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At least 163 records · Page 9

Trellis phase codes for power-bandwith efficient satellite communications

Support work on improved power and spectrum utilization on digital satellite channels was performed. Specific attention is given to the class of signalling schemes known as continuous phase modulation (CPM). The specific work described in this report addresses: analytical bounds on error probability for multi-h phase codes, power and bandwidth characterization of 4-ary multi-h codes, and initial results of channel simulation to assess the impact of band limiting filters and nonlinear amplifiers on CPM performance.

Wilson, S. G.↗

Investigating power capping toward energy-efficient scientific applications: Investigating Power Capping toward Energy-Efficient Scientific Applications

The emergence of power efficiency as a primary constraint in processor and system design poses new challenges concerning power and energy awareness for numerical libraries and scientific applications. Power consumption also plays a major role in the design of data centers, which may house petascale or exascale-level computing systems. At these extreme scales, understanding and improving the energy efficiency of numerical libraries and their related applications becomes a crucial part of the successful implementation and operation of the computing system. In this paper, we study and investigate the practice of controlling a compute system's power usage, and we explore how different power caps affect the performance of numerical algorithms with different computational intensities. Further, we determine the impact, in terms of performance and energy usage, that these caps have on a system running scientific applications. This analysis will enable us to characterize the types of algorithms that benefit most from these power management schemes. Our experiments are performed using a set of representative kernels and several popular scientific benchmarks. Lastly, we quantify a number of power and performance measurements and draw observations and conclusions that can be viewed as a roadmap to achieving energy efficiency in the design and execution of scientific algorithms.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Chemometric modeling of power conversion efficiency of organic dyes in dye sensitized solar cells for the future renewable energy

The present study reports chemometric modeling of power conversion efficiency (PCE) of dye sensitized solar cells (DSSCs) using the biggest available data set till date which comprises around 1200 dyes covering 7 chemical classes. To extract the best structural features required for higher PCE, we have developed multiple partial least squares (PLS) quantitative structure-property relationship (QSPR) models for the Triphenylamine, Phenothiazine, Indoline, Porphyrin, Coumarin, Carbazole and Diphenylamine chemical classes using descriptors derived from the best subset selection method followed by selection of best five models in each dataset based on the Mean Absolute Error (MAE) values. The models were validated both internally and externally followed by the consensus predictions employing “Intelligent Consensus Predictor” tool to examine whether the quality of predictions can be improved with the “intelligent” selection of multiple PLS models. The quality of predictions for the respective external sets showed that the consensus models (CM) are better than the individual models (IM) in most of the cases. From the insights of the developed models, we concluded that attributes like a packed structure toward higher conductivity of electrons, auxiliary donor fragment of aromatic tertiary amines, number of thiophenes inducing the bathochromic shift and augmenting the absorption, presence of additional electron donors, enhancement of electron-donating abilities, number of non-aromatic conjugated C(sp 2 ) which helps as conjugation extension units to broaden the absorption and highly conjugated $π$-systems exert positive contributions to the PCE. On the contrary, features negatively contributing to PCE are the followings: fragments which lower the tendency of localized $π–π*$ transition, fragments related to larger volume and surface area of dyes along with hydrophobicity resulting in poor adhesion, fragment RC = N causing dye hydrolysis, steric hindrance for π electronic mobility, fragments enhancing polarity, etc. Finally, the identified features from the best QSPR model of the coumarin dataset was employed in designing of ten more efficient coumarin dyes (predicted %PCE ranging from 8.93 to 10.62) than the existing ones.

14 SOLAR ENERGY↗

Power transport efficiency during O-X-B 2nd harmonic electron cyclotron heating in a helicon linear plasma device

The principal objective of this work is to report on the power coupled to a tungsten target in the prototype-material plasma exposure experiment device during oblique injection of a microwave beam (<70 kW at 28 GHz) into a high-power (~100 kW at 13.56 MHz) over-dense (${n_e} > 1 \times {10^{19}}{\text{ }}{{\text{m}}^{ - 3}}$) deuterium helicon plasma column. The experimental setup, electron heating system, electron heating scheme, and IR thermographic diagnostic for quantifying the power transport is described in detail. It is demonstrated that the power transported to the target can be effectively controlled by adjusting the magnetic field profile. Using this method, heat fluxes up to 22 MW m -2 and power transport efficiencies in the range of 17%–20% have been achieved using 70 kW of microwave power. It is observed that most of the heat flux is confined to a narrow region at the plasma periphery. Ray-tracing calculations are presented which indicate that the power is coupled to the plasma electrons via an O-X-B mode conversion process. Calculations indicate that the microwave power is absorbed in a single pass at the plasma periphery via collisions and in the over-dense region via 2nd harmonic cyclotron resonance of the electron Bernstein wave. The impact of our results is discussed in the context of MPEX.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Cu 2 ZnSnS 4 solar cells with over 10% power conversion efficiency enabled by heterojunction heat treatment

Sulfide kesterite Cu 2 ZnSnS 4 provides an attractive low-cost, environmentally benign and stable photovoltaic material, yet the record power conversion efficiency for such solar cells has been stagnant at around 9% for years. Severe non-radiative recombination within the heterojunction region is a major cause limiting voltage output and overall performance. Here we report a certified 11% efficiency Cu 2 ZnSnS 4 solar cell with a high 730 mV open-circuit voltage using heat treatment to reduce heterojunction recombination. This heat treatment facilitates elemental inter-diffusion, directly inducing Cd atoms to occupy Zn or Cu lattice sites, and promotes Na accumulation accompanied by local Cu deficiency within the heterojunction region. Consequently, new phases are formed near the hetero-interface and more favourable conduction band alignment is obtained, contributing to reduced non-radiative recombination. Using this approach, we also demonstrate a certified centimetre-scale (1.11 cm2) 10% efficiency Cu 2 ZnSnS 4 photovoltaic device; the first kesterite cell (including selenium-containing) of standard centimetre-size to exceed 10%.

14 SOLAR ENERGY↗

NASA satellite communications application research, phase 2 addendum. Efficient high power, solid state amplifier for EHF communications

This document is an addendum to the NASA Satellite Communications Application Research (SCAR) Phase 2 Final Report, 'Efficient High Power, Solid State Amplifier for EHF Communications.' This report describes the work performed from 1 August 1993 to 11 March 1994, under contract number NASW-4513. During this reporting period an array of transistor amplifiers was repaired by replacing all MMIC amplifier chips. The amplifier array was then tested using three different feedhorn configurations. Descriptions, procedures, and results of this testing are presented in this report, and conclusions are drawn based on the test results obtained.

Benet, James↗

Hierarchical TiO{sub 2} submicron-sized spheres for enhanced power conversion efficiency in dye-sensitized solar cells

Hierarchical TiO{sub 2} submicron-sized sphere scattering layer, with relatively large surface area and effective light scattering, shows enhanced power conversion efficiency in dye-sensitized solar cells. - Highlights: • Hierarchical TiO{sub 2} submicron-sized spheres (TiO{sub 2} HSSs) with diameters of 400–600 nm were synthesized. • The HSSs composed of nanoparticles of ∼14 nm have a relatively large surface area of ∼35 m{sup 2}/g. • DSC exhibited the highest cell efficiency (6.23%) compared with ones with pure P25 (5.50%) or HSS (2.00%) photoanodes. - Abstract: Hierarchical TiO{sub 2} submicron-sized spheres (TiO{sub 2} HSSs) with diameters of 400–600 nm were synthesized by a facile one-step solvothermal method in ethanol solvent. The HSSs composed of nanoparticles of ∼14 nm have a relatively large surface area of ∼35 m{sup 2}/g. When applied as the scattering overlayer in dye-sensitized solar cells (DSCs), such TiO{sub 2} HSSs effectively improved light harvesting and led to the increase of photocurrent in DSCs. Furthermore, bilayer-structured photoanode also provided fast electron transportation and long electron lifetime as confirmed by electrochemical impedance spectra. As a result, DSC based on P25 nanoparticle underlayer and HSS-2 overlayer exhibited the highest cell efficiency (6.23%) compared with ones with pure P25 (5.50%) or HSS-2 (2.00%) photoanodes.

36 MATERIALS SCIENCE↗

Improved power conversion efficiency for bulk heterojunction solar cells incorporating CdTe-CdSe nanoheterostructure acceptors and a conjugated polymer donor

In this paper, we report photovoltaic devices based on composites of a branched nanoheterostructure containing a CdTe core and CdSe arms, CdTe(c)-CdSe(a), combined with either poly(3-hexylthiophene), P3HT, or poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT, with solar power conversion efficiencies of 1.2% and 1.8%, respectively. Finally, a comparison with previously reported composite devices of a related branched nanoheterostructure: CdSe(c)-CdTe(a) reveals an improved device performance that is attributed to a better electron percolation pathway provided by the dominant, higher electron affinity CdSe arms of the nanoheterostructures.

14 SOLAR ENERGY↗

Integrating Magnetics for On-Chip Power: A Perspective

Integration of efficient power converters requires technology for efficient, high-power on-chip inductors and transformers. Increases in switching frequency, facilitated by advances in circuit designs and silicon or wide-bandgap semiconductors, can enable miniaturization, but only if the magnetics technology works well at the higher frequencies. Technologies, geometries, and scaling of air-core and magnetic-core inductors and transformers are examined, and their potential for integration is discussed. Air-core inductors can use simpler fabrication, and increasing frequency can always be used to decrease their size, but magnetic cores can decrease the required thickness without requiring as high a frequency.

Sullivan, CR↗

Lead-free inverted planar formamidinium tin triiodide perovskite solar cells achieving power conversion efficiencies up to 6.22%

Efficient lead (Pb)-free inverted planar formamidinium tin triiodide (FASnI 3 ) perovskite solar cells (PVSCs) are demonstrated. Our FASnI 3 PVSCs achieved average power conversion efficiencies (PCEs) of 5.41% ± 0.46% and a maximum PCE of 6.22% under forward voltage scan. Here, the PVSCs exhibit small photocurrent–voltage hysteresis and high reproducibility. The champion cell shows a steady-state efficiency of ≈6.00% for over 100 s.

14 SOLAR ENERGY↗

Arc-Jet Power Supply And Starting Circuit

Power efficiency high, current regulated, and starting automatic. New circuit for starting arc jets and controlling them in steady operation capable of high power efficiency and constructed in lightweight form. Feedback control system keeps arc-jet current nearly constant, once arc struck by starting pulse. Circuit made of commercially available components. Design capable of high power efficiency.

Gruber, Robert P.↗

Single Atomically Sharp Lateral Monolayer p-n Heterojunction Solar Cells with Extraordinarily High Power Conversion Efficiency

The recent development of 2D monolayer lateral semiconductor has created new paradigm to develop p-n heterojunctions. Albeit, the growth methods of these heterostructures typically result in alloy structures at the interface, limiting the development for high-efficiency photovoltaic (PV) devices. Here, the PV properties of sequentially grown alloy-free 2D monolayer WSe 2 -MoS 2 lateral p-n heterojunction are explores. The PV devices show an extraordinary power conversion efficiency of 2.56% under AM 1.5G illumination. The large surface active area enables the full exposure of the depletion region, leading to excellent omnidirectional light harvesting characteristic with only 5% reduction of efficiency at incident angles up to 75°. Modeling studies demonstrate the PV devices comply with typical principles, increasing the feasibility for further development. Furthermore, the appropriate electrode-spacing design can lead to environment-independent PV properties. As a result, these robust PV properties deriving from the atomically sharp lateral p-n interface can help develop the next-generation photovoltaics.

14 SOLAR ENERGY↗

Role of silicon excess in Er-doped silicon-rich nitride light emitting devices at 1.54 μm

Erbium-doped silicon-rich nitride electroluminescent thin-films emitting at 1.54 μm have been fabricated and integrated within a metal-oxide-semiconductor structure. By gradually varying the stoichiometry of the silicon nitride, we uncover the role of silicon excess on the optoelectronic properties of devices. While the electrical transport is mainly enabled in all cases by Poole-Frenkel conduction, power efficiency and conductivity are strongly altered by the silicon excess content. Specifically, the increase in silicon excess remarkably enhances the conductivity and decreases the charge trapping; however, it also reduces the power efficiency. The main excitation mechanism of Er{sup 3+} ions embedded in silicon-rich nitrides is discussed. The optimum Si excess that balances power efficiency, conductivity, and charge trapping density is found to be close to 16%.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

ACDT: Architected Composite Data Types Trading-in Unfettered Data Access for Improved Execution

With Exascale performance and its challenges in mind, one ubiquitous concern among architects is energy efficiency. Petascale systems projected to Exascale systems are unsustainable at current power consumption rates. One major contributor to system-wide power consumption is the number of memory operations leading to data movement and management techniques applied by the runtime system. To address this problem, we present the concept of the Architected Composite Data Types (ACDT) framework. The framework is made aware of data composites, assigning them a specific layout, transformations and operators. Data manipulation overhead is amortized over a larger number of elements and program performance and power efficiency can be significantly improved. We developed the fundamentals of an ACDT framework on a massively multithreaded adaptive runtime system geared towards Exascale clusters. Showcasing the capability of ACDT, we exercised the framework with two representative processing kernels - Matrix Vector Multiply and the Cholesky Decomposition – applied to sparse matrices. As transformation modules, we applied optimized compress/decompress engines and configured invariant operators for maximum energy/performance efficiency. Additionally, we explored two different approaches based on transformation opaqueness in relation to the application. Under the first approach, the application is agnostic to compression and decompression activity. Such approach entails minimal changes to the original application code, but leaves out potential applicationspecific optimizations. The second approach exposes the decompression process to the application, hereby exposing optimization opportunities that can only be exploited with application knowledge. The experimental results show that the two approaches have their strengths in HW and SW respectively, where the SW approach can yield performance and power improvements that are an order of magnitude better than ACDT-oblivious, hand-optimized implementations.We consider the ACDT runtime framework an important component of compute nodes that will lead towards power efficient Exascale clusters.

exascale↗

Top Stack Optimization for Cu 2 BaSn(S, Se) 4 Photovoltaic Cell Leads to Improved Device Power Conversion Efficiency beyond 6%

Earth-abundant and air-stable Cu 2 BaSnS 4-x Se x (CBTSSe) and related thin-film absorbers are regarded as prospective options to meet the increasing demand for low-cost solar cell deployment. Devices based on vacuum-deposited CBTSSe absorbers have achieved record power conversion efficiency (PCE) of 5.2 % based on a conventional device structure using CdS buffer and i-ZnO/ITO window layers, with open-circuit voltage (V OC ) posing the major bottleneck for improving solar cell performance. The current study demonstrates a >20 % improvement in V OC (from 0.62 V to 0.75 V) and corresponding enhancement in PCE (from 5.1 % to 6.2 % without anti-reflection coating; to 6.5 % with MgF 2 anti-reflection coating) for solution-deposited CBTSSe solar cells. This performance improvement is realized by introducing an alternative successive ionic layer adsorption and reaction (SILAR)-deposited Zn 1-x Cd x S buffer combined with sputtered Zn 1-x Mg x O/Al-doped ZnO window/top contact layer, which offer lower electron affinities relative to the conventional CdS/i-ZnO/ITO stack and better matching with the low electron affinity of CBTSSe. A combined experimental (temperature- and light intensity-dependent V OC measurements) and device simulation (SCAPS-1D) evaluation points to the importance of addressing relative band offsets for both the buffer and window layers relative to the absorber in mitigating interfacial recombination and optimizing CBTSSe solar cell performance.

25 ENERGY STORAGE↗

Unraveling the fundamental mechanisms of solvent-additive-induced optimization of power conversion efficiencies in organic photovoltaic devices

The realization of controllable morphologies of bulk heterojunction (BHJ) in organic photovoltics (OPVs) is one of the key factors in obtaining high-efficiency devices. Here via simultaneous monitoring of the three-dimensional nanostructural modifications in BHJ correlated with the optical analysis and theoretical modeling of charge transport, we provide new insights into the fundamental mechanisms essential for the optimization of (power conversion efficiency) PCEs with additive processing. Our results demonstrate how a trace amount of diiodooctane (DIO) remarkably changes the vertical phase morphology of the active layers resulting in formation of a well-mixed donor-acceptor compact film, augments charge transfer and PCEs. In contrast, excess amount of DIO promotes a massive reordering and results loosely packed mixed phase vertical phase morphology with large clusters leading to deterioration in PCEs. Theoretical modeling of charge transport reveals that DIO increases the mobility of electrons and holes (the charge carriers) by affecting the energetic disorder and electric field dependence of the mobility. Our results show the significant of phase separation and carrier transport pathways to achieve optimal device performances.

14 SOLAR ENERGY↗

Balancing Power Absorption Against Structural Loads With Viscous Drag and Power-Takeoff Efficiency Considerations

The focus of this paper is to balance power absorption against structural loading for a novel fixed-bottom oscillating surge wave energy converter in both regular and irregular wave environments. The power-to-load ratio will be evaluated using pseudospectral control (PSC) to determine the optimum power-takeoff (PTO) torque based on a multiterm objective function. This paper extends the pseudospectral optimal control problem to not just maximize the time-averaged absorbed power but also include measures for the surge-foundation force and PTO torque in the optimization. The objective function may now potentially include three competing terms that the optimizer must balance. Separate weighting factors are attached to the surge-foundation force and PTO control torque that can be used to tune the optimizer performance to emphasize either power absorption or load shedding. To correct the pitch equation of motion, derived from linear hydrodynamic theory, a quadratic-viscous-drag torque has been included in the system dynamics; however, to continue the use of quadratic programming solvers, an iteratively obtained linearized drag coefficient was utilized that provided good accuracy in the predicted pitch motion. Furthermore, the analysis considers the use of a nonideal PTO unit to more accurately evaluate controller performance. The PTO efficiency is not directly included in the objective function but rather the weighting factors are utilized to limit the PTO torque amplitudes, thereby reducing the losses resulting from the bidirectional energy flow through a nonideal PTO. Furthermore, results from PSC show that shedding a portion of the available wave energy can lead to greater reductions in structural loads, peak-to-average power ratio, and reactive power requirement.

16 TIDAL AND WAVE POWER↗