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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Optical remote sensing for measurement of toxic gases

There is renewed interest in using optical remote sensing techniques for measuring and monitoring airborne toxins. Many instruments have been used to measure traces of atmospheric molecular species. Some optical remote sensing technology is in use for measuring or monitoring toxic or pollutant gases. The examples in this article provide a number of lessons that may be of use in the new field of optical remote sensing of toxic gases. Topics covered include the following: atmospheric properties, Fourier transform spectrometry, gas-filter correlation, differential absorption laser systems, aircraft missions, laser long-path instruments, differential optical absorption spectrometry, and ozone measurement.

Grant, William B.↗
NASA NTRS1996

Chemical and Thermal Analysis

Work has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-Ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted changes in the molecular weight distribution of the Coflon material using a dual detector Gel Permeation Analysis. Again these changes may result in variation in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-Ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, Thermogravimetric Analysis, and Differential Scanning Calorimetry. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. Pressurized tests were performed in a modified Fluid G, which we will call G2. In this case the ethylene diamine concentration was increased to 3 percent in methanol. Coflon pipe sections and powdered Coflon were exposed in pressure cells at 1700 psi at three separate test temperatures, 70 C, 110 C, and 130 C. The primary purpose of the pressure tests in Fluid G2 was to further elucidate the aging mechanism of PVDF degradation.

Bulluck, J. W.↗
NASA NTRS1995

Chemical and Thermal Analysis

During the past six months we have conducted significant research in several domains in order to clarify and understanding the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. We organized numerous analytical studies with methods including Fourier Transform Infrared Spectroscopy, Dynamic Mechanical Analysis, Differential Scanning Calorimetry, and Stress Relaxation experiments. In addition we have reanalyzed previous thermogravimetric data concerning the rate of deplasticization of Coflon pipe. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. We conducted stress relaxation experiments of Coflon pipe at several temperatures and determined an activation energy. We also examined the dynamic mechanical response PVDF during deplasticization and during methanol plasticization. We performed numerous DSC analyses to research the changing crystalline morphology. We have noted significant changes in crystallinity upon aging for both PVDF and Tefzel. Little variation in elemental composition was noted for many of the aged Coflon and Tefzel samples tested.

Bulluck, J. W.↗
NASA NTRS2018

The Network for the Detection of Atmospheric Composition Change (NDACC): History, Status and Perspectives

The Network for the Detection of Atmospheric Composition Change (NDACC) is an international global network of more than 90 stations making high-quality measurements of atmospheric composition that began official operations in 1991 after 5 years of planning. Apart from sonde measurements, all measurements in the network are performed by ground-based remote-sensing techniques. Originally named the Network for the Detection of Stratospheric Change (NDSC), the name of the network was changed to NDACC in 2005 to better reflect the expanded scope of its measurements. The primary goal of NDACC is to establish long-term databases for detecting changes and trends in the chemical and physical state of the atmosphere (mesosphere, stratosphere, and troposphere) and to assess the coupling of such changes with climate and air quality. NDACC's origins, station locations, organizational structure, and data archiving are described. NDACC is structured around categories of ground-based observational techniques (sonde, lidar, microwave radiometers, Fourier-transform infrared, UV-visible DOAS (differential optical absorption spectroscopy)-type, and Dobson-Brewer spectrometers, as well as spectral UV radiometers), timely cross-cutting themes (ozone, water vapour, measurement strategies, cross-network data integration), satellite measurement systems, and theory and analyses. Participation in NDACC requires compliance with strict measurement and data protocols to ensure that the network data are of high and consistent quality. To widen its scope, NDACC has established formal collaborative agreements with eight other cooperating networks and Global Atmosphere Watch (GAW). A brief history is provided, major accomplishments of NDACC during its first 25 years of operation are reviewed, and a forward-looking perspective is presented.

lidar↗
NASA NTRS1977

Derivation of an integral equation for transonic flows

It is noted that the nonlinear partial differential equation for the perturbation velocity potential and boundary conditions describing steady inviscid compressible transonic flow past a thin two-dimensional airfoil can be transformed into a singular integrodifferential equation and that differentiation of the latter yields an integral equation. Two forms of this integral equation currently exist: one for the singularity that is enclosed in an infinitely long strip of vanishing thickness and the other for the singularity that is enclosed in a vanishing circle. In the present article, a more general integral equation is derived by enclosing the singularity in a vanishing rectangular cavity of arbitrary aspect ratio. The two existing forms of this equation are deduced as special cases distinguished by the respective values for the aspect ratio (infinity for the first form and unity for the second).

Ogana, W.↗
NASA NTRS1983

Linear approximations of nonlinear systems

A method for designing an automatic flight controller for short and vertical takeoff aircraft is presently being developed at NASA Ames Research Center. This technique involves transformations of nonlinear systems to controllable linear systems and takes into account the nonlinearities of the aircraft. In general, the transformations cannot always be given in closed form. Using partial differential equations, an approximate linear system, called the modified tangent model, was recently introduced. A linear transformation of this tangent model to Brunovsky canonical form can be constructed, and from this an approximation of an exact transformation for the nonlinear system can be found. It is shown that a canonical expansion in Lie brackets about the point x(0) yields the same modified tangent model.

Hunt, L. R.↗
NASA NTRS1994

Calorimetric thermometry of meteoritic troilite: Preliminary thermometer relationships

Thermodynamic properties of the alpha/beta phase transformation in terrestrial troilite (FeS), as measured by differential scanning calorimetry (DSC), vary systematically with prior thermal history of the troilite, as imposed under laboratory conditions. Both the transition temperature and enthalpy change for the alpha/beta transformation decrease with increasing maximum temperature of prior heat treatment. DSC measurements on troilite from various meteorites indicate clear differences in the alpha/beta thermodynamic properties that are consistent with differences in the natural thermal histories of the meteorites.

Allton, Judith H.↗
NASA NTRS1972

Bounded state variables and the calculus of variations

An optimal control problem with bounded state variables is transformed into a Lagrange problem by means of differentiable mappings which take some Euclidean space onto the control and state regions. Whereas all such mappings lead to a Lagrange problem, it is shown that only those which are defined as acceptable pairs of transformations are suitable in the sense that solutions to the transformed Lagrange problem will lead to solutions to the original bounded state problem and vice versa. In particular, an acceptable pair of transformations is exhibited for the case when the control and state regions are right parallelepipeds. Finally, a description of the necessary conditions for the bounded state problem which were obtained by this method is given.

Hanafy, L. M.↗
NASA NTRS1996

Non-Isothermal Calorimetric Studies of the Crystallization of Lithium Disilicate Glass

The influence of preannealing treatments on the polymorphic crystallization of lithium disilicate glasses is examined. As expected, glasses heated at different rates through the temperature range where there is significant nucleation develop widely different numbers of nuclei. This can dramatically influence the stability and transformation characteristics of the annealed glass. Non-isothermal differential scanning calorimetry (DSC) and differential thermal analysis (DTA) measurements are demonstrated to be useful to probe the nucleation behavior. The first systematic investigations of particle size effects on the non-isothermal transformation behavior are presented and discussed. Based on DTA and microscopy experiments, we show that small particles of lithium disilicate glasses crystallize primarily by surface crystallization. The relative importance of surface versus volume crystallization is examined by varying particle size, by introducing nucleating agents and by exposing glasses to atmospheres of different water content. These data are analyzed quantitatively using a numerical model developed in a second paper following in this volume.

Ray, C. S.↗
NASA NTRS1980

Theoretical determination of nozzle admittances using a finite element approach

A finite element method is used to predict the admittances of axisymmetric nozzles. It is assumed that the flow in the nozzle is isentropic and irrotational, and the disturbances are small so that linear analyses apply. An approximate, two dimensional compressible model is used to describe the steady flow in the nozzle. The propagation of acoustic disturbances is governed by the complete linear wave equation. The differential form of the acoustic equation is transformed to an integral equation using Galerkin's method, and Green's theorem is applied so that the acoustic boundary conditions can be introduced through the boundary residuals. A two-dimensional FEM using linear elements is used to solve the acoustic equation. A one dimensional FEM is also used to solve the reduced equation of Crocco, and the solution verifies the sufficiency of the boundary residual formulation. Comparison between computed admittances and experimental data is shown to be quite good.

Sigman, R. K.↗
NASA NTRS1980

An analytical transformation technique for generating uniformly spaced computational mesh

An analytical transformation method which can map arbitrary physical coordinate grid distribution into desired computational coordinate with uniform grid distribution is derived. The transformation function and its higher derivatives are differentiable. Salient features include; (1) precise control of grid sizes; (2) more than one location of clustered grids; (3) exact positioning of particular computational nodes in the physical plane; and (4) ensuring several patches of uniformly spaced grids in the physical plane for the higher accuracies (such as at the boundaries), etc., while keeping the variation of grid spacing continuous to avoid numerical instability.

Oh, Y. H.↗
NASA NTRS1982

Inexpensive Logic-Level Converter

Relatively-simple transformer circuit boosts 0-to-5 volt pulses from TTL circuitry to plus or minus 10-volt pulses for transmission over data bus. Also reduces bus voltages to lower voltages required by TTL circuitry. Circuit consists of transformer, two voltage-reference networks, quad differential line receiver, and line driver.

Wilcox, S. W.↗
NASA NTRS1984

Effects of boundary layer refraction and fuselage scattering on fuselage surface noise from advanced turboprop propellers

An acoustic disturbance's propagation through a boundary layer is discussed with a view to the analysis of the acoustic field generated by a propfan rotor incident to the fuselage of an aircraft. Applying the parallel flow assumption, the resulting partial differential equations are reduced to an ordinary acoustic pressure differential equation by means of the Fourier transform. The methods used for the solution of this equation include those of Frobenius and of analytic continuation; both yield exact solutions in series form. Two models of the aircraft fuselage-boundary layer system are considered, in the first of which the fuselage is replaced by a flat plate and the acoustic field is assumed to be two-dimensional, while in the second the fuselage is a cylinder in a fully three-dimensional acoustic field. It is shown that the boundary layer correction improves theory-data comparisons over simple application of a pressure-doubling rule at the fuselage.

Mcaninch, G. L.↗
NASA NTRS1983

A finite element approach for predicting nozzle admittances

A finite element method is used to predict the admittances of axisymmetric nozzles. It is assumed that the flow in the nozzle is isentropic and the disturbances are small so that linear analyses apply. An approximate, two dimensional compressible model is used to describe the steady flow in the nozzle. The propagation of acoustic disturbances is governed by the complete linear wave equation. The differential form of the acoustic equation is transformed to an integral equation by using Galerkin's method, and Green's theorem is applied so that the acoustic boundary conditions can be introduced through the boundary residuals. The boundary conditions are described for both straight and curved sonic lines. A two dimensional FEM with linear elements is used to solve the acoustic equation. A one dimensional FEM is also used to solve the reduced equation of Crocco, and the solution verifies the sufficiency of the boundary residual formulation. Comparison between computed admittances and experimental data is shown to be quite good.

Sigman, R. K.↗
NASA NTRS2019

Systematic Error Cancellation for a Four-Port Interferometric Polarimeter

The Primordial Inflation Explorer (PIXIE) is an Explorer-class mission concept to measure the gravitational-wave signature of primordial inflation through its distinctive imprint on the linear polarization of thecosmic microwave background (CMB). Its optical system couples a polarizing Fourier transform spectrometerto the sky to measure the differential signal between orthogonal linear polarization states from two co-pointedbeams on the sky. The double differential nature of the four-port measurement mitigates beam-related systematic errors common to the two-port systems used in most CMB measurements. Systematic errors coupling unpolarized temperature gradients to a false polarized signal cancel to first order for any individual detector. Thiscommon-mode cancellation is performed optically, prior to detection, and does not depend on the instrumentcalibration. Systematic errors coupling temperature to polarization cancel to second order when comparing signals from independent detectors. We describe the polarized beam patterns for PIXIE and assess the systematicerror for measurements of CMB polarization.

Kogut, Alan J.↗
NASA NTRS2013

A 294 GHz 0.47m W Caterpillar amplifier based transmitter in 65 nm CMOS for THz data-links

A fully integrated CMOS THz transmitter for short range data-links is presented which provides 0.47 mW of output power to 294 GHz. The output frequency is derived from a 147 GHz on-chip LO and fully differential caterpillar power amplifier combined with a transformer coupled frequency doubler. The transmitter is integrated with an on-chip dipole antenna for use in THz communication systems and consumes a total of 258 mW.

Chang, Mau-Chung Frank↗