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At least 163 records · Page 9

Strain-Dependent Surface Defect Equilibria of Mixed Ionic-Electronic Conducting Perovskites

We report understanding the surface defect chemistry and its strain dependency is essential in developing next-generation electrochemical devices. However, due to their nanoscale dimensions, surface defects cannot be accessed by conventional techniques used in bulk defect studies. Here, we constructed the strain-dependent surface defect equilibria (i.e., the Brouwer diagram) of mixed ionic-electronic conducting perovskite oxides with near ambient pressure X-ray absorption spectroscopy. Using coherently strained thin-film La 0.6 Sr 0.4 Fe O3 (LSF) as model systems, we probed their surface defect equilibria at 400 °C in oxygen partial pressures between 1 to 10 -5 Torr. We found that the electron holes on the LSF surfaces have strong oxygen character, regardless of the strain states. Nevertheless, tensile strain makes the LSF surface more reducible than the compressed counterpart. These two observations were then validated using first-principles calculations. Finally, with the aid of thermodynamic analyses, we showed that the strain-dependent surface defect equilibria of LSF can be captured by bulk-like ideal solution defect models with shifted oxygen chemical potentials. The findings and methodology presented in this study enable quantitative determination of the surface defect chemistry, which is crucial to understanding and designing functional surfaces for efficient conversions of energy and fuels.

36 MATERIALS SCIENCE↗

Multiple large-scale coherent mode interactions in a developing round jet

The integral energy method has been used to study the nonlinear interactions of the large-scale coherent structure in a spatially developing round jet. The streamwise development of a jet is obtained in terms of the mean flow shear-layer momentum thickness, the wave-mode kinetic energy and the wave-mode phase angle. With the energy method, a system of partial differential equations is reduced to a system of ordinary differential equations. The nonlinear differential equations are solved with initial conditions which are given at the nozzle exit. It is shown that the initial wave-mode energy densities as well as the initial phase angles play a significant role in the streamwise evolution of the large-scale coherent wave modes and the mean flow.

Lee, Sang S.↗

Demonstrating magnetic field robustness and reducing temporal T1 noise in transmon qubits through magnetic field engineering

The coherence of superconducting transmon qubits is often disrupted by fluctuations in the energy relaxation time (T1), limiting their performance for quantum computing. While background magnetic fields can be harmful to superconducting devices, we demonstrate that both trapped magnetic flux and externally applied static magnetic fields can suppress temporal fluctuations in T1 without significantly degrading its average value or qubit frequency. Using a three-axis Helmholtz coil system, we applied calibrated magnetic fields perpendicular to the qubit plane during cooldown and operation. Remarkably, transmon qubits based on tantalum-capped niobium (Nb/Ta) capacitive pads and aluminum-based Josephson junctions (JJs) maintained T1 lifetimes near 300 μs even when cooled in fields as high as 600 mG. Both trapped flux up to 600 mG and applied fields up to 400 mG reduced T1 fluctuations by more than a factor of two, while higher field strengths caused rapid coherence degradation. We attribute this stabilization to the polarization of paramagnetic impurities, the role of trapped flux as a sink for non-equilibrium quasiparticles (QPs), and partial saturation of fluctuating two-level systems (TLSs). These findings challenge the conventional view that magnetic fields are inherently detrimental and introduce a strategy for mitigating noise in superconducting qubits, offering a practical path toward more stable and scalable quantum systems.

Abdisatarov, Bektur [Fermilab; Jefferson Lab]↗

Virginia Tech Center for Neutrino Physics HEP Umbrella. Final report

This DOE-supported project of Virginia Tech's Center for Neutrino Physics (VT-CNP), funded for a two-year period from July 1, 2017 through April 30, 2019. Supported the efforts our group in the Intensity Frontier, Theory programs. The Intensity Frontier program Prof. Link and his group included continued efforts on the Daya Bay Reactor Neutrino Experiment, starting of a new effort with the COHERENT collaboration studying coherent elastic neutrino scattering at the Oak Ridge National Laboratory's Spallation Neutrino Source, and an advanced reactor neutrino detector development effort known as CHANDLER, which was only partially supported by this grant. In the theory/phenomenology program of Profs. Huber and Horiuchi and their groups pursued independent (but interconnected) research activities including astrophysical searches for particle dark matter with a focus on combining gamma rays with multiple probes, supernova neutrinos, neutrino phenomenology with an emphasis on physics beyond three flavor oscillation, and further development of the GLoBES neutrino oscillation sensitivity tool kit. This group has strong synergy between its efforts in neutrino phenomenology and neutrino-related experimental research, which is the intellectual foundation for the Center for Neutrino Physics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Excitonic Spin-Coherence Lifetimes in CdSe Nanoplatelets Increase Significantly with Core/Shell Morphology

Here, we report spin-polarized transient absorption for colloidal CdSe nanoplatelets as functions of thickness (2–6 monolayer thickness) and core/shell motif. Using electro-optical modulation of co- and cross-polarization pump–probe combinations, we sensitively observe spin-polarized transitions. Core-only nanoplatelets exhibit few-picosecond spin lifetimes that weakly increase with layer thickness. The spectral content of differenced spin-polarized signals indicate biexciton binding energies that decrease with increasing thickness and smaller values than previously reported. Shell growth of CdS with controlled thicknesses, which partially delocalize the electron from the hole, significantly increases the spin lifetime to ~49 ps at room temperature. Implementation of ZnS shells, which do not alter delocalization but do alter surface termination, increased spin lifetimes up to ~100 ps, bolstering the interpretation that surface termination heavily influences spin coherence, likely due to passivation of dangling bonds. Spin precession in magnetic fields both confirms long coherence lifetime at room temperature and yields the excitonic g factor.

2D semiconductor↗

Difference equation for superradiance

The evolution of a completely excited system of N two-level atoms, distributed over a large region and interacting with all modes of radiation field, is studied. The distinction between r-conserving (RC) and r-nonconserving (RNC) processes is emphasized. Considering the number of photons emitted as the discrete independent variable, the evolution is described by a partial difference equation. Numerical solution of this equation shows the transition from RNC dominance at the beginning to RC dominance later. This is also a transition from incoherent to coherent emission of radiation.

Lee, C. T.↗

Improved methods for fan sound field determination

Several methods for determining acoustic mode structure in aircraft turbofan engines using wall microphone data were studied. A method for reducing data was devised and implemented which makes the definition of discrete coherent sound fields measured in the presence of engine speed fluctuation more accurate. For the analytical methods, algorithms were developed to define the dominant circumferential modes from full and partial circumferential arrays of microphones. Axial arrays were explored to define mode structure as a function of cutoff ratio, and the use of data taken at several constant speeds was also evaluated in an attempt to reduce instrumentation requirements. Sensitivities of the various methods to microphone density, array size and measurement error were evaluated and results of these studies showed these new methods to be impractical. The data reduction method used to reduce the effects of engine speed variation consisted of an electronic circuit which windowed the data so that signal enhancement could occur only when the speed was within a narrow range.

Cicon, D. E.↗

Transfer of resonance-line radiation in differentially expanding atmospheres. II - Analytic solution for the case of coherence in the frame of the fluid.

Derivation of an exact solution for the problem of line transfer by resonant scattering (assumed coherent in the fluid frame) in a differentially expanding atmosphere. The probabilistic method developed is a generalization of the method of addition of layers plus a decomposition of the radiation field into partial radiation fields due to those photons that scatter exactly n times before escaping (n = 0, 1, 2, 3,

Noerdlinger, P. D.↗

Voyager photopolarimeter observations of Uranian ring occultations

Occultation profiles have been derived from Voyager 2 photopolarimeter observations of the nine pre-Voyager Uranian rings as well as of 1986U1R. The epsilon ring, which is the broadest and most massive, is noted to possess a wealth of structure which appears to persist coherently around the ring. The photopolarimeter data do not show any features globally ascribable to all the rings observed. Results are presented from a statistical analysis of photopolarimeter data for previously undetected or partial ring arcs.

Colwell, Joshua E.↗

Investigating the dislocation reactions on Σ3{111} twin boundary during deformation twin nucleation process in an ultrafine-grained high-manganese steel

Abstract Some of ultrafine-grained (UFG) metals including UFG twinning induced plasticity (TWIP) steels have been found to overcome the paradox of strength and ductility in metals benefiting from their unique deformation modes. Here, this study provides insights into the atomistic process of deformation twin nucleation at Σ3{111} twin boundaries, the dominant type of grain boundary in this UFG high manganese TWIP steel. In response to the applied tensile stresses, grain boundary sliding takes place which changes the structure of coherent Σ3{111} twin boundary from atomistically smooth to partly defective. High resolution transmission electron microscopy demonstrates that the formation of disconnection on Σ3{111} twin boundaries is associated with the motion of Shockley partial dislocations on the boundaries. The twin boundary disconnections act as preferential nucleation sites for deformation twin that is a characteristic difference from the coarse-grained counterpart, and is likely correlated with the lethargy of grain interior dislocation activities, frequently seen in UFG metals. The deformation twin nucleation behavior will be discussed based on in-situ TEM deformation experiments and nanoscale strain distribution analyses results.

36 MATERIALS SCIENCE↗

First simultaneous observation of co- and counter-current fast-ion losses in the ASDEX Upgrade tokamak

In ITER and future fusion power plants, the source of the fusion born alpha particles is almost isotropic in pitch angle, thus having co- and counter-current populations. For trapped ions, the co-current side of the orbit corresponds to its outer leg, while the counter-current side corresponds to the inner leg. Understanding the mechanisms responsible for the fast-ion losses (FILs) is critical for future magnetically confined fusion power plants. To further study the interplay of fast ions with plasma instabilities, a double pinhole collimator has been developed for a Fast-Ion Loss Detector (FILD) in the ASDEX Upgrade tokamak (AUG). This new FILD opens the operational window to simultaneous measurements of the co- and counter-current ion velocity-space. In this paper, the first results for the AUG double collimator FILD detector are shown. The commissioning of this new probe is carried out in H-mode plasmas with an on-axis magnetic field $B_0 = -2.5$ T, and a plasma current $I_{\textrm{p}} = 0.7$ MA. Simultaneous co- and counter-current FILs have been measured. Both have shown a similar dependence on Ion Cyclotron Resonance Heating (ICRH) power, where the main difference is the intensity of the losses, with the co-losses being an order of magnitude larger. Toroidal Alfvén eigenmode-coherent ICRH-only losses have been identified for the co-current ions. Additionally, the presence of Edge Localized Modes during the discharge were shown to increment Neutral Beam Injection prompt losses, while partially mitigating ICRH-driven losses on both co- and counter- sides of the velocity-space. Finally, a very trapped and high gyroradius losses, with an unclear origin, have been measured in the co- and counter-current velocity-space. The computed ion trajectories show that these ions remain permanently near the vessel wall, suggesting that they are accelerated within the scrape-off layer.

ELM↗

Efficient light harvesting and photon sensing via engineered cooperative effects

Abstract Efficient devices for light harvesting and photon sensing are fundamental building blocks of basic energy science and many essential technologies. Recent efforts have turned to biomimicry to design the next generation of light-capturing devices, partially fueled by an appreciation of the fantastic efficiency of the initial stages of natural photosynthetic systems at capturing photons. In such systems extended excitonic states are thought to play a fundamental functional role, inducing cooperative coherent effects, such as superabsorption of light and supertransfer of photoexcitations. Inspired by this observation, we design an artificial light-harvesting and photodetection device that maximally harnesses cooperative effects to enhance efficiency. The design relies on separating absorption and transfer processes (energetically and spatially) in order to overcome the fundamental obstacle to exploiting cooperative effects to enhance light capture: the enhanced emission processes that accompany superabsorption. This engineered separation of processes greatly improves the efficiency and the scalability of the system.

42 ENGINEERING↗

Coherent electronic-vibrational dynamics in deuterium bromide probed via attosecond transient-absorption spectroscopy

Ultrafast laser excitation can trigger multiplex coherent dynamics in molecules. Here, we report attosecond transient-absorption experiments addressing simultaneous probing of electronic and vibrational dynamics in a prototype molecule, deuterium bromide (DBr), following its strong-field ionization. Electronic and vibrational coherences in the ionic X$^2\Pi_{3/2}$ and X$^2\Pi_{1/2}$ states are characterized in the Br-$3d$ core-level absorption spectra via quantum beats with 12.6-fs and 19.9-fs periodicities, respectively. Polarization scans reveal that the phase of the electronic quantum beats depends on the probe direction, experimentally showing that the coherent electronic motion corresponds to the oscillation of the hole density along the ionization-field direction. The vibrational quantum beats are found to maintain a relatively constant amplitude, whereas the electronic quantum beats exhibit a partial decrease in time. Quantum wave-packet simulations show that the decoherence effect from the vibrational motion is insignificant because of the parallel relation between the X$^2\Pi_{3/2}$ and X$^2\Pi_{1/2}$ potentials. Finally, a comparison between the DBr and HBr results suggests that rotation motion is responsible for the decoherence since it leads to initial alignment prepared by the strong-field ionization.

74 ATOMIC AND MOLECULAR PHYSICS↗

Search for Pulsations from a Nearby Millisecond Pulsar and Wasilewski 49: Mirror for a Hidden Seyfert 1 Nucleus

Five studies are reported in this final report. The recently discovered 5.3 ms pulsar J1012+5307 at a distance of 520 pc is in an area of the sky which is particularly deficient in absorbing gas. The column density along the line of sight is less than 7.5 x 10(exp 19) CM(exp -2) which facilitates soft X-ray observations. Halpern reported a possible ROSAT Position Sensitive Proportional Counter (PSPC) detection of the pulsar in a serendipitous, off-axis observation. We have now confirmed the X-ray emission of PSR J1012+,5307 in a 23 ksec observation with the ROSAT High Resolution Imager (HRI). A point source is detected within 3" of the radio position. Its count rate of 1.6 +/- 0.3 x 10(exp -3) s(exp -1) corresponds to an unabsorbed 0. 1-2.4 keV flux of 6.4 x 10(exp -14) ergs cm(exp -2) s(exp -1), similar to that reported previously. This counts-to-flux conversion is valid for N(sub H) = 5 x 10(exp 19) cm(exp -2), and either a power-law spectrum of photon index 2.5 or a blackbody of kT = 0.1 keV. The implied X-ray luminosity of 2.0 x 10(exp 30) ergs s(exp -1) is 5 X 10(exp -4) of the pulsar's spin-down power dot-E, and similar to that of the nearest millisecond pulsar J0437-4715, which is nearly a twin of J1012+5307 in P dot-E. We subjected the 37 photons (and 13 background counts) within the source region to a pulsar search, but no evidence for pulsation was found. The pulsar apparently emits over a large fraction of its rotation cycle, and the absence of sharp modulation can be taken as evidence for surface thermal emission, as is favored for PSR J0437-4715, rather than magnetospheric X-ray emission which is apparent in the sharp pulses of the much more energetic millisecond pulsar B1821-24. A further test of this interpretation will be made with a longer ROSAT observation, which will increase the number of photons collected by a factor of 5, and permit a more sensitive examination of the light curve for modulation due to emission from heated polar caps. If found, such modulation will be further evidence that surface reheating by the impact of particles accelerated along open fiel;d lines operates in these approximately 10(exp -9) year old pulsars. In a second study, a new AM Her star serendipitously in a 25 day observation was detected with the EUVE satellite. A coherent period of 85.82 min is present in the EUVE Deep Survey imager light curve of this source. A spectroscopic optical identification is made with a 19th magnitude blue star that has H and He emission lines, and broad cyclotron humps typical of a magnetic cataclysmic variable. A lower limit to the polar magnetic field of 50 MG is estimated from the spacing of the cyclotron harmonics. EUVE J0425.6-5714 is also detected in archival ROSAT HRI observations spanning two months, and its stable and highly structured light curve permits us to fit a coherent ephemeris linking the ROSAT and EUVE data over a 1.3 yr gap. The derived period is 85.82107 +/- 0.00020 min, and the ephemeris should be accurate to 0.1 cycles until the year 2005. A narrow but partial X-ray eclipse suggests that this object belongs to the group of AM Her stars whose viewing geometry is such that the accretion stream periodically occults the soft X-ray emitting accretion spot on the surface of the white dwarf. A non-detection of hard X-rays from ASCA observations that are contemporaneous with the ROSAT HRI shows that the soft X-rays must dominate by at least an order of magnitude, which is consistent with a known trend among AM Her stars with large magnetic field. This object should not be confused with the Seyfert galaxy IH 0419-577 (= LB 1727), another X-ray/EUV source which lies only 3'95 away, and was the principal target of these monitoring observations. In a third report; the identity of the persistent high-energy (> 100 MeV) gamma-ray sources in the Galaxy, still largely a mystery is investigated. The second installment of the EGRET (2EG) lists a total of 128 sources, of which 51 are likely or possibly identified with AGNs, five with rotation-powered pulsars, and one is the LMC. There are 71 unidentified sources, of which 33, or almost half, lie in the narrow band of absolute value of b < 10 degrees along the Galactic plane. This excess of low-latitude sources must, therefore, constitute a Galactic population that is either similar to the already identified gamma-ray pulsars, or an entirely new class of gamma-ray emitters associated with the disk population. We are continuing our program, begun in A06, that is aimed at intermediate-latitude sources, arguing that X-ray detection of them is the most plausible method of identifying the Galactic population. The sources at high latitude must statistically be mostly AGNS, and are more straightforwardly identified through radio and optical means. For the fourth report, identification of the EGRET Source the identity of the persistent, high-energy gamma-ray sources in the Galactic plane is a mystery. The most likely scenario is a population of middle-aged pulsars, many of which could be radio quiet like Geminga. We have an ongoing program of ROSAT, VLA, and optical observations of selected EGRET error circles at intermediate Galactic latitude. For one of these fields, at (l, b) = (106 degrees, +3), our complete census of X-ray and radio sources, reveals a remarkable association between a radio shell with unique properties, and a complete census of X-ray and radio sources reveals a remarkable association between a radio shell with unique properties, and a compact X-ray source. Further observations are needed to determine whether or not this source has a hard X-ray spectrum like that of other gamma ray pulsars and, ideally, to find its pulsations. A fifth report reviews, Wasilewski 49, an interacting pair of Seyfert galaxies at z = 0.063, one of which contains a hidden Seyfert I nucleus as evidenced by broad wings on its Balmer lines.

Halpern, Jules P.↗

Resonance-line transfer with partial redistribution. VII Angle-dependent redistribution

A method is presented for treating radiative transfer in resonance lines, allowing for the full angle and frequency dependence of redistribution in the scattering process, as seen in the laboratory frame. The case of an equivalent-two-level-atom source function is considered; the problem to be treated is then linear in the radiation field. We apply this method to the Ca II lines in the solar atmosphere, using a redistribution function which takes into account a mixture of coherence in the atom's frame, with Doppler redistribution in the laboratory frame (for atoms which have not suffered an elastic collision), and of complete redistribution in the laboratory frame (for atoms that are collisionally perturbed during the emission process). Both the angle-averaged approximation and the full angle-dependent solution were obtained, and were compared to assess, differentially, the effects of angular redistribution upon the computed line profile and its center-to-limb behavior. For the Ca II line in a homogeneous solar chromosphere the angle-dependent effects are found to be negligible, indicating that one may use angle-averaged redistribution functions when studying partial redistribution effects in line profiles.

Milkey, R. W.↗

Generation of the TSL for Zirconium Hydrides from Ab Initio Methods

Zirconium hydride (ZrHx) is a moderator material used in TRIGA and other reactors that may exist in multiple phases with varying stoichiometry, which include the δ phase and the ϵ phase. Current ENDF/B-VIII.0 ZrHx thermal scattering law (TSL) evaluations do not distinguish between phases. These sub-libraries were generated with the LEAPR module of NJOY using historic phonon spectra derived from a central force model and assume incoherent elastic scattering for both bound hydrogen and zirconium, which neglects the effects of crystal structures important for scattering from zirconium bound in ZrHx. In this work, the TSLs for hydrogen and zirconium bound in δ-ZrHx and ϵ-ZrH2 were generated from phonon spectra derived from modern ab initio lattice dynamics methods and ab initio molecular dynamics. Subsequently, TSLs for hydrogen and zirconium in ZrHx and ZrH2 were generated using the Full Law Analysis Scattering System Hub (FLASSH) code. The built-in generalized coherent elastic routine was used to generate the previously neglected elastic contribution from zirconium for this material. The present TSLs provide both a re-evaluation of the current ZrH sub-libraries and expansion of the set of TSLs available for the examination of neutrons in systems with zirconium hydride, permitting explicit treatment of δ and ϵ phases.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Fermionic systems for quantum information people

The operator algebra of fermionic modes is isomorphic to that of qubits, the difference between them is twofold: the embedding of subalgebras corresponding to mode subsets and multiqubit subsystems on the one hand, and the parity superselection in the fermionic case on the other. We discuss these two fundamental differences extensively, and illustrate these through the Jordan–Wigner representation in a coherent, self-contained, pedagogical way, from the point of view of quantum information theory. Our perspective leads us to develop useful new tools for the treatment of fermionic systems, such as the fermionic (quasi-)tensor product, fermionic canonical embedding, fermionic partial trace, fermionic products of maps and fermionic embeddings of maps. We formulate these by direct, easily applicable formulas, without mode permutations, for arbitrary partitionings of the modes. It is also shown that fermionic reduced states can be calculated by the fermionic partial trace, containing the proper phase factors. We also consider variants of the notions of fermionic mode correlation and entanglement, which can be endowed with the usual, local operation based motivation, if the parity superselection rule is imposed. We also elucidate some other fundamental points, related to joint map extensions, which make the parity superselection inevitable in the description of fermionic systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Analysis of the laser welding keyhole using inline coherent imaging

Laser beam welding is a widely used fusion welding process in many industrial applications such as automotive, aerospace, energy, defense, and medical products. Industry has a fundamental need to model the laser welding process to minimize experimental testing and improve confidence in production welds. However, computational models attempting to predict weld formation are limited by an incomplete understanding of the beam-material interactions. As a consequence, these models do not accurately predict the mechanisms associated with laser weld formation. To improve the current state of prediction capabilities, it is vital to better detect/measure the physical aspects of the weld pool during high energy density welding. In this work, a novel real-time laser weld monitoring device using inline coherent imaging (ICI) was used to provide a fundamental understanding of laser weld formation via vaporization. The objective of this work was to investigate and quantify the relationship relating laser weld parameters and the vapor capillary (keyhole) through a state-of-the-art measurement technique. Bead-on-plate laser beam welds were produced with partial penetration on 304L stainless steel, 2205 duplex stainless steel, and Ti-6Al-4V. Keyhole monitoring was performed using a commercially available ICI system to collect keyhole penetration data in real time. These measurements were reconstructed to generate the vapor capillary shape at different welding parameters. Process parameters significantly influenced the keyhole shape and the keyhole root position relative to the process beam. Finally, the keyhole geometry showed distinct differences between the stainless steel alloys and Ti-6Al-4V.

2205↗