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At least 163 records · Page 9

A simple soil mass correction for a more accurate determination of soil carbon stock changes

Abstract Agricultural soils can act as a sink for large quantities of soil organic carbon (SOC) but can also be sources of carbon to the atmosphere. The international standard for assessing SOC stock and measuring stock change stipulates fixed depth sampling to at least 30 cm. The tendency of bulk density (BD) to decrease with decreasing disturbance and increasing SOC concentration and the assumption of constant SOC and BD within this depth profile promotes error in the estimates of SOC stock. A hypothetical but realistic change in BD from 1.5 to 1.1 g cm −3 from successive fixed depth sampling to 30 cm underestimates SOC stock change by 17%. Significant effort has been made to evaluate and reduce this fixed depth error by using the equivalent soil mass (ESM) approach, but with limited adoption. We evaluate the error in SOC stock assessment and change generated from fixed depth measurements over time relative to the ESM approach and propose a correction that can be readily adopted under current sampling and analytical methods. Our approach provides a more accurate estimate of SOC stock accumulation or loss that will help incentivize management practice changes that reduce the environmental impacts of agriculture and further legitimize the accounting practices used by the emerging carbon market and organizations that have pledged to reduce their supply chain greenhouse gas (GHG) footprints.

60 APPLIED LIFE SCIENCES↗

Defect suppression in wet-treated etched-and-regrown nonpolar m-plane GaN vertical Schottky diodes: A deep-level optical spectroscopy analysis

In this work, steady-state photocapacitance (SSPC) was conducted on nonpolar m-plane GaN n-type Schottky diodes to evaluate the defects induced by inductively coupled plasma (ICP) dry etching in etched-and-regrown unipolar structures. An ~10× increase in the near-midgap Ec – 1.9 eV level compared to an as-grown material was observed. Defect levels associated with regrowth without an etch were also investigated. The defects in the regrown structure (without an etch) are highly spatially localized to the regrowth interface. Subsequently, by depth profiling an etched-and-regrown sample, we show that the intensities of the defect-related SSPC features associated with dry etching depend strongly on the depth away from the regrowth interface, which is also reported previously. A photoelectrochemical etching (PEC) method and a wet AZ400K treatment are also introduced to reduce the etch-induced deep levels. A significant reduction in the density of deep levels is observed in the sample that was treated with PEC etching after dry etching and prior to regrowth. An ~2× reduction in the density of Ec – 1.9 eV level compared to a reference etched-and-regrown structure was observed upon the application of PEC etching treatment prior to the regrowth. The PEC etching method is promising for reducing defects in selective-area doping for vertical power switching structures with complex geometries.

36 MATERIALS SCIENCE↗

Artificial linear brush abrasion of coatings for photovoltaic module first-surfaces

Natural soiling and the subsequent necessary cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of anti-reflective and/or anti-soiling coatings as well as the method and frequency of operational maintenance (cleaning). Artificial linear brush abrasion using Nylon 6/12 bristles was therefore examined to explore the durability of representative PV first-surfaces, i.e., the surface of a module incident to direct solar radiation. Specimens examined include silane surface functionalized-, roughened (etched)-, porous silica-coated-, fluoropolymer-coated-, and ceramic (TiO 2 or ZrO 2 /SiO 2 /ZrO 2 /SiO 2 )-coated-glass, which are compared to monolithic-poly(methyl methacrylate) and -glass coupons. Characterization methods used in this study include: optical microscopy, ultraviolet–visible–near-infrared (UV-VIS-NIR) spectroscopy, sessile drop goniometry, white-light interferometry, atomic force microscopy (AFM), and depth-profiling X-ray photoelectron spectroscopy (XPS). The corresponding characteristics examined include: surface morphology, transmittance (i.e., optical performance), surface energy (water contact angle), surface roughness, scratch width and depth, and chemical composition, respectively. The study here was performed to determine coating failure modes; identify characterization methods that can detect nascent failures; compare the durability of popular contemporary coating materials; identify their corresponding damage characteristics; and compare slurry and dry-dust abrasion. This study will also aid in developing an abrasion standard for the PV industry.

14 SOLAR ENERGY↗

Deeper snow increases the net soil organic carbon accrual rate in moist acidic tussock tundra: 210Pb evidence from Arctic Alaska

The net change in the carbon inventory of arctic tundra remains uncertain as global warming leads to shifts in arctic water and carbon cycles. To better understand the response of arctic tundra carbon to changes in winter precipitation amount, we investigated soil depth profiles of carbon concentration and radionuclide activities ( 7 Be, 137 Cs, 210 Pb, and 241 Am) in the active layer of a twenty-two-year winter snow depth manipulation experiment in moist acidic tussock tundra at Toolik Lake, Alaska. Depth correlations of cumulative carbon dry mass (g cm -2 ) vs. unsupported 210 Pb activity (mBq g -1 ) were examined using a modified constant rate of supply (CRS) model. Results were best fit by two-slope CRS models indicating an apparent step temporal increase in the accumulation rate of soil organic carbon. Most of the best-fit model chronologies indicated that the increase in carbon accumulation rate apparently began and persisted after snow fence construction in 1994. The inhomogeneous nature of permafrost soils and their relatively low net carbon accumulation rates make it challenging to establish robust chronologic records. Nonetheless, the data obtained in this study support a decadal-scale increase in net soil organic carbon accumulation rate in the active layer of arctic moist acidic tussock tundra under conditions of increased winter precipitation.

54 ENVIRONMENTAL SCIENCES↗

Lagrangian drifter design for the determination of surface currents by remote sensing

In estuaries, the interaction of wind, tidal current, and mixing of fresh and saline water produces a variable depth profile of current, with foam lines and convergence zones between water types. Careful measurement of surface currents via Lagrangian drifters requires a drifter design appropriate to both the depth of current to be measured and the tide and wind conditions of interest. The use of remote sensing to track drifters contributes additional constraints on drifter design. Several designs of biodegradable drifters which emit uranine dye plumes, resolvable in aerial imagery to 1:60,000 scale, were tested for wind drag in field conditions against data from calibrated current meters. A 20 cm-vaned wooden drifter and a window shade drifter set to 1.5 m depth had negligible wind drag in winds to 8 m/sec. Prediction of oil slick trajectories using surface current data and a wind factor should be approached cautiously, as surface current data may be wind-contaminated, while the usual 3.5% wind factor is appropriate only for currents measured at depth.

Gordon, H. H.↗

Evidence for the constancy of the solar cosmic ray flux over the past ten million years - Mn-53 and Al-26 measurements

Mn-53 and Al-26 activities have been measured in fourteen samples carefully ground from the upper 1.5 cm of rock 68815 to discern whether the magnitude and shape of the solar cosmic ray (SCR) flux in the last 2 m.y. has differed from the recent SCR flux and that averaged over the last 10 m.y. Results yield no evidence that the SCR flux has varied among these time intervals. Assuming the appropriate erosion rates, the measured profiles of rock 68815 (with a 2 m.y. surface exposure) and of rocks 12002 and 14321 (saturated with respect to Mn-53 and Al-26) can all be fit with the SCR parameters of R sub zero = 100 MV and J = 70 protons/sq cm/sec (4 pi, energy greater than 10 MeV). The measured profiles of 68815 and 14310 are incompatible with the short surface exposure age (less than 3 m.y.) proposed for 14310 on the basis of track studies. Activity vs. depth profiles for three different faces of 68815, show surface activities nearly independent of sample inclination.

Kohl, C. P.↗

Artificial Linear Brush Abrasion of Coatings for Photovoltaic Module First Surfaces

Natural soiling and the subsequent requisite cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of anti-reflective and/or anti-soiling coatings as well as the method and frequency of operational maintenance (cleaning). Artificial linear brush abrasion using Nylon 6/12 bristles was therefore examined to explore the durability of representative PV first-surfaces, i.e., the surface of a module incident to direct solar radiation. Specimens examined include silane surface functionalized-, roughened (etched)-, porous silica-coated-, fluoropolymer-coated-, and ceramic (TiO2 or ZrO2/SiO2/ZrO2/SiO2)-coated-glass, which are compared to monolithic-poly(methyl methacrylate) and -glass coupons. Characterization methods used in this study include: optical microscopy, ultraviolet-visible-near-infrared (UV-VIS-NIR) spectroscopy, sessile drop goniometry, white-light interferometry, atomic force microscopy (AFM), and depth-profiling X-ray photoelectron spectroscopy (XPS). The corresponding characteristics examined include: surface morphology, transmittance (i.e., optical performance), surface energy (water contact angle), surface roughness, scratch width and depth, and chemical composition, respectively. The study here was performed to determine coating failure modes; identify characterization methods that can detect nascent failures; compare the durability of popular contemporary coating materials; identify their corresponding damage characteristics; and compare slurry and dry-dust abrasion. This study will also aid in developing an abrasion standard for the PV industry.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Solar activity during the past 10,000 years from radionuclides in lunar samples

The radionuclides Ar-37, Ar-39, H-3, and C-14 in lunar samples are related to solar activity during time periods corresponding to their mean lives. The Ar-37 activities at shallow depths vary with each Apollo mission according to the intensities of the large solar flares preceding the mission. At large depths, the Ar-37 activities are independent of solar flares and decrease with an attenuation length that is in accord with the energy spectrum of the galactic cosmic rays. The Ar-39 depth-profile differs somewhat from galactic cosmic-ray expectation; the difference may be caused by solar modulation during Maunder Minima periods. The H-3 and C-14 activities at shallow depths are considerably higher than expected from galactic cosmic rays. The high H-3 is explained by solar-flare interactions during the past 60 years. The high C-14 activities at shallow depths are caused in part by solar-flare interactions during the past 10,000 years and in part by solar-wind implantations. Solar wind-implanted C-14 is indicated by the grain-size and temperature-release dependence of C-14 in surface soil.

Fireman, E. L.↗

Probing antiferromagnetic coupling in magnetic insulator/metal heterostructures

Using depth- and element-resolved characterization, we report insights into antiferromagnetic coupling in Y 3 ⁢Fe 5 ⁢O 12 /permalloy (YIG/Py) and Y 3 ⁢Fe 5 ⁢O 12 /Co (YIG/Co) thin-film heterostructures grown on Si/SiO 2 and Gd 3⁢ Ga 5⁢ O 12 substrates. We build on recent work demonstrating antiferromagnetic coupling in polycrystalline YIG/metallic-ferromagnetic systems by characterizing differences in the structural and magnetic properties which depend on the choice of ferromagnet (Py vs Co), seed layer (with and without Pt), and substrate (Si/SiO 2 vs Gd 3 ⁢Ga 5 ⁢O 12 ). These differences in the sample structure manifest as notable changes in interface coupling sign, magnetic reversal mechanisms, magnetic depth profiles, and domain structure. Through a combination of magnetometry, polarized neutron reflectometry, and x-ray photoemission electron microscopy, a comprehensive picture of the magnetic interactions is realized, with lateral- and depth resolution at submicrometer and nanometer scales, respectively. These results confirm that both Co and Py share a preference to align antiparallel to polycrystalline YIG grown on some substrates (Si/SiO 2 and Si/SiO 2 /Pt), while coupling ferromagnetically with highly oriented YIG on (111) Gd 3⁢ Ga 5 ⁢O 12 and (110) Gd 3 ⁢Ga 5⁢ O 12 /Pt substrates. The complex interplay among magnetic interactions at the YIG/ferromagnetic interface has important implications for spintronic and magnonic devices based on this platform.

Exchange interaction↗

International Space Station External Contamination Status

PResentation slides examine external contamination requirements; International Space Station (ISS) external contamination sources; ISS external contamination sensitive surfaces; external contamination control; external contamination control for pre-launch verification; flight experiments and observations; the Space Shuttle Orbiter waste water dump, materials outgassing, active vacuum vents; example of molecular column density profile, modeling and analysis tools; sources of outgassing induced contamination analyzed to date, quiescent sources, observations on optical degradation due to induced external contamination in LEO; examples of typical contaminant and depth profiles; and status of the ISS system, material outgassing, thruster plumes, and optical degradation.

Mikatarian, Ron↗

SPRUCE Peat Mercury, Methylmercury and Sulfur Concentrations from Experimental Plot Cores, 2012

This data set reports the results of analyses of peat core samples for total mercury and methylmercury, as well as carbon, nitrogen and sulfur. Samples were collected as part of a larger sampling campaign from the SPRUCE experimental study plots located in the S1-Bog. From 2012-08-13 to 2012-10-15, a team of SPRUCE investigators and collaborators collected core samples of peat in the SPRUCE experimental plots. The goal was to characterize the biological, physical, and chemical characteristics of peat, and how those characteristics changed throughout the depth profile of the bog, prior to the initialization of the SPRUCE experimental warming and CO2 treatments. Cores were collected from 16 experimental plots; peat cores were collected from the hummock and hollow surfaces to depths of 300 cm in 10 cm, 25, and 50 cm increments (Pierce et al, 2022). Three replicate cores were collected from both hummock and hollow locations in each plot. The coring locations within each plot were mapped. This dataset contains one file in comma separated (*.csv) format. User Note: The coring descriptions and some reported data are the same as in the related data set, Iverson et al. (2014). Samples for mercury and carbon, nitrogen and sulfur analyses by the University of Minnesota were collected as part of this sampling campaign.

54 ENVIRONMENTAL SCIENCES↗

Hydrological and Thermal Dynamics of a Supra‐Permafrost Subterranean Estuary

Subterranean estuaries (STEs), where groundwater interacts with seawater, influence surface and subsurface coastal ecology and biogeochemistry. In Arctic-STEs overlying permafrost, groundwater flow and heat transport determine the fate of organic matter. Yet, direct observations of groundwater flow and heat and solute transport processes in Arctic STEs remain limited. This study characterized groundwater flow paths and fluxes and heat transport within an Arctic-STE along Alaska's Beaufort Sea coast during thawing, summer, and freeze-up. Intertidal seabed temperature-depth profiles collected along a 10-m transect captured the active groundwater flow period, from thaw and flow onset in mid-June to freeze-up in late-September. During this period, aquifer geometry evolved non-uniformly due to spatially varying thaw rates across the STE (mean (m) thaw depths–beach: 0.25 to 0.55–0.6 m on 20 June, 25 July, 1 October; seabed: 0.6–0.9 m from 25 July to 1 October). Groundwater and surface water levels, salinity, and subsurface temperature profiles measured over tidal time scales were interpreted alongside groundwater flow-heat transport numerical simulations. Fresh groundwater discharge was sporadic during thawing (m: 0.32 m 3 /day/m), abundant in summer (m: 0.45 m 3 /day/m), and was largely absent during freeze-up. During freeze-up, groundwater flow was driven exclusively by seawater recirculation via tidal pumping (from thawing to summer to freeze-up: 0.00025–0.15–0.5 m3/day/m) and convection. Heat advection dominated near aquatic interfaces (shaping intertidal ice), and conduction controlled vertical temperature gradients in low-flow and unsaturated sediments. These findings will help predict how prolonged summers will alter Arctic-STE cryo-hydrology and biogeochemistry.

54 ENVIRONMENTAL SCIENCES↗

Consequences of a chromospheric temperature gradient on the width of H Alpha in late-type giants

An analytic expression for the integrated H alpha optical depth profile is derived for a one dimensional slab geometry model chromosphere, with electron temperature increasing as a power law with height. The formula predicts H alpha opacity and profile width to be sensitive functions of the thermal gradient. Application of the model to observation reveals that broad H alpha absorption widths in G and K giant stars are consistent with a mean H alpha chromospheric optical depth of 50, while narrower widths in M stars indicate slightly lower opacities. It is proposed that differences in H alpha width between late-type giants of similar spectral type may be due, in part, to differences in their chromospheric thermal gradient, and associated H alpha opacity.

Zarro, D. M.↗

Consequences of a chromospheric temperature gradient on the width of H-alpha in late-type giants

An analytic expression for the integrated H alpha optical depth profile is derived for a one dimensional slab geometry model chromosphere, with electron temperature increasing as a power law with height. The formula predicts H alpha opacity and profile width to be sensitive functions of the thermal gradient. Application of the model to observation reveals that broad H alpha absorption widths in G and K giant stars are consistent with a mean H alpha chromospheric optical depth of 50, while narrower widths in M stars indicate slightly lower opacities. It is proposed that differences in H alpha width between late-type giants of similar spectral type may be due, in part, to differences in their chromospheric thermal gradient, and associated H alpha opacity.

Zarro, D. M.↗

Chemical Interplay of Silicon and Graphite in a Composite Electrode in SEI Formation

In this study, we investigated the effect of the Si/graphite weight ratio in half-cells on the solid electrolyte interphase (SEI) layer's chemistry. The nominal concentrations of active materials were (wt % Si/wt % Gr) 15/73, 30/58, 60/28, and 80/0. The electrolyte in the cells consisted of either 1.2 M LiPF 6 in ethylene carbonate/ethyl methyl carbonate (3:7 by wt) or 1.2 M LiPF 6 in ethylene carbonate:ethyl methyl carbonate (3:7 by wt) + 10 wt % fluoroethylene carbonate. These coin cells were cycled five times at the C/10 rate. As expected, the addition of silicon to the electrode significantly increased the measured capacity. Examination of the aged composite material showed that the electrolyte influenced the concentration of chemical environments on the surface. Depth profiling revealed that these concentrations of surface environments changed with sputtering time. A statistics-of-mixtures model was used to deconvolute how silicon and graphite interacted during the formation of these species and how the interaction changed with depth.

25 ENERGY STORAGE↗

Lunar regolith dynamics based on analysis of the cosmogenic radionuclides Na-22, Al-26, and Mn-53

Depth profiles of Na-22 and Al-26 in the upper portions of five lunar cores are analyzed. From the analyses, it is concluded that the natural gardening processes on the lunar surface result in mixing of the regolith to a depth of 2-3 cm over a time period which is short compared with the half-life of Al-26 (0.73 m.y.). It is also concluded that the rotary drill processes which were used to obtain the deep drill samples generally resulted in loss and/or mixing of the upper portions of the cores. In contrast, the near-surface regions of the drive tube cores appear to have a well-preserved stratigraphy. Analysis of Mn-53 in samples of six lunar rocks helps substantiate the accuracy of age date estimates by other means, and provides definite information that the total lunar surface exposure of two of these rocks has occurred during a single surface event which continued to their collection.

Fruchter, J. S.↗

Metal fluxes at the sediment–water interface in a free water surface constructed wetland

Metal biogeochemistry in the sediment, water, and the sediment–water interface (SWI) was studied in a free water surface constructed wetland. Concentrations of labile copper (Cu), zinc (Zn), sulfate, chloride, and dissolved organic carbon (DOC) were measured with the diffusive gradients in thin film (DGT) and peeper. A good agreement between peeper- and DGT-measured metals was observed for Cu (regression r 2 = 0.3, 95% CI of the slopes > 0), but not for Zn (95% CI of the slopes overlapped with 0), which was attributed to the different complexed compounds between Cu and Zn in porewater. The depth profile of labile metals in sediment porewater varied with time and was consistent with the solid-phase metal deposition, showing higher concentrations in the surface layer (3 to –3 cm) than in the bottom layer (–4 to –13 cm). The depth-averaged labile Cu and Zn concentrations measured by DGT were 1.0 and 3.1 µg/L, and labile sulfate, chloride, and DOC concentrations measured by peeper were 1.8, 3.6, and 2.1 mg/L, respectively. A sharp decrease in sulfate occurred in September when sulfate concentrations became the lowest among sampling months. This was caused by the seasonal sulfur cycles in the wetland, where the dominant sulfur reaction is sulfate reduction in warm seasons and sulfide oxidation in cold seasons. Different metal-removal mechanisms were observed in the two wetland cells; sulfur dynamics controlled the removal processes in the cell without frequent disturbance but failed to influence metal removal in the cell with frequent disturbance due to the interruption of anoxic layers. The flux ratios that compare labile element concentrations between the water column and the SWI (R-Cu, R-Zn, R-DOC, R-sulfate, and R-chloride) were generated to determine metal diffusive fluxes at the interface. Labile Zn was mostly transported from the water to the SWI during all seasons (R-Zn < 1 for all months except January). Labile Cu moved from the SWI to the water during the warm months (R-Cu < 1), which was explained by the bioturbation-induced transport of organic matter based on the positive correlations between R-Cu and R-DOC. In general, sediment can serve either as a sink or a source depending on the environmental conditions, metal speciation, and presence of living organisms. Here, metal flux at the SWI is a key component in the biogeochemical cycling of a constructed wetland.

54 ENVIRONMENTAL SCIENCES↗

Closed-ampoule diffusion of sulfur into Cd-doped InP substrates - Dependence of S profiles on diffusion temperature and time

In order to optimize the fabrication of n(+)-p InP solar cells made by closed-ampoule diffusion of sulfur into p-InP:Cd substrates, we have investigated the influence of diffusion conditions on sulfur diffusion profiles. We show that S diffusion in InP is dominated by the P vacancy mechanism and is not characterized by a complementary error function as expected for an infinite source diffusion. The S diffusion mechanism in p-InP is qualitatively explained by examining the depth profiles of S, P, and In in the emitter layer and by taking into account the presence and composition of different compounds found to form in the In-P-S-O-Cd system as a result of diffusion.

Faur, Mircea↗