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The physical and chemical processes at solid surfaces which can contribute to Space Station contamination problems are reviewed. Suggested areas for experimental studies to provide data to improve contamination modeling efforts are presented.
This work reports experiments on the catalytic interaction occurring between polycyclic aromatic hydrocarbon (PAH) molecules and TiO2 dust grain surfaces under vacuum conditions. The investigation sheds light on the potential catalytic pathways that TiO2 dust surfaces provide in the hydrogenation of PAH molecules and the chemistry that can be driven by PAH-dust interactions under vacuum conditions. Naphthalene, anthracene, and coronene were chosen as the PAH molecules, while titanium dioxide was selected as the dust analog. PAH samples and dust analog mixtures were studied under vacuum for 24 h while monitored via diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The acquired spectra show that PAH molecules are hydrogenated when in contact with TiO2 dust particles without the need for external energy or hydrogen sources. Our results suggest that linear PAHs undergo a similar hydrogenation process where the dominant species are fully hydrogenated PAHs. For larger condensed PAHs, the hydrogenation process yields partially hydrogenated molecules. Fully hydrogenated species can be identified by a band around 2960 per cm, while partially hydrogenated species produce a band around 2825 per cm. In the case of the production of hydrogenated species, our results suggest that the smaller the PAH, the faster the hydrogenation rate.
Electron paramagnetic resonance study of interaction between adsorbed nitric oxide and NaY and decationized Y zeolites surfaces, considering catalytic activity
The physical adsorption of nitrogen on the chemically cleaned surfaces of Pyrex, 347 stainless steel and polycrystalline nickel was investigated over the pressure range 1 x 10 to the minus 12th power to 3 x 10 to the minus 7th power torr and for temperatures 77.4 and 87.4 K. The adsorption data were linearized by the Dubinin-Radushkevich equation. The metal surfaces were cleaned by electron impact desorption (EID) and the desorbed gases analyzed by mass spectrometry. Work function measurements were also used to indicate changes in the surface condition following an EID dose. At least a monolayer of gas was observed to desorb from the metal surfaces. The isotherms revealed that the metal surfaces were very heterogeneous and that the Pyrex surface had been leached. The calculated isosteric heats of adsorption indicated that the relative order of the physical binding of nitrogen to the solids was 347 stainless steel Pyrex nickel. A relationship was observed to exist in the dynamic technique between the equilibration time and the pressure above the absorbed layer. The slope of the log-log plot of these parameters was found to be sensitive to the surface heterogeneity and may be related to the activation energy for surface diffusion of physically absorbed molecules.
Spacecraft of the future will be larger and have higher power requirements than any flown to date. For several reasons, it is desirable to operate a high power system at high voltage. While the optimal voltages for many future missions are in the range 500 to 5000 volts, the highest voltage yet flown is approximately 100 volts. The NASCAP/LEO code is being developed to embody the phenomenology needed to model the environmental interactions of high voltage spacecraft. Some plasma environment are discussed. The treatment of the surface conductivity associated with emitted electrons and some simulations by NASCAP/LEO of ground based high voltage interaction experiments are described.
An experiment was conducted to investigate the effect that a planar surface located near a jet flow has on the noise radiated to the far-field. Two different configurations were tested: 1) a shielding configuration in which the surface was located between the jet and the far-field microphones, and 2) a reflecting configuration in which the surface was mounted on the opposite side of the jet, and thus the jet noise was free to reflect off the surface toward the microphones. Both conventional far-field microphone and phased array noise source localization measurements were obtained. This paper discusses phased array results, while a companion paper discusses far-field results. The phased array data show that the axial distribution of noise sources in a jet can vary greatly depending on the jet operating condition and suggests that it would first be necessary to know or be able to predict this distribution in order to be able to predict the amount of noise reduction to expect from a given shielding configuration. The data obtained on both subsonic and supersonic jets show that the noise sources associated with a given frequency of noise tend to move downstream, and therefore, would become more difficult to shield, as jet Mach number increases. The noise source localization data obtained on cold, shock-containing jets suggests that the constructive interference of sound waves that produces noise at a given frequency within a broadband shock noise hump comes primarily from a small number of shocks, rather than from all the shocks at the same time. The reflecting configuration data illustrates that the law of reflection must be satisfied in order for jet noise to reflect off of a surface to an observer, and depending on the relative locations of the jet, the surface, and the observer, only some of the jet noise sources may satisfy this requirement.
A key capability required for the exploration of planetary bodies is the ability to land on the surface. Previous work performed by NASA and other institutions has primarily focused on landing small spacecraft on planetary surfaces and the associated small-to-medium thrusters required for the soft landing. In the case of human exploration—particularly the establishment of long duration exploration and habitation outposts—the ability to land large landers, such as the SpaceX Starship, is necessary. These larger landing systems require the use of more powerful engines, with higher engine exhaust temperatures and higher landing loads. Understanding the excavation of material by the engines, as well as the potential for the landing legs to sink into the subsurface, is key in ensuring reliable and safe landings. A further improvement in landing reliability can be achieved by constructing landing / launch pads, especially with in-situ resources. Some material excavation by the plume is inevitable, leaving at least a portion of the surface scoured and uneven under the lander and ejecting regolith particles and rocks at very high velocities. One possible solution would be to robotically build landing / launch pads (ideally autonomously) at the destination using in-situ materials. In this case, the first one or few landers will need to land on unimproved surfaces at higher risk; however, they would bring the required equipment to build the landing pads with mostly local resources, thus increasing the reliability of safe landing for subsequent larger landers. A number of methods to build in-situ landing and launch pads have already been developed. These methods include no, or some, addition of required binder additives to the local regolith material, different processing approaches and result in varying landing pad strengths. A sub-scale rocket engine plume, was used to simulate some of the conditions of a landing on the Moon to assess the effectiveness of various materials for an in-situ built landing pad, The GO2/GCH4rocket engine fired on a 1m2area coupons of representative pad materials. The results will allow continued development towards materials that satisfy the landing pad properties required for the effective risk reduction and increased reliability for landing people and equipment on the lunar surface. This work contained two parts: (1) computer modeling of a large rocket engine plume interacting with regolith on the Moon, using the Granular Gas Flow Solver (GGFS) provided by CFD Research Corporation as well as other computational fluid dynamics codes (CFD) such as Loci/CHEM. (2) Developing landing/launch pad materials that could be used for in-situ construction on the lunar surface in the future, to mitigate the calculated effects of a large vehicle rocket engine landing and launching on the Moon.
Lunar nightside electron fluxes were studied with the aid of the ALSEP/CPLEE and other instruments. The flux events were shown to be due to (a) electrons propagating upstream from the earth's bow shock, (b) electrons thermalized and scattered to the lunar surface by disturbances along the boundary of the lunar solarwind cavity, and (c) solar wind electrons scattered to the lunar surface by lunar limb shocks and/or compressional disturbances. These electrons were identified as a cause of the high night surface negative potentials observed in tha ALSEP/SIDE ion data. A study was also made of the shadowing of magnetotail plasma sheet electrons by interactions between the lunar body and the ambient magnetic field and by interactions between charged particles and lunar remnant magnetic fields. These shadowing effects were shown to modify lunar surface and near-lunar potential distributions.
New directions in tribology are described. A range of topics is addressed, extending from fundamental research on tribological materials of all kinds and their surface effects, to final technological applications in mechanical components such as bearings, gears, and seals. The general topics addressed include: importance and definition of materials in tribology; future directions of research in adhesion and friction, wear and wear-resistant materials, and liquid lubricants and additives; status and new directions in elastohydrodynamic lubrication and solid lubricants; and tribological materials for mechanical components of the future.
Examples are given of the accuracy of the results obtained from the HIRS 2/MSU (High Resolution Infrared Sounder and Microwave Sounding Unit) analysis of ocean, atmosphere, and land parameters. Sea surface temperatures are compared with available ship and buoy radiosonde data, and land surface temperatures are compared with shelter temperatures. The seasonal change in land and ocean skin surface temperature is reviewed. The distribution of clouds is examined and their opacities in the visible and infrared parts of the spectrum are compared.
For a number of candidate materials of construction for the dual air density explorer satellites the rate of oxygen atom loss by adsorption, surface reaction, and recombination was determined as a function of surface and temperature. Plain aluminum and anodized aluminum surfaces exhibit a collisional atom loss probability alpha .01 in the temperature range 140 - 360 K, and an initial sticking probability. For SiO coated aluminum in the same temperature range, alpha .001 and So .001. Atom-loss on gold is relatively rapid alpha .01. The So for gold varies between 0.25 and unity in the temperature range 360 - 140 K.
A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, or water. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.
A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, or water. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.
A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, water, or a water-based lubricant. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.
The University of Alabama in Huntsville (UAH) experiment which flew on the STS-8 mission had several objectives which were mostly of a speculative nature since so little was known of the processes of interest. The experiment provided original, if limited, data on: (1) oxidation of metal surfaces, (2) reaction rates of atomic oxygen with carbon and other surfaces and the dependence of these rates on temperature, and (3) the angular distribution of 5eV atoms scattered off a solid surface. Provided is a review of the results, with reference given to fuller published accounts where these are available.
The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base developed from analysis of the two-body potential data, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas surfaces and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.
The goal of this project was to develop computational tools for the calculation of the electronic structure of molecules containing heavy atoms, and to use these tools in the study of catalytic processes, with the overall objective of gaining an understanding of the catalytic process which could be used to design more efficient catalysts. The main catalytic system of interest was the combustion of hydrogen on platinum surfaces. Under this project, a flexible Dirac-Hartree-Fock (DHF) program has been developed, a code to calculate DHF correlation energies at the second-order Moeller-Plesset perturbation (PP2) level is almost complete, and code to include correlation at the MCSCF and MCSCF/MP2 level is planned. The tools so far developed have been validated and used to calibrate some more approximate methods, and applied to investigate the importance of relativistic effects in the bonding of hydrogen to platinum.
Lubrication additives of the current invention require formation of emulsions in base lubricants, created with an aqueous salt solution plus a single-phase compound such that partitioning within the resulting emulsion provides thermodynamically targeted compounds for boundary layer organization thus establishing anti-friction and/or anti-wear. The single-phase compound is termed "boundary layer organizer", abbreviated BLO. These emulsion-contained compounds energetically favor association with tribologic surfaces in accord with the Second Law of Thermodynamics, and will organize boundary layers on those surfaces in ways specific to the chemistry of the salt and BLO additives. In this way friction modifications may be provided by BLOs targeted to boundary layers via emulsions within lubricating fluids, wherein those lubricating fluids may be water-based or oil-based.