Cryogenic properties of a polyurethane adhesive
Polyurethane adhesives differential thermal analysis, rebound resilience and tensile properties at cryogenic temperatures
Robbins, R. F.↗
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Cryogenic properties of a polyurethane adhesive
Resilience and tensile properties of polyurethane adhesive at cryogenic temperatures measured by differential thermal analysis
Robbins, R. F.↗
Pyrotechnic hazards classification and evaluation program. Phase 3, segments 1-4: Investigation of sensitivity test methods and procedures for pyrotechnic hazards evaluation and classification, part A
The findings, conclusions, and recommendations relative to the investigations conducted to evaluate tests for classifying pyrotechnic materials and end items as to their hazard potential are presented. Information required to establish an applicable means of determining the potential hazards of pyrotechnics is described. Hazard evaluations are based on the peak overpressure or impulse resulting from the explosion as a function of distance from the source. Other hazard classification tests include dust ignition sensitivity, impact ignition sensitivity, spark ignition sensitivity, and differential thermal analysis.
Source record↗
Morphology of poly-p-xylylene crystallized during polymerization.
The morphology of as-polymerized poly-p-xylylene grown between -17 and 30 C is found to consist of lame llar alpha crystals oriented with the (010) plane parallel to the support surface. The crystallinity decreases with decreasing polymerization temperature. Spherulitic and nonspherulitic portions of the polymer film consist of folded chain lamellas with the chain axis parallel to the support surface. The results were obtained by small- and wide-angle X-ray measurements, electron and optical microscopy, and differential thermal analysis.
Kubo, S.↗
A study of the effects of solid phase reactions on the thermal degradation and ballistic properties of solid propellants
The thermal stability of perchlorate composite propellants was studied at 135 and 170 C. The experimental efforts were concentrated on determining the importance of heterogeneous oxidizer-fuel reactions in the thermal degradation process. The experimental approach used to elucidate the mechanisms by which the oxidizer fuel composites thermally degrade was divided into two parts: (1) keeping the fuel constant and varying the nature of the oxidizers, and (2) holding the oxidizer constant and varying the fuel components. The fuel component primarily utilized in the first phase was polyethylene. Oxidizers included KClO4, KClO3, NH4ClO4 and NH4ClO4 doped with materials such as chlorate, phosphate and arsenate. In the second phase the oxidizer used was primarily NH4ClO4 while the fuels included saturated and unsaturated polybutadiene prepolymers and a series of bonding agents. Techniques employed in the current study include thermogravimetric measurements, differential thermal analysis, infrared, mass spectrometry, electron microscopy, and appropriate wet chemical analysis.
Schmidt, W. G.↗
Study of recrystallization and devitrification of lunar glass
The technique of differential thermal analysis (DTA) was applied to the study of the Apollo 17 orange soil (74220,63) and the Apollo 16 glass coated anorthite (64455,21). These glasses show accentuated exotherms of strain relief in the annealing range which is indicative of rapid cooling. These are amenable to interpretation by comparison to the known history of synthetic glasses. Synthetic glasses were prepared whose similarity in behavior between the lunar glasses and their synthetic analogs is striking. Approximate rates of cooling of the lunar glasses were determined from comparative DTA of lunar and synthetic glasses and from the determination of the relation of strain relief in the annealing range to quench rate. At higher temperatures the glasses show exotherms of crystallization. The crystallization products associated with the exothermic reactions have been identified by X-ray diffraction and the surface morphologies developed by strain relief and crystallization have been characterized with scanning electron microscopy.
Ulrich, D. R.↗
Lunar sample contracts
The major scientific accomplishments through 1971 are reported for the particle track studies of lunar samples. Results are discussed of nuclear track measurements by optical and electron microscopy, thermoluminescence, X-ray diffraction, and differential thermal analysis.
Walker, R. M.↗
Annealing of aromatic polyimide precursors
A study has been made of the thermal behavior of polyimide precursors: an isomeric pair of crystals of the complex formed by p-phenylenediamine with the separated isomers of the di-isopropyl ester of pyromellitic acid. Specimens of this material were isothermally annealed in the temperature range 120 C to 170 C for periods of time up to 1 week. Although this temperature range is well below that customarily used for imidizations, the working hypothesis was that it would be more likely that a polymer embodying at least part of the precursor structure could be formed if the molecular motion was minimized to that actually required for the formation of the imide linkage. The progress of the annealing was followed by: infrared spectroscopy, differential thermal analysis, powder X-ray diffraction, and thermal gravimetric analysis. Single crystal X-ray analysis of the meta monomer yields a structure of chains of alternating acid and base and suggests that this monomer is amenable to polymerization with a minimum of geometrical disruption.
Wakelyn, N. T.↗
A survey of NASTRAN improvements since level 15.5
Several improvements and capabilities were developed and installed in intermediate levels and are being analyzed and evaluated. A survey of current improvements to the program is presented which includes static analysis with differential stiffness rigid format, normal modes with differential stiffness rigid format, the TRIAAX and TRAPAX elements, the CNGRNT feature, fully stressed design, element strain energy and grid point force balance, and complex modal displacement plots.
Mcdonough, J. R.↗
Development of improved amorphous materials for laser systems
Crystallization calculations were performed in order to determine the possibility of forming a particular type of laser glass with the avoidance of devitrification in an outer space laboratory. It was demonstrated that under the homogenuous nucleating conditions obtainable in a zero gravity laboratory this laser glass may be easily quenched to a virtually crystal-free product. Experimental evidence is provided that use of this material as a host in a neodymium glass laser would result in more than a 10 percent increase in efficiency when compared to laser glass rods of a similar composition currently commercially available. Differential thermal analysis, thermal gradient oven, X-ray diffraction, and liquidus determination experiments were carried out to determine the basics of the crystallization behavior of the glass, and small-angle X-ray scattering and splat-cooling experiments were performed in order to provide additional evidence for the feasibility of producing this laser glass material, crystal free, in an outer space environment.
Neilson, G. F.↗
Electron detachment from negative ions - The effects of isotopic substitution
Absolute total electron-detachment cross sections and relative elastic-scattering cross sections are presented for collisions of H(-) or D(-) with He, Ne, Ar, and N2 for collision energies ranging from about 2 eV up to 100 eV. Special emphasis has been given to the effect of isotopic substitution. It was found that, with the exception of the helium target, the results cannot be in accord with a model using a localized complex potential. On the other hand, the results for H(-) or D(-) with He are in excellent agreement with predictions based on previous (local complex potential) analysis of differential elastic-scattering measurements.
Champion, R. L.↗
Cryogenic temperature control by means of energy storage materials
An investigation was conducted to study the concept of thermal control by means of physical or chemical reaction heats for applications involving the storage of cryogens during long-term space voyages. The investigation included some preliminary experimental tests of energy storage material (ESM) effectiveness. The materials considered can store and liberate large amounts of thermal energy by means of mechanisms such as sensible heat, heat of fusion, and physical or chemical reaction heat. A differential thermal analysis was utilized in the laboratory tests. Attention is given to the evaluation of cryogenic ESM thermal control concepts, the experimental determination of phase change materials characteristics, and adsorption ESMs. It is found that an ESM shield surrounded by multiple layer insulation provides the best protection for a cryogen store.
Grodzka, P. G.↗
Intumescent coatings based on 4,4 prime-dinitrosulfanilide
Nitroaromatic amine-based intumescent coatings which offer improved thermal protection to a substrate by reducing the backface temperature rise have been developed. The intumescent monomer agent is 4,4 prime-dinitrosulfanilide. This agent has an intumescent temperature of 220 deg C, compared with 300 deg C for the ammonium salt of 1,4-nitroaniline-2-sulfonic acid and offers a twelve-fold reduction in water solubility over this compound. On the basis of differential thermal analysis and screening tests, a chlorinated polyolifin epoxy-reactive butadiene acrylonitrile rubber blend was selected as a flame quenching binder.
Sawko, P. M.↗
Determination of liquid-phase immiscibility in the lead-zinc system
A number of different techniques in the past have yielded inconsistent equilibrium measurements of immiscibility in the Pb-Zn system above 600 C. Accurate differential thermal analysis (DTA) measurements were performed on well-homogenized samples of high-purity Pb-Zn, and they indicate that the immiscibility curve is higher than previously accepted for Zn compositions between 20 and 70 at. %. The maximum deviations observed correspond to about 20 C. Below 600 C the DTA results agree with previous results.
Trahan, J. F.↗
Microfractures produced by a laboratory scale hypervelocity impact into granite
Differential strain analysis and scanning electron microscopy are employed to study the microcracks produced in a granite block by shock waves from a hypervelocity impact. The anisotropy of the pre-shock cracks appears to control the orientations of the microcracks. Over the range 2 to 20 kbar, total crack porosity proves to be linearly related to shock pressure. The effect of the peak shock pressure on the width and median closure pressure of the crack spectra is also investigated. The results of the microcrack study may be useful in interpreting lunar samples.
Siegfried, R. W., II↗
Characteristics of microcracks in lunar samples
Differential strain analysis and petrographic microscopy are discussed, and lunar rock studies which use these techniques are reported. Many cracks are present that were produced by nonshock processes in addition to the abundant shock-induced cracks. The crack spectra of lunar samples differ significantly from the spectra for shocked terrestrial rocks in that the lunar samples have very broad distributions of crack closure pressures while shocked terrestrial rocks have sharply peaked distributions with most cracks closing at pressures below 0.5 kbar. The difference may be attributed to either the effects of multiple shock events or the effects of confinement on the response of the rock to shock.
Simmons, G.↗
Charge and energy spectra of heavy cosmic rays at intermediate energies
The energy spectra and the charge composition of the primary elements C, O, Ne, Mg, and Si have been measured in both the low-energy and high-energy modes of the University of Chicago telescope on board the IMP 8 spacecraft. Combining both modes of analysis yields differential energy spectra for each element from about 50 MeV/nucleon to about 1 GeV/nucleon. The charge ratios with respect to oxygen are found to be energy independent over this interval and are consistent with the results of cosmic-ray propagation and solar-modulation calculations. The relative abundances obtained are in substantial agreement with previous investigations in this energy regime.
Garcia-Munoz, M.↗
Characteristics of microcracks in samples from the drill hole Noerdlingen 1973 in the Ries crater, Germany
Samples from the Noerdlingen 1973 drill core contain abundant shock-induced microfractures which exhibit varying amounts of healing and sealing. Many of the microcracks resemble morphologically the open microcracks present in returned lunar samples. Data derived from petrography, scanning electron microscopy, and differential strain analysis indicate that fewer microcracks were formed at greater depths and crack sealing processes are more effective for cracks associated with planar elements. Although the microcracks in the Ries core are now sealed, they are valid analogues of the open shock-induced cracks of lunar rocks and demonstrate that open cracks do form in rocks at depth during a naturally-occurring shock event. The healing of the shock-induced cracks in the Ries core also precludes their use for laboratory measurements of physical properties intended to be used as analogue measurements of lunar samples in situ.
Padovani, E. R.↗