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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Electrothermal Micromirror Adaptive Illumination

As part of the Cyclotron Road program, Helux Lighting aimed to develop a highly adaptive illumination source based on microelectromechanical system (MEMS) technology and next-generation solid state lighting. Solid state lighting has caused a paradigm shift in the industry. Developing systems that put light only where it is needed can reduce energy consumption and have an impact on the well-being of the population by eliminating glare and wasted light. Full control could also reduce the disruption of sensitive ecosystems caused by light pollution. The most advanced fixtures available today are based on mechanical components that are bulky and expensive. The track light is the only inexpensive lighting system that permits redirection and, in some cases, spot size by motorized optical components. The most advanced light fixtures today are composed of a strategically arranged array of LEDs. More recent developments in the research community include dynamic liquid crystal lenses but fail to realize simultaneous dynamic steering and spot size. In this project, Helux worked on the capability development of their controllable micromirror combined with state-of-the-art solid state lighting to electronically adjusting light position, brightness, and illumination area.

42 ENGINEERING↗

X-ray Security Imaging on Personal Dosimetry [Slides]

Federal regulations mandate that personal dosimetry devices — like optically stimulated luminescence (OSLs) — must be worn by all US Department of Energy (DOE) and associated radiation workers to track their occupational dose. Unfortunately, the inadvertent passage of OSLs through x-ray security scanners can compromise their validity. With the advent of high energy, advanced resolution security technology used in airports, this once insignificant issue now requires that Radiological Control (RadCon) be able to accurately discern non-occupational dose to effected OSLs. This presentation will discuss the principles, methods, and, rather surprising, models for establishing the corrective dose estimates at the Idaho National Laboratory (INL), and its implication across the DOE.

61 RADIATION PROTECTION AND DOSIMETRY↗

X-ray Security Imaging on Personal Dosimetry

Federal regulations mandate that personal dosimetry devices — like optically stimulated luminescence (OSLs) — must be worn by all US Department of Energy (DOE) and associated radiation workers to track their occupational dose. Unfortunately, the inadvertent passage of OSLs through x-ray security scanners can compromise their validity. With the advent of high energy, advanced resolution security technology used in airports, this once insignificant issue now requires that Radiological Control (RadCon) be able to accurately discern non-occupational dose to effected OSLs. This presentation will discuss the principles, methods, and, rather surprising, models for establishing the corrective dose estimates at the Idaho National Laboratory (INL), and its implication across the DOE.

61 RADIATION PROTECTION AND DOSIMETRY↗

A Molten Salt Aerosol Spectroscopy Approach to Online Process Monitoring in Molten Salt Reactors

Recent research and development in molten salt reactors (MSRs) has led to many advanced reactor designs, many of which have demonstrations planned in the next decade. However, a significant challenge that must be overcome before liquid fueled MSRs become viable globally is nuclear material accountancy (NMA) and safeguards. Liquid-fueled MSRs are problematic to safeguards because the nuclear material is in the bulk phase, inventories are constantly changing, and there are potentially many outlet pathways that must be monitored, especially in designs with online chemical processing. At the Idaho National Laboratory, we have developed a process monitoring tool to circulate molten salt through a nebulizer and optical cell, where laser-induced breakdown spectroscopy (LIBS) and ultraviolet-visible (UV-VIS) are applied to track the elemental and oxidation states of the constituents in the salt aerosol. This approach has the potential to provide information on the actinides, fission products, and corrosion in the reactor or process. Preliminary testing in aqueous praseodymium chloride (PrCl3) and neodymium chloride (NdCl3) showed good sensitivity detection limits n developed calibration curves. Additional tests and analysis or ongoing in aqueous solutions while equipment is being scaled up for high temperature molten salt testing. Results for continued testing as well as a status of the molten salt design and anticipated commissioning will be presented.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

In Situ Spectroscopic Monitoring of MSR Molten Salt and Off-Gas Systems

A significant challenge that must be overcome before commercialization of molten salt reactors is tracking special nuclear material (SNM) through the reactor and subsystems such as fuel chemical processing and off-gas systems. In recent years, several approaches have been explored to track SNM, fission products, and corrosion products in these different subsystems. One such approach is to employ laser and optical spectroscopy to measure the atomic and molecular signals of MSR salts. The advantages of these approaches are that they typically are non-intrusive and offer the capability of process monitoring while still providing low uncertainties. At the Idaho National Laboratory, spectroscopy approaches such as laser-induced breakdown spectroscopy (LIBS) and ultraviolet-visible (UV-Vis) spectroscopy have been utilized to investigate molten salts in an aerosol (LiCl, KCl, RbCl2, NdCl3, and PrCl3) and vapor phases (MgCl5, NdCl5, and ZrCl4) with success. Testing to date has yielded qualitative information on all the above species and quantitative data and analytical figures of merit for species in the vapor phases. These findings, including results from ongoing testing, as well as the experimental conditions and potential applications will be presented.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

A non-intrusive optical approach to characterize heliostats in utility-scale power tower plants: Flight path generation/optimization of unmanned aerial systems

A newly developed in situ non-intrusive optical (NIO) approach has been developed to survey various types of heliostat optical errors for a concentrating solar power (CSP) tower plant. To measure mirror surface slope error, facet canting error, and heliostat tracking error at a sub-milliradian accuracy, NIO requires several reflection images scanned over each individual heliostat. For a utility-scale plant that typically includes more than 10,000 heliostats, an unmanned aerial system (UAS) is crucial for efficient implementation of the NIO method. Here, we develop a flight path generation/optimization algorithm to plan more efficient UAS paths to collect NIO data over a utility-scale heliostat field. The algorithm considers NIO data requirements, all potential constraints, optimization within each subfield, and operational flexibility. Case studies are presented to illustrate the feasibility and robustness of the developed flight path algorithm. The path planning algorithm may also find applications elsewhere, such as drone-driven imaging under extreme conditions.

14 SOLAR ENERGY↗

Impact of environmental oxygen on nanoparticle formation and agglomeration in aluminum laser ablation plumes

Here, the role of ambient oxygen gas (O 2 ) on molecular and nanoparticle formation and agglomeration was studied in laser ablation plumes. As a lab-scale surrogate to a high explosion detonation event, nanosecond laser ablation of an aluminum alloy (AA6061) target was performed in atmospheric pressure conditions. Optical emission spectroscopy and two mass spectrometry techniques were used to monitor the early to late stages of plasma generation to track the evolution of atoms, molecules, clusters, nanoparticles, and agglomerates. The experiments were performed under atmospheric pressure air, atmospheric pressure nitrogen, and 20% and 5% O 2 (balance N 2 ), the latter specifically with in situ mass spectrometry. Electron microscopy was performed ex situ to identify crystal structure and elemental distributions in individual nanoparticles. We find that the presence of ≈20% O 2 leads to strong AlO emission, whereas in a flowing N 2 environment (with trace O 2 ), AlN and strong, unreacted Al emissions are present. In situ mass spectrometry reveals that as O 2 availability increases, Al oxide cluster size increases. Nanoparticle agglomerates formed in air are found to be larger than those formed under N 2 gas. High-resolution transmission electron microscopy demonstrates that Al 2 O 3 and AlN nanoparticle agglomerates are formed in both environments; indicating that the presence of trace O 2 can lead to Al 2 O 3 nanoparticle formation. The present results highlight that the availability of O 2 in the ambient gas significantly impacts spectral signatures, cluster size, and nanoparticle agglomeration behavior. These results are relevant to understanding debris formation in an explosion event, and interpreting data from forensic investigations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The SHMS 11 GeV/c spectrometer in Hall C at Jefferson Lab

The Super High Momentum Spectrometer (SHMS) has been built for Hall C at the Thomas Jefferson National Accelerator Facility (Jefferson Lab). With a momentum capability reaching 11 GeV/ c , the SHMS provides measurements of charged particles produced in electron-scattering experiments using the maximum available beam energy from the upgraded Jefferson Lab accelerator. The SHMS is an ion-optics magnetic spectrometer comprised of a series of new superconducting magnets which transport charged particles through an array of triggering, tracking, and particle-identification detectors that measure momentum, energy, angle and position in order to allow kinematic reconstruction of the events back to their origin at the scattering target. The detector system is protected from background radiation by a sophisticated shielding enclosure. The entire spectrometer is mounted on a rotating support structure which permits measurements to be taken with a large acceptance over laboratory scattering angles from 5.5° to 40°, thus allowing a wide range of low cross-section experiments to be conducted. Finally, these experiments complement and extend the previous Hall C research program to higher energies.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Light Management in Bifacial Photovoltaics with Spectrally Selective Mirrors

Spectrally-selective mirrors that simultaneously provide above-bandgap anti-reflection and sub-bandgap light rejection are tested for their ability to provide passive cooling to partially sub-bandgap transparent bifacial photovoltaics. The optical and thermal benefits of both idealized and real, low-complexity spectrally-selective mirrors on single-axis tracking, bifacial PERC arrays under realistic conditions are tested via rigorous finite element simulations. Four- and six-layer mirror designs increased carrier generation beyond what traditional antireflection coatings can provide without the associated cell heating. Here, idealized mirrors were found to provide up to 2.4 °C of cooling when included on both air/glass interfaces of the bifacial module.

14 SOLAR ENERGY↗

Magnetic design of the commutational magnet and quadrupoles for PERLE accelerator

ER@CEBAF is an effort to demonstrate multi-GeV multipass energy recovery with a low beam current in CEBAF. The CEBAF race-track-shaped geometry allows its linacs to accommodate multiple energy beams simultaneously. However, five energy recovery passes complicate the beamline optics design process. Individual recirculating arcs each transport one beam energy, and are shared between accelerating/decelerating beams. This paper presents a CEBAF optics redesign to accommodate the ER@CEBAF multi-pass ER scheme. Isochronous arcs were retuned to match into optics solutions for optimized 10-pass linacs. In this paper, we discuss the optics re-design process for ER@CEBAF based on the existing CEBAF layout.

Neththikumara, I.↗

Advancing Temperature Monitoring of the Bottom Anode in a Direct Current Electric Arc Furnace Operations with Distributed Optical Fiber Sensors.

The bottom anode in the Direct Current Electric Arc Furnace (DC EAF) is critical for completing the electrical circuit necessary for sustaining the arc within the furnace. For pin-type bottom anodes, monitoring of the temperature of select pins instrumented with thermocouples is performed to track bottom wear in the EAF and inform the operator when the furnace should be removed from service. Furthermore, this work presents the results from a plant trial using distributed temperature monitoring of bottom anode pins in a 165-ton DC EAF over a two-month service period utilizing two optical fiber sensing techniques: fiber Bragg grating (FBG) and Rayleigh backscattering (RBS). The early detection of temperature anomalies along the length of the anode pin through distributed sensing enhances operational safety, providing a robust alternative to traditional thermocouples.

42 ENGINEERING↗

Nanocrystal-to-Ligand Interfacial Thermal Transport: Plasmonic Indium Tin Oxide to Perylene Diimide Adsorbates

The generation and dissipation of heat in nanocrystals upon optical excitation is a process which may either limit or enhance their performance in certain applications. Using transient absorption spectroscopy, we tracked the flow of heat from plasmonic tin-doped indium oxide (ITO) nanocrystals to surface adsorbed perylenediimide (PDI) molecules upon excitation of the ITO near-infrared plasmon resonance. Here, we rationalize the derivative line shapes observed in the transient absorption bleach features are the result of thermal transfer from the ITO core to surface ligands based on temperature-dependent static absorption studies of the PDI molecules adsorbed on plasmonic ITO. Through a series of pump power dependent measurements, we demonstrate that the PDI heating time is largely fluence independent at the powers measured, while the overall recovery time increases. Elucidating thermal transfer rates at the nanocrystal and organic ligand interface is key for applications such as plasmon mediated photocatalysis, where heating may obfuscate hot carrier transfer processes.

heat dissipation↗

Critical slowing of the spin and charge density wave order in thin film Cr following photoexcitation

We report on the evolution of the charge density wave (CDW) and spin density wave (SDW) orders of a chromium film following photoexcitation with an ultrafast optical laser pulse. The CDW is measured by ultrafast time-resolved x-ray diffraction of the CDW satellite that tracks the suppression and recovery of the CDW following photoexcitation. We find that as the temperature of the film approaches a discontinuous phase transition in the CDW and SDW orders, the time scales of recovery increase exponentially from the expected thermal time scales. We extend a Landau model for SDW systems to account for this critical slowing with the appropriate boundary conditions imposed by the geometry of the thin film system. This model allows us to assess the energy barrier between the available CDW/SDW states with different spatial periodicities.

36 MATERIALS SCIENCE↗

Magnetic Designs of New First Target Beamline Magnets for the ORNL SNS Upgrade

The Spallation Neutron Source (SNS) at ORNL currently is being upgraded from 1.0 GeV to 1.3 GeV. Several water-cooled magnets should be upgraded to transport 30% of higher beam energy. New chicane, injection/extraction septum, and Lambertson magnets were designed. Designing the magnets was a challenging task because the new magnets required good combined integrated field quality and needed to occupy the old magnets space but with about 20% greater integrated magnetic field. Additional strong requirements applied to the magnets fringe field do not disturb the circulating beam. The special field profiles had to be provided in foil areas between magnets. The analysis described here was based on OPERA3D simulations. A special technique was used for analyzing the integrated field harmonics. Initially, the particle track was simulated, and integrated field components were calculated along this track for the reference radius, which were used for the harmonics analysis. In addition, 3D field maps were provided for beam optics simulations. The final beamline analysis confirmed good beam transmission and low losses.

3d field maps↗

Ultra-High Efficiency and Stable All-Perovskite Tandem Solar Cells

In the project period, the research team has fabricated more than 6,000 single-junction wide-bandgap (wide-E g ) and low-bandgap (low-E g ) perovskite solar cells (PSCs) and more than 2,000 all-perovskite tandem solar cells (APTSCs). The best-performing wide-E g and low-E g PSCs and APTSCs showed PCEs greater than 19%, 23%, and 30%, respectively. The average PCEs for wide-E g and low-E g PSCs and APTSCs fabricated by the benchmark processes are (18.5 ± 0.4)%, (21.9 ± 0.8)%, and (26.8 ± 2.1)%, respectively. We have demonstrated APTSCs with T 80 lifetime of more than 1,000 h, which were measured by maximum power point tracking (MPPT) under one sun operation in the air. The team has also utilized various advanced characterization techniques to study the optical and electrical properties of wide-E g and low-E g perovskite materials and devices, developing a better understanding of the unique working principle and degradation mechanism of APTSCs. The team has met most GNG decision criteria except for the stability goal of APTSCs under 85 °C/85 RH accelerated lifetime test (ALT). The shortfall of the device ALT stability is mainly limited by the intrinsic instability of Sn-Pb perovskites under illumination at elevated temperatures. The team discussed with stakeholders in the PV academic and industry about these durability concerns and concluded that this is the major technical barrier preventing the market entry of APTSCs. Future fundamental study and R&D work are needed to advance this promising technology.

14 SOLAR ENERGY↗

In situ observation of short- and long-timescale material property evolution under extreme conditions

Directly observing the evolution of material performance in-situ under extreme conditions remains a great challenge. Emergent behavior, such as the transition from incubation to steady state void swelling, is often difficult to capture in these conditions. To fill this gap, transient grating spectroscopy (TGS) has been used to collect multi-property information in-situ under high temperature exposure to ion beam irradiation. This all-optical method returns elastic and thermal transport properties with second-scale time resolution. Here, recent work using this methodology to track the evolution of Ni-based solid-solution alloys using the in situ ion irradiation TGS (I3TGS) beamline will be described. Tracking material property evolution during long exposure times (hours) provides a clear indication of when void swelling has occurred. On short timescales (seconds to minutes), observing rapid changes in thermoelastic properties as defect generation is initiated allows a unique window into bulk transient defect populations which are otherwise difficult to observe.

36 MATERIALS SCIENCE↗

Unmanned Aerial Vehicle Path Generation for Image Collection to Assist Heliostat Field Optical Characterization

This paper focuses on applications of unmanned aerial vehicles (UAVs) for measuring optical error of heliostats in concentrating solar power (CSP) plants. In CSP, there is a need to measure solar-field optical errors, which is critical for future production improvement as well as for operations and maintenance of a heliostat field. This latter need is particularly challenging because of the large number of heliostats (over 10,000 for a utility-scale power plant) that individually track the sun in the field. To address this issue, a camera-equipped UAV, with an optimized drone flight path developed and uploaded to it, collects images of a precise reflection of the tower on each heliostat to evaluate optical error sources without interrupting plant operation. Generation of the drone path for capturing the reflected images is affected by a number technical and realistic constraints, which include the camera angle used to capture the image, the blocking of the camera view due to surrounding heliostats, the location of the camera in reference to the target heliostat, and the target heliostat position with reference to the tower. The effect of these constraints on calculating the camera position will be discussed in detail in this article. An effective drone-path algorithm is generated to fulfil the need of image collection under various constraints.

concentrated solar power↗