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Excitons in 2D Magnets

Theoretical abilities that we built: In our QSGW formalism, the electronic eigenfunctions are calculated self-consistently in presence of the ladder e-h vertex corrections to the screened Coulomb exchange. Charge and self-energies are recalculated iterated until the desired tolerance is achieved in the one-particle Green's function. Further, to include the multi-determinantal (spin-flip structure of multiplets) nature of many body correlations we combine QSGW with DMFT. Below we explore various classes of strongly correlated magnetic systems where excitons are sufficiently described within either the QSGW or the QSGW +DMFT approach. In the process, we establish the digrammatic requirements for a minimum-sufficient theory for describing excitons in large classes of materials.

2D magnets↗

A correlative comparison of the ring current and auroral electrojects usig geomagnetic indices

From a study of the 21 largest geomagnetic storms during solar cycle 21, a strong correlation is established between the ring current index Dst and the time-weighted accumulation of the 1-hour auroral electrojets indices, AE and AL. The time-weighted accumulation corresponds to convolution of the auroral electrojet indices with an exponential weighting function with an e-folding time of 9.4 hours. The weighted indices AE(sub w) and AL(sub w) have correltation coefficients against Dst ranging between 0.8 and 0.95 for 20 of the 21 storms. Correlation over the entire solar cycle 21 database is also strong but not as strong as for an individual storm. A set of simple Dst prediction functions provide a first approximation of the inferred dependence, but the specific functional relationship of Dst (AL(sub w)) or Dst (AL(sub w)) varies from one storm to the next in a systematic way. This variation reveals a missing parametric dependence in the transfer function. However, our results indicate that auroral electroject indices are potentially useful for predicting storm time enhancements of ring current intensity with a few hours lead time.

Cade, W. B., III↗

Correlations of Power-law Spectral and QPO Features In Black Hole Candidate Sources

Recent studies have shown that strong correlations are observed between low frequency QPO s and the spectral power law index for a number of black hole candidate sources (BHCs), when these sources exhibit quasi-steady hard x-ray emission states. The dominant long standing interpretation of QPO's is that they are produced in and are the signature of the thermal accretion disk. Paradoxically, strong QPO's are present even in the cases where the thermal component is negligible. We present a model which identifies the origin of the QPO's and relates them directly to the properties of a compact coronal region which is bounded by the adjustment from Kepleriaa to sub-Kelperian inflow into the BH, and is primarily responsible for the observed power law spectrum. The model also predicts the relationship between high and low frequency QPO's and shows how BH's can be unique identified from observations of the soft states of NS's and BHC's.

Fiorito, Ralph↗

Forecasting Coronal Mass Ejections from Vector Magnetograms

Identification of active regions from which Earthward halo Coronal Mass Ejections (CMEs) are likely to originate is important both for understanding how CMEs are produced and for prediction of hazardous space weather. In previous work, from a set of 17 MSFC (Marshall Space Flight Center) vector magnetograms of 12 bipolar active regions situated within +/- 2 days of rotation from central meridian, we have evaluated four different measures of the global nonpotentiality of the magnetic field of each active region, and have found that the nonpotentiality of these active regions is strongly correlated with their CME productivity during the time interval of +/- 2 days centered on the day of the magnetogram: strongly nonpotential bipolar active regions are much more likely to produce a CME during this interval that are weakly nonpotential bipolar active regions. To further establish the use of active-region nonpotentiality for forecasting CMEs, we have expanded the sample to 19 additional bipolar active regions, with vector magnetograms taken with the upgraded MSFC vector magnetograph from September 2000 through June 2001 with support from our LWS grant (M. J. Hagyard, PI). The four global measures of nonpotentiality are the length of strong-shear, strong-field main neutral line, the net current, and two other measures of the overall twist in the magnetic field of the active-region bipole. We find: 1) The statistical significance of the correlation of the nonpotentiality of active regions with their CME productivity within +/- 2 days of the day of the magnetogram is greater than 99%. 2) 67% of the strongly nonpotential active regions produced CMEs within the +/- 2 day window, while only 17% of the weakly nonpotential ones did. 3) The statistical significance of the correlation of the nonpotentiality of active regions with their CME productivity during 0-2 days after the day of the magnetogram is about 97%. 4) 42% of the strongly nonpotential active regions produced CMEs within the 0-2 day window, while only 10% of the weakly nonpotential ones did. 5) The four different measures of an active region's nonpotentiality agree most of the time in their classification of the nonpotentiality as strong or weak (75%-90% depending on the pair of measurements). Additional information is included in the original extended abstract.

Moore, R. L.↗

A groundwater convection model for Rio Grande rift geothermal resources

It has been proposed that forced convection, driven by normal groundwater flow through the interconnected basins of the Rio Grande rift is the primary source mechanism for the numerous geothermal anomalies along the rift. A test of this concept using an analytical model indicates that significant forced convection must occur in the basins even if permeabilities are as low as 50-200 millidarcies at a depth of 2 km. Where groundwater flow is constricted at the discharge areas of the basins forced convection can locally increase the gradient to a level where free convection also occurs, generating surface heat flow anomalies 5-15 times background. A compilation of groundwater data for the rift basins shows a strong correlation between constrictions in groundwater flow and hot springs and geothermal anomalies, giving strong circumstantial support to the convection model.

Morgan, P.↗

Polar motion, atmospheric angular momentum excitation and earthquakes - Correlations and significance

Equatorial atmospheric angular momentum (AAM) excitation functions and polar motion excitation functions (derived by Kalman filtering Very Long Baseline Interferometry polar motion estimates) are compared with the times of 1984-mid-1988 large earthquakes (magnitude greater than or equal to 7.5). There is a moderate correlation between times of large earthquakes and peaks in polar motion excitation. A strong correlation exists between the times of large earthquakes and large peaks in equatorial AAM amplitude; such a correlation is evident for six out of the eight large earthquakes occurring over the studied time interval. The AAM results indicate potential for the temporal prediction of large/great earthquakes.

Preisig, Joseph R.↗

The Spectral Energy Distribution of Fermi Bright Blazars

We have conducted a detailed investigation of the broadband spectral properties of the gamma-ray selected blazars of the Fermi LAT Bright AGN Sample (LBAS). By combining our accurately estimated Fermi gamma-ray spectra with Swift, radio, infra-red, optical, and other hard X-ray /gamma-ray data, collected within 3 months of the LBAS data taking period, we were able to assemble high-quality and quasi-simultaneous spectral energy distributions (SED) for 48 LBAS blazars. The SED of these gamma-ray sources is similar to that of blazars discovered at other wavelengths, clearly showing, in the usual log v-log v Fv representation, the typical broadband spectral signatures normally attributed to a combination of low-energy synchrotron radiation followed by inverse Compton emission of one or more components. We have used these SED to characterize the peak intensity of both the low- and the high-energy components. The results have been used to derive empirical relationships that estimate the position of the two peaks from the broadband colors (i.e., the radio to optical, alpha(sub ro) , and optical to X-ray, alpha(sub ox), spectral slopes) and from the gamma-ray spectral index. Our data show that the synchrotron peak frequency (v(sup S) (sub peak)) is positioned between 10(exp 12.5) and 10(exp 14) Hz in broad-lined flat spectrum radio quasars (FSRQs) and between 10(exp 13) and 10(exp 17) Hz in featureless BL Lacertae objects. We find that the gamma-ray spectral slope is strongly correlated with the synchrotron peak energy and with the X-ray spectral index, as expected at first order in synchrotron-inverse Compton scenarios. However, simple homogeneous, one-zone, synchrotron self-Compton (SSC) models cannot explain most of our SED, especially in the case of FSRQs and low energy peaked (LBL) BL Lacs. More complex models involving external Compton radiation or multiple SSC components are required to reproduce the overall SED and the observed spectral variability. While more than 50% of known radio bright high energy peaked (HBL) BL Lacs are detected in the LBAS sample, only less than 13% of known bright FSRQs and LBL BL Lacs are included. This suggests that the latter sources, as a class, may be much fainter gamma-ray emitters than LBAS blazars, and could in fact radiate close to the expectations of simple SSC models. We categorized all our sources according to a new physical classification scheme based on the generally accepted paradigm for Active Galactic Nuclei and on the results of this SED study. Since the LAT detector is more sensitive to flat spectrum gamma-ray sources, the correlation between v(sup S) (sub peak) and gamma-ray spectral index strongly favors the detection of high energy peaked blazars, thus explaining the Fermi overabundance of this type of sources compared to radio and EGRET samples. This selection effect is similar to that experienced in the soft X-ray band where HBL BL Lacs are the dominant type of blazars.

Abdo, A. A.↗

Spectral Index and Quasi-Periodic Oscillation Frequency Correlation in Black Hole Sources: Observational Evidence of Two Phases and Phase Transition in Black Holes

Recent studies have shown that strong correlations are observed between the low frequencies (1-10 Hz) of quasi-periodic oscillations (QPOs) and the spectral power law index of several black hole (BH) candidate sources, in low (hard) states, steep power law (soft) states, and transitions between these states. The observations indicate that the X-ray spectra of such state (phases) show the presence of a power-law component and are sometimes related to simultaneous radio emission, indicating the probable presence of a jet. Strong QPOs (>20% rms) are present in the power density spectrum in the spectral range where the power-law component is dominant (i.e., 60%90%). This evidence contradicts the dominant, long-standing interpretation of QPOs as a signature of the thermal accretion disk. We present the data from the literature and our own data to illustrate the dominance of power-law index-QPO frequency correlations. We provide a model that identifies and explains the origin of the QPOs and how they are imprinted on the properties of the power-law flux component. We argue for the existence of a bounded compact coronal region that is a natural consequence of the adjustment of the Keplerian disk flow to the innermost sub-Keplerian boundary conditions near the central object and that ultimately leads to the formation of a transition layer (TL) between the adjustment radius and the innermost boundary. The model predicts two phases or states dictated by the photon upscattering produced in the TL: (1) a hard state, in which the TL is optically thin and very hot (kT approximately greater than 50 keV), producing photon upscattering via thermal Comptonization (the photon spectrum index Gamma approximates 1.7 for this state is dictated by gravitational energy release and Compton cooling in an optically thin shock near the adjustment radius), and (2) a soft state that is optically thick and relatively cold (kT approximately less than 5 keV the index for this state, Gamma approximates 2.8, is determined by soft-photon upscattering and photon trapping in a converging flow into the BH). In the TL model for the corona, the QPO frequency V(sub high) is related to the gravitational (close to Keplerian) frequency V(sub K) at the outer (adjustment) radius and v(sub low) is related to the TL's normal mode (magnetoacoustic) oscillation frequency v(sub MA) . The observed correlations between index and low and high QPO frequencies are readily explained in terms of this model. We also suggest a new method for evaluation of the BH mass using the index-frequency correlation.

Titarchuk, Lev↗

Spectral Index and Quasi-Periodic Oscillation Frequency Correlation in Black Hole (BH) Sources: Observational Evidence of Two Phases and Phase Transition in BHs

Recent studies have shown that strong correlations are observed between the low frequencies (1-10 Hz) of quasiperiodic oscillations (QPOs) and the spectral power law index of several Black Hole (BH) candidate sources, in low hard states, steep power-law (soft) states and in transition between these states. The observations indicate that the X-ray spectrum of such state (phases) show the presence of a power-law component and are sometimes related to simultaneous radio emission indicated the probable presence of a jet. Strong QPOs (less than 20% rms) are present in the power density spectrum in the spectral range where the power-law component is dominant ( i.e. 60-90% ). This evidence contradicts the dominant long standing interpretation of QPOs as a signature of the thermal accretion disk. We present the data from the literature and our own data to illustrate the dominance of power-law index-QPO frequency correlations. We provide a model, that identifies and explains the origin of the QPOs and how they are imprinted on the properties of power-law flux component. We argue the existence of a bounded compact coronal region which is a natural consequence of the adjustment of Keplerian disk flow to the innermost sub-Keplerian boundary conditions near the central object and that ultimately leads to the formation of a transition layer (TL) between the adjustment radius and the innermost boundary. The model predicts two phases or states dictated by the photon upscattering produced in the TL: (1) hard state, in which the TL is optically thin and very hot (kT approx. greater than 50 keV) producing photon upscattering via thermal Componization; the photon spectrum index Gamma appprox.1.5 for this state is dictated by gravitational energy release and Compton cooling in an optically thin shock near the adjustment radius; (2) a soft state which is optically thick and relatively cold (approx. less than 5 keV); the index for this state, Gamma approx. 2.8 is determined by soft-photon upscattering and photon trapping in converging flow into BH. In the TL model for corona the QPO frequency vnu(sub high) is related to the gravitational (close to Keplerian) frequency nu(sub K) at the outer (adjustment) radius and nu(sub low) is related to the TL s normal mode (magnetoacoustic) oscillation frequency nu(sub MA). The observed correlations between index and low and high QPO frequencies are readily explained in terms of this model. We also suggest a new method for evaluation of the BH mass using the index-frequency correlation.

Titarchuk, Lev↗

Science Driven Discovery of Nanoparticle Photocatalysts

Photocatalytic water splitting using suspensions of nanoparticle photocatalysts is a promising route to economically sustainable production of green hydrogen. The principal challenge is to develop photocatalysts with overall solar-to-hydrogen conversion efficiency that exceeds 10 percent. In this project we have developed a new platform for investigating candidate materials for photocatalytic water splitting. Our platform consists of patterned Au electrodes and a Ag/AgCl reference electrode on an insulating substrate onto which we disperse nanoparticle photocatalysts. We then cover the substrate with a thin layer of ionogel containing a protic ionic liquid that dissolves water from the ambient. Using this platform we have demonstrated photoelectrochemical activity mapping for single and small clusters of BiVO 4 nanoparticle photocatalysts and correlated these results to their Raman and photoluminescence spectra. The preliminary results suggest a strong correlation for low efficiency nanoparticles, followed by saturation for those with higher activities, indicating that interface reaction or electrolyte transport become the limiting factor. We anticipate that further application of this platform to investigation of candidate photocatalyst materials will provide useful insights into the mechanisms that limit their performance.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

An analysis of Jupiter data from the RAE-1 satellite

The analysis of Radio Astronomy Explorer Satellite data are presented. Radio bursts from Jupiter are reported in the frequency range 4700 KHz to 45 KHz. Strong correlations with lo were found at 4700, 3930, and 2200 KHz, while an equally strong Europa effect was observed at 1300, 900, and 700 KHz. Histograms indicating the relative probability and the successful identification of Jupiter activity were plotted, using automatic computer and visual search techniques.

Carr, T. D.↗

A preliminary analysis of the Mariner 10 color ratio map of Mercury

A preliminary geological analysis of the Mariner 10 orange/UV color ratio map of Mercury is given, assuming a basaltic crust. Certain errors in the map are pointed out. The relationship between color and terrain are distinctly non-lunar. Rays and ejecta are bluer than average on Mercury, whereas they are redder on the Moon. This fact, along with the lack of the ferrous band in Mercury's spectral reflectance and smaller albedo contrasts, implies that the crust is low in Fe and Ti. There is no correlation between color boundaries and the smooth plains on Mercury, in contrast with the strong correlation between color and maria-highlands contacts on the Moon. The smooth plains are not Mercurian analogs of lunar maria, and a lunar-type of second wave melting did not occur. Ambiguous correlations between color and topography indicate that older, redder materials underlie younger, bluer rocks in many places on the planet, implying that the last stages of volcanism involved low-Fe lavas covering higher-Fe rocks. There is some evidence of late Fe-rich pyroclastic activity.

Rava, Barry↗

A survey of rich clusters of galaxies with HEAO 1. II

Results are presented of an X-ray survey of approximately 1900 Abell clusters of galaxies performed with the NRL large-area X-ray detectors on HEAO 1. The cluster luminosity function derived from the observations made at ecliptic longitudes between 80 and 180 deg and 260 and 360 deg is fit with both power law and exponential relations, and used to estimate a total contribution of Abell clusters to the volume emissivity of the diffuse X-ray background of between 3 and 10%. No strong correlation is found between X-ray luminosity and Bautz-Morgan class, richness class or 26-MHz radio power, although B-M type I and Abell richness class 3 appear more likely to be strong X-ray sources. A correlation is suggested between optical radius and X-ray luminosity.

Ulmer, M. P.↗

Turbulence and Cloudiness in Cumulus-Topped Marine Boundary Layers

Turbulence and cloudiness in cumulus-topped marine boundary layers are studied using data from the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic (ENA) site. The analysis includes eight periods of nonprecipitating shallow cumulus clouds, spanning 141 h and encompassing 603 individual clouds. On average, the cumulus had bases at 558 m, were 99 m thick, had a chord length of 500 m, and exhibited an hourly base-layer cloudiness of 12%. Changes in cloud fraction were primarily driven by variations in cloud number not chord length. High-resolution Doppler lidar and cloud radar observations were used to estimate updraft and downdraft mass fluxes in the cumulus base layer under both clear and cloudy regions. Cloudy updrafts contributed only ∼23% of the total updraft mass flux at cloud base, indicating that most upward mass flux originated from clear-air eddies. Updraft strength, rather than updraft fraction, was found to predominantly control both clear and cloudy updraft mass fluxes. Cloud-base cloudiness strongly correlated with cloudy updraft mass flux but showed negligible correlation with clear-air updraft mass flux. Clear-air downdraft mass flux exhibited a strong relationship with the ratio of surface buoyancy to inversion strength. Mesoscale analysis revealed that moist patches had greater cloudiness, updraft mass flux, and vertical velocity variance compared to dry patches. Additionally, mesoscale base-layer cloud fraction was highly and significantly correlated with cloudy updraft mass flux in both dry and moist environments. Results presented herein have implications for cumulus parameterization development along with climatological and model evaluation studies conducted at the ENA site.

cumulus clouds↗

Longitudinal variability of methane and ammonia bands on Jupiter. II - Temporal variations

A set of spectra has been obtained of the Jovian equatorial zone central meridian 6190 A CH4 and 6450 A NH3 bands on the nights of February 26, 27, and 28, 1980, a year after the data reported by Cochran and Cochran (1980), in order to check the previous results and search for possible temporal variations. The new data confirm the results of the previous study. A correlation of the NH3 and CH4 equivalent widths, as well as a lack of any strong correlation of red continuum reflectivity with equivalent width, are found. Longitude regions of larger or smaller than average equivalent width still seem to exist a year later, with some slight drift in longitude. An increase in the average CH4 and NH3 equivalent width over the entire planet was detected during the one year interval. This is easily understood as the result of a global decrease in the mean altitude of the NH3 cloud.

Cochran, W. D.↗

Si-29 NMR spectroscopy of naturally-shocked quartz from Meteor Crater, Arizona: Correlation to Kieffer's classification scheme

We have applied solid state Si-29 nuclear magnetic resonance (NMR) spectroscopy to five naturally-shocked Coconino Sandstone samples from Meteor Crater, Arizona, with the goal of examining possible correlations between NMR spectral characteristics and shock level. This work follows our observation of a strong correlation between the width of a Si-29 resonance and peak shock pressure for experimentally shocked quartz powders. The peak width increase is due to the shock-induced formation of amorphous silica, which increases as a function of shock pressure over the range that we studied (7.5 to 22 GPa). The Coconino Sandstone spectra are in excellent agreement with the classification scheme of Kieffer in terms of presence and approximate abundances of quartz, coesite, stishovite, and glass. We also observe a new resonance in two moderately shocked samples that we have tentatively identified with silicon in tetrahedra with one hydroxyl group in a densified form of amorphous silica.

Boslough, M. B.↗

A Passive Method for Detecting Vegetation Stress from Orbit: Chlorophyll Fluorescence Spectra from Fraunhofer Lines

Solar-stimulated chlorophyll fluorescence measured with the Fraunhofer line depth method has correlated well with vegetation stress in previous studies. However, the instruments used in those studies were limited to a single solar absorption line (e.g. 656.3 nm), obviating the red/far-red ratio (R/FR) method. Optics and detector technology have reached the level whereby multiple, very narrow Fraunhofer lines are resolvable. Thirteen such lines span the visible spectrum in the red to far-red region where chlorophyll fluorescence occurs. Fluorescence intensities at the 13 Fraunhofer line wavelengths were used to model emission spectra. The source data were collected for summer and fall bean crops (Phaseolus vulgaris L.) subjected to various levels of nitrogen fertilization. The intensities were adjusted to account for Fraunhofer line depth and atmospheric transmittance. Multiple R/FR fluorescence ratios, calculated from the modeled fluorescence spectra, correlated strongly with leaf chlorophyll concentration and well with applied nitrogen. The ratio yielding the best correlation with chlorophyll utilized red fluorescence at the 694.5 nm Fraunhofer line and farred fluorescence at the 755.6 nm Fraunhofer line. Twenty R/FR ratios, each evaluated for the maximum differential between low and high (optimal) nitrogen treatments, ranked higher in some cases and lower in others, possibly related to the time of year the crops were grown and the stage of growth of the crops. Ratios with 728.9 nm and 738.9 nm in the denominator consistently ranked in the lowest and next lowest quartile, respectively. Ratios of the 656.3 nm Fraunhofer line and the 755.6 nm line consistently ranked highest for the summer crop. Ratios with 755.6 nm in the denominator ranked in the upper quartile for 10 out of 12 measurement dates. Differences in ratio ranking indicate that physiological conditions may be estimated using selected ratios of Fraunhofer lines within the context of R/FR analysis. A passive instrument designed to monitor R/FR chlorophyll fluorescence (i.e. vegetation stress) from orbit could be built today.

Theisen, Arnold F.↗

The Hot Horizontal-Branch Stars in omega Centauri

Context. UV observations of some massive globular clusters have revealed a significant population of stars hotter and fainter than the hot end of the horizontal branch (HB), the so-called blue hook stars. This feature might be explained either by the late hot flasher scenario where stars experience the helium flash while on the white dwarf cooling curve or by the progeny of the helium-enriched sub-population recently postulated to exist in some clusters. Previous spectroscopic analyses of blue hook stars in co Cen and NGC 2808 support the late hot flasher scenario, but the stars contain much less helium than expected and the predicted C, N enrichment could not be verified. Aims. We compare observed effective temperatures, surface gravities, helium abundances, and carbon line strengths (where detectable) of our targets stars to the predictions of the two scenarios. Methods. Moderately high resolution spectra of hot HB stars in the globular cluster omega-Cen were analysed for radial velocity variations, atmospheric parameters and abundances using LTE and non-LTE model atmospheres. Results. We find no evidence for close binaries among our target stars. All stars below 30 000 K are helium-poor and very similar to HB stars observed in that temperature range in other globular clusters. In the temperature range 30000 K to 50000 K we find that 28% of our stars are helium-poor (log ((sup n)He/(sup n )H)< - 1.6), while 72% have roughly solar or super-solar helium abundance (log ((sup n)He/(sup n )H) >/= -1.5). We also find carbon enrichment strongly correlated with helium enrichment, with a maximum carbon enrichment of 3% by mass. Conclusions. The strong carbon enrichment in tandem with helium enrichment is predicted by the late hot flasher scenario, but not by the helium-enrichment scenario. We conclude that the helium-rich HB stars in omega-Cen cannot be explained solely by the helium-enrichment scenario invoked to explain the blue main sequence.

Moehler, S.↗