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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Electrically Conductive Amine Functionalized Reduced Graphite Oxide Foam for CO 2 Removal from the Air

Rapid regeneration of CO 2 adsorbents is critical to improving the productivity of direct air capture (DAC) systems. In this study, we codesigned a material to have appropriate electrical conductivity and CO 2 adsorption properties to enable efficient CO 2 capture from air. Specifically, we present a poly(ethylenimine) (PEI)-impregnated thermally annealed graphite oxide (TAGO900) foam adsorbent tailored for vacuum-assisted electrically driven thermal swing adsorption (V-ETSA). This structured adsorbent leverages the high electrical conductivity of the reduced graphite oxide framework to enable fast and direct heating of the adsorbent material by electrical resistance heating (Joule heating). An optimal sample, 40 wt % PEI (molecular weight 25k) impregnated TAGO900, shows the best balance between adsorption capacity (1.54 mmol g –1 ) and adsorption rates (0.016 mmol g –1 min –1 ) using fixed bed breakthrough experiments at 25 °C and 70% RH using 50 sccm 400 ppm of CO 2 /N 2 flow. Compared to conventional temperature vacuum swing adsorption (TVSA), the V-ETSA approach achieves substantially faster CO 2 desorption, achieving average desorption rates (including cooling time) of 0.09 mmol g –1 min –1 ─approximately 2.5 times faster than TVSA under similar operating conditions. The maximum desorption rate reaches 0.23 mmol/g/min during the desorption stage. These results underscore the importance of the direct heating strategy, such as Joule heating, for fast and highly productive vacuum swing adsorption in DAC systems.

amines↗
NASA NTRS1974

Lunar electrical conductivity, permeability,and temperature from Apollo magnetometer experiments

Magnetometers were deployed at four Apollo sites on the moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments were used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients, were analyzed to calculate and electrical conductivity profile for the moon, and those profiles were used to calculate the lunar temperature for an assumed lunar material of olivine. Simultaneous measurements by magnetometers on the lunar surface and in orbit around the moon were use to construct a whole-moon hysteresis curve, from which the global lunar magnetic permeability is determined. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) was calculated for two assumed compositional models of the lunar interior. Other lunar models with an iron core and with a shallow iron-rich layer also discussed in light of the measured global lunar permeability. Simultaneous magnetic field and solar plasma pressure measurements show that the remanent fields at the Apollo 12 and 16 sites interact with, and are compressed by, the solar wind. Velocities and thicknesses of the earth's magnetopause and bow shock were also estimated from simultaneous magnetometer measurements.

Dyal, P.↗
DOE OSTI2020

In Situ Structural and Electrical Conductivity Characterization of Sr2MMoO6-δ Double Perovskite Solid Oxide Fuel Cell Anode Materials

In this study, a series of Sr 2 MMoO 6-δ double perovskite solid oxide fuel cell (SOFC) anode materials (where 0 <= δ <= 0.041 and M = Fe, Co, or Ni) were synthesized, and the changes in their morphologies under relevant SOFC operating conditions were explored. Ultra-small-angle X-ray scattering (USAXS), small-angle X-ray scattering (SAXS), and wide-angle X-ray scattering (WAXS) were used to determine changes in the microstructures and phase compositions of the anode materials at high temperatures and under a reducing atmosphere. The stability of the double perovskite structure was found to be highly dependent on the identity of the cation M, such that when M = Fe, the material remained stable over the course of the experiments. However, when M = Co or Ni, significant changes in the microstructure and phase composition were observed. An in situ study of the M = Co sample, in which electrical conductivity and USAXS/SAXS/WAXS measurements were conducted simultaneously, revealed the structural degradation mechanisms and electrical conductivity changes over a range of temperatures. To conduct these measurements, a cell was developed that allowed for a sample mounted on Pt wires to be placed in the X-ray beam and heated under gas flow comprising 4% mass H 2 and 96% mass N 2 . The resulting measurements allowed for the direct comparison of the electrical and morphological changes occurring in the material under operating conditions, such that increases in conductivity could be attributed to the growth of new phases.

25 ENERGY STORAGE↗
NASA NTRS2019

Predictability of Ocean Heat Content From Electrical Conductance

Ocean heat content (OHC) is a key climate variable that needs to be monitored to know how Earth's energy imbalance is changing, yet observing OHC remains a challenge. The present study examines whether a depth integral of the ocean's electrical conductivity (“conductance”), which may be inferred from both in situ methods and satellite magnetometers over the global ocean, could help monitor OHC. The ocean's electrical conductivity locally depends on temperature, salinity, and pressure, but it is not as well known how the conductance depends on OHC and ocean salt content. By examining the output of an ocean state estimate shown to agree well with observations that have not been assimilated, this study evaluates the fundamental limitations of using perfectly known ocean conductance to predict OHC, rather than the challenges associated with accounting for observational error. It is found that the ocean's conductance and OHC fields are nonlinearly related but nevertheless highly correlated. A statistical framework tends to predict OHC more accurately than ocean salt content from ocean conductance in regions where conductivity is more sensitive to salinity than temperature. The annually (bidecadally) averaged OHC can be predicted from a combination of conductance and depth‐averaged conductivity ocean fields to within nearly 0.1% (1%) error globally and even more accurately in many poorly observed (e.g., ice‐covered) regions. Practical application of this statistical framework to monitor OHC requires examination of the effect of uncertainties in the observed bathymetry and ocean conductance, which vary with application.

Trossman, D. S.↗
NASA NTRS1974

Temperature and electrical conductivity of the lunar interior from magnetic transient measurements in the geomagnetic tail

Magnetometers were deployed at four Apollo sites on the moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments were used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients in the geomagnetic tail field, were analyzed to calculate an electrical conductivity profile for the moon: the conductivity increases rapidly with depth from 10 to the minus 9 power mhos/meter at the lunar surface to .0001 mhos/meter at 200 km depth, then less rapidly to .02 mhos/meter at 1000 km depth. A temperature profile is calculated from conductivity: temperature rises rapidly with depth to 1100 K at 200 km depth, then less rapidly to 1800 K at 1000 km depth. Velocities and thicknesses of the earth's magnetopause and bow shock are estimated from simultaneous magnetometer measurements. Average speeds are determined to be about 50 km/sec for the magnetopause and 70 km/sec for the bow shock, although there are large variations in the measurements for any particular boundary crossing.

Dyal, P.↗
NASA NTRS1977

Lunar electrical conductivity, permeability and temperature from Apollo magnetometer experiments

Magnetometers were deployed at four Apollo sites on the moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments were used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. The measured lunar remanent fields range from 3 gammas minimum at the Apollo 15 site to 327 gammas maximum at the Apollo 16 site. Simultaneous magnetic field and solar plasma pressure measurements show that the remanent fields at the Apollo 12 and 16 sites interact with, and are compressed by, the solar wind. Remanent fields at Apollo 12 and Apollo 16 are increased 16 gammas and 32 gammas, respectively, by a solar plasma bulk pressure increase of 1.5 X 10 to the -7th power dynes/sq cm. Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients, were analyzed to calculate an electrical conductivity profile for the moon. From nightside magnetometer data in the solar wind it was found that deeper than 170 km into the moon the conductivity rises from .0003 mhos/m to .10 mhos/m at 100 km depth. Recent analysis of data obtained in the geomagnetic tail, in regions free of complicating plasma effects, yields results consistent with nightside values.

Dyal, P.↗
NASA NTRS1994

The electrical conductivities of candidate beam-waveguide antenna shroud materials

The shroud on the beam-waveguide (BWG) antenna at DSS 13 is made from highly magnetic American Society for Testing and Materials (ASTM) A36 steel. Measurements at 8.42 GHz showed that this material (with paint) has a very poor electrical conductivity that is 600 times worse than aluminum. In cases where the BWG mirrors might be slightly misaligned, unintentional illumination and poor electrical conductivity of the shroud walls can cause system noise temperature to be increased significantly. This potential increase of noise temperature contribution can be reduced through the use of better conductivity materials for the shroud walls. An alternative is to attempt to improve the conductivity of the currently used ASTM A36 steel by means of some type of plating, surface treatment, or high-conductivity paints. This article presents the results of a study made to find improved materials for future shrouds and mirror supports.

Otoshi, T. Y.↗
NASA NTRS1982

The deep lunar electrical conductivity profile - Structural and thermal inferences

Simultaneous lunar surface and orbital magnetometer records are reexamined, to ascertain intervals which may be suitable for measuring lunar inductive response in the solar wind and terrestrial magnetosheath. Power spectral estimates of the response tangent to the lunar surface, defined in terms of transfer and gain functions, are obtained for the 0.0001-0.01 Hz frequency range. The maximum consistency of estimates from different time intervals is found when the initial analysis is limited to the tangential direction of maximum incident power, or that direction in which the ratio of signal to background noise is greatest. Spherically symmetric plasma confinement theory is used in the interpretation of transfer function data, by way of forward model calculations, under the assumption of continuous electrical conductivity increase with depth. Results are presented for internal electrical conductivity profile, metallic core radius, and selenotherm limits.

Hood, L. L.↗
DOE OSTI2020

Model for the electrical conductivity in dense plasma mixtures

A new density functional theory, average atom based model for the electrical conductivity of dense plasmas with a mixture of ion species, containing no adjustable parameters, is presented herein. The model takes the temperature, mass density and relative abundances of the species as input. It takes into account partial ionization, ionic structure, and core-valence orthogonality, and uses quantum mechanical calculations of cross sections. Comparison to an existing high fidelity but computationally expensive method reveals good agreement. The new model is computationally efficient and can reach high temperatures. A new mixing rule is also presented that gives reasonably accurate conductivities for high temperature plasma mixtures.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Electrical conductivity of multilayered Cu/Nb composites fabricated by accumulative roll bonding

The electrical conductivity of nanolayered copper/niobium composites fabricated using accumulative roll bonding was investigated as a function of layer thickness. Cu/Nb was used as a model system to evaluate the processing-structure–property relationship stemming from the accumulative roll bonding process. The physical properties were compared against samples of individual average layer heights ranging from 193 to 25 nm. The electrical resistivity was measured over a temperature range of ~3–300 K. Analysis on the role of interfaces on temperature dependence is conducted including the residual resistivity ratio and temperature coefficient of resistivity. It was found that electrical resistivity increases with decreasing layer height.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Critical review of electrical conductivity measurements and charge distribution analysis of magnesium oxide

The electrical conductivity sigma of MgO single crystals shows a sharp increase at 500-800 C, in particular of sigma surface, generally attributed to surface contamination. Charge Distribution Analysis (CDA), a new technique providing information on fundamental properties that was previously unavailable, allows for the determination of surface charges, their sign and associated internal electric field. Data on 99.99% purity, arc-fusion grown MgO crystals show that mobile charge carriers start to appear in the bulk of the MgO crystals between 200 and 400 C when sigma (measured by conventional techniques) is in t he 10(exp -14) to 10(exp -16) /omega/cm range. Above 500 C, as sigma increases to 10(exp -6) to 10(exp -7)/omega/cm, more charges appear giving rise to a strong positive surface charge supported by a strong internal field. This indicates that charges are generated in the bulk and diffuse to the surface by an internally controlled process. On the basis of their positive sign they are identified as holes (defect electrons). Because of the low cation content of these very pure MgO crystals, theses holes cannnot be associated with transition metal impurties. Instead, they are associated with the O(2-) sublattice, e.g. consist of O(-) states or positive holes. This conclusion is supported by magnetic susceptibility data showing the appearance of 1000 +/- 500 ppm paramagnetic species between 200-500 C. The magnetic data are consistent with strongly coupled, diamagnetic O(-) pairs below 200-500 C, chemically equivalent to peroxy anions, O2(2-), and probably associated with cation vacancies in the MgO matrix. The formation of O2(2-) in arc-fusion grown MgO crystals is very unexpected because of the highly reducing growth conditions. Their presence implies an internal redox reaction involving dissolved 'water' by which OH(-) pairs convert to O2(2-) plus H2 molecules. This redox conversion is supported by mass spectroscopic measurements of the H2 release from highly OH(-)-doped, finely divided MgO and by wet-chemical analysis of its oxidant concentration.

Freund, Friedemann↗
DOE OSTI2025

Contact with Electrically Conductive Inert Solids Alters Intrinsic Heterogeneous Brønsted Acid Catalysis

Interfacial electric fields at heterogeneous catalyst surfaces have been demonstrated to alter kinetics of liquid-phase reactions. In these systems, electric fields are generated from applying a potential to the catalyst through connection to a potentiostat or through electron transfer from redox-active species in solution. Here, we demonstrate that catalyst polarization can also occur by simply contacting electrically conductive inert solids, leading to the counterintuitive conclusion that a catalyst particle touching an inert solid can alter intrinsic reaction rates. Using dehydration of 1-methylcyclopentanol to 1-methylcyclopentene catalyzed by Brønsted-acidic carboxylic acid groups on carbon nanotubes as a proof-of-concept probe reaction, we show that catalyst contact with inert, thermally reduced carbon nanotubes leads to order-of-magnitude changes in reaction rate. Furthermore, we demonstrate that these contact-induced effects can also be observed under standard laboratory reaction conditions, where particle-to-particle contact in stirred catalyst powder suspensions is sufficient to demote rates by ∼8-fold. This work provides the foundation for a new method of reaction rate control, which could have implications whenever heterogeneous catalyst particles are in contact with inert materials for liquid-phase reactions in the presence of electrolyte.

Alcohols↗
NASA NTRS1988

Electrically Conducting Polymer-Copper Sulphide Composite Films, Preparation by Treatment of Polymer-Copper (2) Acetate Composites with Hydrogen Sulfide

Polymer copper sulfide composite films were prepared by treatment of polymer poly(vinyl chloride), poly(acrylonitrile), copolymer of vinyl chloride and vinyl acetate (90:10), and ABS resin copper (2) acetate composites with hydrogen sulfide. The films showed electrical conductivity higher than 0.015 S/cm when they contained more than 20 wt percent of copper sulfide. A poly(acrylonitrile)-copper sulfide composite film containing 40 to 50 wt percent of copper sulfide showed electrical conductivity of 10 to 150.0 S/cm and had relatively high mechanical strength to be used in practical purposes.

Yamamoto, Takakazu↗