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At least 163 records · Page 9

Surface plasmons at the Brillouin zone boundary of an oblique lattice

In periodic systems of low-symmetry, the Bragg condition for the complete interference of waves along the contour of the Brillouin zone (BZ) boundary is not generally satisfied. As a result, band-gaps do not necessarily occur at this boundary. This letter demonstrates this experimentally by recording the iso-frequency contours for surface plasmon polaritons (SPPs) supported on a diffraction grating with an underlying 2D oblique Bravias lattice. It is shown that these contours do not intersect the BZ boundary perpendicularly, as the symmetry operations of the lattice place no conditions on the surface wave interference at this boundary.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Dynamic spin localization and γ -magnets

Here, we explore an unusual type of quantum matter that can be realized by qubits having different physical origins. Interactions in this matter are described by essentially different coupling operators for all qubits. We show that the simplest such models, which can be realized with localized states in Dirac materials, satisfy integrability conditions that we use to describe pseudospin dynamics in a linearly time-dependent magnetic field. Generalizing to an arbitrary number of qubits, we construct a spin Hamiltonian, which we call the γ -magnet. This system does not conserve polarization of any spin and the net spin polarization. Nevertheless, for arbitrarily strong interactions, nonadiabatic dynamics, and any initial eigenstate, we find that quantum interference suppresses spin flips. This behavior resembles many-body localization but occurs in phase space of many spins rather than real space. This effect may not have a counterpart in classical physics and can be a signature of a new type of spin ordering, which is different from both disordered spin glasses and ordered phases of spin lattices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effects of stray lights on Faraday rotation measurement for polarimeter-interferometer system on EAST

A double-pass radially view 11 chords polarimeter-interferometer system has been operated on the experimental advanced superconducting tokamak and provides important current profile information for plasma control. Stray light originating from spurious reflections along the optical path (unwanted reflections from various optical components/mounts and transmissive optical elements such as windows, waveplates, and lens as well as the detectors) and also direct feedback from the retro-reflector used to realize the double-pass configuration can both contribute to contamination of the Faraday rotation measurement accuracy. Modulation of the Faraday rotation signal due to the interference from multiple reflections is observable when the interferometer phase (plasma density) varies with time. Direct reflection from the detector itself can be suppressed by employing an optical isolator consisting of a λ/4-waveplate and polarizer positioned in front of the mixer. A Faraday angle oscillation during the density ramping up (or down) can be reduced from 5°–10° to 1°–2° by eliminating reflections from the detector. Residual modulation arising from misalignment and stray light from other sources must be minimized to achieve accurate measurements of Faraday rotation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Feasibility study of a high spatial and time resolution beam emission spectroscopy diagnostic for localized density fluctuation measurements in Lithium Tokamak eXperiment-β (LTX-β)

Trapped electron mode (TEM) is the main source of turbulence predicted for the unique operation regime of a flat temperature profile under low-recycling conditions in the LTX-β tokamak, while ion temperature gradient driven turbulence may also occur with gas fueling from the edge. To investigate mainly TEM scale density fluctuations, a high spatial and time resolution 2D beam emission spectroscopy (BES) diagnostic is being developed. Apart from spatially localized density turbulence measurement, BES can provide turbulence flow and flow shear dynamics. This BES system will be realized using an avalanche photodiode-based camera and narrow band interference filter. The system can acquire data at 2 MHz. Simulations with the Simulation of Spectra (SOS) code indicate that a high signal to noise ratio can be achieved with the proposed system. This will enable sampling the density fluctuations at this high time resolution. Finally, the design considerations and system optimization using the SOS code are presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evaluation of a semiconductor-based atmospheric radioxenon detection system

A prototype radioxenon detection system for beta–gamma coincidence measurements has been designed using a PIPSBox and a pair of coplanar CdZnTe (CZT) detectors. Coincidence events are identified in real-time using a Field-Programmable Gate Array (FPGA). The measurement of 131m Xe and studies on electron backscatter and memory effect in the PIPSBox have been presented previously; this paper details the measurement of 133/133m Xe, 135 Xe, and background. Here, absolute efficiencies were determined, regions of interest were defined, and Minimum Detectable Concentrations (MDC) for all four radioxenon isotopes were calculated. When neglecting interferences between the radioxenons, the prototype system has an estimated MDC of 0.61 ± 0.15 mBq/m 3 for 133 Xe when using gas processing parameters associated with Xenon International, satisfying the CTBTO requirement for sensitivity of ≤1 mBq/m 3 for 133 Xe. Simulation suggests that by increasing number of CZT detectors used by a factor of 16, the MDCs of the system can be improved by a factor of 2-3. The design shows great promise for future improvement and expansion due to its exceptional energy resolution, high background rejection rate, room temperature operation, minimal memory effect, and simple readout electronics.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Proximity effect bilayer nano superconducting quantum interference devices for millikelvin magnetometry

Superconducting quantum interference devices (SQUIDs) incorporating thin film nanobridges as weak links have sensitivities approaching that required for single spin detection at 4.2 K. However, due to thermal hysteresis they are difficult to operate at much lower temperatures which hinder their application to many quantum measurements. To overcome this, we have developed nanoscale SQUIDs made from titanium-gold proximity bilayers. We show that their electrical properties are consistent with a theoretical model developed for heat flow in bilayers and demonstrate that they enable magnetic measurements to be made on a sample at system temperatures down to 60 mK.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Rapid Analytical Methodology for Chloride Molten Salt Reactor Safeguards and Process Monitoring

Technologies that enable near real-time isotopic analysis of advanced molten salt reactor (MSR) fuels are critically needed to safeguard these reactors, increase their operational efficiency, and enable their widespread deployment with confidence. We present a systematic approach to developing near real-time dissolution and chemical isolation of U, Pu, and major fission products from highly radioactive chloride molten salt samples. Chemical yields greater than 95% were observed for both uranium and the lanthanides. Interference reduction enabled the detection and quantification of key diagnostic isotopes (including 112Ag, 147Nd, and 153Sm) that were previously undetectable in the original sample. The results from this initial scoping study lay the foundation for the development of future automated systems that can enable cost-efficient, near-real time chemical separation and analysis of extremely highly radioactive molten salt samples.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗

Commercial Building Technology Demonstration (Final Scientific/Technical Report)

The background for this project was a unique and innovative concept that had been proposed and demonstrated by enVerid Systems, reducing the energy consumption in HVAC systems in commercial and public buildings by up to 50% at peak loads. The concept involves selective scrubbing of gas contaminants from indoor air as a practical substitute for outside air ventilation, the latter being the conventional practice today. This scrubbing enables recycling of most of the indoor air and significantly decreasing the amount of outside air, resulting in a reduced HVAC load and commensurate energy savings for the facility. Key to our approach is low cost scrubbing of all gas contaminants from indoor air using novel, efficient and regenerable sorbent materials. The total solution, labeled HLR (HVAC Load Reduction) is implemented by means of compact modules that can be retrofitted onto virtually any building, and utilizes novel sorbents that have been developed and brought to scale production by enVerid. Although the technology had been deployed and demonstrated, the US commercial building and HVAC markets, famously conservative with respect to innovation and new technologies, had yet to embrace the idea or the product. The overarching goal of the project was to help overcome market hesitancy and enable widespread adoption, by creating a critical mass of success stories across different regions and building types, all under oversight and verification of the DOE and NREL, to ensure credibility and accuracy. The project, overall, was a resounding success. Several installations were deployed and tested comprehensively for the impact on both energy consumption and indoor air quality, and results were not only excellent, but quantitatively in line with expectations. A total number of eight (8) installations were attempted, with 2 aborted due to building issues. Of the six successful installations, however, complete M&V was performed by NREL on 2 (Miami and NYC) and partial analysis on a third site (ArcBest), and these three, along with their results, were therefore presented from a financial and reporting standpoint. Although the number of case studies fell short of the original target of 10, we nevertheless had excellent demonstrations in vastly different climate zones: Southeast, Northeast and Midwest, and in very different building types. This included a modern high-rise office building in New York City and a University Campus health center in Miami, and a mid-rise high-density office in Arkansas. The cooling load reduction was shown to be significant, averaging 37% during the final cooling season in the Miami site. In the NYC site, the cooling energy savings were generally less, at around 12%, as expected. While this is a lower number for average/total savings, two comments are important to note: (i) the outside airflow (OA) reduction was not consistent during the data collection period, at least in part understating the attainable savings through incorrect measurement of the “high energy” reference state; and (ii) the peak impact in NYC is almost certainly as high as Miami, with critical ramifications for peak load reduction and equipment downsizing ability. Importantly, the measured energy savings in all locations were related to the outdoor climate conditions and the actual achievable reduction in outside air, very much in line with models and calculations; this leaves us with increased confidence in our understanding of the interaction between the technology and the building, and our ability to project the impact of this innovation in the future, through broad adoption. Simply put: the energy savings and load reduction impact of the HLR solution has been confirmed quantitatively. The results also confirmed the air quality objective. This may be even more significant, in that air quality is more complex and harder to measure and quantify, and the performance of the HLR as an air scrubber is the linchpin of the entire solution. In all sites, indoor air quality met or exceeded the required parameters, in terms of achieving the target (low) levels of indoor pollutants. Furthermore, the concentrations of outdoor sourced pollutants were markedly lower, as expected, mostly due to the reduction in outside air intake although in part also due to the scrubbing. The success was not immediate nor easy, and early challenges with the systems, especially (but not only) around controls and communication, caused delays in commissioning and undermined some of our M&V schedules. The good news is no fundamental issues were encountered and the number of such glitches was declining quickly by the end of the project. Other challenges had to do with coordinating the control of the building OA dampers, which the HLR needs to have in order to deliver the load reduction, but which the facility manager controls regularly and independently. This is not necessarily a problem for normal HLR operation but interferes with accurate M&V, where switching OA settings back and forth on a precise timetable is essential for clean data. The project provided valuable experience in retrofitting buildings that had been originally designed to operate with less recirculation and more outside air, and some key learnings related to the cyclical regeneration of the sorbents in the operational environment of the building. Some of these learnings gave already been incorporated into ongoing improvements in the design of the HLR module as well as the software that is used to control its operation. The cost and time of retrofit installations is much better understood; so is the test and balance procedure of the building that determines the available range of outside air reduction, which in turn determines the amount of load reduced. We had also implemented at least one annual cycle of sorbent cartridge replacement in the field, after which we tested the used sorbent to assess the rate of degradation of sorbent potency – an important factor affecting the long-term economics of HLR deployments. A notable shortfall of the project, other than the fact that the number of sites was below target, was that we had not (yet) completed testing to measure and verify (M&V) the winter energy savings. This is primarily due to late start on the NYC sites (Miami does not portend any heating savings associated with reduced outside air), combined with the issues of OA damper control. It is by no means suggested that such savings cannot be captured, only that the M&V with respect to winter in NYC has been incomplete. The value of this project and its interest to the general public are hard to overstate. The case studies created from Miami and especially from NYC have, without a doubt, opened up the interest of the broad HVAC industry to HLR in the past year. Major manufacturer reps have signed up to represent and promote the product, and dozens of top tier engineering consultants have introduced HLR as a base of design in upcoming construction and renovation projects – precisely the overarching goal of this project. These would not have happened without the highly visible installation in NYC and its ultimately satisfied customer. Furthermore, the DOE itself issued a report in late 2017 analyzing hundreds of candidate technologies for reducing energy consumption in HVAC; remarkably, the budding HLR solution ranked among the top 3(!); no doubt, its status as a viable and significant contender on this list is informed by the success of these demonstrations. And furthermore, in the wake of these demos, several major energy utilities, led by ConEdison in NYC, have endorsed the HLR solution and now routinely provide substantial cash rebates for customers choosing to incorporate the HLR in their buildings and reap the benefit of the reduced peak load as well as reduced cumulative energy demand. Last but not least, in January of 2019, as this report was being written, the HLR module won the AHR Expo Innovation Award for Green Buildings and, remarkably, the prestigious and only Product of the Year 2019, being selected by an independent professional panel of judges from AHR and ASHRAE. Given the confirmation of the enormous energy saving potential of HLR in widescale deployment, as well as ancillary but significant benefits in terms of equipment downsizing and indoor air quality, the benefit of this effort to the public speaks for itself. Accelerating adoption of HLR, without dependence on subsidies and driven by the private sector, is well under way. There is still much work to be done in terms of educating the HVAC and construction ecosystems and improving the product’s robustness and simplicity, to further facilitate the adoption of this technology and the capture of its potential value. But the American public will greatly benefit both directly and indirectly in the immediate future and beyond.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Control voltage and power fluctuations when connecting wind farms

Voltage, frequency, active power and reactive power are very important parameters in terms of power quality. These parameters are followed when connecting any power plant, the more the connection of wind farms. Connecting wind farms to the electricity system must not cause interference outside the limits set by regulations. Modern solutions for fast and automatic voltage control and power fluctuations using electronic control systems of reactive power flows. FACTS (Flexible Alternating Current Transmision System) systems, established on the basis of power electronic circuits ensure control of electrical status quantities to achieve the necessary transfer of power to the power grid. FACTS devices can quickly control parameters and sizes of state power lines, such as impedance line voltages and phase angles of the voltages of the two ends of the line. Their use can lead to improvement in power system operation by increasing the transmission capacity of power lines, power flow control lines, improved static and transient stability reserve.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Signal Processing of Multiplexed Optical PWM Signals for Sensor Arrays in Nuclear Environments

Safe and effective generation of terrestrial nuclear power greatly benefits from the actionable data provided by the array of sensors located throughout a plant to provide a holistic online indication of reactor operation. This array includes sensors for monitoring coolant flow and pressure, temperature and heat transfer, radiation levels, structure health monitoring, and other critical parameters for reactor operation. While sensors capable of measuring these parameters have been developed, the electronics used in the pre-amplification and analog-to-digital conversion of the small signals they produce are extremely sensitive and susceptible to damage by high-temperatures and radiation environments nuclear reactors encounter while generating power. The small signals from sensors in nuclear power plants (NPPs) are transmitted over long cable runs which introduce dispersion artifacts into the signals of interest as well as electromagnetic interference (EMI) from lighting fixtures, pumps, mains electricity, and other equipment. To overcome these challenges, a front-end digitization (FREND) platform has been developed to use radiation-tolerant electronics to multiplex, amplify, and optically encode signals from an array of sensors for transmission over an optical fiber to mitigate dispersion and EMI artifacts from long runs of electrical cabling. To recover the optically transmitted data, a signal processing scheme based on 1-dimensional template matching to an indexing channel is described herein and demonstrated to have an effective bit-depth of 9.2 bits (1%). This scheme has been validated in proof-of-concept, non-nuclear testing and preliminary experimental results show good agreement between the measured optical output and and sensor input signals. The FREND system represents a low-loss data link between sensors in nuclear environments and data acquisition hardware which is aimed at improving the signal-to-noise ratio of the data acquired from these sensors to provide better information to operators and researchers.

Sweeney, Dan↗

Data assimilation in a solar dynamo model using Ensemble Kalman Filters: sensitivity and robustness in reconstruction of meridional flow speed

We implement an Ensemble Kalman Filter procedure using the Data Assimilation Research Testbed for assimilating “synthetic” meridional flow-speed data in a Babcock–Leighton-type flux-transport solar dynamo model. By performing several “observing system simulation experiments,” we reconstruct time variation in meridional flow speed and analyze sensitivity and robustness of reconstruction. Using 192 ensemble members including 10 observations, each with 4% error, we find that flow speed is reconstructed best if observations of near-surface poloidal fields from low latitudes and tachocline toroidal fields from midlatitudes are assimilated. If observations include a mixture of poloidal and toroidal fields from different latitude locations, reconstruction is reasonably good for ⩽40% error in low-latitude data, even if observational error in polar region data becomes 200%, but deteriorates when observational error increases in low- and midlatitude data. Solar polar region observations are known to contain larger errors than those in low latitudes; our forward operator (a flux-transport dynamo model here) can sustain larger errors in polar region data, but is more sensitive to errors in low-latitude data. An optimal reconstruction is obtained if an assimilation interval of 15 days is used; 10- and 20-day assimilation intervals also give reasonably good results. Assimilation intervals <5 days do not produce faithful reconstructions of flow speed, because the system requires a minimum time to develop dynamics to respond to flow variations. Reconstruction also deteriorates if an assimilation interval >45 days is used, because the system’s inherent memory interferes with its short-term dynamics during a substantially long run without updating.

79 ASTRONOMY AND ASTROPHYSICS↗

Reference Model 2: "Rev 0" Rotor Design

The preliminary design for a three-bladed cross-flow rotor for a reference marine hydrokinetic turbine is presented. A rotor performance design code is described, along with modifications to the code to allow prediction of blade support strut drag as well as interference between two counter-rotating rotors. The rotor is designed to operate in a reference site corresponding to a riverine environment. Basic rotor performance and rigid-body loads calculations are performed to size the rotor elements and select the operating speed range. The preliminary design is verified with a simple finite element model that provides estimates of bending stresses during operation. A concept for joining the blades and support struts is developed and analyzed with a separate finite element analysis. Rotor mass, production costs, and annual energy capture are estimated in order to allow calculations of system cost-of-energy. Evaluation Only. Created with Aspose.Pdf.Kit. Copyright 2002-2011 Aspose Pty Ltd Evaluation Only. Created with Aspose.Pdf.Kit. Copyright 2002-2011 Aspose Pty Ltd

42 ENGINEERING↗

Prioritizing ICS Beachhead Systems for Cyber Vulnerability Testing

Cyber Testing for Resilient Industrial Control Systems™ (CyTRICS™) is the Department of Energy’s (DOE’s) program for cybersecurity vulnerability testing, digital subcomponent enumeration, and forensic assessment. CyTRICS leverages best-in-class test facilities and analytic capabilities at six DOE National Laboratories and strategic partnerships with key stakeholders including technology developers, manufacturers, asset owners and operators, and interagency partners. During the program’s development, CyTRICS established a unique methodology for prioritizing digital components within operational technology (OT) and industrial control systems (ICS) in the Energy Sector Industrial Base (ESIB) for cyber vulnerability testing. The CyTRICS Prioritization Process leverages multiple characteristics of systems, components, and their contextual deployment to calculate a quantification of individual digital components for CyTRICS testing. The initial version of the CyTRICS Prioritization Process was premised largely upon the impact which could result to an industrial control system if the digital component under testing was compromised, either through malicious means, faulty engineering, or other modes. The worldwide compromise of the SolarWinds Orion platform, first reported in December 2020, through malicious interference with the digital patching cycle was a watershed event in cyber supply chain security. The SolarWinds compromised demonstrated the strategic importance of certain types of ubiquitous software, and the ability to generate widespread cybersecurity effects. To address this challenge and as a part of the Department of Energy’s response to the SolarWinds compromise, DOE’s Office of Cybersecurity, Energy Security, and Emergency Response (CESER) directed the National Laboratories to evolve the CyTRICS Prioritization Process methodology to encompass additional factors related to the strategic importance of digital components. CESER directed CyTRICS researchers to identify, characterize, and append strategic factors to the CyTRICS Prioritization Process to provide additional weight to these characteristics. National Laboratory expert researchers identified functionality, distribution, and platform characteristics for digital components in ICS and OT that they assessed would be likely targeted in strategic initial-access cyber attack. CyTRICS has termed these factors “ICS Beachhead Systems,” leveraging a definition first advanced by Schneider Electric, which is intended as a blanket term to encompass digital components, products, and systems in OT. This paper describes the ICS Beachhead Systems identified and the rationale for inclusion. As a next step in the research and refinement process, the National Laboratories will validate this initial set of characteristics against digital components evaluated by the CyTRICS program and current implementation of the CyTRICS Prioritization Process. After validation, CyTRICS researchers will then develop a scoring methodology to generate a quantitative score to assess the degree to which a digital component is characterized as an ICS Beachhead System. Finally, the National Laboratories will append this scoring to the existing CyTRICS Prioritization Process algorithm.

97 MATHEMATICS AND COMPUTING↗

Development, Testing and Validation of a Waste Assay System for the Measurement and Characterisation of Active Spent Fuel Element Debris From UK Magnox Reactors - 12533

This paper describes the development, testing and validation of a waste measurement instrument for characterising active remote handled radioactive waste arising from the operation of Magnox reactors in the United Kingdom. Following operation in UK Magnox gas cooled reactors and a subsequent period of cooling, parts of the magnesium-aluminium alloy cladding were removed from spent fuel and the uranium fuel rods with the remaining cladding were removed to Sellafield for treatment. The resultant Magnox based spent fuel element debris (FED), which constitutes active intermediate level waste (ILW) has been stored in concrete vaults at the reactor sites. As part of the decommissioning of the FED vaults the FED must be removed, measured and characterised and placed in intermediate storage containers. The present system was developed for use at the Trawsfynydd nuclear power station (NPS), which is in the decommissioning phase, but the approach is potentially applicable to FED characterisation at all of the Magnox reactors. The measurement system consists of a heavily shielded and collimated high purity Germanium (HPGe) detector with electromechanical cooling and a high count-rate preamplifier and digital multichannel pulse height analyser. The HPGe based detector system is controlled by a software code, which stores the measurement result and allows a comprehensive analysis of the measured FED data. Fuel element debris is removed from the vault and placed on a tray to a uniform depth of typically 10 cm for measurement. The tray is positioned approximately 1.2 meters above the detector which views the FED through a tungsten collimator with an inverted pyramid shape. At other Magnox sites the positions may be reversed with the shielded and collimated HPGe detector located above the tray on which the FED is measured. A comprehensive Monte Carlo modelling and analysis of the measurement process has been performed in order to optimise the measurement geometry and eliminate interferences from radioactive sources and FED in the immediate vicinity of the measurement position. The detector system has been calibrated and high activity radioactive sources of Cs-137, Co-60 and Na-22 have been used to validate the measurement process. The data acquisition and analysis software code has been tested and validated in keeping with the software quality assurance requirements of both ISO:9001-2008 - TICK-IT in the UK and NQA-1. The measurement and analysis system has been comprehensively tested with high activity sources, is flexible and may be applicable to a wide range of remote handled radioactive waste measurement applications. It is due to be installed at Trawsfynydd NPS later this year. This paper describes the Waste Tray Assay System (WTAS) that has been developed for the measurement of Magnox FED waste. The WTAS has been tested with a range of radioactive sources and its operation has been simulated with benchmarked MCNP Monte Carlo calculations. The measurement software has been validated as has the operation of the system for a range of strong radioactive sources. A system based on the design is due for installation and operation in 2012. The system has application to the measurement of Magnox Fuel Element Debris (FED) waste at other Magnox reactor sites. The major design objective of the WTAS that has been achieved is the ability of the assay system to determine the content of Cs-137, and in turn to enable the fissile burden to be assessed using a radionuclide fingerprint, in the presence of higher and highly variable quantities of Co-60, typically from nimonic springs. The approach can be used in other Magnox FED waste configurations where the detector is located above the FED waste sorting tray and where the collimation is fixed below the detector and at a distance above the tray. In this case, which has also been investigated, there are different shielding problems and mechanical support issues. The extensive use of MCNP Monte Carlo modelling to simulate the geometry of the sorting cell and the distribution of radioactive sources has helped to ensure that all of the detector shielding requirements are addressed and suitable Cs-137 and Co-60 discrimination can be achieved. The WTAS in its present form or in other configurations has relevance to the measurement of other active ILW and highly active RH waste. Examples include high activity RH LLW and RH TRU (Transuranic) waste as defined in the United States arising from both commercial nuclear and Department of Energy (DOE) operations. The analysis is able to analyse a range of radionuclides beyong those expected in the Magnox FED cases. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of Thermoacoustic Sensors for Sodium-cooled Fast Reactors

This Final Report refers to the project “Development of Thermoacoustic Sensors for Sodium-cooled Fast Reactor Systems”, which was led by Westinghouse Electric Company (Westinghouse) and carried out in collaboration with Argonne National Laboratory (ANL) and University of Pittsburgh. Thermo-acoustic Power Sensors (TAPS) are self-powered, wireless sensors envisioned for measuring key parameters, such as local temperature and neutron flux, in a nuclear reactor core. This project was intended to specifically investigate their applicability to Sodium-cooled Fast Reactors (SFR). TAPS are non-invasive (wireless) and passive (self-powered) devices. The passivity derives from their ability to use conditions that “naturally” exist in a nuclear reactor, such as gamma and neutron flux, as power sources. They generate oscillating pressure waves (i.e., sound waves) which, with a frequency and amplitude dependent upon these conditions, can travel through the core and associated structures, and reach the outside of the reactor vessel where a properly designed network of receivers can detect and interpret them. These receivers require a very small amount of power which, during loss of power events, can be provided for example by harvesting gamma radiation energy, thus resulting in a monitoring system that can function both during normal operation and during loss of power events. The project aimed at TAPS development through a series of tasks which are listed and briefly discussed as follows. TASK 1 – Sensor hardware design Subtask 1a: Assessment of sensor applications to SFRs Subtask 1b: Development of sensor functional requirements Subtask 1c: Definition of sensor hardware design specifications Task description: TAPS design was informed by considerations on their application (Subtask 1a), both the ultimate one in an SFR and the actual one in the ANL testing facilities that was intended to be used in support of the project. Considerations were made to identify optimum sensor design features that optimize the sensor size, materials, and output signal, for installation inside an SFR core. These considerations led to the development of Functional Requirements (Subtask 1b) and Design Requirements (Subtask 1c). TASK 2 – Sensor Hardware Manufacture Subtask 2a: Sensor hardware construction drawing development Subtask 2b: Sensor manufacture and assembly Task description: TAPS technical drawings were developed (Subtask 2a) using the Design Requirements established under Task 1. Subsequently, in spite of some problems which ultimately caused the program to be delayed, TAPS manufacturing was completed based on drawings (Subtask 2b). TASK 3 – Development of TAPS Signal Measurement System and TAPS Testing in Water Subtask 3a: Design, assembly and testing of signal measurement system, and TAPS testing in water Subtask 3b: Signal prediction-correction methodology development Task description: An assessment was performed on the techniques that can potentially be used to detect the signals emitted by the TAPS, e.g. a fiber-optic based acoustic signal measurement system, a laser vibrometer system, or an accelerometer-based system. The most suited technology, i.e. the accelerometer-based system, was developed further, and tested in water (Subtask 3a). Moreover, efforts were made to develop the methodology required to determine the actual system temperature and neutron flux distribution using differences between the measured and predicted TAPS responses (Subtask 3b). TASK 4 – Sensor System Testing in Sodium Subtask 4a: Test plan development Subtask 4b: Design, assembly and testing in small-scale sodium facility Subtask 4c: Design, assembly and testing in large-scale sodium and structures facility Task description: Upon proper test plan development (Subtask 4a), the fabricated TAPS was planned to be tested in sodium, by using two sodium facilities at ANL having different size and different purpose. The Under Sodium Viewing (USV) small-scale facility was intended to be used to investigate the effect of sodium on the sensor and its performance (Subtask 4b). The Mechanism Engineering Test Loop (METL) large-scale facility was instead intended to be used to assess the additional effect of prototypical SFR structures, such as fuel assembly mockup or parts of the core restrain structure, on sensor performance (Subtask 4c). As discussed in Section 3.2.2.7, unexpected issues during the TAPS manufacturing process resulted in some activities being delayed, with the TAPS and USV facility developed to the point to be ready for testing in sodium, however without the possibility to actually perform such testing (including the testing in METL) due to the end of the program’s performance period. Overall, through the development and testing (in water only) of two TAPS devices (a First-Generation TAPS followed by an optimized Second-Generation TAPS), the project confirmed the capability of this technology to generate acoustic signals proportional to temperature, which can be detected through a network of accelerometers identified as the best-suited type of receivers for acoustic signal detection. Moreover, the project also developed a computational model to predict the characteristics of the acoustic signals being generated, which combines thermal analysis of the TAPS with Finite Element Modeling (FEM)-aided acoustic characterization of the system. This model was benchmarked against experimental data collected during the project and, although general agreement was obtained, some limitations of the modeling methods were identified, which require additional development. Additional testing is needed in order to assess the effect, on TAPS operation and performance, of environmental changes resulting from the transition from water to liquid sodium. Such testing, which is suggested to be performed in the future, should look specifically at 1) both the effect resulting from the different thermoacoustic behavior of sodium (relative to water) and the effects of higher temperature on TAPS performance, and 2) the performance of the sensor-receiver system when multiple TAPS are used simultaneously and prototypical reactor structures are positioned in the testing environment. The latter testing is needed to assess the effects that potential signal attenuation/ distortion phenomena, as well as potential interference between signals emitted simultaneously, have on the performance of the technology for ultimate application in a nuclear reactor.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

High-throughput ab initio reaction mechanism exploration in the cloud with automated multi-reference validation

Quantum chemical calculations on atomistic systems have evolved into a standard approach to studying molecular matter. These calculations often involve a significant amount of manual input and expertise, although most of this effort could be automated, which would alleviate the need for expertise in software and hardware accessibility. Here, we present the AutoRXN workflow, an automated workflow for exploratory high-throughput electronic structure calculations of molecular systems, in which (i) density functional theory methods are exploited to deliver minimum and transition-state structures and corresponding energies and properties, (ii) coupled cluster calculations are then launched for optimized structures to provide more accurate energy and property estimates, and (iii) multi-reference diagnostics are evaluated to back check the coupled cluster results and subject them to automated multi-configurational calculations for potential multi-configurational cases. All calculations are carried out in a cloud environment and support massive computational campaigns. Key features of all components of the AutoRXN workflow are autonomy, stability, and minimum operator interference. We highlight the AutoRXN workflow with the example of an autonomous reaction mechanism exploration of the mode of action of a homogeneous catalyst for the asymmetric reduction of ketones.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessment of Impact of Monoenergetic Photon Sources on Prioritized Nonproliferation Applications: Simulation Study Report

Near-monoenergetic photon sources (MPSs) have the potential to improve sensitivity at greatly reduced dose in existing applications and enable new capabilities in other applications. MPS advantages include the ability to select energy, energy spread, flux, and pulse structures to deliver only the photons needed for the application, while suppressing extraneous dose and background. Some MPSs also offer narrow divergence photon beams which can target dose and/or mitigate scattering contributions to image contrast degradation. Current broad-band, bremsstrahlung photon sources (e.g., linacs and betatrons) deliver unnecessary dose that in some cases also interferes with the signature to be detected and/or restricts operations, and must be collimated (reducing flux) to generate narrow divergence beams. While MPSs can in principle resolve these issues, they are technically challenging to produce. Candidate MPS technologies for nonproliferation applications are now being developed, each of which have different properties (e.g. broad divergence vs. narrow). Within each technology, source parameters trade off against one another (e.g. flux vs. energy spread), representing a large operation space. To guide development, requirements for each application of interest must be defined and simulations conducted to define MPS parameters that deliver benefit relative to current systems. The present project conducted a broad assessment of potential nonproliferation applications where MPSs may provide new capabilities or significant performance enhancement (reported separately), which led to prioritization of several applications for detailed analysis. The applications prioritized were: cargo screening and interdiction of Special Nuclear Materials (SNM), detection of hidden SNM, treaty/dismantlement verification, and spent fuel dry storage cask content verification. High resolution imaging for stockpile stewardship was considered as a sub-area of the treaty topic, as it is also of interest for future treaty use. This report presents higher-fidelity calculations and modeling results to quantitatively evaluate the prioritized applications, and to derive the key MPS properties that drive application benefit. Simulations focused on the conventional signatures of radiography, photofission, and NRF to enable comparison to present methods and evaluation of benefit.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

2013 R&D 100 Award: 'SHIELD' protects NIF optics from harmful pulses

In the past, it took as long as 12 hours to manually screen 48 critical checkpoints at the National Ignition Facility (NIF) for harmful laser pulses. The screening equipment had to be moved from point to point throughout a facility the size of three football fields. Now with a new technology, called Laser SHIELD (Screening at High-throughput to Identify Energetic Laser Distortion), and with the push of a button, the screening can be done in less than one second. Proper screening of pulses is critical for the operation of high-energy lasers to ensure that the laser does not exceed safe operating conditions for optics. The energetic beams of light are so powerful that, when left uncontrolled, they can shatter the extremely valuable glass inside the laser. If a harmful pulse is found, immediate adjustments can be made in order to protect the optics for the facility. Laser SHIELD is a custom-designed high-throughput screening system built from low-cost and commercially available components found in the telecommunications industry. Its all-fiber design makes it amenable to the unique needs of high-energy laser facilities, including routing to intricate pick-off locations, immunity to electromagnetic interference and low-loss transport (up to several kilometers). The technology offers several important benefits for NIF. First, the facility is able to fire more shots in less time-an efficiency that saves the facility millions of dollars each year. Second, high-energy lasers are more flexible to wavelength changes requested by target physicists. Third, by identifying harmful pulses before they damage the laser's optics, the facility potentially saves hundreds of thousands of dollars in maintenance costs each year.

42 ENGINEERING↗