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At least 163 records · Page 9

Atmospheric particulate analysis using angular light scattering

Using light scattering matrix elements measured by a polar nephelometer, a procedure for estimating the characteristics of atmospheric particulates was developed. A theoretical library data set of scattering matrices derived from Mie theory was tabulated for a range of values of the size parameter and refractive index typical of atmospheric particles. Integration over the size parameter yielded the scattering matrix elements for a variety of hypothesized particulate size distributions. A least squares curve fitting technique was used to find a best fit for the experimental measurements. This was used as a first guess for a nonlinear iterative inversion of the size distribution. A real index of 1.50 and an imaginary index of -0.005 are representative of the smoothed inversion results for the near ground level atmospheric aerosol in Tucson.

Hansen, M. Z.↗

Airborne particulate soiling of terrestrial photovoltaic modules and cover materials

Results are presented for the first phase of a photovoltaic-module soiling study that was carried out with NASA participation to investigate the problem of the electrical performance degradation of flat-plate photovoltaic modules exposed at outdoor sites that is due to the accumulation of airborne particulates on sensitive optical surfaces. The results were obtained in both field and laboratory soiling experiments, as well as in materials field experiments using candidate encapsulants and top covers. It is concluded that: (1) the electrical performance degradation shows a significant time and site dependence, ranging from 2% to 60% power loss; (2) the rate of particulate accumulation appears to be largely material independent when natural removal processes do not dominate; (3) the effectiveness of natural removal processes, especially rain, is strongly material dependent; (4) top-cover materials of glass and plexiglass retain fewer particles than silicone rubber; and (5) high module voltages relative to ground do not appear to affect the rate of dirt accumulation on modules.

Hoffman, A. R.↗

Coprostanol as a potential tracer of particulate sewage effluent to shelf waters adjacent to the Chesapeake Bay

Samples were collected in the Chesapeake Bay entrance and contiguous shelf waters and were subsequently analyzed for particulate coprostanol and cholesterol concentrations. Surface coprostanol concentrations were fairly uniform, with a slight increase with depth. This increase with depth may be due to sewage-associated particulates settling as they leave the Bay, or the resuspension of contaminated sediment. Preliminary findings indicate sewage-associated materials are being transported from the Chesapeake Bay to shelf waters, where they may have a detrimental affect on living marine resources.

Brown, R. C.↗

Diesel Particulate Destruction

Pulsed electrical discharge eliminates particulates in diesel exhaust. Particulates in diesel exhaust gas destroyed by passing them through agglomerator and series of high voltage-biased grids.

Yang, L. C.↗

Remote sensing of atmospheric particulates: Technological innovation and physical limitations in applications to short-range weather prediction

Techniques for remote sensing of particles, from cloud droplet to hailstone size, using optical and microwave frequencies are reviewed. The inherent variability of atmospheric particulates is examined to delineate conditions when the signal can give information to be effectively utilized in a forecasting context. The physical limitations resulting from the phase, size, orientation and concentration variability of the particulates are assessed.

Curran, R. J.↗

The effects of particulates from solid rocket motors fired in space

The orbits attained by kick motor solid propellant particulates are modeled, and an estimate is made of the number of particulates which will remain in orbit. The fuel, Al2O3, is burned while inserting spacecraft into a transfer orbit and again while circularizing the GEO station. It is shown that 23 percent of 1 micron particles deorbit immediately, while most particles enter a retrograde orbit. The resulting flux is an order of magnitude larger than the micrometeoroid flux. The pressures exerted by solar radiation ensure that only 5 percent of the original flux is still in orbit after the first year. The estimates provided are valid for a large number of transfer orbit operations, but will vary widely over the short term.

Mueller, A. C.↗

Particulate contaminant relocation during shuttle ascent

The dislodgement, venting, and redeposition of particles on a surface in the shuttle bay by the vibroacoustic, gravitational, and aerodynamic forces present during shuttle ascent have been investigated. The particles of different sizes which are displaced, vented, and redistributed have been calculated; and an estimate of the increased number of particles on certain surfaces and the decrease on others has been indicated. The average sizes, velocities, and length of time for certain particles to leave the bay following initial shuttle doors opening and thermal tests have been calculated based on indirect data obtained during several shuttle flights. Suggestions for future measurements and observations to characterize the particulate environment and the techniques to limit the in-orbit particulate contamination of surfaces and environment have been offered.

Scialdone, J. J.↗

Particulate matter in the Venus atmosphere

The paper presents a summary of the data currently available (June 1984) describing the planet-enshrouding particulate matter in the Venus atmosphere. A description and discussion of the state of knowledge of the Venus clouds and hazes precedes the tables and plots. The tabular material includes a precis of upper haze and cloud-top properties, parameters for model-size distributions for particles and particulate layers, and columnar masses and mass loadings.

Ragent, B.↗

Airborne particulate matter in spacecraft

Acceptability limits and sampling and monitoring strategies for airborne particles in spacecraft were considered. Based on instances of eye and respiratory tract irritation reported by Shuttle flight crews, the following acceptability limits for airborne particles were recommended: for flights of 1 week or less duration (1 mg/cu m for particles less than 10 microns in aerodynamic diameter (AD) plus 1 mg/cu m for particles 10 to 100 microns in AD); and for flights greater than 1 week and up to 6 months in duration (0.2 mg/cu m for particles less than 10 microns in AD plus 0.2 mg/cu m for particles 10 to 100 microns in AD. These numerical limits were recommended to aid in spacecraft atmosphere design which should aim at particulate levels that are a low as reasonably achievable. Sampling of spacecraft atmospheres for particles should include size-fractionated samples of 0 to 10, 10 to 100, and greater than 100 micron particles for mass concentration measurement and elementary chemical analysis by nondestructive analysis techniques. Morphological and chemical analyses of single particles should also be made to aid in identifying airborne particulate sources. Air cleaning systems based on inertial collection principles and fine particle collection devices based on electrostatic precipitation and filtration should be considered for incorporation into spacecraft air circulation systems. It was also recommended that research be carried out in space in the areas of health effects and particle characterization.

Source record↗

Particulate contaminant relocation during shuttle ascent

The dislodgement, venting, and redeposition of particles on a surface in the shuttle bay by the vibroacoustic, gravitational, and aerodynamic forces present during shuttle ascent have been investigated. The particles of different sizes which are displaced, vented, and redistributed have been calculated; and an estimate of the increased number of particles on certain surfaces and the decrease on others has been indicated. The average sizes, velocities, and length of time for certain particles to leave the bay following initial shuttle doors opening and thermal tests have been calculated based on indirect data obtained during several shuttle flights. Suggestions for future measurements and observations to characterize the particulate environment and the techniques to limit the in-orbit particulate contamination of surfaces and environment have been offered.

Scialdone, John J.↗

An intercomparison of measurement systems for vapor and particulate phase concentrations of formic and acetic acids

During June 1986, eight systems for measuring vapor phase and four for measuring particulate phase concentrations of formic acid (HCOOH) and acetic acid (CH3COOH) were intercompared in central Virginia. HCOOH and CH3COOH vapors were sampled by condensate, mist, Chromosorb 103 GC resin, NaOH-coated annular denuders, NaOH-impregnated quartz filters, K2CO3 and NaCO3-impregnated cellulose filters, and Nylasorb membranes. Atmospheric aerosol was collected on Teflon and Nuclepore filters using both hi-vol and lo-vol systems to measure particulate phase concentrations. Performances of the mist chamber and K2CO3-impregnated filter techniques were evaluated using zero air and ambient air spiked with HCOOH(g) and CH3COOH(g), and formaldehyde from permeation sources. The advantages and drawbacks of these methods are reported and discussed.

Keene, William C.↗

The in-situ cometary particulate size distribution measured for one comet: P/Halley

The close approach of Giotto to comet Halley during its 1986 apparition offered an opportunity to study the particulate mass distribution to masses of up to one gram. Data acquired by the front end channels of the highly sensitive mass spectrometer PIA and the dust shield detector system, DIDSY, provide definition to the detected distribution as close as 1000 km to the nucleus. Dynamic motion of the particulates after emission leads to a spatial differentiation affecting the size distribution in several forms: (1) ejecta velocity dispersion; (2) radiation pressure; (3) varying heliocentric distance; and (4) anisotropic nucleus emission. Transformation of the in-situ distribution from PIA and DIDSY weighted heavily by the near-nucleus fluxes leads to a presumed nucleus distribution. The data lead to a puzzling distribution at large masses, not readily explained in an otherwise monotonous power law distribution. Although temporal changes in nucleus activity could and do modify the in-situ size distribution, such an explanation is not wholly possible, because the same form is observed at differing locations in the coma where the time of flight from the nucleus greatly varies. Thus neither a general change in comet activity nor spatial variations lead to a satisfactory explanation.

Mcdonnell, J. A. M.↗

Measurement of the effects of particulate contamination on X-ray reflectivity

Because particles of sizes larger than a few tenths microns adversely affect high resolution X-ray telescopes by scattering and absorbing X-rays, the cleanliness required to maintain the about 1 percent overall calibration precision desired for the Advanced X-ray Astrophysics Facility (AXAF) is being investigated. At the grazing angles used for the AXAF mirrors, each particle shadows a surface area about 100 times its geometric area, necessitating glass occlusion specifications much more stringent than typically stipulated for visible-light particulate contamination. On test flats coated with gold, controlled levels of contamination have been deposited spanning the range from 5 x 10 to the -5th to 0.005 fractional area covered, and the absorption component of extinction has been measured over a range of grazing angles and X-ray energies to verify the predicted effects of particulate contamination.

Slane, P.↗

Foil perforation particulate impact records on LDEF MAP AO023: Incident mass distributions

An array of multiple foils varying from 1.5 to 3.0 microns exposed on Long Duration Exposure Facility's (LEDF's) geocentrically stabilized exposure platform provides perforation distributions which relate to particulate flux mass distributions and impact velocity in LDEF's orbital reference frame. The application of physical modeling enables a preliminary separation into orbital and interplanetary components, both of which have differing velocities and hence penetration effectiveness. Thin foil hypervelocity calibration data and parametric penetration formulae developed to relate target hole diameter to projectile dimensions are critically examined and a new formula offered for the ballistic limit situation. Incorporating projectile density, target density, and target strength and dimensional scaling from submicron particulates to centimeter scale data, it contrast very significantly with previous formulae in the interpretation of space impact data. Perforation flux distributions for the leading, trailing, and space pointing faces and associated mass distributions for the two populations are presented.

Mcdonnell, J. A. M.↗

Compression studies on particulate composites of ternary Al-Ti-Fe, and quaternary Al-Ti-Fe-Nb and Al-Ti-Fe-Mn L1(2) compounds

Compression studies were conducted on monolithic and TiB2 particulate-reinforced composites of Al22Fe3Ti8, both with and without minor quaternary alloying additions (2 at. pct Nb and 2 at. pct Mn) as a function of temperature and as a function of strain rate at high temperature. The volume fraction of reinforcement was varied between 0 and 20 percent. The particulate reinforcements were found to be effective in increasing ambient- and warm-temperature strength; at high temperatures, the monolithic material is stronger than the composites, although the composites are superior at slow strain rates. The microstructures of the monolithic and composite specimens were examined before and after deformation to explain these observations.

Kumar, K. S.↗

A TEOM (tm) particulate monitor for comet dust, near Earth space, and planetary atmospheres

Scientific missions to comets, near earth space, and planetary atmospheres require particulate and mass accumulation instrumentation for both scientific and navigation purposes. The Rupprecht & Patashnick tapered element oscillating microbalance can accurately measure both mass flux and mass distribution of particulates over a wide range of particle sizes and loadings. Individual particles of milligram size down to a few picograms can be resolved and counted, and the accumulation of smaller particles or molecular deposition can be accurately measured using the sensors perfected and toughened under this contract. No other sensor has the dynamic range or sensitivity attained by these picogram direct mass measurement sensors. The purpose of this contract was to develop and implement reliable and repeatable manufacturing methods; build and test prototype sensors; and outline a quality control program. A dust 'thrower' was to be designed and built, and used to verify performance. Characterization and improvement of the optical motion detection system and drive feedback circuitry was to be undertaken, with emphasis on reliability, low noise, and low power consumption. All the goals of the contract were met or exceeded. An automated glass puller was built and used to make repeatable tapered elements. Materials and assembly methods were standardized, and controllers and calibrated fixtures were developed and used in all phases of preparing, coating and assembling the sensors. Quality control and reliability resulted from the use of calibrated manufacturing equipment with measurable working parameters. Thermal and vibration testing of completed prototypes showed low temperature sensitivity and high vibration tolerance. An electrostatic dust thrower was used in vacuum to throw particles from 2 x 10(exp 6) g to 7 x 10(exp -12) g in size. Using long averaging times, particles as small as 0.7 to 4 x 10(exp 11) g were weighted to resolutions in the 5 to 9 x 10(exp -13) g range. The drive circuit and optics systems were developed beyond what was anticipated in the contract, and are now virtually flight prototypes. There is already commercial interest in the developed capability of measuring picogram mass losses and gains. One area is contamination and outgassing research, both measuring picogram losses from samples and collecting products of outgassing.

Source record↗

X-ray evidence for particulate contamination on the AXAF VETA-1 mirrors

X-ray testing of the AXAF outer mirror pairs, in the VETA-1 configuration, reveals a point spread function (PSF) with unexpectedly large wings at low energies. Although the angular dependence in the wings of the PSF is close to that expected for diffractive scattering from surface roughness, the energy dependence differs substantially. Analyses of the observed X-ray PSF, images near ring focus, and single-quadrant images at conjugate focus suggest that the excess scattering observed at low X-ray energies results from diffractive scattering by relatively small grains (as small as a few tenths micrometer in radius). We develop a simple model for the contribution of scattering by particulates to the PSF. Merging this model with that for scattering by surface roughness, we fit the combined model to the observed energy-dependent PSF, in order to estimate parameters and associated uncertainties characterizing the grain-size distribution and the surface-roughness power spectral density. In particular, we find that the fractional coverage of the mirrors by particulates is approximately 1 x 10 exp -4 (for grain radii between 0.1 and 10 microns), and that the rms surface-roughness is approximately 0.7 nm (for spatial frequencies between 1/mm and 1000/mm).

O'Dell, S. L.↗

Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

Henderson, B. G.↗