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At least 163 records · Page 9

Metallurgical and Thermal Properties of 57Ni-40Ti-3Hf (wt%)

Selected properties of 57Ni-40Ti-3Hf (wt%) were measured to further develop this material for use in aerospace rolling-element bearings. The average grain size and microindentation hardness of the material at room temperature were 90 μm and 549 HV, respectively. From room temperature to 500 °C, electrical resistivity increased from 8.9×10–7 to 11.3×10–7 Ω⋅m, thermal expansion coefficients varied from 1.1×10–5 to 1.2×10–5 mm/mm⋅°C, specific heat increased from 0.44 to 0.53 W⋅sec/g⋅K, thermal diffusivity rose from approximately 0.003 to 0.005 cm2/sec and thermal conductivity increased from approximately 0.09 to 0.19 W/cm⋅K. The behavior of the material can be explained by well-known metallurgical theory. These results are expected to provide a basis for design and modeling of future aerospace components.

rule of mixtures↗

Study of beryllium and beryllium-lithium complexes in single-crystal silicon.

When beryllium is thermally diffused into silicon, it gives rise to acceptor levels 191 and 145 meV above the valence band. Quenching and annealing studies indicate that the 145-meV level is due to a more complex beryllium configuration than the 191-meV level. When lithium is thermally diffused into a beryllium-doped silicon sample, it produces two new acceptor levels at 106 and 81 meV. Quenching and annealing studies indicate that these new levels are due to lithium forming a complex with the defects responsible for the 191- and 145-meV beryllium levels, respectively. Electrical measurements imply that the lithium impurity ions are physically close to the beryllium impurity atoms. The ground state of the 106-meV beryllium-lithium level is split into two levels, presumably by internal strains. Tentative models are proposed to explain these results.

Crouch, R. K.↗

A study of beryllium and beryllium-lithium complexes in single crystal silicon

When beryllium is thermally diffused into silicon, it gives rise to acceptor levels 191 MeV and 145 meV above the valence band. Quenching and annealing studies indicate that the 145-MeV level is due to a more complex beryllium configuration than the 191-MeV level. When lithium is thermally diffused into a beryllium-doped silicon sample, it produces two acceptor levels at 106 MeV and 81 MeV. Quenching and annealing studies indicate that these levels are due to lithium forming a complex with the defects responsible for the 191-MeV and 145-MeV beryllium levels, respectively. Electrical measurements imply that the lithium impurity ions are physically close to the beryllium impurity atoms. The ground state of the 106-MeV beryllium level is split into two levels, presumably by internal strains. Tentative models are proposed.

Crouch, R. K.↗

Heat-Pulse Measurements Reveal Fiber Volume Fractions

Measurements of thermal diffusivities by heat-pulse method constitutes basis of noncontact, nondestructive method of determining fiber volume fractions (FVFs) of samples of composite (matrix/fiber) materials. Modulated radiant heat applied to sample, while resulting modulated infrared emitted is monitored. Phase shift between two modulations indicative of thermal diffusivity and fiber volume fraction of sample. Testing method takes less time, provides data to characterize sample through its thickness, and amenable to scanning for global determination of gradual spatial variations in FVF along sample.

Winfree, William P.↗

Analysis of opposed-jet hydrogen-air counter flow diffusion flame

An opposed-jet counterflow diffusion-flame configuration is considered for the analysis of a nitrogen-diluted hydrogen-air diffusion flame. A boundary-layer similarity solution is employed in order to reduce the governing equations to a set of equations in one independent variable. The equation set is written in the time-dependent form and solved by the finite-volume time-marching technique. This model uses detailed chemistry and accounts for the variations of Prandtl number and Lewis number as well as the effect of thermal diffusion on the flame. It is noted that a one-step model can predict several features of the flame, while the detailed-chemistry model can be used for fine-tuning the results. The present results indicate that thermal diffusion has negligible effect on the characteristics of the flame.

Ho, Y. H.↗

Influence of mass diffusion on the stability of thermophoretic growth of a solid from the vapor phase

The stability of solid planar growth from a binary vapor phase with a condensing species dilute in a carrier gas is examined when the ratio of depositing to carrier species molecular mass is large and the main diffusive transport mechanism is thermal diffusion. It is shown that a deformation of the solid-gas interface induces a deformation of the gas phase isotherms that increases the thermal gradients and thereby the local mass deposition rate at the crests and reduces them at the valleys. The initial surface deformation is enhanced by the modified deposition rates in the absence of appreciable Fick/Brownian diffusion and interfacial energy effects.

Castillo, J. L.↗

Thermophysical properties of foodstuffs

Minimum overall nutritional deterioration of foodstuffs is generally attained by maximizing the rate of heat input and minimizing the duration of heating. Measurement of thermophysical data for foodstuffs is discussed in terms of specific heat, latent energy, enthalpy, thermal conductivity, thermal diffusivity, and density. Since phase change in foodstuffs occurs over a temperature range rather than at a discrete temperature, enthalpy is preferred over sensible and latent energy measurements as it can be used to fix the state of a sample very accurately; also, in the fusion process there is no precise way of separating sensible and latent energies. The first step in determining property data for foodstuffs is to describe the material in conventionally accepted terms. Future work should be concentrated in the area of thermal diffusivity and enthalpy measurements.

Witte, L. C.↗

Ion temperature anisotropy and heat flow in the Venus lower ionosphere

Motivated by the recent observations of supersonic ion flow in the Venus ionosphere near the terminator, the paper studies the extent to which such a flow can induce an ion temperature anisotropy and a diffusion-thermal heat flow. Calculations indicate that appreciable ion temperature anisotropies can be induced at altitudes below about 220 km. The temperature anisotropy is with respect to the ion-neutral relative drift velocity vector, with the ion temperature parallel to the relative drift velocity greater than the perpendicular ion temperature. The parallel to perpendicular ion temperature ratio is likely to be in the range of from 2 to 4, depending on the ionospheric conditions. It is also found that in the same ionospheric region the ion neutral relative drift induces a diffusion-thermal heat flow that is considerably more important than ordinary ion thermal conduction.

Schunk, R. W.↗

Space processing of electronic materials

The relative values of thermal conductivity of solid and liquid HgCdTe are critically important in the design configuration of the furnaces used for Bridgman crystal growth. The thermal diffusivity of the material is closely linked to the conductivity by the defining relation D = k/rho c, where D is the diffusivity, K is the thermal conductivity, rho is the density, and c is the specific heat. The use of transient and periodic heating approaches to measure the diffusivity are explored. A system for securing and extracting heat from silica or glass tubes under high C vacuum conditions is described.

Workman, G. L.↗

Thermal conductivity and diffusivity of Apollo 15 fines at low density

The thermal conductivity of the Apollo 15 fines, sample 15031,38, was measured under vacuum conditions as a function of temperature. Measurements were made for a sample density of 1300 kg/cu m. The conductivity was found to vary from about .00057 W per m per K at 95 K to about .00136 W per m per K at 406 K. The data are compared with the correlation using a cubic temperature dependence and also with data from samples gathered during prior Apollo missions. The thermal diffusivity is obtained for the sample by calculation using the given density and measured thermal conductivity along with specific heats from the literature.

Cremers, C. J.↗

Modified Laser Flash Method for Thermal Properties Measurements and the Influence of Heat Convection

The study examined the effect of natural convection in applying the modified laser flash method to measure thermal properties of semiconductor melts. Common laser flash method uses a laser pulse to heat one side of a thin circular sample and measures the temperature response of the other side. Thermal diffusivity can be calculations based on a heat conduction analysis. For semiconductor melt, the sample is contained in a specially designed quartz cell with optical windows on both sides. When laser heats the vertical melt surface, the resulting natural convection can introduce errors in calculation based on heat conduction model alone. The effect of natural convection was studied by CFD simulations with experimental verification by temperature measurement. The CFD results indicated that natural convection would decrease the time needed for the rear side to reach its peak temperature, and also decrease the peak temperature slightly in our experimental configuration. Using the experimental data, the calculation using only heat conduction model resulted in a thermal diffusivity value is about 7.7% lower than that from the model with natural convection. Specific heat capacity was about the same, and the difference is within 1.6%, regardless of heat transfer models.

Lin, Bochuan↗

Characterization and durability testing of plasma-sprayed zirconia-yttria and hafnia-yttria thermal barrier coatings. Part 1: Effect of spray parameters on the performance of several lots of partially stabilized zirconia-yttria powder

Initial experiments conducted on thermal barrier coatings prepared in the newly upgraded research plasma spray facility and the burner rig test facilities are discussed. Part 1 discusses experiments which establish the spray parameters for three baseline zirconia-yttria coatings. The quality of five similar coating lots was judged primarily by their response to burner rig exposure supplemented by data from other sources such as specimen characterizations and thermal diffusivity measurements. After allowing for burner rig variability, although there appears to be an optimum density (i.e., optimum microstructure) for maximum burner rig life, the distribution tends to be rather broad about the maximum. In Part 2, new hafnia-yttria-based coatings were evaluated against both baseline and alternate zirconia-yttria coatings. The hafnia-yttria coatings and the zirconia-yttria coatings that were prepared by an alternate powder vendor were very sensitive to plasma spray parameters, in that high-quality coatings were only obtained when certain parameters were employed. The reasons for this important observation are not understood. Also not understood is that the first of two replicate specimens sprayed for Part 1 consistently performed better than the second specimen. Subsequent experiments did not display this spray order affect, possibly because a chiller was installed in the torch cooling water circuit. Also, large changes in coating density were observed after switching to a new lot of electrodes. Analyses of these findings were made possible, in part, because of the development of a sensitive density measurement technique described herein in detail. The measured thermal diffusivities did not display the expected strong relationship with porosity. This surprising result was believed to have been caused by increased microcracking of the denser coatings on the stainless steel substrates.

Miller, Robert A.↗

Modified MEE Industries static thermal gradient diffusion cloud chamber

The experiments performed at the Workshop were undertaken to confirm the calculated sample volume, determine the usable range of supersaturation, and minimum detectable size. Comparison of absolute CCN concentrations with other state-of-the-art continuous flow diffusion chambers at supersaturations near 1 percent indicated that the volume used produced CCN concentrations well within the range of CCN concentrations determined at the workshop. This agreement is interpreted to mean the sample volume was correct. Direct measurements of the beam geometry done in the laboratory indicated a factor of 4-5 error. This error is apparently due to the larger apparent visible beam diameter versus the actual usable beam diameter given the droplet illumination, chamber optical geometry, microscope optics and film characteristics.

Borys, R. D.↗

Ionospheric hot spot at high latitudes

Schunk and Raitt (1980) and Sojka et al. (1981) have developed a model of the convecting high-latitude ionosphere in order to determine the extent to which various chemical and transport processes affect the ion composition and electron density at F-region altitudes. The numerical model produces time-dependent, three-dimensional ion density distributions for the ions NO(+), O2(+), N2(+), O(+), N(+), and He(+). Recently, the high-latitude ionospheric model has been improved by including thermal conduction and diffusion-thermal heat flow terms. Schunk and Sojka (1982) have studied the ion temperature variations in the daytime high-latitude F-region. In the present study, a time-dependent three-dimensional ion temperature distribution is obtained for the high-latitude ionosphere for an asymmetric convection electric field pattern with enhanced flow in the dusk sector of the polar region. It is shown that such a convection pattern produces a hot spot in the ion temperature distribution which coincides with the location of the strong convection cell.

Schunk, R. W.↗

Steady-state thermal-solutal diffusion in a float zone

A model for a float zone in a thin vertical sheet is used to study the formation of the zone configuration for both pure and binary systems of Si and GeGa. Equations describing the steady two-dimensional diffusion of solute in the melt and diffusion of heat in the feed material and the product crystal are presented. The material properties, asymptotic solutions for the temperature and concentration profiles, and melting, solidifying, and melt/gas interfacial shapes are determined in the small aspect ratio limit.

Young, G. W.↗

Constraints on the thermal evolution of Venus inferred from Magellan data

The impact craters with diameters from 1.5 to 280 km compiled from Magellan observations indicate that the crater population on Venus has a completely spatially random distribution and the size/density distribution of craters with diameters greater than or equal to 35 km is consistent with a 'production' population with an age of 500 plus or minus 250 m.y. The similarity in size distribution from area to area indicates that the crater distribution is independent of crater size. Also, the forms of the modified craters are virtually identical to those of the pristine craters. These observations imply that Venus reset its cratering record by global resurfacing 500 m.y. ago, and resurfacing declined relatively fast. The fact that less than 40 percent of all craters have been modified and that the few volcanically embayed craters are located on localized tectonic regions indicate that only minor and localized volcanism and tectonism have occurred since the latest vigorous resurfacing event approximately 500 m.y. ago and the interior of Venus has been solid and possibly colder than Earth's. This is because the high-temperature lithosphere of Venus would facilitate upward ascending of mantle plumes and result in extensive volcanism if the venusian upper mantle were as hot as or hotter than Earth's. Therefore, the present surface morphology of Venus may provide useful constraints on the pattern of that vigorous convection, and possibly on the thermal state of the venusian mantle. We examine this possibility through numerical calculations of three-dimensional thermal convection models in a spherical shell with temperature- and pressure-dependent Newtonian viscosity, temperature-dependent thermal diffusivity, pressure-dependent thermal expansion coefficient, and time-dependent internal heat production rate solar magnitude.

Arkani-Hamed, Jafar↗