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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Effects of Disinfectants in Water on Mir- and Earth-Grown Wheat

Iodine and silver fluoride are used to purify water onboard U. S. Shuttles and the Russian Space Station, Mir, respectively. In 1995, iodine-treated water, which ranged from 1.0-4.0 mg x kg(exp -1) with a mean of 2.9 mg x kg(exp -1), was applied to Super Dwarf wheat (Triticum aestivum L.) plants when Mir water (grey or tech grade) became scarce. The potential phytotoxicity of iodine on Super Dwarf wheat is an unknown. Since use of iodine-treated water was not part of the experiment, we sought to determine whether it accounted for the subsequent poor wheat seedling growth and floral development onboard the Mir. Super Dwarf wheat seeds were imbibed in iodine or silver fluoride concentrations of 0.0, 1.0, 2.0, 4.0, 8.0 or 16.0 mg x kg(exp -1) for 96 h at 4 C. Five seeds were then planted per 13.3 cm x 13.3 cm pots containing a granular clinoptilolite (Cp) zeolite (1 -2 mm dia.) and placed in Percival(TM) growth chambers programmed for 20/15 C and 18/6 h d/n regime. Plants were irrigated with distilled water, and Iodine- or silver fluoride-treated distilled water. In separate experiments, seeds were treated as above and germination and early seedling growth were determined by examining seedling responses to disinfectants in rolled paper towels. Silver fluoride had very little effect on wheat seed germination. By contrast, iodine reduced germination at all treatment levels. Seedlings exposed to 1.0, 2.0, and 4.0 mg x kg(exp -1) of iodine or silver fluoride levels exhibited a slight stimulation in shoot and root growth. Both disinfectants at 8 and 16 mg x kg(exp -1) showed significantly (p is less than or equal to 0.01) reduced seedling shoot and root lengths and fresh biomasses compared to the control and lower disinfectant levels. The number of spikelets per spike, florets per spikelet, seeds per spike and seed weight were also significantly reduced at the 8 and 16 mg x kg(exp -1) compared to the control and lower levels of disinfectant. Based on these ground-based post-flight analyses, the levels of iodine- and/or silver fluoride-treated water used on Mir-grown plants onboard the Mir did not cause the poor growth and development of the wheat plants.

Campbell, William .F.↗
NASA NTRS2002

First Commerical Operations on the International Space Station

As part of NASA's mission of furthering the commercial development of space, the Space Product Development Office has sponsored the flight of seven commercial payloads to the International Space Station (ISS) during calendar year 2001. Most of these payloads, which are among the first users of this new laboratory, build upon successful commercial investigations that previously were restricted to the limited flight duration of the Space Shuttle. These commercial operations range from multi-media, in the form of Dreamtime, to biotechnology such as in Advanced Astroculture, to advanced materials such as Zeolite Crystal Growth. Industry investment in the commercial program has continued to remain high, while awaiting long term access to space, which the ISS provides. While the majority of early commercial use of the ISS is in the area of biotechnology, there is a significant shift towards commercial materials research over the next two years. In order to take fall advantage of the ISS, much of the commercial hardware is designed to be left on Station, while the Shuttle brings samples up and down. This not only makes good use of this valuable space resource, it has the added benefit of having commercial hardware available on the ISS for scientific users. In order to provide benefit to the entire NASA microgravity program, the scientific community on a space available basis can use a variety of commercial apparatus at very low cost. In addition to the solution crystal growth capability of Creosote Crystal Growth, in 2002 containerless processing will be available in the form of Space-DRUMS, and in 2003, thermophysical properties research can be performed in the Vulcan furnace. The first commercial operations on the ISS provides not only a much needed capability to the commercial development of space program, it also has the potential to augment the science program as well.

Nall, Mark E.↗
NASA NTRS2002

Fundamental Studies of Crystal Growth of Microporous Materials

Microporous materials are framework structures with well-defined porosity, often of molecular dimensions. Zeolites contain aluminum and silicon atoms in their framework and are the most extensively studied amongst all microporous materials. Framework structures with P, Ga, Fe, Co, Zn, B, Ti and a host of other elements have also been made. Typical synthesis of microporous materials involve mixing the framework elements (or compounds, thereof) in a basic solution, followed by aging in some cases and then heating at elevated temperatures. This process is termed hydrothermal synthesis, and involves complex chemical and physical changes. Because of a limited understanding of this process, most synthesis advancements happen by a trial and error approach. There is considerable interest in understanding the synthesis process at a molecular level with the expectation that eventually new framework structures will be built by design. The basic issues in the microporous materials crystallization process include: (1) Nature of the molecular units responsible for the crystal nuclei formation; (2) Nature of the nuclei and nucleation process; (3) Growth process of the nuclei into crystal; (4) Morphological control and size of the resulting crystal; (5) Surface structure of the resulting crystals; (6) Transformation of frameworks into other frameworks or condensed structures. The NASA-funded research described in this report focuses to varying degrees on all of the above issues and has been described in several publications. Following is the presentation of the highlights of our current research program. The report is divided into five sections: (1) Fundamental aspects of the crystal growth process; (2) Morphological and Surface properties of crystals; (3) Crystal dissolution and transformations; (4) Modeling of Crystal Growth; (5) Relevant Microgravity Experiments.

Dutta, P.↗
NASA NTRS2003

Flight Day 2 Highlights

The STS-107 second flight day begins with a shot of the Spacehab Research Double Module. Live presentations of experiments underway inside of the Spacehab Module are presented. Six experiments are shown. As part of the Space Technology and Research Student Payload, students from Australia, China, Israel, Japan, New York, and Liechtenstein are studying the effect that microgravity has on ants, spiders, silkworms, fish, bees, granular materials, and crystals. Mission Specialist Kalpana Chawla is seen working with the zeolite crystal growth experiment.

Source record↗
NASA NTRS2002

Mapping Lithologic Units Exposed on the Summit of Mauna Kea Using AVIRIS Hyperspectral Reflectance Data

The Mauna Kea summit region is largely comprised of cinder cones and lava flows that form the cap of the Mauna Kea Volcano. The cones and flows at the summit are part of the Laupahoehoe Volcanic series. The Laupa hoehoe volcanism occurred both during and after the late Pleistocene Makanaka glacial episode at the summit. In addition, a few Laupahoehoe cones have been glacially eroded as evidenced by oversteepened slopes, which suggests that they predate the Makanaka glacial period. Two notable examples of possible preglacial cones are Puu Waiau and Puu Poliahu. These two cones are also significantly altered, most likely by hydrothermal activity that has weakly cemented the materials on the cones. Well-crystalline sulfates (alunite and jarosite), phyllosilicates, and zeolites, have been found in samples collected from altered cones at the summit. In addition, palagonitic tephra, which have nanophase ferric oxide, allophane, and other poorly crystalline forms of weakly altered basaltic glass (i.e., no phyllosilicates), have been described at several locations on Mauna Kea. While several studies have discussed the occurrence of alteration products on Mauna Kea, the distribution of these materials exposed at the summit has not been extensively mapped. Hyperspectral imaging can provide information for identifying and mapping lithologic units containing alteration minerals, such as are found on Mauna Kea. The Airborne Visible Infrared Imaging Spectrometer (AVIRIS) is a hyperspectral imaging instrument that covers the wavelength range from about 0.4 to 2.5 micron in 224 bands, with a band spacing of 10 nm and average band width of 10 nm

Guinness, E. A.↗
NASA NTRS2003

Fundamental Studies of Crystal Growth of Microporous Materials

Microporous materials are framework structures with well-defined porosity, often of molecular dimensions. Zeolites contain aluminum and silicon atoms in their framework and are the most extensively studied amongst all microporous materials. Framework structures with P, Ga, Fe, Co, Zn, B, Ti and a host of other elements have also been made. Typical synthesis of microporous materials involve mixing the framework elements (or compounds, thereof) in a basic solution, followed by aging in some cases and then heating at elevated temperatures. This process is termed hydrothermal synthesis, and involves complex chemical and physical changes. Because of a limited understanding of this process, most synthesis advancements happen by a trial and error approach. There is considerable interest in understanding the synthesis process at a molecular level with the expectation that eventually new framework structures will be built by design. The basic issues in the microporous materials crystallization process include: (a) Nature of the molecular units responsible for the crystal nuclei formation; (b) Nature of the nuclei and nucleation process; (c) Growth process of the nuclei into crystal; (d) Morphological control and size of the resulting crystal; (e) Surface structure of the resulting crystals; and (f) Transformation of frameworks into other frameworks or condensed structures.

Singh, Ramsharan↗
NASA NTRS2003

Theory of Transport of Long Polymer Molecules through Carbon Nanotube Channels

A theory of transport of long chain polymer molecules through carbon nanotube (CNT) channels is developed using Fokker-Planck equation and direct molecular dynamics (MD) simulations. The mean transport or translocation time tau is found to depend on the chemical potential energy, entropy and diffusion coefficient. A power law dependence tau approx. N(sup 2)is found where N is number of monomers in a molecule. For 10(exp 5)-unit long polyethylene molecules, tau is estimated to be approx. 1micro-s. The diffusion coefficient of long polymer molecules inside CNTs, like that of short ones, are found to be few orders of magnitude larger than in ordinary silicate based zeolite systems.

Wei, Chenyu↗
NASA NTRS2003

Mars Exploration Rovers as Virtual Instruments for Determination of Terrain Roughness and Physical Properties

The two 2003 Mars Exploration Rovers (MERs), in combination with the Athena Payload, will be used as virtual instrument systems to infer terrain properties during traverses, in addition to using the rover wheels to excavate trenches, exposing subsurface materials for remote and in-situ observations. The MERs are being modeled using finite element-based rover system transfer functions that utilize the distribution of masses associated with the vehicle, together with suspension and wheel dynamics, to infer surface roughness and mechanical properties from traverse time series data containing vehicle yaw, pitch, roll, encoder counts, and motor currents. These analyses will be supplemented with imaging and other Athena Payload measurements. The approach is being validated using Sojourner data, the FIDO rover, and experiments with MER testbed vehicles. In addition to conducting traverse science and associated analyses, trenches will be excavated by the MERs to depths of approximately 10-20 cm by locking all but one of the front wheels and rotating that wheel backwards so that the excavated material is piled up on the side of the trench away from the vehicle. Soil cohesion and angle of internal friction will be determined from the trench telemetry data. Emission spectroscopy and in-situ observations will be made using the Athena payload before and after imaging. Trenching and observational protocols have been developed using Sojourner results; data from the FIDO rover, including trenches dug into sand, mud cracks, and weakly indurated bedrock; and experiments with MER testbed rovers. Particular attention will be focused on Mini-TES measurements designed to determine the abundance and state of subsurface water (e.g. hydrated, in zeolites, residual pore ice?) predicted to be present from Odyssey GRS/NS/HEND data.

R E Arvidson↗
NASA NTRS2003

Raman Spectroscopic Characterization of the Feldspars: Implications for Surface Mineral Characterization in Planetary Exploration

The availability in the last decade of improved Raman instrumentation using small, stable, intense lasers, sensitive CCD array detectors, and advanced fast grating systems enabled us to develop the Mars Microbeam Raman Spectrometer (MMRS), a field-portable Raman spectrometer with precision and accuracy capable of identifying minerals and their different compositions. For example, we can determine Mg cation ratios in pyroxenes and olivines to +/-0.1 on the basis of Raman peak positions. Feldspar is another major mineral formed in igneous systems whose characterization is important for determining rock petrogenesis and alteration. From their Raman spectral pattern, feldspars can be readily distinguished from ortho- and chain-silicates and from other tecto-silicates such as quartz and zeolites. We show here how well Raman spectral analysis can distinguish among members within the feldspar group.

Freeman, J. J.↗
NASA NTRS2003

Nitrification in a zeoponic substrate

Clinoptilolite is a zeolite mineral with high cation exchange capacity used in zeoponic substrates that have been proposed as a solid medium for growing plants or as a fertilizer material. The kinetics of nitrification has not been measured for NH4+ saturated zeoponic substrate. Experiments were conducted to evaluate the production of NO2- and NO3-, and nitrifier populations in zeoponic substrates. Small columns were filled with zeoponic substrate inoculated with a commercial inoculum or soil enrichment culture of nitrifying bacteria. In addition to column studies, a growth chamber study was conducted to evaluate the kinetics of nitrification in zeoponic substrates used to grow radishes (Raphanus sativus L.). The zeoponic substrate provided a readily available source of NH4+, and nitrifying bacteria were active in the substrate. Ammonium oxidation rates in column studies ranged from 5 to 10 micrograms N g-1 substrate h-1, and NO2- oxidation rates were 2 to 9.5 micrograms N g-1 substrate h-1. Rates determined from the growth chamber study were approximately 1.2 micrograms N g-1 substrate h-1. Quantities of NH4+ oxidized to NO2- and NO3- in inoculated zeoponic substrate were in excess of plant up-take. Acidification as a result of NH4+ oxidation resulted in a pH decline, and the zeoponic substrate showed limited buffering capacity.

NASA Discipline Life Support Systems↗
NASA NTRS1993

Solubility and cation exchange in phosphate rock and saturated clinoptilolite mixtures

Mixtures of zeolite and phosphate rock (PR) have the potential to provide slow-release fertilization of plants in synthetic soils by dissolution and ion-exchange reactions. This study was conducted to examine solubility and cation-exchange relationships in mixtures of PR and NH4- and K-saturated clinoptilolite (Cp). Batch-equilibration experiments were designed to investigate the effect of PR source, the proportion of exchangeable K and NH4, and the Cp to PR ratio on solution N, P, K, and Ca concentrations. The dissolution and cation-exchange reactions that occurred after mixing NH4- and K-saturated Cp with PR increased the solubility of the PR and simultaneously released NH4 and K into solution. The more reactive North Carolina (NC) PR rendered higher solution concentrations of NH4 and K when mixed with Cp than did Tennessee (TN) PR. Solution P concentrations for the Cp-NC PR mixture and the Cp-TN PR mixture were similar. Solution concentrations of N, P, K, and Ca and the ratios of these nutrients in solution varied predictably with the type of PR, the Cp/PR ratio, and the proportions of exchangeable K and NH4 on the Cp. Our research indicated that slow-release fertilization using Cp/PR media may provide adequate levels of N, P, and K to support plant growth. Solution Ca concentrations were lower than optimum for plant growth.

NASA Discipline Number 61-10↗
NASA NTRS2004

Microlith Based Sorber for Removal of Environmental Contaminants

The development of energy efficient, lightweight sorption systems for removal of environmental contaminants in space flight applications is an area of continuing interest to NASA. The current CO2 removal system on the International Space Station employs two pellet bed canisters of 5A molecular sieve that alternate between regeneration and sorption. A separate disposable charcoal bed removes trace contaminants. An alternative technology has been demonstrated using a sorption bed consisting of metal meshes coated with a sorbent, trademarked and patented as Microlith by Precision Combustion, Inc. (PCI); thesemeshes have the potential for direct electrical heating for this application. This allows the bed to be regenerable via resistive heating and offers the potential for shorter regeneration times, reduced power requirement, and net energy savings vs. conventional systems. The capability of removing both CO2 and trace contaminants within the same bed has also been demonstrated. Thus, the need for a separate trace contaminant unit is eliminated resulting in an opportunity for significant weight savings. Unlike the charcoal bed, zeolites for trace contaminant removal are amenable to periodic regeneration. This paper describes the design and performance of a prototype sorber device for simultaneous CO2 and trace contarninant removal and its attendant weight and energy savings.

Roychoudhury, S.↗
NASA NTRS2005

Resistively-Heated Microlith-based Adsorber for Carbon Dioxide and Trace Contaminant Removal

An integrated sorber-based Trace Contaminant Control System (TCCS) and Carbon Dioxide Removal Assembly (CDRA) prototype was designed, fabricated and tested. It corresponds to a 7-person load. Performance over several adsorption/regeneration cycles was examined. Vacuum regenerations at effective time/temperature conditions, and estimated power requirements were experimentally verified for the combined CO2/trace contaminant removal prototype. The current paper details the design and performance of this prototype during initial testing at CO2 and trace contaminant concentrations in the existing CDRA, downstream of the drier. Additional long-term performance characterization is planned at NASA. Potential system design options permitting associated weight, volume savings and logistic benefits, especially as relevant for long-duration space flight, are reviewed. The technology consisted of a sorption bed with sorbent- coated metal meshes, trademarked and patented as Microlith by Precision Combustion, Inc. (PCI). By contrast the current CO2 removal system on the International Space Station employs pellet beds. Preliminary bench scale performance data (without direct resistive heating) for simultaneous CO2 and trace contaminant removal was reviewed in SAE 2004-01-2442. In the prototype, the meshes were directly electrically heated for rapid response and accurate temperature control. This allowed regeneration via resistive heating with the potential for shorter regeneration times, reduced power requirement, and net energy savings vs. conventional systems. A novel flow arrangement, for removing both CO2 and trace contaminants within the same bed, was demonstrated. Thus, the need for a separate trace contaminant unit was eliminated resulting in an opportunity for significant weight savings. Unlike the current disposable charcoal bed, zeolites for trace contaminant removal are amenable to periodic regeneration.

Roychoudhury, S.↗
NASA NTRS2006

Plant productivity and characterization of zeoponic substrates after three successive crops of radish

The National Aeronautics and Space Administration (NASA) has developed advanced life support (ALS) systems for long duration space missions that incorporate plants to regenerate the atmosphere (CO2 to O2), recycle water (via evapotranspiration), and produce food. NASA has also developed a zeolite-based synthetic substrate consisting of clinoptilolite and synthetic apatite to support plant growth for ALS systems (Ming et al., 1995). The substrate is called zeoponics and has been designed to slowly release all plant essential elements into "soil" solution. The substrate consists of K- and NH4-exchanged clinoptilolite and a synthetic hydroxyapatite that has Mg, S, and the plant-essential micronutrients incorporated into its structure in addition to Ca and P. Plant performance in zeoponic substrates has been improved by the addition of dolomite pH buffers, nitrifying bacteria, and other calcium-bearing minerals (Henderson et al., 2000; Gruener et al., 2003). Wheat was used as the test crop for all of these studies. The objectives of this study were to expand upon the previous studies to determine the growth and nutrient uptake of radish in zeoponic substrates and to determine the nutrient availability of the zeoponic substrate after three successive radish crops.

Gruener, J. E.↗
NASA NTRS2007

Metabolic Heat Regenerated Temperature Swing Adsorption for CO2 and Heat Removal/Rejection in a Martian PLSS

Two of the fundamental problems facing the development of a Portable Life Support System (PLSS) for use on Mars, are (i) heat rejection (because traditional technologies use sublimation of water, which wastes a scarce resource and contaminates the premises), and (ii) rejection of carbon dioxide (CO2) in an environment with a CO2 partial pressure (ppCO2) of 0.4-0.9 kPa. Patent-pending Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed to address both these challenges. The technology utilizes an adsorbent that when cooled with liquid CO2 to near sublimation temperatures (~195K) removes metabolically-produced CO2 in the ventilation loop. Once fully loaded, the adsorbent is then warmed externally by the ventilation loop (~300K), rejecting the captured CO2 to Mars ambient. Two beds are used to provide a continuous cycle of CO2 removal/rejection as well as facilitate heat exchange out of the ventilation loop. Any cryogenic fluid can be used in the application; however, since CO2 is readily available on Mars and can be easily produced and stored on the Martian surface, the solution is rather elegant and less complicated when employing liquid CO2. As some metabolic heat will need to be rejected anyway, finding a practical use for metabolic heat is also an overall benefit to the PLSS. To investigate the feasibility of the technology, a series of experiments were conducted which lead to the selection and partial characterization of an appropriate adsorbent. The Molsiv Adsorbents 13X 8x12 (also known as NaX zeolite) successfully removed CO2 from a simulated ventilation loop at the prescribed temperature swing anticipated during PLSS operating conditions on Mars using a cryogenic fluid. Thermal conductivity of the adsorbent was also measured to eventually aid in a demonstrator design of the technology. These results provide no show stoppers to the development of MTSA technology and allow its development to focus on other design challenges as listed in the conclusions section of this paper.

Iacomini, Christine↗
NASA NTRS2008

Crystalline Membranes

In certain aspects, the invention features methods for forming crystalline membranes (e.g., a membrane of a framework material, such as a zeolite) by inducing secondary growth in a layer of oriented seed crystals. The rate of growth of the seed crystals in the plane of the substrate is controlled to be comparable to the rate of growth out of the plane. As a result, a crystalline membrane can form a substantially continuous layer including grains of uniform crystallographic orientation that extend through the depth of the layer.

Tsapatsis, Michael↗