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At least 163 records · Page 9

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NASA NTRS1988

The effect of an electric field on the morphological stability of the crystal-melt interface of a binary alloy

A fully time-dependent linear stability analysis of the morphological stability of a planar interface during directional solidification of a binary alloy at constant velocity in the presence of an electric field, is performed. The electromigration of solute and the differing electrical conductivities of solid and liquid for a model in which the temperature gradient is constant are taken into account. The present results are compared with the constitutional supercooling criterion, and it is shown there may be substantial differences. A modified constitutional supercooling criterion which is valid over a large range of conditions is derived. It is also found under certain conditions that the onset of instability may be time dependent.

Wheeler, A. A.↗

NASA NTRS1949

Investigation of Meteorological Conditions Associated with Aircraft Icing in Layer-Type Clouds for 1947-48 Winter

Rotating-cylinder measurements of the icing conditions encountered in flight during the winter of 1947-48 are presented. Liquid water content, drop size, and temperature data are shown to be consistent with previously measured conditions and with proposed maximum icing conditions in supercooled layer-type clouds. Cumulative frequency graphs of meteorological parameters indicate the frequency with which various icing conditions have been encountered in the Great Lakes area and surrounding states.

WATER, SUPERCOOLED↗

NASA NTRS1978

Effects of kinetics on the crystallization of quartz normative basalt 15597 - An experimental study

Equilibrium experiments on a residual liquid composition from the dynamic crystallization study on quartz normative basalt (QNB) 15597 are used to evaluate the effects of kinetics on the crystallization of pyroxene-porphyritic basalts. The results indicate that the liquids coexisting with pyroxene phenocryst rims before the precipitation of groundmass plagioclase + pyroxene have left the equilibrium liquid line of descent and metastably penetrated the plagioclase primary phase volume. The precipitation of groundmass plagioclase + pyroxene brings the basalt system closer to equilibrium with respect to the residual liquid and crystals. At rapid cooling rates pyroxene phenocryst growth produces substantial compositional gradients in the residual silicate liquid at the pyroxene/liquid interface. The compositional gradients enhance the nucleation and growth of groundmass phases at the phenocryst interface, because effects related to constitutional supercooling for these phases (e.g., plagioclase, pyroxene, etc.) favor nucleation at the interface.

Grove, T. L.↗

NASA NTRS1999

The Isothermal Dendritic Growth Experiment (IDGE): USMP-4 One-Year-Report

Dendrites describe the tree-like crystal morphology commonly assumed in many material systems--particularly in metals and alloys that freeze from supercooled or supersaturated melts. There remains a high level of engineering interest in dendritic solidification because of the role of dendrites in the determination of cast alloy microstructures. Microstructure plays a key role in determining the physical properties of cast or welded products. In addition, dendritic solidification provides an example of non-equilibrium physics and is one of the simplest non-trivial examples of dynamic pattern formation, where an amorphous melt, under simple starting conditions, evolves into a complex ramified microstructure. Although it is well-known that dendritic growth is controlled by the transport of latent heat from the moving solid-melt interface as the dendrite advances into a supercooled melt, an accurate, and predictive model has not been developed. Current theories consider: 1) the transfer of heat or solute from the solid-liquid interface into the melt, and 2) the interfacial crystal growth and growth selection physics for the interface. However, the effects of gravity-induced convection on the transfer of heat from the interface prevent either element from being adequately tested solely under terrestrial conditions. The Isothermal Dendritic Growth Experiment (IDGE) constituted a series of three NASA-supported microgravity experiments, all of which flew aboard the space shuttle, Columbia. This experimental space flight series was designed and operated to grow and record dendrite solidification in the absence of gravity-induced convective heat transfer, and thereby produce a wealth of benchmark-quality data for testing solidification scaling laws. The data collection from the on-orbit phase of the IDGE flight series is now complete. We are currently completing analyses and moving towards final data archiving.

Glicksman, M. E.↗

NASA NTRS2011

The Winter 2010 and 2011 FRONT/NIRSS In-Flight Icing Hazard Detection Project

The NASA Icing Remote Sensing System (NIRSS) deploys a vertically-pointing K-band radar, a lidar ceiliometer, and a profiling microwave radiometer to obtain measurements for diagnosing local inflight icing conditions. RAL is working with NASA GRC to develop algorithms and data ingest and display software for the system. NASA has an ongoing activity to develop remote sensing technologies for the detection and measurement of icing conditions aloft. As part of that effort NASA teamed with NCAR to develop software that fuses data from multiple instruments into a single detected icing condition product. The multiple instrument approach, which is the current emphasis of this activity, utilizes a K-band vertical staring radar, a microwave radiometer that detects twelve frequencies between 22 and 59 GHz, and a lidar ceilometer. The radar data determine cloud boundaries, the radiometer determines the sub-freezing temperature heights and total liquid water content, and the ceilometer refines the lower cloud boundary. Data is post-processed in C++ program with a Java-based web display of resultant supercooled LWC profile and aircraft hazard identification. In 2010, a multi-channel scanning radiometer, designed and built by Radiometrics, Inc. under a SBIR grant,,was added to the system to assess its utility in improving icing diagnoses.

Serke, David↗

NASA NTRS1978

Onset of condensation effects with a NACA 0012-64 airfoil tested in the Langley 0.3-meter cryogenic tunnel

A 0.137m airfoil was tested in a 0.3m transonic cryogenic tunnel at free stream Mach numbers of 0.75, 0.85, and 0.95 over a total pressure range from 1.2 to 5.0 atmospheres. The onset of condensation effects were found to correlate more with the amount of supercooling in the free stream than it did with the supercooling in the region of maximum local Mach number over the airfoil. Effects in the pressure distribution over the airfoil were generally seen to appear over its entire length at nearly the same total temperature. Both observations suggest the possibility of heterogeneous nucleation occurring in the free stream. The potential operational benefits of the supercooling realized are presented in terms of increased Reynolds number capability at a given tunnel total pressure, reduced drive fan power if Reynolds number is held constant, and reduced liquid nitrogen consumption if Reynolds number is again constant. Depending on total pressure and free stream Mach number, these three benefits are found to respectively vary from 7 to 19%, 11 to 25%, and 9 to 20%.

Hall, R. M.↗

NASA NTRS1994

Preliminary flight results from the second U.S. Microgravity Payload (USMP-2)

The second U.S. Microgravity Payload (USMP-2) was flown on the Space Shuttle in March 1994. It carried four major microgravity experiments plus a sophisticated accelerometer system to record the microgravity environment during USMP-2 operations. The USMP program is designed to accommodate experiments requiring extensive resources short of a full Spacelab mission, and the experiments are remotely operated and monitored. Results are reviewed from the four experiments: the Advanced Automated Directional Solidification Facility (AADSF), the Isothermal Dendrite Growth Experiment (IDGE), the Materiel por Etude des Phenomenes Interessant la Soldification sur Terre et en Orbite (MEPHISTO), and the Critical Fluid Light Scattering Experiment (Zeno). AASDF grew what is expected to be the largest steady-state sample ever of HgCdTe during 240 hours of operation. IDGE provided 60 growth cycles over a wide range of supercooling conditions studying the dendritic solidification of succinonitrile. MEPHISTO achieved 55 melt-solidify cycles and grew over 1 m of Bi/Sn alloy. Zeno located the critical point temperature for liquid Xe to 0.00001 K. IDGE and Zeno also provided the most extensive demonstrations to date of telescience.

Curreri, Peter↗

NASA NTRS2003

Data and Modeling of Dendrites Subject to A Step Change in Pressure (TDSE)

There is considerable interest in dendritic solidification because of the influence dendrites have in the determination of microstructure, and thereby in the physical properties of cast metals and alloys. Current theories and models of dendritic growth generally couple diffusion effects in the melt with the physics of the interface. Data and subsequent analysis prior of the tip growth speed and radii of thermal succinonitrile dendrites in the near-convection free, on-orbit, free-fall environment demonstrate that these theories yield predictions that are reasonably in agreement with the results of experiment. However, data and analysis for assessing the interfacial physics component of theory are not sufficiently detailed or definitive. To study fundamental aspects of dendritic interface stability, we are measuring and modeling the kinetics and morphology of dendrites as they evolve from one well-defined steady state at a pre-set supercooling, through a transient stage, to a different well-defined steady state. More specifically, we subject succinonitrile dendrites, growing under steady-state conditions, to a rapid change in pressure. This leads to a rapid change in thermal driving force from the corresponding change in both the equilibrium melting temperature due to the Clapeyron effect, and a change in the far-field temperature due to adiabatic temperature changes in the bulk liquid and solid. Subsequently, we observe transformations from a well-characterized initial state into a new steady-state. Initial data reveal that the dendrite tip velocity changes almost as fast as the pressure charges, while the tip radius changes occur more slowly, taking from 10 60 seconds depending on the size of the step change and the final supercooling. Computer modeling of this process shows both agreements and disagreements with the experimental data. In making these observations and measurements, we are gaining new understandings of interfacial dynamics and state-selection physics.

Koss, Matthew B.↗

NASA NTRS1996

Stratospheric Heterogeneous Chemistry and Microphysics: Model Development, Validation and Applications

The objectives of this project are to: define the chemical and physical processes leading to stratospheric ozone change that involve polar stratospheric clouds (PSCS) and the reactions occurring on the surfaces of PSC particles; study the formation processes, and the physical and chemical properties of PSCS, that are relevant to atmospheric chemistry and to the interpretation of field measurements taken during polar stratosphere missions; develop quantitative models describing PSC microphysics and heterogeneous chemical processes; assimilate laboratory and field data into these models; and calculate the extent of chemical processing on PSCs and the impact of specific microphysical processes on polar composition and ozone depletion. During the course of the project, a new coupled microphysics/physical-chemistry/ photochemistry model for stratospheric sulfate aerosols and nitric acid and ice PSCs was developed and applied to analyze data collected during NASA's Arctic Airborne Stratospheric Expedition-II (AASE-II) and other missions. In this model, detailed treatments of multicomponent sulfate aerosol physical chemistry, sulfate aerosol microphysics, polar stratospheric cloud microphysics, PSC ice surface chemistry, as well as homogeneous gas-phase chemistry were included for the first time. In recent studies focusing on AASE measurements, the PSC model was used to analyze specific measurements from an aircraft deployment of an aerosol impactor, FSSP, and NO(y) detector. The calculated results are in excellent agreement with observations for particle volumes as well as NO(y) concentrations, thus confirming the importance of supercooled sulfate/nitrate droplets in PSC formation. The same model has been applied to perform a statistical study of PSC properties in the Northern Hemisphere using several hundred high-latitude air parcel trajectories obtained from Goddard. The rates of ozone depletion along trajectories with different meteorological histories are presently being systematically evaluated to identify the principal relationships between ozone loss and aerosol state. Under this project, we formulated a detailed quantitative model that predicts the multicomponent composition of sulfate aerosols under stratospheric conditions, including sulfuric, nitric, hydrochloric, hydrofluoric and hydrobromic acids. This work defined for the first time the behavior of liquid ternary-system type-1b PSCS. The model also allows the compositions and reactivities of sulfate aerosols to be calculated over the entire range of environmental conditions encountered in the stratosphere (and has been incorporated into a trajectory/microphysics model-see above). Important conclusions that derived from this work over the last few years include the following: the HNO3 content of liquid-state aerosols dominate PSCs below about 195 K; the freezing of nitric acid ice from sulfate aerosol solutions is likely to occur within a few degrees K of the water vapor frost point; the uptake and reactions of HCl in liquid aerosols is a critical component of PSC heterogeneous chemistry. In a related application of this work, the inefficiency of chlorine injection into the stratosphere during major volcanic eruptions was explained on the basis of nucleation of sulfuric acid aerosols in rising volcanic plumes leading to the formation of supercooled water droplets on these aerosols, which efficiently scavenges HCl via precipitation.

Turco, Richard P.↗

NASA NTRS1995

Freezing Behavior of Stratospheric Sulfate Aerosols Inferred from Trajectory Studies

Based on the trajectory analysis presented in this paper, a new mechanism is described for the freezing of the stratospheric sulfate aerosols. Temperature histories based on 10-day back trajectories for six ER-2 flights during AASE-I (1989) and AAOE (1987) are presented. The mechanism requires, as an initial step, the cooling of a H2SO4/H2O aerosol to low temperatures. If a cooling cycle is then followed up by a warming to approximately 196-198 K, the aerosols may freeze due to the growth of the crystallizing embryos formed at the colder temperature. The HNO3 absorbed at colder temperatures may increase the nucleation rate of the crystalling embryos and therefore influence the crystallization of the supercooled aerosols upon warming. Of all the ER-2 flights described, only the polar stratospheric clouds (PSC), observed on the flights of January 24, and 25, 1989 are consistent with the thermodynamics of liquid ternary solutions of H2SO4/HNO3/H2O (type Ib PSCs). For those two days, back trajectories indicate that the air mass was exposed to sulfuric acid tetrahydrate (SAT) melting temperatures about 24 hours prior to being sampled by the ER-2. Temperature histories, recent laboratory measurements, and the properties of glassy solids suggest that stratospheric H2SO4 aerosols may undergo a phase transition to SAT upon warming at approximately 198 K after going through a cooling cycle to about 194 K or lower.

Tabazadeh, A.↗

NASA NTRSDate not supplied

SLD Instrumentation in Icing Wind Tunnels – Investigation Overview

A collaborative effort to better understand cloud characterization probes in Supercooled Large Drop (SLD) conditions, as well the ability to simulate these conditions in several icing wind tunnels, was undertaken by NASA, NRCC, CIRA, ECCC, FAA and Met Analytics, Inc. Both drop sizing and liquid water content, LWC, were measured with various probes using current to emerging technologies. To ensure the best possible data quality from the newest probes, the probe manufacturers, SEA, Inc. and Artium, Inc. were invited to support testing and data analysis efforts. A common set of probes was identified to test in each of the three participating facilities: NRCC’s Altitude Icing Wind Tunnel, NASA’s Icing Research Tunnel and CIRA’s Icing Wind Tunnel. From the common set of probes, a subset were identified to use for comparison across the three facilities. These were the CDP-2 and 2D-S for drop sizing, and the Multi-wire for LWC. The LWC value was also checked by measuring the ice accretion thickness under hard rime conditions on a NACA-0012 airfoil. A common test matrix with sweeps in both LWC and median volume diameter, MVD, was developed. Each facility achieved these conditions as determined by their own calibration. The MVD ranged from 20 to at least 200 um, and LWC ranged from 0.5 to 3 g/m3. The comparison probes tested at common conditions in each facility were intended to allow for a direct comparison, and check of potential facility bias.

Icing Wind Tunnel↗

NASA NTRS2021

Physics and Chemistry of Te and HgTe-based Ternary Melts

Historically, the theoretical treatment of the liquid phases has always been more difficult and complicated than that for solid and gas phases. A liquid has no lattice structure as crystalline solids and the atoms/molecules in the liquid can migrate through it relatively rapidly. On the other hand, it is also interacting with many other atoms/molecules so that the simplifications of the kinetic theory of gases cannot be employed. For more complicated liquids, such as the liquids of high ionicity and those containing hydrogen bonds and electric dipoles, the understanding is far from complete. At the same time, accurate information on the physics and chemistry of semiconductor melts is needed for the quantitative descriptions of the process of crystal growth from melt. The pre-crystallization phenomena in the liquid phase are critical because the properties of the grown crystals depend on the state and structure of the melt as well as the thermal history of the melt during solidification process. However, the data on the liquid phase, such as thermophysical properties of semiconductor melts are scarce, especially for the HgTe-based II-VI ternary compound semiconductors because of their high vapor pressure and extreme toxicity. Analysis of the thermophysical properties of the melt can provide information about structural transitions of the melt during the solidification process. From a broader point of view, the structure of liquids is much more complicated than the crystalline solids, especially the relaxation behavior through different thermal histories. The theory of hetero-phase fluctuations of liquids is applicable to any many-body systems including condensed-matter physics, field theory, physics of nuclear-matter, cosmology, biology and even sociology. This book summarizes the physics and chemistry from the experimental measurements and theoretical analyses of phase diagram, thermodynamic properties, density, thermal conductivity, viscosity, and electrical conductivity on the binary, pseudo-binary and ternary melts of the most advanced IR-detector material systems of HgCdTe and HgZnTe as well as the analyses of these results. The main objectives of this study are: (1) to provide the phase diagrams and thermodynamic properties of Hg-Cd-Te and Hg-Zn-Te systems through quantitatively fitting the experimental data by assuming an associated solution model for the liquid phase, (2) to experimentally measure the thermophysical properties of the Hg-Cd-Te and Hg-Zn-Te melts, including density, viscosity, electrical conductivity and thermal conductivity as functions of temperature and composition and (3) to enhance the fundamental knowledge of hetero-phase fluctuations and relaxation phenomena in the melts and extend our understanding of the solidification process in order to interpret the experimental results of crystal growth so as to improve the melt growth processes of the compound semiconductor. The physics and chemistry of Te and HgTe-based ternary melts were explored through the studies of the structural transformation during melting, the supercooling during solidification, the relaxation phenomena after rapid cooling of the melts and the metal-semiconductor transition in the melts through the analyses of electrical conductivity and Lorenz number. An in-depth study on the thermophysical properties and their time-dependent structural dynamic processes taking place in the vicinity of the solid-liquid phase transition of the narrow homogeneity range HgTe-based ternary semiconductors as well as the analysis of the homogenization process in the melt will also be presented.

Thermophysical properties↗

NASA NTRSDate not supplied

Test Results for the SEA Ice Crystal Detector (ICD) under SLD Conditions at the NASA IRT

The Science Engineering Associates hot-wire Ice Crystal Detector was tested under Appendix C and Supercooled Large Drop Conditions at the NASA Icing Research Tunnel, with the purpose of comparing the measurements to the tunnel LWC calibration, and to test the performance of the mixed-phase retrievals of the probe. The liquid water content measured by the total water content sensor of the probe agreed well with the tunnel calibration over a wide range of MVDs, not unexpectedly since the tunnel was calibrated with a similar Multiwire hot-wire probe. A scale factor difference of about 7% was attributed to the lack of an efficiency correction for the Ice Crystal Detector at smaller median volume diameters, and typical sample area uncertainties of liquid water content devices. In addition, the simultaneous equations that are used to retrieve liquid and ice water contents were tested under liquid and glaciated conditions. Using constant ice and water efficiencies for each wire, the equations were found to produce a large and false ice water content retrieval in large median volume diameter liquid cases. By applying a liquid efficiency to the liquid water content sensor that varied with median volume diameter, retrievals were improved such that false ice water content was less than ±10% of the total water content out to the 460 μm median volume diameter limit of the testing. The probe was also tested in glaciated conditions by freezing out a small median volume diameter spray. Using constant ice efficiencies for the two sensors provided from aircraft measurements, the retrieved ice water content was about 40% higher than expected for the case presented, likely due to the ice efficiencies that were used from aircraft measurements of natural clouds being too low for the tunnel’s glaciated sprays. Application of ice efficiencies that vary with particle size and potentially other parameters will be explored for future improvement of retrievals.

Air Craft Icing↗

NASA NTRS2021

Test Results for the SEA Ice Crystal Detector (ICD) under SLD Conditions at the NASA IRT

o Aircraft Icing↗

NASA NTRS1981

LPE growth of 1.3 micron InGaAsP CW lasers on /110/ InP substrates

A description is presented of the liquid-phase epitaxial (LPE) growth of high-quality InGaAsP/InP continuous-wave (CW) laser structures on (110) InP substrates using conventional LPE without the need for special growth procedures. Double heterojunction laser structures were grown using the LPE supercooling method with a horizontal sliding boat. Low broad-area current densities (970 A/sq cm) and CW operation achieved at room temperature indicate that results comparable to up-to-date devices may be achieved. The inherent tendency for surface planarity maintenance due to the perfect surface stoichiometry of the (110) surface is a feature that may lend itself to the generation of improved interface growth in quaternary III-V and related semiconductor alloy systems. The similar cross-sectional appearance of structures grown on (110) and (100) orientations show that conventional LPE can be used with (110) surface planes without introducing special growth procedures.

Hawrylo, F. Z.↗

NASA NTRS1986

The vapor pressures of solid and liquid ozone

Vapor pressures of solid and liquid ozone have been measured over a temperature range 87 to below 66 K. The experiment was performed under flow conditions, and the gas was analyzed by a precision mass spectrometer system. In the range of solid ozone two forms, supercooled and crystalline ozone, were found. A least-square fit of the data for crystalline ozone resulted in the equation log P(torr) = A + B/T, where A = 10.460 and B = -1021.6. The estimated uncertainty of the data is + or - 1.0 percent. A triple-point temperature of 79.6 + or - 0.3 K was found where supercooled and crystalline ozone data intersect.

Hanson, David↗

NASA NTRSDate not supplied

Wind Tunnel PSD and MVD Characterization Using New 1D2D Optical Array Probes

This work explores characterization of the liquid clouds using a combination of a forward scattering probe and two Optical Array Probes. Current OAP probes provide particle shape, size, and number concentration from two-dimensional shadow images. However, past studies have shown that such images are subject to distortion when outside of the focal plane. This affects the retrieval of particle size distributions, particularly in the Supercooled Large Droplet size range. In this article, the use of a Droplet Measurement Technologies Cloud Droplet Probe and two new OAPs produced by Science Engineering Associates, is examined using wind tunnel data, to assess suitability for use in a wind tunnel calibration in SLD conditions. The new OAP probes exploit a flexible and simple grey scale imaging method to eliminate some present shortcomings of commonly used OAPs, and to reduce correction factors. Spinning disk measurements were used to specify probe depth of field, and average size errors. Composite spectra covering the nominal 2-3200 µm size range were formed by crossing over from the CDP to 1D2D-X at 48 µm, and then to the 1D2D-Y at about 400 µm. A good overlap was found at the crossover points without any artificial scaling. Composite spectra adequately closed the liquid water content distribution, and provided integrated LWCs within about 35% of the hot-wire LWCs used for tunnel calibration. This discrepancy was at least partially attributed to LWC underestimation by the hot-wire at high MVD. A model of probe performance was used to show an example of expected accuracy of ideal probes subject to the same OAP distortions and using the same mitigating procedures and corrections, predicting PSD Median Volume Diameter and integrated LWC errors of less than 10%.

Aircraft Icing↗

NASA NTRS2017

Creating a Bimodal Drop-Size Distribution in the NASA Glenn Icing Research Tunnel

The Icing Research Tunnel at NASA Glenn has demonstrated that they can create a drop-size distribution that matches the FAA Part 25 Appendix O FZDZ, MVD40 m normalized cumulative volume within 10. This is done by simultaneously spraying the Standard and Mod1 nozzles at the same nozzle air pressure and different nozzle water pressures. It was also found through these tests that the distributions that are measured when the two nozzle sets are sprayed simultaneously closely matched what was found by combining the two individual distributions analytically. Additionally, distributions were compared between spraying all spraybars and also by spraying only every-other spraybar, and were found to match within 4. The cloud liquid water content uniformity for this condition has been found to be excellent: 10. It should be noted, however, that the liquid water content for this condition in the IRT is much higher than the requirement specified in Part 25 Appendix O.

drop-size↗