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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Genesis of the cumulate eucrites Serra de Mage and Moore County - A geochemical study

An instrumental neutron activation analysis of element abundances in whole rock and plagioclase separates of the Serra de Mage chondrite has been conducted; plagioclase data and plagioclase mineral/liquid partition coefficients are employed to determine the REE abundances in the derivative equilibrium magmas from which Serra de Mage and Moore County chondrite plagioclases crystallized. No simple genetic relationship between the two chondrites appears likely through the route of fractional crystallization. A difference in degrees of partial melting of a similar source material (different from the source proposed for noncumulate eucrites) could be invoked to relate the two chondrites.

Ma, M.-S.↗
NASA NTRS1978

Geophysical and geochemical evolution of the lunar magma ocean

There is increasing evidence that at least the outer few hundred kilometers of the moon were melted immediately following accretion. This paper studies the evolution of this lunar magma ocean. The long time scale for solidification leads to the inference that the plagioclase-rich (ANT) lunar crust began forming, perhaps preceded by local accumulations termed 'rockbergs', at the very beginning of the magma ocean epoch. In this view the cooling and solidification of the magma ocean was primarily controlled by the rate at which heat could be conducted across the floating ANT crust. Thus the thickness of the crust was the factor controlling the lunar solidification time. Heat arising from enthalpy of crystallization was transported in the magma by convection. Mixing length theory is used to deduce the principal flow velocity (typically several cm/s) during convection. The magma ocean is deduced to have been turbulent down to a characteristic length scale of the order of 100 m, and to have overturned on a time scale of the order of 1 yr for most of the magma ocean epoch.

Herbert, F.↗
NASA NTRS1979

A global geochemical model for the evolution of the mantle

It is proposed that the upper mantle transition region, 220 to 670 km, is composed of eclogite which has been derived from primitive mantle by about 20 percent partial melting and that this is the source and sink of oceanic crust. The remainder of the upper mantle is garnet peridotite which is the source of continental basalts and hotspot magmas. This region is enriched in incompatible elements by hydrous and CO2 rich metasomatic fluids which have depleted the underlying layers in the L.I.L. elements and L.R.E.E. The volatiles make this a low-velocity, high attenuation, low viscosity region. The eclogite layer is internally heated and its controls the convection pattern in the upper mantle. Plate tectonics is intermittent. The continental thermal anomaly at a depth of 150-220 km triggers kimberlite and carbonatite activity, alkali and flood basalt volcanism, vertical tectonics and continental breakup. Hot spots remain active after the continents leave and build the oceanic islands. Mantle plumes rise from a depth of about 220 km. Midocean ridge basalts rise from the depleted layer below this depth. Material from this layer can also be displaced upwards by subducted oceanic lithosphere to form back-arc basins.

Anderson, D. L.↗
NASA NTRS1979

The Sr and Nd isotopic record of Apollo 12 basalts - Implications for lunar geochemical evolution

Alkali, alkaline earth, and rare earth element data are reported for several Apollo 12 basalts which are representative of the four Apollo 12 magma types. Results confirm the heterogeneity of the lunar mantle and show that the Sm/Nd ratio of at least the Apollo 12 ilmenite basalts was decreased by 13-24% during magma genesis. In addition, whole mare basalt Sm-Nd data are not collinear on an isochron diagram; thus it is no longer possible to explain these data via mixing of 'primitive material' and 'early differentiates' as in the hybridization and assimilation models.

Nyquist, L. E.↗
NASA NTRS1981

Mineralogical, optical, geochemical, and particle size properties of four sediment samples for optical physics research

X-ray diffraction and spectroscopy were used to investigate the mineralogical and chemical properties of the Calvert, Ball Old Mine, Ball Martin, and Jordan Sediments. The particle size distribution and index of refraction of each sample were determined. The samples are composed primarily of quartz, kaolinite, and illite. The clay minerals are most abundant in the finer particle size fractions. The chemical properties of the four samples are similar. The Calvert sample is most notably different in that it contains a relatively high amount of iron. The dominant particle size fraction in each sample is silt, with lesser amounts of clay and sand. The indices of refraction of the sediments are the same with the exception of the Calvert sample which has a slightly higher value.

Bice, K.↗
NASA NTRS1981

Geochemical and spectral characterization of naturally altered rock surfaces

The possibility of using the visible-near infrared region for compositional analysis of remotely sensed rock surfaces is studied. This would allow mapping rock type both on the Earth's surface and on other planetary surfaces. Reflectance spectroscopy, economic geology, optical depth determination, and X-ray diffraction mineralogy are discussed.

Chang, L. L. Y.↗
NASA NTRS1980

Geochemical constraints on the igneous evolution of the lunar crust

Ti/Sm and Sc/Sm ratios confirm and extend the mineralogical dichotomy between the Mg-suite and the ferroan anorthosites. The latter have Ti/Sm near the chondritic ratio while the Ti/Sm of the pristine troctolites, norites, and KREEP basalts is nearly an order of magnitude lower. The two suites cannot be comagmatic; this implies that at least two major episodes of magmatism were involved in lunar crustal formation. Ferroan anorthosites probably formed as relatively direct products of the magma ocean. Mixing between a 'primitive' magma and a more 'evolved' magma may be necessary to account for both the major and trace element compositions of the Mg-suite.

Norman, M. D.↗
NASA NTRS1982

Geochemical studies of rocks from North Ray Crater, Apollo 16

The samples included in the study were all collected as individual specimens from Station 11 near the rim of North Ray Crater. Samples were selected to cover the entire range of rock types from anorthosites to subophitic impact melts, giving particular attention to the feldspathic breccias which predominate at the site. The chemical composition of North Ray Crater rocks is discussed along with the compositional variations among North Ray Crater samples, and the relationships between North Ray Crater and other Apollo 16 stations. It is pointed out that the primary objective in sampling the Apollo 16 site was to characterize materials from the Cayley Plains and Descartes Highlands.

Lindstrom, M. M.↗
NASA NTRS1982

The geochemical coherence of Pu and Nd and the Pu-244/U-238 ratio of the early solar system

Two very different sets of Pu-244/U-238 ratios have been reported for early solar system materials, one high and the other low, and this paper examines how one of these groups may yield an incorrect ratio. Recently measured partition coefficients for Pu and Sm (Jones, 1981) are used to evaluate Pu-Nd fractionation during achondrite genesis, and Pu-244/U-238 ratios of chondrites, achondrites, and Ca-Al-rich inclusions are compared and discussed. A low Pu-244/U-238 ratio is favored, and some implications of this low ratio for galactic nucleosynthesis and meteorite age dating are briefly discussed.

Jones, J. H.↗
NASA NTRS1983

Geochemical studies of feldspathic fragmental breccias and the nature of North Ray Crater ejecta

Wide variations in clast assemblages and bulk compositions are found in the matrix and clasts from feldspathic fragmental breccias by means of major and trace element analyses. The major components are found to be anorthosites, ferroan anorthositic norites, magnesian granulites, feldspathic melt rocks, and very high alumina impact melts. The compositional characteristics of bulk breccias and feldspathic melt rocks are quantitatively modeled as two- to five-component mixtures. Breccia 67455 is unique in consisting entirely of ferroan, KREEP-free components.

Lindstrom, M. M.↗
NASA NTRS1983

The use of hydroxyacids as geochemical indicators

The distributions of hydroxyacids in a variety of recent and ancient sediments have been determined by gas chromatography-mass spectrometry. A lacustrine sediment (Rostherne Mere, U.K.) and two marine situations (Cariaco Trench, Black Sea) were analyzed as examples of recent depositional environments. Beta-hydroxyacids occurred in all of the recent sediments, consistent with their presumed microbial origin, whereas di- and trihydroxyacids were present in the sediments with a significant higher plant input (Black Sea and Rostherne Mere sediments). The two ancient (Eocene) sediments examined, viz, the Greene River (U.S.) and Messel (Germany) oil shales, contained only trace amounts of hydroxyacids. These results provide evidence that hydroxyacids are in general not well preserved over geological time.

Cardoso, J. N.↗
NASA NTRS1983

Possible lunar source areas of meteorite ALHA 81005 Geochemical remote sensing information

Antarctic meteorite ALHA 81005 is a regolith breccia apparently sent to earth by an impact event in the lunar highlands. Laboratory studies of this sample provide information that is used to understand the source region on the moon using remote sensing data. The meteorites low thorium content is inconsistent with thorium values measured for the central lunar nearside from orbit with Apollo gamma-ray spectrometers. Similarly, the mineral assemblages inferred from near-IR spectra of small impact craters on the lunar nearside do not exhibit the significant component of olivine and Fe-bearing feldspar that is observed in the meteorite spectra. The existing remote sensing data suggest the most probable source region for ALHA 81005 is the nearside limb or the lunar farside and that the composition of ALHA 81005 represents a surface unit that has not previously been extensively sampled.

Pieters, C. M.↗
NASA NTRS1983

Isotopic evidence from the eastern Canadian shield for geochemical discontinuity in the Proterozoic mantle

The Nd and Sr isotopic compositions presently reported for anorthosites and related rocks from the Grenville and Nain Provinces of the eastern Canadian shield indicate that the massifs were delivered from at least two distinct mantle source regions which were established before 1650 Myr ago. These regions were episodically involved in magmatism over about 500 Myr. One reservoir was isotopically similar to the depleted, modern midocean ridge basalt source. The other reservoir was chondritic-to-moderately-enriched, and is most easily identified in the Nain Province, but may have occurred scattered throughout Superior Province, as well.

Ashwal, L. D.↗
NASA NTRS1983

The response of vegetation to geochemical conditions

An understanding of the factors of vegetation response to changes in the geochemistry of the environment may give exploration geologists and other researchers an additional and effective tool for rock type discrimination. The factors of vegetation response can be grouped into three principal categories: structural or morphological factors, taxonomic factors which include indicator flora as well as vegetation assemblages, and spectral factors which represent the manner in which the vegetation interacts with electromagnetic radiation. The response of these factors over areas of anomalous mineralization is often unique and may be due to nutrient deficiencies and/or imbalances, toxicity and stress caused by anomalous mineral concentrations in the soil, low water retention, and plant competition. The successful use of geobotanical techniques results from the integration of the geobotanical observations with other techniques. The use of remote sensing in such a program must be predicated on those factors which can be discriminated within the constraints of the spatial, spectral, radiometric, and temporal resolutions of the sensing system and with appropriate analytical techniques.

Mouat, D. A.↗
NASA NTRS1983

Geochemical evidence bearing on the origin of aerobiosis, a speculative hypothesis

It is pointed out that the atmosphere and hydrosphere of the early Archean earth were essentially anoxic. The paleontological record shows that life existed in spite of the absence of oxygen. The present investigation is concerned with the presentation of a plausible sequence of events, linking features in the carbon isotopic record to the origin of oxygenic photosynthesis. The investigation takes into account that the record of carbon isotopic abundances in sedimentary organic matter displays marked variations about 2.8 Ga before the present. At least by 2.8 Ga before the present, if not before, something in the carbon cycle began to allow the incorporation in sediments of organic material extraordinarily depleted in C-13. Attention is given to a model for the development of C-13 depleted kerogens, conclusions regarding the late Archean carbon cycle, and the transition in the global ecosystem.

Hayes, J. M.↗
NASA NTRS1984

An integrated dynamical and geochemical approach to lunar origin modelling

The three major categories of models of lunar origin which explain the Moon's properties are complete and a more general scenario is presented. The model presented is as the Earth grew by planetesimal bombardment, a circumterrestrial cloud of particles was created from a combination of impact ejected mantle material and planetismals captured directly into orbit around the Earth. The compositional properties are explained two ways: (1) a few big late planetismals of diverse composition are captured in orbit and/or hit the Earth; and (2) the circumterrestrial swarm acts as a filter, preferentially capturing small weak silicate bodies, while passing large iron planetismals.

Greenberg, R.↗