A model for gas phase chemistry in interstellar clouds. I - The basic model, library of chemical reactions, and chemistry among C, N, and O compounds
Explore the source record for details and available documents.
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Explore the source record for details and available documents.
Techniques for measuring the local and global parameters that describe molecular clouds are presented and illustrated by selected results. The local parameters which characterize a given location in a cloud are gas kinetic temperature, dust temperature, total density, magnetic field strength, abundance of species i, volume cooling and heating rates for gas and dust, and the thermal and turbulent velocities. Global properties which characterize the cloud as a whole include the size expressed as a length or area, the orientation and shape, the mass, and the integrated heating and cooling rates. If the cloud as a whole is collapsing or rotating, then the collapse velocity and the rotational velocity or angular momentum are global properties. An intermediate class of parameters which shares features of local and global properties includes the column density of species i, the total column density, and the average density.
The principal issues are addressed: the fragmentation of molecular clouds into units of stellar mass and the impact of star formation on molecular clouds. The observational evidence for fragmentation is summarized, and the gravitational instability described of a uniform spherical cloud collapsing from rest. The implications are considered of a finite pressure for the minimum fragment mass that is attainable in opacity-limited fragmentation. The role of magnetic fields is discussed in resolving the angular momentum problem and in making the collapse anisotropic, with notable consequences for fragmentation theory. Interactions between fragments are described, with emphasis on the effect of protostellar winds on the ambient cloud matter and on inhibiting further star formation. Such interactions are likely to have profound consequences for regulating the rate of star formation and on the energetics and dynamics of molecular clouds.
Explore the source record for details and available documents.
Properties of self-consistent numerical hydrodynamic models are compared with observed properties of several dark clouds. The results are consistent with the view that these clouds are undergoing gravitational collapse. The clouds appear to have evolved from similar initial states and to have ages comparable to their free-fall times. Derived cloud masses range between 10 and 1000 solar masses, correlating with cloud size. The models reproduce observed cloud-to-cloud variations in the (C-13)O abundance, and they offer additional evidence that the (C-13)O abundance varies within individual clouds.
The evolutions of the envelopes of collapsing, accreting, isothermal clouds have been numerically calculated for both spherically symmetric and rotating (axisymmetric) clouds. The results provide a cohesive picture of isothermal collapse, and their relationship to previous numerical calculations and similarity solutions is discussed. Even with a large initial rotation rate, the majority of the cloud envelope is accreted, in one case leaving behind a large-scale circulation current. The calculations are performed for both initially uniform density and centrally condensed clouds. Density and velocity profiles for a wide variety of observed systems are compared with those obtained in this study, providing a preliminary assessment of the stage of evolution and initial structure for the observed systems.
A heuristic criterion, based on linear perturbation analysis, is applied to the initial growth of density perturbations in isothermal or adiabatic gas clouds, with initially uniform density and uniform rotation. The heuristic criterion is shown to be consistent with the available results from numerical calculations of cloud collapse. The criterion predicts that perturbations varying as cos(m-phi) will be most likely to grow when m is small, unless the cloud is nearly pressureless.
Carbon monoxide column densities are compared to visual extinctions toward field stars in the rho Oph and Taurus molecular cloud complexes. The relationship of C(0-18) column density to extinction is established, and new determinations for (C-13)O column densities are given for a range of visual extinctions extended to beyond 20 mag. A prescription for determining hydrogen column densities and masses of molecular clouds from observations of CO isotopes is presented and discussed critically. These measurements agree well with the predictions of gas phase chemistry models which include chemical fractionation and selective isotopic photodestruction. The functional dependence of the C(O-18) column density on extinction is characterized by two different regimes separated by a distinct transition observed to occur at 4 mag in both molecular cloud complexes, whereas the functional dependence of (C-13)O is quite different in the two regions. Some saturation is found to occur for C(O-18) emission at high visual extinction and use the rarer isotopic species C(O-17) and (C-13)(O-18) to correct for it.
Explore the source record for details and available documents.
Explore the source record for details and available documents.
Explore the source record for details and available documents.
A theory of molecular formation by radiative association is presented which is consistent with angular momentum being conserved during the encounter and which incorporates explicitly the long-range attraction between the reactants. It is pointed out that the activated complex would not have a Boltzmann energy distribution should the rotational and kinetic temperatures of the reactants differ, and it is shown how allowance for this may be made. Account is taken of the inaccessibility of a considerable fraction of the nuclear spin states of the complex. Methods are given for treating the effect which the finiteness of the dissociation frequency may have on the association rate. Calculations on some reactions of interest are performed. A very simple semiempirical formula for the rate coefficient for radiative association is also given.
Methyl acetylene (propyne) appears to be a convenient and reliable probe of kinetic temperature for dense (few x 10 to the 4th/ cu cm) molecular clouds. A method is presented for fitting a (J + 1) - J K-multiplet to obtain the kinetic temperature from a single observation, facilitating the direct construction of kinetic temperature maps. Observations of Tau MC1, Ori MC1, Sgr B2, DR 21, DR 21 (OH), and S140 are presented to demonstrate the validity of the technique. Determination of methyl acetylene column densities requires, in addition, knowledge of the rotational excitation temperature. The relative abundance of CH3CCH appears to be within a factor of 2 of 2.5 x 10 to the -9th. Because of the large uncertainties in estimates of total gas column density, it is not clear whether there is genuine source-to-source variation in the CH3CCH relative abundance.
Radiative transfer in the Eddington approximation is included in a multidimensional, self-gravitational, hydrodynamical computer code. Details of the numerical solution and thermodynamic relations are given. Comparison calculations with previous spherically symmetrical models of protostellar collapse are used to validate the basic approach and the artifices which allow the explicit hydrodynamics code to follow the accretion of gas onto a quasi-equilibrium core. A series of axisymmetric models is used to investigate the importance of rotation in collapsing clouds, as the initial amount of angular momentum is lowered, with an emphasis on the possible formation of rings. Rings readily form even in the nonisothermal regime except for very low initial angular momenta; even these clouds may experience ring formation prior to reaching stellar densities. The models imply that other effects (such as gravitational torques or turbulent viscosity) may be necesary to avoid binary formation and thus result in a presolar nebula consistent with the assumptions of either Safronov or Cameron.
A summary is presented of airborne observations of the far-infrared fine structure lines of neutral atomic oxygen and singly-ionized carbon, and of the far-infrared rotational lines of CO, OH, NH3 and HD, together with a brief description of the analysis and interpretation of the spectra. The 'state of the art' in instrument performance and the prospects for improved sensitivity and resolution are also surveyed.
Numerical calculations are presented for rigorous models spanning a four-dimensional parameter space of initial conditions of the three-dimensional collapse of rotating protostellar clouds, encompassing radiative transfer in the Eddington approximation and detailed thermodynamical relations. It is found that protostellar formation may involve a few stages of hierarchical fragmentation terminated by increased thermal pressure in the nonisothermal regime, that high thermal energy clouds remain nearly axisymmetric during the first dynamic collapse phase, and that very slowly rotating clouds can fragment. The presolar nebula was probably formed from a cloud with very little initial rotation.
Observations, which have been published since 1979, of molecular species in diffuse clouds are discussed. Particular attention is given to the ultraviolet measurements of CO with the Copernicus and IUE satellites and to ground-based optical measurements of CH, CH(+), CN, and 02. These data encompass large enough samples to test the chemical schemes expected to occur in diffuse clouds. Upper limits for other species (e.g., H2O, H2O(+), and C3) place restrictions on the pathways for molecular production. Moreover, analysis of the rotational distribution of the C2 molecule results in the determination of the physical conditions of the cloud. These parameters, including density, temperature, and the intensity of the radiation field, are necessary for modeling the chemistry.
Research in the use of FIR and sub-mm lines to provide data relevant to astrochemistry is examined. Spectroscopic features in the FIR and sub-mm are dominated by transitions from species of atoms and atomic ions, metal hydrides, and heavy molecules. The data of Lester et al.(1983) and Dinerstein et al. (1984) on the N/O abundance ratio are discussed. The N/O abundance ratio is analyzed as a function of the galactic radius, and the procedure for determining the N/O abundance ratio from the FIR and sub-mm lines is given. The conditions at the surface of molecular clouds and the chemical profile of molecular clouds are studied in the forbidden lines O I 63.18 and 145.53 microns and the forbidden line C II 157.74 microns. Results of recent FIR/sub-mm observations of post-shocked gas which relate to modeling the chemical processing that occurs in the wake of shock waves are considered.