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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

A high-temperature wideband pressure transducer

Progress in the development of a pressure transducer for measurement of the pressure fluctuations in the high temperature environment of a jet exhaust is reported. A condenser microphone carrier system was adapted to meet the specifications. A theoretical analysis is presented which describes the operation of the condenser microphone in terms of geometry, materials, and other physical properties. The analysis was used as the basis for design of a prototype high temperature microphone. The feasibility of connecting the microphone to a converter over a high temperature cable operating as a half-wavelength transmission line was also examined.

Zuckerwar, A. J.↗

Effects of hydrogen on iron/nickel/cobalt/alloy

Commercially available alloy, Incoloy 903, is candidate for various high-pressure, high-temperature applications. Recent study of properties in hydrogen and helium atmospheres under extreme environments indicates that alloy can be degraded by gaseous hydrogen, particularly at elevated temperatures. Study also reports that water vapor added to hydrogen environments causes reductions in low-cycle fatigue life of material.

Harris, J. A.↗

Dynamic hyperfiltration membranes for high-temperature spacecraft wash water recycle

The effect of operating parameters on the performance of the hyperfiltration membrane when operating on washwater was examined. The parameters were pressure, temperature, velocity, and concentration. Data taken included rejections of organic materials, ammonia, urea, and an assortment of ions. The membrane used was a dual layer, polyacrylic acid over zirconium oxide, deposited in situ on a porcelain ceramic substrate.

Gaddis, J. L.↗

High-temperature ceramics for automobile gas turbines

The employment of the high operational temperatures makes it necessary to use, for the construction of the turbines, ceramic materials such as silicon nitride or silicon carbide. Investigations concerning the development of turbine components made of such materials are conducted by a German automobile manufacturer and the ceramics industry. The current status of these investigations is reviewed. Flame tubes and guide-vane rings have successfully passed tests lasting 20 hours. Prototype turbine wheels have withstood the effects of peripheral speeds of 450 m/s. They also showed resistance to thermal shocks which were as high as 6-0 K/s.

Walzer, P.↗

Shear rupture of a directionally solidified eutectic gamma/gamma-prime - alpha /Mo/ alloy

Directionally solidified gamma/gamma-prime - alpha (Mo) eutectic alloys are being evaluated for application as advanced aircraft engine turbine blades. Their excellent high-temperature strength is partly due to their directionally aligned microstructure. However, alloys with such directional structures may display low shear strength at 760 C, the operating temperature of advanced blade roots. The objective of this investigation was to determine the shear rupture strength of the gamma/gamma-prime - alpha eutectic alloy and possibly to improve it by microstructural and heat-treatment variations. Bars of gamma/gamma-prime - alpha alloy containing nominally 5.7% Al and 33.5% Mo by weight with balance Ni were directionally solidified at rates between 10 and 100 mm per hour. Materials were solidified in furnaces with thermal gradients at the liquid-solid interface of 250 or 100 C per cm. A limited number of longitudinal shear rupture tests were conducted at 760 C and 207 MPa in the as-solidified and in several heat-treated conditions. It was found that the shear rupture failures are partly transgranular and that resistance to failure is promoted by good fiber alignment and a matrix structure consisting mainly of gamma-prime. Well-aligned as-solidified specimens sustained the shear stress for an average of 81 hours, while cellular material failed in one hour or less.

Harf, F. H.↗

Ortho and parahydrogen in interstellar material

The ortho/para molecular hydrogen ratio in the interstellar medium is considered. It is shown that the ortho/para ratio will be 3:1 in practically all chemical reactions, even at relatively low temperatures. Two examples of exothermic processes that will result in the formation of a 3:1 ortho:para ratio, corresponding to a high-temperature equilibrium, are examined: H2 formation via three-body or surface recombination and catalytic recombination involving electrons and H(-) ions. Gas-phase scrambling ion reactions are also discussed, and it is suggested that virtually all the H2 equilibrated via scrambling reactions involving H(+) and H3(+) ions should exist as parahydrogen in the J ? 0 quantum state. Arguments are given that deuterium cannot interfere with the long scrambling chain that results in parahydrogen formation.

Reeves, R. R.↗

Silicon halide-alkali metal flames as a source of solar grade silicon

The feasibility of using continuous high-temperature reactions of alkali metals and silicon halides to produce silicon in large quantities and of suitable purity for use in the production of photovoltaic solar cells was demonstrated. Low pressure experiments were performed demonstrating the production of free silicon and providing experience with the construction of reactant vapor generators. Further experiments at higher reagent flow rates were performed in a low temperature flow tube configuration with co-axial injection of reagents and relatively pure silicon was produced. A high temperature graphite flow tube was built and continuous separation of Si from NaCl was demonstrated. A larger scaled well stirred reactor was built. Experiments were performed to investigate the compatability of graphite based reactor materials of construction with sodium. At 1100 to 1200 K none of these materials were found to be suitable. At 1700 K the graphites performed well with little damage except to coatings of pyrolytic graphite and silicon carbide which were damaged.

Olson, D. B.↗

Metamorphism of the H-group chondrites - Implications from compositional and textural trends in chondrules

The paper discusses element bulk compositions of 373 chondrules from 18 H3 to H6 chondrites determined by broad-beam electron probe analysis. Bulk chondrule FeO and Al2O3 amounts increase and TiO2 and Cr2O3 decrease with increasing petrologic type; normative faylite, albite, and plagioclase amounts increase through the petrologic sequence. Chondrule diameters correlate with phenocryst sizes in porphyritic chondrules of type 3 chondrites, but this correlation is diminished in the higher petrologic types. The compositional trends in chondrules through the petrologic sequence are attributed to diffusion and equilibration among chondrules, and between chondrules and matrix in response to increasing degrees of thermal metamorphism. It is suggested that H-group chondrites are formed by accretion of high-temperature (chondrules) and low-temperature (matrix) materials. Internal reheating of the parent materials to different temperatures caused compositional equilibration, grain coarsening, and reduction of FeO to Fe(0) by carbon.

Lux, G.↗

Composite wall concept for high-temperature turbine shrouds - Heat transfer analysis

The variables affecting the design of a composite turbine shroud, consisting of a metal base, an interlayer of porous metal, and an outer layer of yttria-stabilized zirconia, are analyzed. Results show that significant reductions in the cooling-air to gas-flow ratio are indicated for the composite shrouds compared to an all-metal shroud that was only impingement air cooled. The good insulating properties of the ceramic reduced the temperatures of the porous metal and support wall significantly. For a given porous metal density and coolant- to gas-flow ratio, decreasing the thickness of the porous metal and increasing ceramic thickness resulted in lower support wall temperatures. To maintain given allowable inter-layer temperatures and coolantto gas-flow ratios, porous-metal density or thermal conductivity must increase as the ratio of the thickness of the ceramic-to-porous metal decreases. It is concluded that a 1.78 mm thickness of porous material with a density of 0.2 and a 1.78 mm thickness of ceramic appears to be a good composite wall configuration for the assumed conditions

Ludwig, L. P.↗

High-Temperature Strain-And-Temperature Gauge

Two-element gauge used alternately in two different bridge circuits to measure both temperature and strain. Three-lead strain-and-temperature gauge developed for use at temperatures up to 750 degree F (390 degree C) on fiber-reinforced carbon/carbon composite material having coefficient of thermal expansion of 0.8 ppm/degree F. Unlike most temperature-compensated gauges, gauge gives accurate results even during rapid heating and cooling cycles. Similar gauges produced for materials with different coefficients of thermal expansion.

Wnuk, S. P.↗

Determination of elastic stresses in gas-turbine disks

A method is presented for the calculation of elastic stresses in symmetrical disks typical of those of a high-temperature gas turbine. The method is essentially a finite-difference solution of the equilibrium and compatibility equations for elastic stresses in a symmetrical disk. Account can be taken of point-to-point variations in disk thickness, in temperature, in elastic modulus, in coefficient of thermal expansion, in material density, and in Poisson's ratio. No numerical integration or trial-and-error procedures are involved and the computations can be performed in rapid and routine fashion by nontechnical computers with little engineering supervision. Checks on problems for which exact mathematical solutions are known indicate that the method yields results of high accuracy. Illustrative examples are presented to show the manner of treating solid disks, disks with central holes, and disks constructed either of a single material or two or more welded materials. The effect of shrink fitting is taken into account by a very simple device.

Manson, S S↗

Halogen Containing Gases as Lubricants for Crystallized Glass Ceramic Metal Combinations at Temperatures to 1500 F

Pyroceram 9608 (a crystallized glass ceramic) has been considered for use in high-temperature bearing and seal applications. One of the problems encountered with Pyroceram is the lack of availability of lubricants for the temperature range in which this material becomes practical. Experiments were conducted with Pyroceram sliding on various nickel- and cobalt-base alloys using reactive halogen-containing gases as lubricants. Friction and wear data were obtained as a function of sliding velocity and temperature. Studies were made with a hemispherical rider (3/16-in. rad., Pyroceram 9608) sliding in a circumferential path on the flat surface of a rotating disk (2(1/2) in. diam., nickel- or cobalt-base alloys). The specimens were run in an atmosphere of the various gases with a load of 1200 grams, a sliding velocity of 3200 feet per minute, and temperatures from 75 to 1500 F. The gas CF2Br-CF2Br was found to be an effective lubricant for Pyroceram 9608 sliding on Hastelloy R-235 and Inconel X up to 1400 F. The gas CF2Cl-CF2Cl provided effective lubrication for Pyroceram sliding on various cobalt-base alloys at 1000 F.

Buckley, Donald H.↗

Metallurgical Research Relating to the Development of Metals and Alloys for Use in the High-Temperature Components of Jet-Engines, Gas Turbines and Other Aircraft Propulsion Systems

Considerable work has been done on report preparation. All items listed in the March program report will be reported during July. Fundamental studies are in progress to establish the fundamental processes by which treatments and composition control properties of commercial alloys at high temperatures. As yet work has been confined to Low-Carbon N155 alloy and progress has been reported twice previously. The work is divided into two sections: studies of solution treated and aged material and studies of rolled structures. Electron microscopic work has been started as an additional technique for the studies. Brief descriptions of experimental techniques used, results, and interpretation of the data obtained since the last report covering this field are summarized below. Since the work outlined is to a large extent still in progress, the discussion given is to be considered tentative and subject to further modification as additional data becomes available.

Source record↗

Material Properties and Modeling of Room Temperature Vulcanizing Silicone

Room Temperature Vulcanizing silicone (RTV) is a high-temperature adhesive that has successfully been used as a gap-filler between Thermal Protection System (TPS) tiles for heatshields on numerous missions. It is also used to bond instrumentation plugs such as temperature and pressure sensors into the heatshields. While RTV has been traditionally assumed to be a non-porous and non-ablating material, numerous experiments have shown that RTV pyrolyzes and becomes highly porous as it is heated. Heating RTV has also shown swelling, or intumescence, which can pose unique problems that lead to roughness induced boundary-layer transition, surface oxide formation and contamination of heat shield sensors. Therefore, it is crucial to understand and model the intumescence phenomenon of RTV. As data for RTV material properties is limited, the first step in modeling RTV is to collect material properties such as pyrolysis mass-loss, microstructure change, virgin and char porosity, etc. which was performed in our initial study. Additionally, thermomechanical properties such as Young’s modulus and Poisson ratio are required for modeling the intumescence of RTV, which were taken from literature and the coefficient of thermal expansion was collected using in-situ heating and Micro Computed Tomography (µ-CT) in previous studies. Finally, numerous other properties such as pyrolysis gas properties, virgin and char thermal conductivity and specific heat were compiled from previous experiments and literature into a material database that can be used for simulations. In Porous Material Analysis Toolbox based on OpenFOAM (PATO) [4], structural mechanics coupled with material response was used for simulating the intumescence of RTV as it is heated. However, since the permeability of the material is very low, the pyrolysis gas creates an internal pressure build-up as the material is being heated, significantly contributing to the deformation of the material. To correctly characterize this phenomenon, additional physics models were implemented into PATO's stress analysis solver, and results were compared with RTV dilatometry test data as a preliminary verification case. Future work will include experiments of RTV at the Plasmatron X facility and the in-situ heating cell with µ-CT, and improvement of simulation tools to more accurately model RTV intumescence.

PATO↗

Thermo-Poro-Mechanical Modeling of RTV Intumescence

Room temperature vulcanizing (RTV) silicone is a high-temperature adhesive used as a gap-filler between heatshield tiles in numerous entry missions. Its propensity to intumesce, or swell upon exposure to heat, is a well-known effect that needs to be carefully quantified during design. At tile interfaces of charring ablators, intumescence, combined with differential recession, could cause the gap filler to protrude past the ablator outer mold line, forming a “fence”. Fencing can in turn cause transition to turbulence of the flow wetting the heat shield, leading to augmented surface heating. Recent experiments conducted at the Plasmatron X facility, the high enthalpy wind tunnel of the Center for Hypersonics and Entry Systems Studies, have shown prominent fencing of RTV gap fillers in PICA, under both nitrogen and air plasmas. Similar observations are well known in the arcjet literature. Further experiments under controlled environment, performed using in situ X-ray micro-computed tomography (micro-CT) at the Advanced Light Source (ALS), have shown heating rate-dependent swelling and shrinkage of RTV during pyrolysis. To simulate RTV intumescence, a novel model was introduced in the Porous Materials Analysis Toolbox based on OpenFOAM, PATO, to account for pore-pressure buildup within both closed- and open-pores. The governing equation for the thermo-poro-mechanical response were developed, assuming linear elasticity for the charring silicone. A new multi-pyrolysis model that tracks non-monotonic advancement of material properties with pyrolysis was proposed. This model addresses the limitations of state-of-the-art ablator models to capture the different stages of thermal degradation and coupled thermomechanics. Swelling of RTV was simulated using the new thermo-poro-mechanical model and compared against in situ micro-CT data. Results showed good agreement in intumescence height and temperature profiles at all heating rates, indicating that the key factor contributing to RTV swelling is the internal pressure build-up within closed- and open-pores. As RTV is cured into a soft (rubbery) compound with low-porosity and permeability, initial temperature increase and pyrolysis gas production cause a significant increase of internal pressure, causing a pronounced volume growth. As thermal degradation progresses, rigidization of the silicone occurs due to char hardening which counteract volume shrinkage after gas pressure relief. Overall, our model shows that accounting for changes in properties such porosity, permeability and key thermomechanical coefficients is crucial for capturing the RTV volume change during ablation and enable a predictive capability for heatshield tile interface response. A plan for future calibration of thermomechanical properties evolution during degradation is discussed, as a key next step to close the new model.

RTV↗

A Review of Direct Ink Writing of Polymer Derived Ceramics

With the growing demand for materials capable of withstanding extreme temperatures and pressures, ceramic components with exceptional corrosion resistance and reliable mechanical properties have experienced a significant surge in demand. However, traditional ceramic forming methods involve high-temperatures and energy-intensive processes that often struggle to produce complex parts or composites efficiently. Polymer-Derived Ceramics (PDCs) offer a transformative solution by using polymeric precursors that can be converted into a wide variety of silicon-based and non-silicon-based ceramics through heat treatment. The polymeric nature of PDC precursors enables the fabrication of geometrically intricate components using conventional polymer-forming techniques at significantly lower processing temperatures. Furthermore, PDCs are well-suited for additive manufacturing (AM), allowing the production of complex structural and functional components through cost-effective, low-temperature processes. By leveraging the diverse properties of PDC materials – each with unique advantages and limitations – manufacturers can optimise performance for specific applications. This review provides an overview of the types of PDCs developed to date and their broad range of applications. Specifically, it delves into the Direct Ink Writing (DIW) process, exploring its rheological requirements and the critical role of fillers in tailoring the rheological properties of polymeric precursors to meet the specific demands of DIW.

Victoria Bishop↗