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At least 163 records · Page 9

Air Pollutant Emissions and Regulatory Implications of Co-Processing Raw Bio-Oil in U.S. Petroleum Refineries

Pyrolysis oil, often referred as bio-oil or biocrude, has attracted considerable attention because it has higher energy density and carbon content compared to the raw biomass. Using pyrolysis oil derived from low cost and underutilized biomass to produce renewable hydrocarbon fuels provides a viable link between the agriculture/forestry and (petro-) chemical industry. Co-processing bio-oil with vacuum gas oil (VGO) in petroleum refinery is appealing due to the relatively low capital requirement to retrofit refinery and the compatibility of fuel products with existing infrastructure. In order to implement co-processing, a petroleum refinery would need to consider several process modifications and therefore could be subject to varying levels of air permitting requirements based on bio-oil co-processing ratio, co-processing capacity in existing units, the amount of regulated pollutants expected to be emitted, among other factors. This analysis considers co-processing 5% (by weight) of raw bio-oil with VGO in the fluidized catalytic cracking (FCC) unit(s) in a petroleum refinery. We estimate the potential increase in emissions of regulated air pollutants resulting from the modifications required to implement bio-oil co-processing and evaluate the regulatory and permitting implications for three FCC size categories in the U.S. refineries, which could co-processes raw bio-oil to produce partially renewable transportation fuels. We also assess technically feasible emission control options petroleum refineries could adopt to avoid being subject to major source permitting requirements if the estimated increase in regulated air pollutant emission exceeds the applicable threshold for major modifications. Insights from our analysis can help overcome challenges and risks associated with timely obtaining air permits required to implement bio-oil co-processing in existing refineries. Our analysis also provides needed information for decision makers (e.g., local air quality agencies) to understand the potential air quality implications for retrofitting refineries to co-process bio-oil, particularly in areas with high concentration of petroleum refineries.

09 BIOMASS FUELS↗

Hierarchical Resilience Planning for Networked Microgrids: A Case Study of Puerto Rico

Microgrids can be designed to enhance the energy resilience of communities and critical infrastructures, such as hospitals, data centers, and communication networks, which are vulnerable to frequent weather-related disruption. Coordinating multiple microgrids in a network can leverage the geographical diversity of load and generation resources while enabling resilient and cost-effective planning of the distribution system. Designing a networked microgrid is complex, involving intricate technical assessment, cost-benefit analysis, site-specific requirements, and the evaluation of existing resources. Therefore, this paper proposes a hierarchical resilience planning framework and performs an extensive techno-economic analysis for the design of a networked microgrid. Hierarchical resilience planning involves technology sizing at an individual community level to meet the critical load and satisfy resilience criteria, and resource optimization at networked microgrid level to provide a higher level of resilience and energy adequacy. A real-world case of Puerto Rico's cooperative microgrid “Microrred de la Montaña” is investigated considering localized electricity tariffs, site-specific demand profiles, solar generation, and existing hydro resources. Multiple optimization scenarios are developed based on the resiliency requirement to estimate the capacity of solar photovoltaic and battery energy storage (BES) to be installed at each substation. The results provide the optimal sizing for individual community and networked microgrid to withstand 1day and 3-day outages along with the criteria for critical load.

13 - HYDRO ENERGY↗

Equipment Assessment Guide: A Technical Inspection and Hardening Guide for Devices in Power Grid Operations

This Equipment Assessment Guide, developed by Idaho National Laboratory (INL), provides a comprehensive framework designed to enhance the security of operational technology (OT) devices within power grid operations. The guide outlines essential steps for asset owners to conduct technical inspections and harden vulnerable hardware and firmware components commonly found in embedded systems. It focuses on components frequently targeted by cyber threats, offering valuable identification techniques for locating and recognizing critical components on devices. Additionally, the guide presents recommended secure configurations aimed at minimizing exposure and reinforcing defenses, along with impact analysis that highlights the potential consequences for grid operations if components are compromised. By implementing the recommendations outlined in this guide, asset owners can significantly enhance their cybersecurity posture, reduce the attack surface of field-deployed devices, and improve the resilience of grid services against emerging cyber threats.

42 - ENGINEERING↗

Technical and economic assessment of processes for the production of butanol and acetone

This report represents a preliminary technical and economic evaluation of a process which produces mixed solvents (butaol/acetone/ethanol) via fermentation of sugars derived from renewable biomass resources. The objective is to assess the technology of producing butanol/acetone from biomass, and select a viable process capable of serving as a base case model for technical and economic analysis. It is anticipated that the base case process developed herein can then be used as the basis for subsequent studies concerning biomass conversion processes capable of producing a wide range of chemicals. The general criteria utilized in determining the design basis for the process are profit potential and non-renewable energy displacement potential. The feedstock chosen, aspen wood, was selected from a number of potential renewable biomass resources as the most readily available in the United States and for its relatively large potential for producing reducing sugars.

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Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) (Technical Reference Manual V.4)

The HyRAM+ software toolkit provides a basis for conducting quantitative risk assessment and consequence modeling for hydrogen, methane, and propane infrastructure and transportation systems. HyRAM+ is designed to facilitate the use of state-of-the-art science and engineering models to conduct robust, repeatable assessments of safety, hazards, and risk. HyRAM+ includes generic probabilities for equipment failures, probabilistic models for the impact of heat flux on humans and structures, and experimentally validated first-order models of release and flame physics. HyRAM+ integrates deterministic and probabilistic models for quantifying accident scenarios, predicting physical effects, and characterizing hazards (thermal effects from jet fires, overpressure effects from delayed ignition), and assessing impact on people and structures. HyRAM+ is developed at Sandia National Laboratories to support the development and revision of national and international codes and standards. HyRAM+ is a research software in active development and thus the models and data may change. This report will be updated at appropriate developmental intervals. This document provides a description of the methodology and models contained in HyRAM+ version 4.0. The most significant change for HyRAM+ version 4.0 from HyRAM version 3.1 is the incorporation of other alternative fuels, namely methane (as a proxy for natural gas) and propane into the toolkit. This change necessitated significant changes to the installable graphical user interface as well as changes to the back-end Python models. A second major change is the inclusion of physics models for the overpressure associated with the delayed ignition of an unconfined jet/plume of flammable gas.

02 PETROLEUM↗

Parcel-Scale Assessment of Rooftop Solar Technical Potential

Understanding the potential for rooftop solar and other distributed energy resources (DERs) to contribute to power system planning is increasingly relevant for cities, utilities, and other planning entities. Such planning efforts typically require an estimate of technical potential, or the feasible technology potential independent of economic considerations. Currently, best-in-class rooftop solar technical potential methods use Light Detection and Ranging (LiDAR) data which can identify each roof plane tilt, azimuth, and unshaded area. However, LiDAR data is not universally available and, even when available, obtaining and processing this data can be expensive. In contrast, parcel-level data is easy to use and widely available as it is generated by jurisdictions to levy property taxes. Such data universally reports building footprint area, which is highly correlated with roof area suitable (developable) for rooftop solar. Moreover, parcel data identifies building end-use, tenure, and other building characteristics not provided by LiDAR. To explore the feasibility of using parcel data to assess technical potential more broadly, we compare estimates using parcel data in Orlando, Florida (HIFLD 2020) to those generated using LiDAR data (Koebrich et al. 2021). We find that the parcel-based method results in accurate technical potential estimates at a block and city-scale, though only after accounting for shading and other factors that derate developable roof area. The results of this study demonstrate a scalable, low-effort approach to assess rooftop solar technical potential for every city and community in the U.S.

census blocks↗

Technical and Economic Assessment and Gap Analysis of Advanced Nuclear Reactor Integration with a Reference Oil Refinery

Efforts to identify the most-economic methods to decarbonize several sectors of the U.S. economy are underway. Industrial processes such as crude-oil refining rely heavily on energy-dense and easily stored and transported fossil fuels for powering their operations. Refineries use large amounts of energy, primarily derived from fossil sources to separate crude-oil components, break down heavier hydrocarbons into lighter compounds, remove impurities, reform hydrocarbon molecules, and generate steam and electricity for pumps and compressors and other various auxiliary systems. Crude-oil refining operations such as distillation, cracking, desulfurization, reforming, utilities systems and some offsite facilities collectively account for most of the energy consumption. Other operations such as hydrocracking or hydrotreating also require hydrogen for developing hydrogenation reactions which involve substantial heating to keep the reactors at high-temperature and pressure levels. All heat and energy demands are typically provided by natural gas (NG), oil, or other fuels, which makes refinery industry one of the most-difficult sectors to decarbonize. Nuclear power is a viable and energy-dense source of clean electricity, heat, and hydrogen to provide the large, sustainable energy supply that the refining industry demands. The U.S. Department of Energy’s (DOE’s) Integrated Energy Systems (IES) program is working to perform research and development, design, economic siting, and risk analysis. This state-of-the-art work will enable the first on-site demonstrations and commercial deployments of advanced small modular nuclear reactors (SMNRs) integrated with industries such as chemical production, refining, iron and steel making, and more. IES seeks to demonstrate the ability of advanced nuclear reactors to meet the heat and power demands of these industries while reducing carbon emissions in a sustainable and cost-competitive way. The primary objective of this research effort is to analyze industrial-scale SMNR integration intended to decarbonize refining facilities. The foreseen outcome is the provision of reliable, cost-competitive, and sustainable clean energy, alongside a reduction of carbon emissions. Specifically, the focus of this work lies on meeting the reference facilities’ heat and electricity demands with nuclear power while also supplying clean hydrogen via integrated high-temperature steam electrolysis (HTSE). This report presents a comprehensive technical and economic assessment of the integration of advanced nuclear reactors into a reference refinery, leveraging financial incentives from the Inflation Reduction Act (IRA). The evaluation aims to explore the potential economic benefits and challenges associated with incorporating advanced nuclear reactors into refinery operations, particularly in terms of energy efficiency, economic implications and environmental impact. By examining both the technical feasibility and economic viability, this analysis seeks to identify existing gaps and propose solutions for successful nuclear integration implementation. The findings are intended to provide valuable insights for stakeholders considering the adoption of advanced nuclear reactors in the refining sector. A refinery reference-plant was developed, using an open-source refinery model, Petroleum Refinery Lifecycle Inventory Model (PRELIM) and expert assessment, as a base case for comparison with various nuclear integration options. The capacity of 100 kbd/day (KBD) of heavy crude-oil feed was selected to represent a general coking-type refinery with deep conversion capabilities (incorporating heavy-oil upgrading with FCC, coking, and associated hydrotreating process units), using a heavy crude-oil feed, which represents about 70% of U.S. refineries configurations. A summary of all cases considered in this study is shown in Table 1.

13 HYDRO ENERGY↗

Satellite power system: Concept development and evaluation program. Volume 3: Power transmission and reception. Technical summary and assessment

Efforts in the DOE/NASA concept development and evaluation program are discussed for the solar power satellite power transmission and reception system. A technical summary is provided together with a summary of system assessment activities. System options and system definition drivers are described. Major system assessment activities were in support of the reference system definition, solid state system studies, critical technology supporting investigations, and various system and subsystem tradeoffs. These activities are described together with reference system updates and alternative concepts for each of the subsystem areas. Conclusions reached as a result of the numerous analytical and experimental evaluations are presented. Remaining issues for a possible follow-on program are identified.

Dietz, R. H.↗

A Method for Assessing Effectiveness and Technical Capabilities Required for Integrated Deterrence (NSLP-Final Report-Draft2022)

The United States faces an ever-increasingly multi-polar security environment dominated by great power competition with China and a lingering Russian threat as well as from would-be regional hegemons led by ambitions from Iran and North Korea. Our adversaries are pursuing and expanding the strategic means by-which they have an asymmetric offset (e.g., cyber, space, and other modes below the level of armed conflict). To combat and deter against the widening range of hostile actions, the U.S. must have additional capabilities with-which to deter. All of which drives us towards a more thoughtful integrated approach to deterrence, attempting to best align deterrent tools with the adversary actions in order to maximize the credibility of our deterrent. Such an approach complicates our deterrence strategy and demands a methodology to assess whether the U.S. has the deterrent tools necessary to deter the adversarial actions most costly to the U.S. To address this complexity, we create a framework to comprehensively and systematically assess our deterrent tools as qualitatively measured against the adversarial actions we wish to deter. Deterrence is ultimately an operation in the cognitive domain and at the heart of the framework presented here is the fundamental deterrence calculus which we use as the defining measure of whether a tool will credibly deter a given action. We describe the eight levers of the deterrence calculus and distill these levers to four products that are used to qualitatively assess the overall effectiveness of deterrence tools against adversarial actions. Credibility is determined by two principal variables: the technical credibility of the deterrent tool, and the principle of proportionality. Technical credibility of realized deterrence products is assessed through development of key mission requirements and hardware (e.g., components) that will impose costs, deny benefits, or encourage restraint. The principle of proportionality qualitatively asserts that for a deterrent tool to be cognitively credible, the costs imposed against, or benefits denied by, an action are commensurate to the magnitude of costs received from the adversarial action. By basing this framework on these two fundamentals, it is possible to compare deterrent tools in a systematic approach across the broad spectrum of hostile actions.

42 ENGINEERING↗

Multi factor Assessment for Decarbonization via Technically Viable Carbon Storage

Final poster presenting research under EDX4CCS portfolio, Task 21, on multi-factor assessment for technically viable carbon storage. To date, carbon storage viability assessments have focused on the technically recoverable storage resources to estimate the volume of carbon storage in reservoirs targeted for geologic carbon sequestration. The Carbon Storage Technical Viability Approach (CS TVA) was developed to account for all factors determining the viability of carbon storage at a given site, including socioeconomic and environmental aspects in addition to the classic subsurface geologic assessment. Abstract accepted to the American Geophysical Union Fall Meeting 2023.

Mark-Moser, Mackenzie K.↗

Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) Technical Reference Manual (V.6.0)

The HyRAM+ software is an open-source toolkit that provides publicly available models and default input values to enable straightforward and consistent safety assessments for hydrogen and other alternative fuel systems, such as natural gas and propane. The HyRAM+ quantitative risk assessment calculation incorporates annual likelihood of leaks or failures for both compressed gaseous and liquefied flammable fuels, as well as probabilistic models for the effects of heat flux and overpressure. HyRAM

08 HYDROGEN↗

Midwest Industrial Assessment Center (Final Technical Report)

The Midwest IAC’s prime center was at the University of Missouri (MU) and the satellite center was at Wichita State University, Kansas. During the 5-year period we conducted at least 96 energy assessments, with recommended energy cost savings of $10.3 million of which $6.5 million was implemented savings. The implemented energy savings were 0.63 Terra BTU and CO2 emissions reduction was 400,000 tons. Thirty-five students completed requirements for a certificate of completion from DOE. IAC students received training in cybersecurity basics and application to manufacturing, fundamentals of energy efficiency, ISO50001, smart manufacturing.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Technical and Economic Assessment of Span-Loaded Cargo Aircraft Concepts

The benefits are assessed of span distributed loading concepts as applied to future commercial air cargo operations. A two phased program is used to perform this assessment. The first phase consists of selected parametric studies to define significant configuration, performance, and economic trends. The second phase consists of more detailed engineering design, analysis, and economic evaluations to define the technical and economic feasibility of a selected spanloader design. A conventional all-cargo aircraft of comparable technology and size is used as a comparator system. The technical feasibility is demonstrated of the spanloader concept with no new major technology efforts required to implement the system. However, certain high pay-off technologies such as winglets, airfoil design, and advanced structural materials and manufacturing techniques need refinement and definition prior to application. In addition, further structural design analysis could establish the techniques and criteria necessary to fully capitalize upon the high degree of structural commonality and simplicity inherent in the spanloader concept.

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Los Alamos National Laboratory Floodplain Assessment for the Technical Area 8 to Technical Area 22 Natural Gas Line Replacement Project

The National Nuclear Security Administration (NNSA), a semi-autonomous agency within the U.S. Department of Energy (DOE), is proposing new construction that crosses through upper Pajarito Canyon and upper Starmer Canyon from Technical Area (TA) 8 to TA-22 at Los Alamos National Laboratory (LANL). The project proposes to install a new 12 inch natural gas line to replace the existing 70+ year old natural gas line. Replacement will prevent loss of service to several LANL TAs and Bandelier National Monument. The project activities within the 100- year floodplains include 1) new natural gas line installation to replace and existing aging gas line, 2) relocating a section of fence and 3) three construction equipment and materials storage areas. NNSA has prepared this floodplain assessment in accordance with 10 Code of Federal Regulations (CFR) Part 1022 Compliance with Floodplain and Wetland Environmental Review Requirements (10 CFR Part 1022) (CFR 2003) which was promulgated to implement DOE requirements under Executive Order 11988 Floodplain Management (EO 1977). A floodplain is defined in 10 CFR 1022 as “the lowlands adjoining inland and coastal waters and relatively flat areas and flood prone areas of offshore islands,” and a base floodplain as “the 100-year floodplain, that is, a floodplain with a 1.0 percent chance of flooding in any given year (CFR 2003).” This floodplain assessment evaluates potential impacts to floodplain values and functions from implementation of the proposed action, identifies alternatives to the Proposed Action, and allows for meaningful public comment.

54 ENVIRONMENTAL SCIENCES↗

A Technical and Economic Assessment of LWR Flexible Operation for Generation and Demand Balancing to Optimize Plant Revenue

With increased penetration of subsidized variable renewable energy (VRE) resources and competition from low natural gas prices, existing light water reactor (LWR) nuclear power plants (NPPs) are struggling to remain economically competitive. This work examines the potential economic competitiveness of various thermal energy storage (TES) technologies when coupled directly or indirectly with a NPP. To highlight their relative economic competitiveness, we contrast several energy storage solutions in stochastic dispatch optimization. We leverage data from recent work analyzing a range of TES technologies with varying capital costs, performance, and technology readiness level (TRL) to establish our case. We explore inserting these technologies into an electricity market with existing nuclear generation and large projected variable renewable energy (VRE) penetration. Although these technologies' projected capital costs may make them unlikely candidates in their current state, this analysis demonstrates a high-fidelity techno-economic analysis of energy storage. Furthermore, as the projected cost of energy storage technologies evolves, this analysis sets a precedent for similar future investigations. One region with projected trends that may be unfavorable for existing nuclear capacity is the New York Independent System Operator (NYISO) market. New York state’s baseload generation has been historically provided by fossil-fired and nuclear assets. However, amid economic pressures from subsidized VREs and low natural gas prices, the state has recently deactivated Indian Point nuclear power plant units 2 and 3. Furthermore, the state plans to meet its zero-emission generation target by 2040 by replacing fossil-fired capacity with significant investments in VRE resources like wind and solar photovoltaic (PV) and battery storage. Increased intermittent resource penetration lowers the baseload power requirement, adding further economic pressure to the state’s three remaining NPPs still in operation. With three NPPs still in operation in New York, this work analyzes potential economic benefits to NPPs on the New York grid when directly or indirectly coupled with various TES technologies. This work requires two modeling steps to analyze the potential economic benefits of various system configurations of the TES directly or indirectly coupled with nuclear. First, this analysis leverages capacity expansion modeling by experts at the Electric Power Research Institute (EPRI). Using their deterministic capacity expansion model, U.S. Regional Economy, Greenhouse Gas, and Energy (US-REGEN), EPRI analysts evaluated the capacity and generation evolution of the New York state energy market under four projection scenarios. These four projection scenarios were developed to represent the potential evolution of the capacity and generation in NYISO from 2015 to 2050 under various economic, technology, and policy constraints. The results from these capacity expansion models are then used as boundary conditions in the second modeling step. The second modeling step uses the Holistic Energy Resource Optimization Network (HERON) for a set of stochastic techno-economic analyses (STEAs) to investigate the potential increase in the economic viability of various configurations of the TES. With no current capacity expansion capabilities, HERON takes the data generated from US-REGEN for 2050 to generate synthetic load, solar, and wind data. Then HERON economically optimizes the capacity and dispatch of the various TES configurations. The potential economic benefit is the differential net present value (NPV) of the TES configurations from the no-TES baseline. As a stochastic techno-economic analysis package, HERON introduces uncertainty into the economic metrics, while US-REGEN trades resolution for reduced computational complexity. Using HERON also allows the modeling of direct thermal coupling, a feature not common in capacity and dispatch models. As expected, with high capital costs, the costs of introducing energy storage for all the technologies considered outweighed the potential economic benefit of this strategy for flexible plant operation. The benefit of this analysis is primarily in demonstrating a workflow that examines innovative solutions to increase NPP revenue via TES coupling. HERON’s stochastic capacity and dispatch optimization process used in this work has proven an effective tool in observing and evaluating the impact of introducing storage technologies in a grid energy system.

25 ENERGY STORAGE↗

Los Alamos National Laboratory Floodplain Assessment for the Technical Area 72 Outdoor Live Fire Range Safety Upgrades Project

The National Nuclear Security Administration (NNSA), a semi-autonomous agency within the U.S. Department of Energy (DOE), is proposing new construction and upgrade activities in lower Sandia Canyon at Technical Area (TA) 72 at the Outdoor Live Fire Range facility at Los Alamos National Laboratory (LANL). The proposed upgrades are intended to improve range safety to help fulfill the mission requirements of maintaining a trained and qualified armed Protective Force.

54 ENVIRONMENTAL SCIENCES↗

Los Alamos National Laboratory Floodplain Assessment for the Technical Area 72 Outdoor Live Fire Range Gate Installation Project

The National Nuclear Security Administration (NNSA), a semi-autonomous agency within the U.S. Department of Energy (DOE), is proposing new construction in lower Sandia Canyon at Technical Area (TA) 72 at the Outdoor Live Fire Range facility at Los Alamos National Laboratory (LANL). The proposed upgrades are intended to improve range safety.

54 ENVIRONMENTAL SCIENCES↗