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At least 163 records · Page 9

Metal-Organic Framework Glasses as Rad Contaminant Sequesters and Nuclear Waste Forms

Remediation of Tc remains an unresolved problem at SRS and other DOE sites. The objective of this project was to develop novel metal organic framework (MOF) glasses for radioactive contaminant sequestration and stabilization from aqueous media. During FY20, we synthesized, characterized and evaluated additional cetyltrimethylcimmonium bromide (CTAB)-functionalized and F - , Cl - , I - , CF 3 SO 3 - exchanged MIL-101-Cr samples. MIL-10l-Cr-NO 3 -CTAB was demonstrated to have high ReO 4 - removed capacity (139 mg/g sorbent) from artificial groundwater (AGW). Re chemical specicition and binding mechanism on MIL-101-CTAB were also studied by synchrotron X-ray absorption spectroscopy. ReO 4 - was demonstrated as being in the pore structure with slightly larger Re-O bond distances than those in NciReO 4 and binding with the positively charged sites of CTAB. In addition, a new Ni-TIPA MOF was demonstrated to be very stable, selective and effective for TcO 4 - removed from the SRS tank waste stream (~90% removed). The Ni-TIPA MOF sample containing ReO 4 - was prepared and shipped/planned for vitrification studies by a high-pressure technique. This research may provide a highly applicable platform for solving critical DOE and industrial problems related to nuclear environmental stewardship and nuclear power production.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Standard Operating Procedure for the Inadvertent Discovery of Native American Human Remains and Associated Funerary Objects, Sacred Objects, or Objects of Cultural Patrimony at Los Alamos National Laboratory

Los Alamos National Laboratory (LANL or Laboratory) is one of several national laboratories that support the mission of the United States Department of Energy (DOE), National Nuclear Security Administration (NNSA), Los Alamos Field Office (Field Office). It is located in Los Alamos and Santa Fe Counties, New Mexico. LANL occupies approximately 40 square miles of land owned by the U.S. Government and under the administrative control of DOE/NNSA. Cultural resources management at LANL is the responsibility of the Field Office’s Cultural Resources Program Manager, with the assistance and facilitation of the LANL Environmental Stewardship Group (ES) Cultural Resources Programs (archaeology and historic buildings), which are part of the LANL Environmental Protection and Compliance (EPC) Division. LANL, which is primarily located on the Pajarito Plateau, is extremely rich in cultural resources. Nearly 2,000 archaeological sites have been recorded at LANL, based on the systematic archaeological survey of ~90% of LANL lands. Most of the known sites (~ 85%) date from the Ancestral Pueblo Late Coalition and Classic Periods of around AD 1150 to 1600. The remaining sites date to the Archaic Period (ca. 5500 BC to 600 AD), the Late Developmental and Early Coalition Periods (ca. 900 to 1200), and the Homestead Period (ca. 1890 to 1942).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Natural Resources Assessment for the SNS Second Target Station, Oak Ridge, Tennessee

The US Department of Energy’s Oak Ridge National Laboratory (ORNL) is a leading institution in advanced materials, supercomputing, neutrons, and nuclear science. As a research laboratory managed by UT-Battelle, LLC for DOE, ORNL has national priorities in energy, security, and scientific discovery that necessitate facility improvements and expansions. DOE is also committed to environmental stewardship. The laboratory is located on the ~32,000-acre Oak Ridge Reservation (ORR), much of which is categorized as a National Environmental Research Park and a state Wildlife Management Area. DOE works with the Tennessee Wildlife Resources Agency (TWRA), Tennessee Department of Environment and Conservation (TDEC), US Fish and Wildlife Service (USFWS), US Department of Agriculture, and other agencies to serve as an effective steward of the ORR. Accordingly, project managers must conform to environmental regulations, agreements, and policies at the federal, state, and institutional levels. Per 40 CFR (Code of Federal Regulations) 1508.14, potential effects on research and science education on the National Environmental Research Park represent potential impacts of federal actions. Moreover, federal actions that affect the quantity and quality of hunting opportunities and deer reduction harvest on the Oak Ridge Wildlife Management Area must be considered whenever other aspects of the human environment (as defined by NEPA) are affected. The Spallation Neutron Source (SNS) is a premiere facility at ORNL that provides advanced capabilities in neutron scattering to promote new discoveries and research opportunities in material sciences, physics, chemistry, biological sciences, and others. A conceptual design for a Second Target Station (STS) has been in consideration for several years. The STS is intended to complement and enhance existing ORNL capabilities, notably research and exploration of complex materials. The proposed STS will involve development of existing natural areas on the ORR, which might contain sensitive resources that require mitigation or avoidance in accordance with existing policies and regulation. This report summarizes current knowledge of natural and cultural resources within the STS project area. At the time of this report, the proposed STS project consisted of an operations area comprising 55.4 acres (22.4 ha) and a total review area for potential construction comprising ~224 acres (90.6 ha). The review area is located primarily within forested natural areas of the ORR with minor development in the form of power-line rights-of-way and secondary/graveled roads (Figure 1). The primary goal was to evaluate potential effects on sensitive resources that might result from development of the STS. In addition to onthe-ground surveys during summer 2009 and fall 2019 to summer 2020 by ORNL Natural Resources Management Program and Aquatic Ecology Group staff, this report makes use of historical (pre-1995) and contemporary (1995 to present) data from additional confirmed sources (e.g., TDEC). Likewise, forest conditions were compiled primarily from a 2013 forest inventory effort for Forest Management Compartment 17 and supplemented with limited ground observations in 2019. The individuals who obtained and compiled the data that are presented here are familiar with and routinely assess sensitive resources on the ORR.

54 ENVIRONMENTAL SCIENCES↗

Tribal Renewable Energy: Bishop Paiute Tribe Youth Solar Job Training Development (Final Report)

This Project provided workshops and hands on opportunities for young tribal adults to gain education,training,and employment in the solar industry; including 1 youth to meet the eligibility requirements for the NABCEP Solar Installer Exam. 10 tribal youth, ages 16-24, attended workshops focused on learning solar fundamentals and then applied those learned skills to hands on training, installing solar on 2 tribal homes. GRID provided certificates authenticating their volunteer hours and skills learned. This program of youth training really excited the tribal leadership as well as the tribal youth. This opportunity was in alignment with the tribe’s Strategic Energy Plan, and supported tribal self-sufficiency, a path to economic development and for the youth it also represented the environmental stewardship the tribe believes in.

14 SOLAR ENERGY↗

2019 Site Environmental Report (Volume 1)

Brookhaven National Laboratory (BNL) is managed on behalf of the Department of Energy (DOE) by Brookhaven Science Associates (BSA), a partnership between the Research Foundation for the State University of New York on behalf of Stony Brook University and Battelle. For over 70 years, the Laboratory has played a lead role in the DOE Science and Technology mission and continues to contribute to the DOE’s missions in energy resources, environmental quality, and national security. BNL manages its world-class scientific research with particular sensitivity to environmental issues and community concerns. The Laboratory’s Environmental, Safety, Security, and Health (ESSH) Policy reflects the commitment of BNL’s management to fully integrate environmental stewardship into all facets of its mission and operations. BNL prepares an annual Site Environmental Report (SER) in accordance with DOE Order 231.1B, Environment, Safety, and Health Reporting. The report is written to inform the public, regulators, employees, and other stakeholders of the Laboratory’s environmental performance during the calendar year in review. Volume I of the SER summarizes environmental data; environmental management performance; compliance with applicable DOE, federal, state, and local regulations; and performance in restoration and surveillance monitoring programs. BNL has prepared annual SERs since 1971 and has documented nearly all its environmental history since the Laboratory’s inception in 1947. Volume II of the SER, the Groundwater Status Report, is also prepared annually to report on the status of groundwater protection and restoration efforts. Volume II includes detailed technical summaries of groundwater data and treatment system operations and is intended for regulators and other technically oriented stakeholders. A summary of the information contained in Volume II is included in Chapter 7, Groundwater Protection, of this volume.

54 ENVIRONMENTAL SCIENCES↗

Additive Manufacturing of MITL's and Convolutes

Stockpile stewardship requires accurate and predictive models relying on the generation of extreme environments which is both incredibly difficult and profoundly necessary. Next generation pulsed power facilities (NGPPF), where these environments are created, may require a paradigm shift in equipment engineering/manufacture to fulfill this need. Therefore, this research aims to investigate the limitations, capabilities and efficacy of leveraging advancements in the field of additive manufacturing (AM) in order to produce novel power flow components for NGPPFs. This work focused on commercial 3D metal AM equipment producing several prototypes addressing prescient needs/shortcomings, and a technique wherein a lightweight polymer core is metalized. Ultimately, commercial 3D metal AM is considered a viable path forward but would require a sizeable investment and does not currently support the scale and complexity necessary for NGPPFs. Moreover, initial results from our composite technique are promising and is considered a realizable path forward given further investigation.

42 ENGINEERING↗

Sensitive Resources Assessment and Forest Analysis for the Proposed Versatile Test Reactor, Oak Ridge, Tennessee

The US Department of Energy’s (DOE’s) Oak Ridge National Laboratory (ORNL) is a leading institution in advanced materials, supercomputing, neutrons, and nuclear science. As a research laboratory managed by UT-Battelle, LLC for DOE, ORNL has national priorities in energy, security, and scientific discovery that necessitate facility improvements and expansions. DOE is also committed to environmental stewardship. The laboratory is located on the ~32,000-acre (~13,000-ha) Oak Ridge Reservation (ORR), much of which is categorized as a National Environmental Research Park (NERP) and a state Wildlife Management Area. DOE works with the Tennessee Wildlife Resources Agency (TWRA), Tennessee Department of Environment and Conservation (TDEC), US Fish and Wildlife Service (USFWS), US Department of Agriculture, and other agencies to serve as an effective steward of the ORR. Accordingly, project managers must conform to environmental regulations, agreements, and policies at the federal, state, and institutional levels. Per 40 CFR (Code of Federal Regulations) 1508.14, potential effects on research and science education also represent potential effects of federal actions on the NERP, and impacts on, e.g., deer harvest, must be considered on the Oak Ridge Wildlife Management Area when other aspects of the human environment are affected. The United States currently has no fast neutron testing capability to support advanced nuclear research and development. The proposed Versatile Test Reactor (VTR) will take advantage of current investments by the US government and private industry in nuclear reactors to expedite the design and construction process, using proven technology to create a world-class scientific infrastructure. The VTR will take advantage of fast neutrons provided by this proven technology, along with a capability to rapidly insert, conduct, and remove state-of-the-art experiments. An advantage of the VTR is that it can support future innovations in experimental capabilities without modifying the facility. The VTR will support progress in a variety of science and technology areas, including testing and qualification of advanced reactor fuels; testing and qualification of innovative structural materials; testing of innovative components and instruments; validation of advanced modeling and simulation tools; and versatility for future technical missions. Through proven technology, the VTR can take advantage of existing reactor designs and operating experience to reduce the risk, cost, and time for design and construction. The top available resources of DOE laboratories, industry, and universities will be used to expedite reactor design and construction toward developing the scientific infrastructure that affords a strong testing capability that can be sustained over many years. This report summarizes current knowledge of natural and cultural resources primarily within the VTR construction area. At the time of this report, the proposed VTR site design includes a construction area of ~150.4 acres (~69.9 ha), which contains an ~51.3-acre (~20.8-ha) operations area, located within forested natural areas of the ORR. The primary goal of the work presented here was to evaluate potential effects on sensitive resources that might result from development and construction activities associated with VTR. In addition to on-the-ground surveys during spring and summer 2020 by the ORNL Natural Resources Management Program and Aquatic Ecology Group staff, this report makes use of historical (pre-1995) and contemporary (1995 to present) data from additional confirmed sources (e.g., TDEC). Likewise, forest conditions were compiled from a 2011 forest inventory and supplemented with limited ground observations in 2020. The individuals who obtained and compiled the data presented here are familiar with and routinely assess sensitive resources on the ORR. Anyone who references this report must consider that the timing of surveys did not permit a complete delineation of the resources that will be affected. If the VTR project proceeds, additional surveys will be required to account for the seasonal patterns of various threatened and endangered species. Data deficiencies and potential resources that likely went undetected are indicated where possible. Accordingly, this report should facilitate more environmentally sound decisions during planning and 2 development of the VTR site, provide a foundation for further assessment of sensitive and cultural resources, and help project managers better address regulatory guidance and DOE policies on sustainable development in compliance with, for example, the US Endangered Species Act (ESA), Migratory Bird Treaty Act (MBTA), Tennessee Rare Plant Protection and Conservation Act of 1985, Tennessee Nongame and Endangered or Threatened Wildlife Species Conservation Act of 1974, several federal and state regulations regarding aquatic resource protection, and site-specific policies as outlined in various ORR management plans developed by ORNL and TWRA for DOE.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Transuranic Waste Volume Reduction Methods for Los Alamos National Laboratory

Los Alamos National Laboratory (LANL, or the Lab) is one of the United States’ (U.S.) weapons complex nuclear security laboratories; it is owned by the Department of Energy (DOE) and operated by Triad National Security, LLC. LANL’s mission is to solve national security challenges through scientific excellence, which includes nuclear deterrence and stockpile stewardship. Such activities generate a variety of radioactive waste types, including transuranic (TRU) waste. The National Nuclear Security Administration (NNSA) is under a congressional mandate to produce no fewer than 80 plutonium pits per year by 2030 to meet Department of Defense requirements and support the nuclear deterrent. LANL is responsible for producing at least 30 pits per year by 2026, while the Savannah River Site will produce 50 pits per year by 2030. As of August 2018, the NNSA TRU waste inventory at LANL was at 53% capacity. In order to ensure the nuclear material missions are able to continue uninterrupted, the storage of TRU waste needs to remain below 60% of total capacity. As LANL increases production and prepares to meet the 30 pits per year goal, waste generation will increase substantially. Thus, there is a need to rejuvenate current infrastructure and implement TRU waste reduction methods in the coming years.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Multiphysics on Advanced Platforms Project

In 2015, the Lawrence Livermore National Laboratory started development of next-generation multiphysics simulation capabilities for the National Nuclear Security Administration under the Advanced Technologies Development and Mitigation (ATDM) element of the Advanced Simulation and Computing program in collaboration with the Exascale Computing Project (ECP). A key driver for this effort across the NNSA tri-lab was the emergence of advanced high performance computing (HPC) architectures based on heterogeneous compute capabilities, including GPU based systems, as part of the national drive toward exascale computing platforms at multiple Department of Energy (DOE) facilities. Developing a multiphysics code capable of meeting the various simulation needs of the NNSA as defined by the current generation of integrated codes (or ICs), initially developed as part of the Accelerated Strategic Computing Initiative (ASCI) program beginning in 1996, and able to scale to the current 100 petaflop class pre-exascale systems, as well the forthcoming exaflop class computers, is a daunting challenge. To accomplish this ambitious goal, LLNL has embraced two key themes: use of high-order numerical methods and a modular approach to code development. The LLNL next generation effort is organized under the Multi-Physics on Advanced Platforms Project (MAPP). A foundational component of MAPP is the Axom computer science (CS) toolkit which provides infrastructure for the development of modular, performance portable, multi-physics application codes. MARBL is a next-generation application code built on the Axom base to address the modeling needs of the high energy density physics (HEDP) community for simulating high-explosive, magnetic or laser driven experiments such as inertial confinement fusion (ICF), pulsed-power magneto-hydrodynamics (MHD), equation of state (EOS) and material strength studies as part of the NNSA’s stockpile stewardship program (SSP).

97 MATHEMATICS AND COMPUTING↗

Advancing Fissile Materials Production Modeling with Adaptive Computing Environment and Simulations (ACES)

The Department of Energy’s National Nuclear Security Administration (DOE/NNSA) provides advanced capabilities to simulate the uranium enrichment process to support international negotiations on the peaceful use of nuclear energy. Uranium isotope separation centrifuges connected in a cascade configuration can produce the low-enriched uranium needed for nuclear power. However, those same centrifuges connected in a different configuration can also produce highly enriched uranium for nuclear weapons. Having the capability to assess cascade operations and identify nefarious activities promotes the peaceful uses of nuclear energy while restricting nuclear weapons proliferation. DNN R&D's Nonproliferation Stewardship Program Adaptive Computing Environment and Simulations (ACES) project is creating a modern, sustainable ecosystem of physics-based models and data-analytics tools that enables analysts to model uranium enrichment systems, simulate operational scenarios, and apply various policy options to explore potential outcomes.

07 ISOTOPE AND RADIATION SOURCES↗

Solar Photovoltaic Module Recycling: A Survey of U.S. Policies and Initiatives

Industry stakeholders, regulators, and policymakers in the United States are starting to develop policies for PV module recycling. Well-designed policies could reduce negative environmental impacts and resource constraints while opening new market and employment opportunities. This paper summarizes drivers, barriers, and enablers related to PV module recycling, which might be addressed via policy. It then analyzes existing and proposed U.S. policies that may affect PV module recycling. Among the global and national voluntary industry stewardship standards related to EoL PV management, this paper discusses a Solar Energy Industries Association program encouraging PV recycling among its U.S. membership. The paper concludes with a synthesis of policy-related factors that may encourage effective EoL PV module management.

14 SOLAR ENERGY↗

TA-55 Plutonium Facility Fact Sheet

At the Los Alamos National Laboratory (LANL), virtually all plutonium operations occur within the Plutonium Facility at Technical Area 55 (TA-55). TA-55 is the nation’s most modern plutonium science and manufacturing facility, and is the only fully operational, full capability plutonium facility in the nation. TA-55 supports a wide range of national security programs that involve: 1) stockpile stewardship. 2) plutonium processing. 3) nuclear materials stabilization. 4) materials disposition. 5) nuclear forensics. 6) nuclear counter-terrorism. 7) nuclear energy. Operations at TA-55 maintain a critical skill base of plutonium expertise across a broad suite of technical capabilities. These capabilities form a center of excellence for actinide science and technology, including world-class manufacturing for solving significant national security challenges.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

EPC-ES WIPP WAC Appendix A Equivalence Support Measurements 2019-2020

Characterization of low-level waste (LLW) at Los Alamos National Laboratory (LANL) is primarily performed by the Environmental Protection and Compliance - Environmental Stewardship (EPC-ES) Characterization Services team and/or the Nuclear Process Infrastructure (NPI--9) Nuclear Material Support Services team (hereafter referred to as the gamma spectroscopy teams). The gamma spectroscopy teams use portable high-purity germanium (HPGe) detector systems for the nondestructive assay (NDA) characterization of LLW. Controlled-approved procedures and processes for the use of such systems to assay LLW items are currently in place. Additionally, a number of performance studies have been conducted by the gamma spectroscopy teams to support the efficacy and quality of assay results generated by the established NDA process.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Systems Engineering Approach for Design and Implementation of a Gas Breech for Actinide Experiments at the JASPER Facility

The Joint Actinide Shock Physics Experimental Research (JASPER) Facility is located approximately 65 miles north of Las Vegas, Nevada at the Nevada National Security Site (NNSS). The primary mission is to conduct shock physics research on actinide materials in support of NNSA’s Stockpile Stewardship Program. JASPER experiment uses a two-stage light gas gun to accelerate projectiles into targets at velocities up to 8 km/s (17,000 mph). The first stage uses an ignited propellent to drive a piston to compress gas in the pump tube. At the second stage, the gas compression exceeds a specified pressure and a rupture valve at the end of the pump tube opens. This launches a projectile to impact the target. The target is housed inside the target assembly and the debris field is contained inside the primary target chamber (PTC). The PTC is placed inside the secondary confinement chamber (SCC) as an added protection against possible contamination. These major components are illustrated in Figure 1.JASPER is capable of generating and measuring data on the properties of radioactive chemical elements at high shock pressures, temperatures, and strain rates approximating the conditions in nuclear weapons by using a two-stage gas gun. The data is used to determine material equations-of-state and validate computer models of material response. The work advances predictive capability, thus ensuring confidence in the nuclear stockpile.

42 ENGINEERING↗

DARPA beyond CMOS RFI

The Lawrence Livermore National Laboratory Center for Micro and Nanotechnology (CMNT) is located on the LLNL campus in Livermore, CA. LLNL employs over 7000 employees with a broad range of science and engineering backgrounds with an administrative structure that encourages multidisciplinary teaming, a key ingredient in our ability to address diverse technical problems. Our CMNT facility houses a 6,400 ft 2 class 100 cleanroom (class 10 capable) with an additional 1,000 ft 2 Class 1000 space, and 6000 ft 2 of other laboratories. Most equipment can accommodate 6” wafers, although some is limited to 4”. The CMNT is a multi-user, multi-programmatic facility that offers a broad set of instruments for microfabrication to invent, develop, and apply microscale and nanoscale technologies to support national security missions in Stockpile Stewardship, Homeland Security, Directed Energy, Nonproliferation, biomedical research, and more. The research and capabilities of the Center cover materials, devices, instruments, and systems that require microfabricated components, including microelectromechanical systems (MEMS), electronics, photonics, micro- and nanostructures, bio-implantable devices, and micro- and nanoactuators.

42 ENGINEERING↗

Serendipitous discovery connects grandfather and granddaughter at the Lab 60 years apart A third-generation employee learns about Los Alamos family history

The Lab’s enduring mission work means staff like Cameron Townsend are one of many family members who have careers at LANL. Cameron is her family’s third generation to work at the Lab, starting with her great grandparents, followed by her grandparents (skipping her parents), and now including her and her husband. She didn’t know about her family history at the Lab until she started working here three years ago when a typical day on the job became a serendipitous window into her family’s long history with the Lab. Cameron, who is an architect in EPC-ES: Environmental Stewardship and helps manage the Lab’s historic buildings program, was given a drawing from 1960 to aid in an assessment. The drafter’s name on the sketch: Ron Turner, her grandfather.

99 GENERAL AND MISCELLANEOUS↗

HED Hydrodynamics in the Common Modeling Framework

Within the Common Modeling Framework (CMF), the HED Hydrodynamics Project has implemented a common methodology, or "Authority", for modeling high energy density (HED) experiments by extending development of the Eulerian Applications Project code Authority, "EAPA," to include relevant physics models, customization tools and templates, and in situ and post-processing capabilities. Additionally, several models for small-scale HED experiments were successfully added to the CMF and simulations reproduce the results of preexisting, benchmarked input decks. We expect use of the CMF to improve our effectiveness in developing predictive capabilities for experiments ranging from small-scale planar single-interface, single-shock to multi-interface, multi-shock configurations and up through multi-shell inertial confinement fusion (ICF) implosions. Additionally, this will strengthen our ability to design future targeted experiments. Using the CMF infrastructure and Authorities for HED modeling has three key impacts. First, it enables a version-controlled, pedigreed and archived base model for each experiment with tools that allow easy setup, execution and analysis of simulations to assess and/or expose sensitivities to various parameters. Second, having a common base set of inputs and physics definitions helps identify systematic differences between models in the codes and experimental data to support code validation, and build confidence in our predictive capabilities. Finally, designed to work in concert with multiple programs and projects including PEM, IC, OES, V&V and DSW, the CMF supports improved collaboration and integration through shared model definitions, data, simulations and results, enhancing the workflow required to underwrite the knowledge base and capabilities ultimately required for stockpile stewardship

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗