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Results for “electronic dynamics”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Photoinduced Charge Carrier Dynamics and Electron Injection Efficiencies in Au Nanoparticle-Sensitized TiO 2 Determined with Picosecond Time-Resolved X-ray Photoelectron Spectroscopy
Progress in the development of plasmon-enabled light-harvesting technologies requires a better understanding of their fundamental operating principles and current limitations. In this work, we employ picosecond time-resolved X-ray photoemission spectroscopy to investigate photoinduced electron transfer in a plasmonic model system composed of 20 nm sized gold nanoparticles (NPs) attached to a nanoporous film of TiO 2 . The measurement provides direct, quantitative access to transient local charge distributions from the perspectives of the electron donor (AuNP) and the electron acceptor (TiO 2 ). On average, approximately two electrons are injected per NP, corresponding to an electron injection yield per absorbed photon of 0.1%. Back electron transfer from the perspective of the electron donor is dominated by a fast recombination channel proceeding on a time scale of 60 ± 10 ps and a minor contribution that is completed after ~1 ns. The findings provide a detailed picture of photoinduced charge carrier generation in this NP–semiconductor junction, with important implications for understanding achievable overall photon-to-charge conversion efficiencies.
Correlated electron–nuclear dynamics of photoinduced water dissociation on rutile TiO2
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Simulation of the photodetachment spectra of the nitrate anion (NO 3 ₋ ) in the B ~ 2 E' energy range and non-adiabatic electronic population dynamics of NO 3
The photodetachment spectrum of the nitrate anion (NO 3 ₋ ) in the energy range of the NO 3 second excited state is simulated from first principles using quantum wave packet dynamics. The prediction at 10 K and 435 K relies on the use of an accurate full-dimensional fully coupled five state diabatic potential model utilizing an artificial neural network. The ability of this model to reproduce experimental spectra was demonstrated recently for the lower energy range. Analysis of the spectra indicates a weaker Jahn–Teller coupling compared to the first excited state. The detailed non-adiabatic dynamics is studied by computing the population dynamics. An ultra-fast non-statistical radiationless decay is found only among the Jahn–Teller components, which is followed by a slow statistical non-radiative decay among the different state manifolds. The latter is reproduced perfectly by a simple first order kinetics model. The dynamics in the second excited state is not affected by the presence of a conical intersection with the first excited state manifold.
Unimolecular dissociation dynamics of electronically excited HCO(Ã 2 A"): rotational control of nonadiabatic decay
The photoinduced unimolecular decay of the electronically excited HCO(Ã 2 A") is investigated in a combined experimental–theoretical study. The molecule is excited to the (1, n 2 , 0) combination bands, which decay via Renner–Teller coupling to the ground electronic state. The rovibrational state distribution of the CO fragment was measured via the high-n Rydberg H-atom time-of-flight method and calculated using a wave packet method on an accurate set of potential energy surfaces. It is shown that the non-adiabatic decay rate is strongly modulated by the HCO rotational angular momentum, which leaves unique signatures in the product state distribution. Finally, the experimentally observed bimodal rotational distribution of the dominant CO(v = 0) fragment is likely due to decay of different vibronic states populated by the excitation and modulated by the excited state lifetime, which is in turn controlled by the parent rotational quantum number.
Bottom-up carbon dots: purification, single-particle dynamics, and electronic structure
For carbon dots, careful purification and electronic structure calculations facilitate learning about the origin of optical properties.
Submicropulse electron-beam dynamics correlated with short-range wakefields in Tesla-type superconducting rf cavities
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Submacropulse electron-beam dynamics correlated with higher-order modes in a Tesla-type cryomodule
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Error dynamics during electron spin shuttling
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An investigation of wave-particle interactions and particle dynamics using electron beams injected from sounding rockets
Electrons with energy up to 40 kV have been injected into semi-trapped orbits from sounding rockets at Wallops Island, Virginia, and at Fort Churchill, Manitoba, Canada. By directing the rocket trajectory to have a horizontal component which in direction and speed matched the bounce displacement of the injected electrons, it was possible to detect conjugate echoes at Wallops and possibly at Churchill, and to study the distribution of the echoes in space, time and energy. By combining observations of many echoes, a composite picture can be obtained of the beam patterns. Atmospheric scattering at the conjugate point of Wallops Island has been extensively studied, and the process produces a scale width of 5-10 m, but with an echo intensity which is only 10% of theoretical estimates.
Effects of the solar wind on magnetospheric dynamics: Energetic electrons at the synchronous orbit
A correlation of the observations of energetic electron fluxes at the synchronous orbit with the interplanetary medium and the behavior of energetic trapped radiation at the synchronous altitude were analyzed. Data covering the 1967 to 1978 interval were obtained by the ATS 1, ATS 5, and ATS 6 spacecraft. Long term (year) and short term (days) electron flux averages are found to correlate positively with corresponding averages of the solar wind velocity.
Effects of the solar wind on magnetospheric dynamics - Energetic electrons at the synchronous orbit
Data on energetic electron fluxes at the synchronous orbit, covering the 1967-1978 time interval, obtained by experiments flown on the ATS-1, ATS-5 and ATS-6 spacecraft, have been analyzed. Long term (year) and short term (days) electron flux averages are found to correlate positively with corresponding averages of the solar wind velocity.
Pulsars as cosmic ray particle accelerators: Dynamics of electrons
The Lorentz-Dirac-equation with Landau approximation has been solved numerically for electrons in the electromagnetic field of a magnetic dipole rotating with the angular velocity omega perpendicular to its magnetic moment mu. Results are discussed with respect to electron orbits and energy development.