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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Observation of Vacancies, Faults, and Superstructures in Ln 5 Mo 2 O 12 (Ln = La, Y, and Lu) Compounds with Direct Mo–Mo Bonding

Among oxide compounds with direct metal–metal bonding, the Y 5 Mo 2 O 12 (A 5 B 2 O 12 ) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2 O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal–metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal–metal bonding have integer oxidation states resulting from the lifting of orbital degeneracy typically induced by the metal–metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5 Mo 2 O 12 (Ln = La–Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown in this paper that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2 O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1–2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5 Mo 2 O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. Finally, this represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Influence of weakening minerals on ensemble strength and slip stability of faults: Influence of Weakening Minerals on Fault

We explore the impact of phyllosilicate (weak but velocity strengthening) in a majority tectosilicate (strong but velocity weakening) matrix on bulk shear strength and slip stability of faults. Numerical simple shear experiments using a distinct element model (DEM) are conducted on both uniform mixtures of quartz and talc analogs and on textured mixtures consisting of a talc layer embedded in a quartz matrix. The mechanical response of particles is represented by a linear elastic contact model with a slip-weakening constitutive relation representing the essence of rate-state friction. The weight percentage of the talc in the uniform mixtures and the relative thickness of the talc layer in the textured mixtures are varied to investigate the transitional behavior of shear strength and slip stability. Specifically, for uniform mixtures, ~50% reduction on bulk shear strength is observed with 25% talc present, and a dominant influence of talc occurs at 50%; for textured mixtures, a noticeable weakening effect is shown at a relative layer thickness of 1 particle, ~50% shear strength reduction is observed with 3-particles, and a dominant influence occurs at 5 particles. In terms of slip stability, a transition from velocity weakening to velocity strengthening is observed with 10% to 25% talc present in the uniform mixtures or with 3 particles to 5 particles in the textured mixtures. In addition, further analysis suggests that quartz has a high tendency toward dilation, potentially promoting permeability; while talc dilates with increased slip rate but compacts rapidly when slip rate is reduced, potentially destroying permeability. The simulation results match well with previous laboratory observations.

58 GEOSCIENCES↗
NASA NTRS1983

Seismicity, fault plane solutions, depth of faulting, and active tectonics of the Andes of Peru, Ecuador, and southern Colombia

The long-period P waveforms observed for 17 earthquakes in the Peruvian Andes during 1963-1976 are compared with synthetic waveforms to obtain fault-plane solutions and focal depths. The morphological units of the Peruvian Andes are characterized: coastal plains, Cordillera Occidental, altiplano and central high plateau, Cordillera Oriental, and sub-Andes. The data base and analysis methodology are discussed, and the results are presented in tables, diagrams, graphs, maps, and photographs illustrating typical formations. Most of the earthquakes are shown to occur in the transition zone from the sub-Andes to the Cordillera Oriental under formations of about 1 km elevation at focal depths of 10-38 km. It is suggested that the sub-Andean earthquakes reflect hinterland deformation of a detached fold and thrust belt, perhaps like that which occurred in parts of the Canadian Rockies. From the total crustal shortening evident in Andean morphology and the shortening rate of the recent earthquakes it is estimated that the topography and crustal root of the Andes have been formed during the last 90-135 Myr.

Suarez, G.↗
NASA NTRS1990

Software reliability through fault-avoidance and fault-tolerance

The use of back-to-back, or comparison, testing for regression test or porting is examined. The efficiency and the cost of the strategy is compared with manual and table-driven single version testing. Some of the key parameters that influence the efficiency and the cost of the approach are the failure identification effort during single version program testing, the extent of implemented changes, the nature of the regression test data (e.g., random), and the nature of the inter-version failure correlation and fault-masking. The advantages and disadvantages of the technique are discussed, together with some suggestions concerning its practical use.

Vouk, Mladen A.↗
NASA NTRS1992

Advanced information processing system: The Army fault tolerant architecture conceptual study. Volume 1: Army fault tolerant architecture overview

Digital computing systems needed for Army programs such as the Computer-Aided Low Altitude Helicopter Flight Program and the Armored Systems Modernization (ASM) vehicles may be characterized by high computational throughput and input/output bandwidth, hard real-time response, high reliability and availability, and maintainability, testability, and producibility requirements. In addition, such a system should be affordable to produce, procure, maintain, and upgrade. To address these needs, the Army Fault Tolerant Architecture (AFTA) is being designed and constructed under a three-year program comprised of a conceptual study, detailed design and fabrication, and demonstration and validation phases. Described here are the results of the conceptual study phase of the AFTA development. Given here is an introduction to the AFTA program, its objectives, and key elements of its technical approach. A format is designed for representing mission requirements in a manner suitable for first order AFTA sizing and analysis, followed by a discussion of the current state of mission requirements acquisition for the targeted Army missions. An overview is given of AFTA's architectural theory of operation.

Harper, R. E.↗
NASA NTRS2009

Functional Fault Modeling of a Cryogenic System for Real-Time Fault Detection and Isolation

When setting out to model and/or simulate a complex mechanical or electrical system, a modeler is faced with a vast array of tools, software, equations, algorithms and techniques that may individually or in concert aid in the development of the model. Mature requirements and a well understood purpose for the model may considerably shrink the field of possible tools and algorithms that will suit the modeling solution. Is the model intended to be used in an offline fashion or in real-time? On what platform does it need to execute? How long will the model be allowed to run before it outputs the desired parameters? What resolution is desired? Do the parameters need to be qualitative or quantitative? Is it more important to capture the physics or the function of the system in the model? Does the model need to produce simulated data? All these questions and more will drive the selection of the appropriate tools and algorithms, but the modeler must be diligent to bear in mind the final application throughout the modeling process to ensure the model meets its requirements without needless iterations of the design. The purpose of this paper is to describe the considerations and techniques used in the process of creating a functional fault model of a liquid hydrogen (LH2) system that will be used in a real-time environment to automatically detect and isolate failures.

Ferrell, Bob↗