungsten have attracted substantial interest as alternative catalysts for the hydrogen evolution reaction (HER). These materials have high intrinsic per-site HER activity; however, a significant challenge is the limited density of active sites, which are concentrated at the layer edges. Here we unravel electronic factors underlying catalytic activity on MX 2 surfaces, and leverage the understanding to report group-5 MX 2 (H-TaS 2 and H-NbS 2 ) electrocatalysts whose performance instead mainly derives from highly active basal-plane sites, as suggested by our first-principles calculations and performance comparisons with edge-active counterparts. Beyond high catalytic activity, they are found to exhibit an unusual ability to optimize their morphology for enhanced charge transfer and accessibility of active sites as the HER proceeds, offering a practical advantage for scalable processing. In conclusion, the catalysts reach 10 mA cm –2 current density at an overpotential of ~50–60 mV with a loading of 10–55 μg cm –2 , surpassing other reported MX 2 candidates without any performance-enhancing additives.

30 DIRECT ENERGY CONVERSION↗

A new Cu–cysteamine complex: structure and optical properties

Here we report the structure and optical properties of a new Cu–cysteamine complex (Cu–Cy) with a formula of Cu3Cl(SR)2 (R ¼ CH2CH2NH2). This Cu–Cy has a different structure from a previous Cu–Cy complex, in which both thio and amine groups from cysteamine bond with copper ions. Single-crystal X-ray diffraction and solid-state nuclear magnetic resonance results show that the oxidation state of copper in Cu3Cl(SR)2 is +1 rather than +2. Further, Cu3Cl(SR)2 has been observed to show intense photoluminescence and X-ray excited luminescence. More interesting is that Cu3Cl(SR)2 particles can produce singlet oxygen under irradiation by light or X-ray. This indicates that Cu3Cl(SR)2 is a new photosensitizer that can be used for deep cancer treatment as X-ray can penetrate soft tissues. All these findings mean that Cu3Cl(SR)2 is a new material with potential applications for lighting, radiation detection and cancer treatment.

Ma, Lun↗

Mechanistic investigation of the Zn/Pd/C catalyzed cleavage and hydrodeoxygenation of lignin

While current biorefinery processes use lignin only for its heat value, the conversion of lignin to high value chemicals is an area of increasing interest. In this article we present a detailed mechanistic study of the hydrodeoxygenation (HDO) of lignin by using a synergistic Pd/C and Zn II catalyst through use of both lignin model compounds and lignocellulosic biomass. Spectroscopic data coupled with the study of lignin model compounds suggest that Zn II activates and facilitates removal of the hydroxyl group at the Cγ position of the β-O-4 ether linkage. Activation is proposed to occur through formation of a six-membered ring complex of Zn II coordinated to the oxygen atoms at Cα and Cγ of the lignin model compound guaiacylglycerol-β-guaiacyl.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Soft particles and infinite-dimensional geometry

Abstract In the sigma model, soft insertions of moduli scalars enact parallel transport ofS-matrix elements about the finite-dimensional moduli space of vacua, and the antisymmetric double-soft theorem calculates the curvature of the vacuum manifold. We explore the analogs of these statements in gauge theory and gravity in asymptotically flat spacetimes, where the relevant moduli spaces are infinite-dimensional. These models have spaces of vacua parameterized by (trivial) flat connections on the celestial sphere, and soft insertions of photons, gluons, and gravitons parallel transportS-matrix elements about these infinite-dimensional manifolds. We argue that the antisymmetric double-soft gluon theorem ind + 2 bulk dimensions computes the curvature of a connection on the infinite-dimensional space Map ( S d , G ) / G , whereGis the global part of the gauge group. The analogous metrics in abelian gauge theory and gravity are flat, as indicated by the vanishing of the antisymmetric double-soft theorems in those models. In other words, Feynman diagram calculations not only know about the vacuum manifold of Yang–Mills theory, they can also be used to compute its curvature. The results have interesting implications for flat space holography.

Astronomy & Astrophysics↗

Genome-resolved insights into microbial diversity and elemental cycling in Winogradsky columns

We retained 18 MAGs with ≥50% completion and <10% contamination (i.e., at least medium quality). Of these, 10 had >90% completion and <5% contamination; however, only one (Paceibacteria Bin.003_MG) can be described as high-quality, as the others lacked a full suite of 5S, 16S, and 23S rRNA genes. To maximize the diversity of our recovered MAGs, we also retained one MAG (Chromatiaceae Bin.008_AM) with >40% (but less than 50%) completion and <5% contamination, as well as one (Rhodopseudomonas Bin.015_MK) with >90% completion and <20% (but>10%) contamination. Interestingly, significant chimerism was not detected in this MAG (40) , suggesting that the elevated contamination (20%) may instead reflect two closely related strains collapsing into a single bin. Consistent with this, contig coverage was bimodal, with roughly 17% of the assembly at ~115x and the remaining 83% at ~282x, while GC content remained uniform across both groups (~64%), arguing against contamination from a taxonomically distinct source.

59 BASIC BIOLOGICAL SCIENCES↗

Estimation and detection of signals in multiplicative noise

We define a class of detection-estimation problems on matrix Lie groups in which the observation noise is multiplicative in nature. By examining the differential versions of the hypotheses, which are bilinear, we are able to derive the relevant likelihood ratio formula and the associated optimal estimation equations for the signal given the observations and the assumption that the signal is present. These estimation equations are of interest in their own right, in that they represent a finite-dimensional optimal solution to a nonlinear estimation problem and consist of a Kalman-Bucy filter along with the on-line computation of the solution of the associated Riccati equation, which is driven by the observations. The usefulness of these results is illustrated via an example concerning the detection of an actuator failure in a rigid-body rotational control system.

Willsky, A. S.↗

New monomers for high performance polymers

This laboratory has been concerned with the development of new polymeric materials with high thermo-oxidative stability for use in the aerospace and electronics industries. Currently, there is special emphasis on developing matrix resins and composites for the high speed civil transport (HSCT) program. This application requires polymers that have service lifetimes of 60,000 hr at 350 F (177 C) and that are readily processible into void-free composites, preferably by melt-flow or powder techniques that avoid the use of high boiling solvents. Recent work has focused on copolymers which have thermally stable imide groups separated by flexible arylene ether linkages, some with trifluoromethyl groups attached to the aromatic rings. The presence of trifluoromethyl groups in monomers and polymers often improves their solubility and processibility. The goal of this research was to synthesize several new monomers containing pendant trifluoromethyl groups and to incorporate these monomers into new imide/arylene ether copolymers. Initially, work was begun on the synthesis of three target compounds. The first two, 3,5-dihydroxybenzo trifluoride and 3-amino 5-hydroxybenzo trifluoride, are intermediates in the synthesis of more complex monomers. The third, 3,5-bis (3-amino-phenoxy) benzotrifluoride, is an interesting diamine that could be incorporated into a polyimide directly.

Gratz, Roy F.↗

From Present Surveying to Future Prospecting of the Asteroid Belt

We have applied a future mission architecture, the Autonomous Nano-Technology Swarm (ANTS), to a proposed mission for in situ survey, or prospecting, of the asteroid belt, the Prospecting Asteroid Mission (PAM) as part of a NASA 2003 Revolutionary Aerospace Concept (RASC) study. ANTS architecture builds on and advances recent trends in robotics, artificial intelligence, and materials processing to minimize costs and maximize effectiveness of space operations. PAM and other applications have been proposed for the survey of inaccessible, high surface area populations of great interest from the standpoint of resources and/or solar system origin. The ANTS architecture is inspired by the success of social insect colonies, a success based on the division of labor within the colonies in two key ways: 1) within their specialties, individual specialists generally outperform generalists, and 2) with sufficiently efficient social interaction and coordination, the group of specialists generally outperforms the group of generalists. Thus systems designed as ANTS are built from potentially very large numbers of highly autonomous, yet socially interactive, elements. The architecture is self-similar in that elements and sub-elements of the system may also be recursively structured as ANTS on scales ranging from microscopic to interplanetary distances. Here, we analyze requirements for the mission application at the low gravity target end of the spectrum, the Prospecting Asteroid Mission (PAM), and for specialized autonomous operations which would support this mission. ANTS as applied to PAM involves the activities of hundreds of individual specialist 'sciencecraft'. Most of them, called Workers, carry and operate eight to nine different scientific instruments, as listed in the table, including spectrometers, ranging and radio science devices, and imagers. The remaining specialists, Messenger/Rulers, provide communication and coordination functions among specialists operating autonomously as individuals, team members, and subswarms.

Clark, P. E.↗

Accumulation of gadolinium isotopes in used nuclear fuel - 14374

For the criticality safety control of damaged nuclear fuel, i.e., fuel debris, accounting for burnup credit (BUC) may become important if higher initial-uranium-enrichment fuel almost 5 wt% loaded into the reactor. In this case, if the presence of fission products (FP) could be confirmed, the negative reactivity effect of FP allows us to treat a substantially greater quantity of fuel debris in one removal and storage operation. In the technical development of the criticality safety control for fuel debris from the Fukushima accident in Japan, adopting BUC assuming the presence of the FP is being considered because the fuel used in the Fukushima Daiichi Nuclear Power Plant had a higher initial {sup 235}U enrichment, i.e., almost 5 wt%, than the fuel used at TMI-2. The Expert Group on Burnup Credit Criticality Safety (EGBUC) under the Working Party on Nuclear Criticality Safety (WPNCS) in the OECD/NEA Nuclear Science Committee carried out international burnup calculation benchmarks 'Phase-IIIB' and 'Phase-IIIC' for BWR fuel assemblies. In these benchmarks, the differences in the {sup 155}Gd calculation results of the participants generated keen interest because these differences were rather large. As the coordinators of the Phase-IIIC benchmark, the authors have conducted additional analyses on the accumulation of the gadolinium isotopes in used nuclear fuel during burnup. Without cooling time, the assembly-averaged amount of {sup 155}Gd against the burnup value depends on the burnout property of gadolinium in burnable poison rods. This is because the amount of gadolinium isotopes accumulated owing to the fission reaction is less than the residual gadolinium in the burnable poison rods. After the burnout of gadolinium isotopes in the burnable poison rods, the amount of {sup 155}Gd isotopes remains almost constant, which is defined by the balance between depletion due to the neutron capture reaction and generation due to beta-decay of {sup 155}Eu generated by the fission reaction. However, after a few years of cooling, the amount of {sup 155}Gd drastically increases owing to {sup 155}Eu decay. This effect is important for higher burnup fuel. In this case, the amount of gadolinium isotopes in the burnable poison rods is of less importance. This means that for better prediction of {sup 155}Gd, the adopted parameters and data pertaining to {sup 155}Eu generation have significantly greater importance than the burnup treatment of the burnable poison rods. The release behavior of europium as well as gadolinium during the severe accident should be examined. This paper provides basic information for considering {sup 155}Gd in the criticality safety evaluation of fuel debris. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gas Sorption and Storage Properties of Calixarenes

Calixarenes, a class of organic macrocyclic molecules have shown interesting gas sorption properties towards industrially important gases such as carbon di-oxide, hydrogen, methane and acetylene. These macrocycles are involved in weak van der Waals interaction to form multidimensional supramolecular frameworks. The gas-diffusion and subsequent sorption occurs due to a cooperative behavior between neighboring macrocycles. Furthermore, the flexibility at the upper rim functional group also plays a key role in the overall gas uptake of calixarene. In this book chapter, we give a brief account of interaction and diffusion of gases in calixarene and selected derivatives.

Patil, Rahul S.↗