Emergent electronic and thermal behavior in cobaltates with high-entropy superlattice distortions
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Single crystal p-type zinc antimonide in thermoelectric, thermoconductivity and electronic transport measurements
Development of polymers with improved heat transfer coefficients for use in encapsulating electronic modules is discussed. Chemical reactions for synthesizing the polymers are described and thermodynamic and physical properties are analyzed.
Ion conics are commonly observed along auroral-zone field lines and involve all major terrestrial ion species, including H, He, and O. It is believed that low-frequency plasma waves, driven unstable by field-aligned currents, transversely heat the ion distributions via wave-particles interactions, creating the ion conics. Considered here are low-frequency oblique electrostatic instabilities found in a mixed plasma that includes an electron beam streaming through a background of electrons, H and O. The addition of O not only modifies the lower hybird frequency, but allows the existence of an ion-ion (Buchsbaum) hybrid mode with a frequency between the H and O gyrofrequencies. Because of its low frequency, the ion-ion hybrid instability can be effective in transversely heating heavy ions. When the electron beam drift speed is greater than 3 times the background electron thermal velocity and the electron gyrofrequency to plasma frequency ratio is less than 10, the lower hybrid instability dominates. However, for ratios greater than 20, which is a condition commonly found in the auroral-zone nightside region, the ion-ion instability has the largest growth rates; in these regions, heavy ion transverse heating can occur. When the ratio is between 10 and 20, the H to O density ratio determines which instability dominates.
This presentation describes power electronics thermal management technologies used for on-road EVs. Examples are provided and heat exchangers are described. Advanced cooling technologies developed are NREL to enable increased power density and enable high WBG temperature operation are then presented. The performance (e.g., thermal resistance, pumping power) of the advanced power electronics cooling technologies are compared to the performance of current, on-road technology.
This presentation describes power electronics thermal management technologies used for on-road EVs. Examples are provided and heat exchangers are described. Advanced cooling technologies developed are NREL to enable increased power density and enable high WBG temperature operation are then presented. The performance (e.g., thermal resistance, pumping power) of the advanced power electronics cooling technologies are compared to the performance of current, on-road technology.
We report on experimental investigation of thermal contact resistance, RC, of the noncuring graphene thermal interface materials with the surfaces characterized by different degree of roughness, Sq. It is found that the thermal contact resistance depends on the graphene loading, ξ, non-monotonically, achieving its minimum at the loading fraction of ξ ~15 wt%. Decreasing the surface roughness by Sq~1 μm results in approximately the factor of ×2 decrease in the thermal contact resistance for this graphene loading. The obtained dependences of the thermal conductivity, KTIM, thermal contact resistance, RC, and the total thermal resistance of the thermal interface material layer on ξ and Sq can be utilized for optimization of the loading fraction of graphene for specific materials and roughness of the connecting surfaces. Our results are important for the thermal management of high-power-density electronics implemented with diamond and other wide-band-gap semiconductors.
Thermal energy storage (TES) based on phase-change materials (PCMs) has many current and potential applications, such as climate control in buildings, thermal management for batteries and electronics, thermal textiles, and transportation of pharmaceuticals. Despite its promise, the adoption of TES has been limited, in part due to limited tunability of the transition temperature, which hinders TES performance for varying use temperatures. Transition temperature tuning of a material using an external stimulus, such as pressure or an electric field, typically requires very large stimuli. To circumvent this problem, here, we report on the dynamic transition temperature tunability of a PCM using ions. We achieve a transition temperature tunability up to 6°C in polyethylene glycol (PEG) by using the salt lithium oxalatodifluoroborate at a low voltage of 2.5 V, which may enable simpler and safer devices/system designs. We also explain the thermal properties of the salt/PCM solution using the Flory-Huggins theory.
Warm dense matter is a highly energetic phase characterized by strong correlations, thermal effects, and quantum mechanical electrons. Thermal density functional theory is commonly used in simulations of this challenging phase, driving the development of temperature-dependent approximations to the exchange–correlation free energy. Approaches using the adiabatic connection formula are well known at zero temperature and have been recently leveraged at non-zero temperatures as well. In this work, a generalized thermal adiabatic connection (GTAC) formula is proposed, introducing a fictitious temperature parameter. This allows extraction of the exchange–correlation entropy S XC using simulated interaction strength scaling. Here, this procedure uses a Hellmann–Feynman approach to express the exchange–correlation entropy in terms of a temperature- and interaction strength-dependent exchange–correlation potential energy. In addition, analysis of S XC as a function of interaction strength suggests new forms for approximations, and GTAC itself offers a new framework for exploring both the exact and approximate interplay of temperature, density, and interaction strength across a wide range of conditions.
The equations giving the response of a slightly ionized plasma with monatomic components to sinusoidal perturbations have been formulated. Included in the model equations were the electron Hall effect, electron thermal diffusion, radiation, and electron-atom rate processes. Plasma conditions were limited to those where viscous effects, the induced magnetic field, ion slip, and atom-atom inelastic processes can be neglected. Presented are results of numerical calculations for MHD generators with a working fluid of potassium seeded argon.
The quiet north polar cleft at 1400 km was studied by Isis-2 instruments, and data from the retarding potential analyzer and the cylindrical electrostatic probe show that thermal plasma density fluctuations are distributed in a region between 75 deg and 82 deg invariant latitude and approximately dawn to dusk. Cleft shape and shape variations are described. Thermal ions and thermal electrons usually fluctuated together, but suprathermal electrons fluctuated independently. Data on thermal plasma patterns correlates fairly well with observations of soft particles and auroral optical emissions and not as well with measurements of high-energy particles. The data suggest that the energy source for the thermal irregularities is associated with soft particles and that precipitating high-energy particles do not drive the thermal plasma at these altitudes.
We find a strong correlation between the kinetic energies (KEs) of the coronal mass ejections (CMEs) and the radiated energies of the associated solar flares for the events that occurred during the period of intense solar activity between 18 October and 08 November 2003. CME start times, speeds, mass and KEs were taken from Gopalswamy et al. (2005), who used SOHO/LASCO observations. The GOES observations of the associated flares were analyzed to find the peak soft X-ray (SXR) flux, the radiated energy in SXRs (L(sub sxR)), and the radiated energy from the emitting plasma across all wavelengths (L(sub hot)). RHESSI observations were also used to find the energy in non-thermal electrons, ions, and the plasma thermal energy for some events. For two events, SORCE/TIM observations of the total solar irradiance during a flare were also available to give the total radiated flare energy (L(sub total)).W e find that the total flare energies of the larger events are of the same order of magnitude as the CME KE with a stronger correlation than has been found in the past for other time intervals.
We find a strong correlation between the kinetic energies (KEs) of the coronal mass ejections (CMEs) and the radiated energies of the associated solar flares for the events that occurred during the period of intense solar activity between 18 October and 08 November 2003. CME start times, speeds, mass, and KEs were taken from Gopalswamy et al. (2005), who used SOHO/LASCO observations. The GOES observations of the associated flares were analyzed to find the peak SXR flux, the radiated energy in SXRs (L(sub sxr)), and the radiated energy from the SXR emitting plasma across all wavelengths (L(sub hot)). RHESSI observations were also used to find the energy in non-thermal electrons, ions, and the plasma thermal energy for some events. For two events, SORCE/TIM observations of the total solar irradiance during a flare were also available to give the total radiated flare energy (L(sub total)). We find that the total flare energies of the larger events are of the same order of magnitude as the CME KE with a stronger correlation than has been found in the past for other time intervals. The following rule-of-thumb (good to an order of magnitude for the larger events} can be used to relate flare and CME energies: CME KE ~ l(sub total) ~ 10 L(sub hot) ~ 100 L(sub SXR).
Electron thermal conductivity of non-ideal metals, taking into account arbitrary change and amplitude of electron scattering on ions and phonon spectra deformation by impurities
The next generation of integrated power electronics packages will implement wide-bandgap devices with ultrahigh device heat fluxes. Although jet impingement has received attention for power electronics thermal management, it is not used in commercial electric vehicles (EVs) because of the associated pressure drop and reliability concerns. Here, in this paper, we present a modular thermal management system designed for automotive power electronics. The system achieves superior thermal performance to benchmarked EVs, while adhering to reliability standards and with low pumping power. The system utilizes a low-cost and lightweight plastic manifold to generate jets over an optimized heat sink, which is embedded in the direct-bonded-copper (DBC) substrate. The embedded heat sink concept leverages additive manufacturing to add elliptical pin fins to the DBC substrate. The heat sink geometry is optimized for submerged jet impingement using a unit-cell model and an exhaustive search algorithm. The model predictions are validated using unit-cell experiments. A full-scale power module model is then used to compare the DBC-embedded heat sink against direct DBC cooling and baseplate-integrated heat sinks for single-sided (SS) and double-sided (DS) cooling concepts. Using the SS and DS DBC-embedded cooling concepts, the models predict a thermal resistance that represents a reduction of 75% and 85% compared to the 2015 BMW i3, respectively, for the same water-ethylene glycol inverter flow rate. We have shown that an inverter with a 100-kilo-Watt-per-liter power density is achievable with the proposed design.
Peculiar electron-phonon interaction characteristics underpin the ultrahigh mobility, electron hydrodynamics, superconductivity, and superfluidity observed in graphene heterostructures. Here, the Lorenz ratio (L) between the electronic thermal conductivity and the product of the electrical conductivity and temperature provides unique insight into electron-phonon interactions that is inaccessible to past graphene measurements. Here we show an unusual L peak in degenerate graphene near 60 Kelvin and decreased peak magnitude with increased mobility. When combined with ab initio calculations of the many-body electron-phonon self-energy and analytical models, this experimental observation reveals that broken reflection symmetry in graphene heterostructures can relax a restrictive selection rule to allow quasielastic electron coupling with an odd number of flexural phonons, contributing to the increase of L toward the Sommerfeld limit at an intermediate temperature sandwiched between the low-temperature hydrodynamic regime and the inelastic electron-phonon scattering regime above 120 Kelvin. In contrast to past practices of neglecting flexural phonon contributions to transport in two-dimensional materials, this work suggests that tunable electron-flexural phonon coupling can provide a handle to control quantum matter at the atomic scale, such as magic angle twisted bilayer graphene where low-energy excitations may mediate Cooper pairing of flat-band electrons.
A challenging aspect of the description of a tokamak disruption is evaluating the hot tail runaway electron seed that emerges during the thermal quench. This problem is made challenging due to the requirement of describing a strongly non-thermal electron distribution, together with the need to incorporate a diverse range of multiphysics processes, including magnetohydrodynamic instabilities, impurity transport, and radiative losses. Here this work develops a physics-informed neural network (PINN) tailored to the solution of the hot tail seed during an axisymmetric thermal quench. Here, a PINN is developed to identify solutions to the adjoint relativistic Fokker–Planck equation in the presence of a rapid quench of the plasma's thermal energy. It is shown that the PINN is able to accurately predict the hot tail seed across a range of parameters, including the thermal quench timescale, initial plasma temperature, and local current density, in the absence of experimental or simulation data. The hot tail PINN is verified by comparison with direct Monte Carlo simulations, with excellent agreement found across a broad range of thermal quench conditions.
A case study of a pulsating auroral event imaged optically at high time resolution presents direct observational evidence in agreement with the interhemispheric electron bouncing predicted by the Super Thermal Electron Transport model. Pulsation-on times are identified and subsequent equally spaced fainter pulsations are also noted and can be explained by a portion/percentage of the primary precipitating electrons reflecting upward from the ionosphere, traveling to the opposite hemisphere and reflecting upward again. The high time resolution of these data, combined with the short duration of the pulsation-on time (approx. 1 s) and the relatively long spacing between pulsations (approx. 6 to 9 s) made it possible to observe the faint optical pulses caused by the reflected electrons coming from the opposite hemisphere.