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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

High-temperature processing of oxide superconductors and superconducting oxide-silver oxide composite

High temperature processing was found to partially convert the green 211 phase oxide to 123 phase. High Tc superconductivity was observed in Bi-Sr-Cu-O and Y-Sr-Cu-O systems prepared using the same heat treatment process. High temperature processing presents an alternative synthetic route in the search for new high Tc superconductors. An unusual magnetic suspension with enhancement in critical current density was observed in the 123 and AgO composite.

Wu, M. K.↗
NASA NTRS1999

Magnetic Flux Compression Using Detonation Plasma Armatures and Superconductor Stators: Integrated Propulsion and Power Applications

This presentation discusses the use of magnetic flux compression for space flight applications as a propulsion and other power applications. The qualities of this technology that make it suitable for spaceflight propulsion and power, are that it has high power density, it can give multimegawatt energy bursts, and terawatt power bursts, it can produce the pulse power for low impedance dense plasma devices (e.g., pulse fusion drivers), and it can produce direct thrust. The issues of a metal vs plasma armature are discussed, and the requirements for high energy output, and fast pulse rise time requires a high speed armature. The plasma armature enables repetitive firing capabilities. The issues concerning the high temperature superconductor stator are also discussed. The concept of the radial mode pulse power generator is described. The proposed research strategy combines the use of computational modeling (i.e., magnetohydrodynamic computations, and finite element modeling) and laboratory experiments to create a demonstration device.

Litchford, Ron↗
NASA NTRS1990

Magnetism and superconductivity of some Tl-Cu oxides

Many copper oxide based Thallium compounds have now been discovered. In comparison to the Bi-compounds, the Tl-system shows a richer diversity; viz., High Temperature Superconductors (HTSC) can be obtained with either one or two Tl-0 layers (m = 1,2); also, the triple-digit phases are easier to synthesize. The value of d, oxygen stoichiometry, is critical to achieving superconductivity. The Tl system is robust to oxygen loss; Tl may be lost or incorporated by diffusion. A diffusion coefficient equal to 10 ms at 900 C was determined. Both ortho-rhombic and tetragonal structures are evidenced, but HTSC behavior is indifferent to the crystal symmetry. This system has the highest T(sub c) confirmed. T(sub c) generally increases with p, the number of CuO layers, but tends to saturate at p = 3. Zero resistance as high as 125K has been observed. Most of these HTSC's are hole type, but the Ce-doped specimens may be electronic. The magnetic aspects were studied; because in addition to defining the perfectly diamagnetic ground state as in the conventional superconductors, magnetism of the copper oxides show a surprising variety. This is true of both the normal and the superconducting states. Also, due to the large phonon contribution to the specific heat at the high T(sub c) accurate thermal measurement of important parameters such as the sp. heat jump, electronic density of states, D(Ef) and coherence length are uncertain, and thus, are estimated from the magnetic results. Results from the Tl-system CuO, LaBaCuO, 120 and the Bi-CuO compounds are discussed. The emphasis is on the role of magnetism in the TlCuO HTSC, but technological aspects are also pointed out.

Datta, Timir↗
NASA NTRS2010

Study - Radiation Shielding Effectiveness of the Prototyped High Temperature Superconductivity (HTS) 'Artificial' Magnetosphere for Deep Space Missions

The high temperature superconductor (HTS) is being used to develop the magnets for the Variable Specific Impulse Magneto-plasma Rocket (VASIMR ) propulsion system and may provide lightweight magnetic radiation shielding to protect spacecraft crews from radiation caused by GCR and SPEs on missions to Mars. A study is being planned to assess the radiation shielding effectiveness of the artificial magnetosphere produced by the HTS magnet. VASIMR is an advanced technology propulsion engine which is being touted as enabling one way transit to Mars in 90 days or less. This is extremely important to NASA. This technology would enable a significant reduction in the number of days in transit to and from Mars and significantly reduce the astronauts exposure to a major threat - high energy particles from solar storms and GCR during long term deep space missions. This paper summarizes the plans for the study and the subsequent testing of the VASIMR technology onboard the ISS slated for 2013.

Denkins, Pamela↗
NASA NTRSDate not supplied

Using Lunar Superconducting Magnetic Energy Storage (LSMES) for NASA Artemis Program

The development of High temperature Superconductors (HTS) with transition temperatures >91K allows for their application in the Permanently Shadowed Regions (PSRs) on the Moon, where temperatures range from ~40K-60K. These are well below the critical temperature, Tc for the YBa2Cu3O7-x HTS material. An HTS coil installed in a PSR would not require cooling to remain below Tc. The coil can be energized with solar panels during daylight and maintain a magnetic field during night. The coil can be loaded and unloaded in millisecond time scales. The long lifetime with minimal losses is an attractive option for NASA’s Artemis program to consider for energy management on the Moon.

High Temperature Superconductivity (HTS)↗
NASA NTRS2017

Development of Stable, Low Resistance Solder Joints for a Space-Flight HTS Lead Assemblies

The solder joints in spaceflight high temperature superconductor (HTS) lead assemblies for certain astrophysics missions have strict constraints on size and power dissipation. In addition, the joints must tolerate years of storage at room temperature, many thermal cycles, and several vibration tests between their manufacture and their final operation on orbit. As reported previously, solder joints between REBCO coated conductors and normal metal traces for the Astro-H mission showed low temperature joint resistance that grew approximately as log time over the course of months. Although the assemblies worked without issue in orbit, for the upcoming X-ray Astrophysics Recovery Mission we are attempting to improve our solder process to give lower, more stable, and more consistent joint resistance. We produce numerous sample joints and measure time- and thermal cycle-dependent resistance, and characterize the joints using x-ray and other analysis tools. For a subset of the joints, we use SEMEDS to try to understand the physical and chemical processes that effect joint behavior.

high temperature superconductivity↗
NASA NTRS2013

Passivation of Flexible YBCO Superconducting Current Lead With Amorphous SiO2 Layer

Adiabatic demagnetization refrigerators (ADR) are operated in space to cool detectors of cosmic radiation to a few 10s of mK. A key element of the ADR is a superconducting magnet operating at about 0.3 K that is continually energized and de-energized in synchronism with a thermal switch, such that a piece of paramagnetic salt is alternately warm in a high magnetic field and cold in zero magnetic field. This causes the salt pill or refrigerant to cool, and it is able to suck heat from an object, e.g., the sensor, to be cooled. Current has to be fed into and out of the magnets from a dissipative power supply at the ambient temperature of the spacecraft. The current leads that link the magnets to the power supply inevitably conduct a significant amount of heat into the colder regions of the supporting cryostat, resulting in the need for larger, heavier, and more powerful supporting refrigerators. The aim of this project was to design and construct high-temperature superconductor (HTS) leads from YBCO (yttrium barium copper oxide) composite conductors to reduce the heat load significantly in the temperature regime below the critical temperature of YBCO. The magnet lead does not have to support current in the event that the YBCO ceases to be superconducting. Cus - tomarily, a normal metal conductor in parallel with the YBCO is a necessary part of the lead structure to allow for this upset condition; however, for this application, the normal metal can be dispensed with. Amorphous silicon dioxide is deposited directly onto the surface of YBCO, which resides on a flexible substrate. The silicon dioxide protects the YBCO from chemically reacting with atmospheric water and carbon dioxide, thus preserving the superconducting properties of the YBCO. The customary protective coating for flexible YBCO conductors is silver or a silver/gold alloy, which conducts heat many orders of magnitude better than SiO2 and so limits the use of such a composite conductor for passing current across a thermal gradient with as little flow of heat as possible to make an efficient current lead. By protecting YBCO on a flexible substrate of low thermal conductivity with SiO2, a thermally efficient and flexible current lead can be fabricated. The technology is also applicable to current leads for 4 K superconducting electronics current biasing. A commercially available thin-film YBCO composite tape conductor is first stripped of its protective silver coating. It is then mounted on a jig that holds the sample flat and acts as a heat sink. Silicon dioxide is then deposited onto the YBCO to a thickness of about 1 micron using PECVD (plasma-enhanced chemical vapor deposition), without heating the YBCO to the point where degradation occurs. Since SiO2 can have good high-frequency electrical properties, it can be used to coat YBCO cable structures used to feed RF signals across temperature gradients. The prime embodiment concerns the conduction of DC current across the cryogenic temperature gradient. The coating is hard and electrically insulating, but flexible.

Johannes, Daniel↗
NASA NTRS1987

Consortium for Materials Development in Space. Technical section

Several topics related to materials development in space are discussed. Physical vapor transport crystal growth, the mass spectroscopic facility, surface coatings and catalyst production by electrodeposition, mass transfer by diffusion, electrooptical organic materials, and high temperature superconductors are among the topics covered.

Source record↗
NASA NTRS1988

Analysis of the performance of the space ultravacuum research facility in attached and free-flyer mode

The old concept of using the wake of a spacecraft to obtain an ultrahigh vacuum is revisited with a somewhat different emphasis. Since it is possible to configure a wake shield so that a surface of interest does not subtend any walls that could become contaminated, it appears that it should be possible to achieve a contamination-free, ultrahigh vacuum capability with infinite pumping speed even in the presence of high heat loads and moderate gas loads. With the new interest in developing thin films with precision controlled synthetic microstructures such as superlattices, mixed metal oxide high temperature superconductors, rare-earth magneto-optical devices, and nano-crystalline alloys, the ability to work with a variety of different materials without cross contamination should be of significance. This paper analyzes the performance of the conceptual design for a Space Ultravacuum Research Facility (SURF), both in a Shuttle-attached mode and as a free-flyer. It is shown that even in the Shuttle-attached mode, it should be possible to obtain vacuum levels equivalent to 10 to the -10 Torr with O and N2 as the primary constituents. This should be sufficient to demonstrate the feasibility of the concept, particularly the infinite pumping speed and virtual elimination of contamination aspects. As a free-flyer the SURF will be limited primarily by the gas load associated with the process being performed. For chemical beam epitaxy (CBE) it is shown that equivalent vacuum levels of 10 to the -14 Torr should be possible at 300 km.

Naumann, Robert J.↗
NASA NTRS1988

Characterization of ZrO2 buffer layers for sequentially evaporated Y-Ba-CuO on Si and Al2O3 substrates

Thin film high temperature superconductors have the potential to change the microwave technology for space communications systems. For such applications it is desirable that the films be formed on substrates such as Al2O3 which have good microwave properties. The use of ZrO2 buffer layers between Y-Ba-Cu-O and the substrate has been investigated. These superconducting films have been formed by multilayer sequential electron beam evaporation of Cu, BaF2 and Y with subsequent annealing. The three layer sequence of Y/BaF2/Cu is repeated four times for a total of twelve layers. Such a multilayer film, approximately 1 micron thick, deposited directly on SrTiO3 and annealed at 900 C for 45 min produces a film with a superconducting onset of 93 K and critical temperature of 85 K. Auger electron spectroscopy in conjunction with argon ion sputtering was used to obtain the distribution of each element as a function of depth for an unannealed film, the annealed film on SrTiO3 and annealed films on ZrO2 buffer layers. The individual layers were apparent. After annealing, the bulk of the film on SrTiO3 is observed to be fairly uniform while films on the substrates with buffer layers are less uniform. The Y-Ba-Cu-O/ZrO2 interface is broad with a long Ba tail into the ZrO2, suggesting interaction between the film and the buffer layer. The underlying ZrO2/Si interface is sharper. The detailed Auger results are presented and compared with samples annealed at different temperatures and durations.

Valco, George J.↗
NASA NTRS1988

A proposal for epitaxial thin film growth in outer space

A new concept for materials processing in space exploits the ultravacuum component of space for thin film epitaxial growth. The unique low earth orbit space environment is expected to yield 10 to the -14th torr or better pressures, semiinfinite pumping speeds, and large ultravacuum volume without walls. These space ultravacuum properties promise major improvement in the quality, unique nature, and the throughput of epitaxially grown materials. Advanced thin film materials to be epitaxially grown in space include semiconductors, magnetic materials, and thin film high temperature superconductors.

Ignatiev, Alex↗
NASA NTRS1989

Relaxation behavior of ultrasonic attenuation in YBa2Cu3O7

It is shown that temperature-dependent ultrasonic attenuation data of YBa2Cu3O7 at various frequencies exhibit anomalies at temperatures close to Tc. These attenuation maxima are found to be the result of a relaxation mechanism added on top of an unusual attenuation background. It is proposed that the grain boundary motions induced by the structural distortion and the propagation of sound waves enhances the energy dissipation around Tc. Whether this structural distortion is the consequence of the onset of a superconducting state remains undetermined. It is also possible that either a tunneling effect or the acoustoelectric effect contributes to sound energy dissipation. The temperature dependence of ultrasonic velocity shows a softening around Tc which may be an intrinsic property of high-temperature superconductors.

Sun, K. J.↗
NASA NTRS1988

Epitaxial thin film growth in outer space

A new concept for materials processing in space exploits the ultravacuum component of space for thin-film epitaxial growth. The unique LEO space environment is expected to yield 10-ftorr or better pressures, semiinfinite pumping speeds, and large ultravacuum volume (about 100 cu m) without walls. These space ultravacuum properties promise major improvement in the quality, unique nature, and throughput of epitaxially grown materials, including semiconductors, magnetic materials, and thin-film high-temperature superconductors.

Ignatiev, Alex↗
NASA NTRS1990

Consortium for materials development in space

The status of the Consortium for Materials Development in Space (CMDS) is reviewed. Individual CMDS materials projects and flight opportunities on suborbital and orbital carriers are outlined. Projects include: surface coatings and catalyst production; non-linear optical organic materials; physical properties of immiscible polymers; nuclear track detectors; powdered metal sintering; iron-carbon solidification; high-temperature superconductors; physical vapor transport crystal growth; materials preparation and longevity in hyperthermal oxygen; foam formation; measurement of the microgravity environment; and commercial management of space fluids.

Source record↗
NASA NTRS1990

Navy superconductivity efforts

Both the new high temperature superconductors (HTS) and the low temperature superconductors (LTS) are important components of Navy's total plan to integrate superconductivity into field operational systems. Fundamental research is an important component of the total Navy program and focuses on the HTS materials. Power applications (ship propulsion, etc.) use LTS materials while space applications (MMW electronics, etc.) use HTS materials. The Space Experiment being conducted at NRL will involve space flight testing of HTS devices built by industry and will demonstrate the ability to engineer and space qualify these devices for systems use. Another important component of the Navy's effort is the development of Superconducting Quantum Interference Device (SQUID) magnetometers. This program will use LTS materials initially, but plans to implement HTS materials as soon as possible. Hybrid HTS/LTS systems are probable in many applications. A review of the status of the Navy's HTS materials research is given as well as an update on the Navy's development efforts in superconductivity, with particular emphasis on the related SDIO sponsored program on HTS applications.

Gubser, D. U.↗
NASA NTRS1990

Microwave conductivity of laser ablated YBaCuO superconducting films and its relation to microstrip transmission line

The discovery of high temperature superconductor oxides has raised the possibility of a new class of millimeter and microwave devices operating at temperatures considerably higher than liquid helium temperatures. Therefore, materials properties such as conductivity, current density, and sheet resistance as a function of temperature and frequency, possible anisotropies, moisture absorption, thermal expansion, and others, have to be well characterized and understood. The millimeter wave response was studied of laser ablated YBa2Cu3O(7-x)/LaAlO3 thin films as a function of temperature and frequency. In particular, the evaluation of their microwave conductivity was emphasized, since knowledge of this parameter provides a basis for the derivation of other relevant properties of these superconducting oxides, and for using them in the fabrication of actual passive circuits. The microwave conductivity for these films was measured at frequencies from 26.5 to 40.0 GHz, in the temperature range from 20 to 300 K. The values of the conductivity are obtained from the millimeter wave power transmitted through the films, using a two fluid model.

Bhasin, K. B.↗
NASA NTRS1989

Reaction of nonaqueous halogen solutions with YBa2Cu3O(7-x)

The reaction of the surfaces of the new high-temperature superconductor YBa2Cu3O(7-x) with nonaqueous halogen solutions is investigated, and the species formed in the reactions are identified. Treatment of films with HF/EtOH (EtOH = HI in absolute ethanol) results in the formation of an oxyfluoride with Y:Ba:Cu relative concentrations of 1:4:3. Results of X-ray photoelectron spectroscopy of HF-treated films are consistent with the formation of CuF, a compound which does not exist in bulk form. Treatment of films with HCl/EtOH results primarily in the formation of BaCl2, with smaller amounts of YCl3, CuCl, and CuCl2. Treatment with Br2/EtOH or HBr/EtOH results in the formation of YBr3, BaBr2, and CuBr with relative concentrations of 1:4:3.

Vasquez, R. P.↗
NASA NTRS1990

Phase separation in the t-J model

A detailed understanding of the motion of 'holes' in an antiferromagnet is of fundamental importance for the theory of high-temperature superconductors. It is shown here that, for the t-J model, dilute holes in an antiferromagnet are unstable against phase separation into a hole-rich and a no-hole phase. When the spin-exchange interaction J exceeds a critical value Jc, the hole-rich phase has no electrons. It is proposed that, for J slightly less than Jc, the hole-rich phase is a low-density superfluid of electron pairs. Phase separation in related models is briefly discussed.

Emery, V. J.↗