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At least 163 records · Page 9

Formation and photochemistry of methylamine in Jupiter's atmosphere

In the upper troposphere and lower stratosphere of Jupiter, translationally hot H atoms are produced in the photolysis of ammonia, phospine, and acetylene which react with methane to form methyl radicals. The latter combine with NH2 to form methylamine. It is presently shown that the combined production of methylamine and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. The recommendation of NH2 and C2H3 radicals to yield C2H5N, followed by photolysis to HCN, is the preferred path. An upper limit column density on CH3PH2 is estimated to be about 10 to the 13th/sq cm, as compared to 10 to the 15th/sq cm for CH3NH2.

Kaye, J. A.↗

The construction of a highly transportable laser ranging station

The technology of the transportable Laser Ranging Station (TLRS) used in crustal dynamics studies was examined. The TLRS used a single photoelectron beam of limited energy density returned from the Laser Geodynamic Satellite (LAGEOS). Calibration was accomplished by the diversion of a small portion of the outgoing beam attenuated to the same level as the satellite return. Timing for the system was based on a self calibrating Ortec TD811, 100 picosec time interval device. The system was contained in a modified, single chassis recreational vehicle that allowed rapid deployment. The TLRS system was only airmobile on the largest transport aircraft. A 30 cm simple plano/concave transfer lens telescope aided in beam direction. The TLRS system fulfills the need for an accurate method of obtaining range measurements to the LAGEOS satellite incorporated in a mobile, air transportable, and economical configuration.

Source record↗

Desired characteristics of catalogs for cometary astrometry

Reference star catalogs for cometary astrometry have to provide an all-sky coverage with suitable stellar density and limiting magnitude on a fundamental coordinate system. A general catalog meeting all these requirements will not be available for a foreseen timescale. The suitability of various existing catalogs for cometary astrometry is discussed.

Devegt, C.↗

Simultaneous dual-wavelength VLBI observations of the compact radio source near the Galactic center

Preliminary results from simultaneous VLBI observations at 3.6 and 13 cm confirm that, in this wavelength range, the size of the compact radio source near the Galactic center varies as lambda-squared, where lambda is the wavelength of observation. These results also establish a flux density upper limit at 3.6 cm of 5 mJy for any source in Sgr A West smaller than 8 mas (80 AU).

Marcaide, J. M.↗

Spectrophotometry of six broad absorption line QSOs

Spectrophotometric observations of six broad absorption-line QSOs (BALQSOs) are presented. The continua and emission lines are compared with those in the spectra of QSOs without BALs. A statistically significant difference is found in the emission-line intensity ratio for (N V 1240-A)/(C IV 1549-A). The median value of (N V)/(C IV) for the BALQSOs is two to three times the median for QSOs without BALs. The absorption features of the BALQSOs are described, and the column densities and limits on the ionization structure of the BAL region are discussed. If the dominant ionization mechanism is photoionization, then it is likely that either the ionizing spectrum is steep or the abundances are considerably different from solar. Collisional ionization may be a significant factor, but it cannot totally dominate the ionization rate.

Junkkarinen, Vesa T.↗

Discovery of radio emission from AE Aquarii

VLA 1.4-GHz and 4.9-GHz observations of six DQ Her cataclysmic variables, obtained in the C/D hybrid configuration with 50-MHz bandwidth, 7-sec time resolution, and limiting flux density about 200 microJy on July 21, 1984, are reported. Variable radio emission with time scale less than 5 min, circular polarization less than 15 percent, and flux density 3-5 mJy at 1.4 GHz and 8-16 mJy at 4.9 GHz is detected from AE Aqr. This emission is tentatively attributed to synchrotron emission from mildly relativistic electrons, powered by the MHD torque coupling the magnetic white dwarf to either (1) a secondary with a strong magnetic field or (2) an accretion disk.

Bookbinder, J. A.↗

Polymer solution phase separation: Microgravity simulation

In many multicomponent systems, a transition from a single phase of uniform composition to a multiphase state with separated regions of different composition can be induced by changes in temperature and shear. The density difference between the phase and thermal and/or shear gradients within the system results in buoyancy driven convection. These differences affect kinetics of the phase separation if the system has a sufficiently low viscosity. This investigation presents more preliminary developments of a theoretical model in order to describe effects of the buoyancy driven convection in phase separation kinetics. Polymer solutions were employed as model systems because of the ease with which density differences can be systematically varied and because of the importance of phase separation in the processing and properties of polymeric materials. The results indicate that the kinetics of the phase separation can be performed viscometrically using laser light scattering as a principle means of following the process quantitatively. Isopycnic polymer solutions were used to determine the viscosity and density difference limits for polymer phase separation.

Cerny, Lawrence C.↗

Abundances of hydrogen sulfide in star-forming regions

Interstellar H2S and its isotopic variant H2(S-34) have been observed toward several star-forming regions via their 1(10)-1(01) transitions at 2 mm, using the FCRAO telescope. In sources where both isotopic species were observed, column densities of about 10 to the 16th/sq cm were measured. Column density lower limits of about 10 to the 14th/sq cm for H2S were found for other sources, where only the main isotopic line was observed. The fractional abundances of H2S relative to molecular hydrogen appear to be enhanced by at least an order of magnitude relative to quiescent cloud values (about 10 to the -9th) for many of the observed sources.

Minh, Y. C.↗

A lower limit of the cosmic mean density from the ages of clusters of galaxies

The presence of substructure in clusters of galaxies indicates that they have recently formed or accreted a significant fraction of their mass. The cosmic time at which this occurs is set in large part by the density of that region of space at very large redshift. If the distribution of density perturbations at high redshift is Gaussian, then the frequency of subclustering now is set by the mean density at recombination. Thus, the observed frequency of subclustering can be used to constrain. Surprisingly, plausible values of Lambda have little effect on this result. Unless three independent evaluations of the incidence of subclustering are all overestimates, or substructure lasts significantly longer than a crossing time in clusters, or perturbations at high redshift are not Gaussian, the universe is fairly dense (Omega sub 0 greater than about 0.5). The same line of argument suggests that direct observations (e.g., with Rosat) of evolution of the cluster population with shifts will provide a complementary direct measure of Omega sub 0.

Richstone, D.↗

High velocity clouds in nearby disk galaxies

Clouds of neutral hydrogen in our galaxy with the absolute value of v greater than 100 km/s cover approximately 10 percent of the sky to a limiting column density of 1 x 10(exp 18) cm(exp -2). These high velocity clouds (HVCs) may dominate the kinetic energy of neutral hydrogen in non-circular motion, and are an important though poorly understood component of galactic gas. It has been suggested that the HVCs can be reproduced by a combination of three phenomena: a galactic fountain driven by disk supernovae which would account for most of the HVCs, material tidally torn from the Magellanic Clouds, and an outer arm complex which is associated with the large scale structure of the warped galactic disk. We sought to detect HVCs in external galaxies in order to test the galactic fountain model.

Schulman, Eric↗

On the use of the noncentral chi-square density function for the distribution of helicopter spectral estimates

A probability density function for the variability of ensemble averaged spectral estimates from helicopter acoustic signals in Gaussian background noise was evaluated. Numerical methods for calculating the density function and for determining confidence limits were explored. Density functions were predicted for both synthesized and experimental data and compared with observed spectral estimate variability.

Garber, Donald P.↗

Software quality: Process or people

This paper will present data related to software development processes and personnel involvement from the perspective of software quality assurance. We examine eight years of data collected from six projects. Data collected varied by project but usually included defect and fault density with limited use of code metrics, schedule adherence, and budget growth information. The data are a blend of AFSCP 800-14 and suggested productivity measures in Software Metrics: A Practioner's Guide to Improved Product Development. A software quality assurance database tool, SQUID, was used to store and tabulate the data.

Palmer, Regina↗

Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF

Three new rotational transitions of aluminum fluoride (AlF) at 0.8 and 1.2 mm have been observed. The J = 10-9, J = 8-7, and J = 7-6 lines of AlF at 230, 263, and 329 GHz, respectively, were seen toward IRC +10216 using the Caltech Submillimter Observatory (CSO). Combined with the earlier data obtained for this species at IRAM at 2 and 3 mm, these measurements confirm the presence of the metal halide in this carbon-rich circumstellar shell. Analysis of the CSO and IRAM data suggests that AlF arises from a source with a diameter of theta(sub s) approximately = 5-10 sec and hence is present chiefly in the inner envelope of IRC +10216. In this region, the molecule has a column density of (0.3-1.1) x 10(exp 15)/sq cm, which indicates a fractional abundance of at least approximately 10(exp -9), relative to H2. Searches for the metal fluoride species CaF and MgF have also been conducted toward IRC +10216, but with negative results. The column density upper limits for MgF and CaF are N(sub tot) less than (1-4) x 10(exp 14)/sq cm. Relative abundances of these metal fluoride molecules can be understood in terms of chemical thermodynamic equilibrium. The presence of AlF in IRC +10216 also indicates that large quantities of fluorine must be present in the inner stellar envelope, suggesting that this element may be produced not primarily in explosive nucleosynthesis but rather in helium shell flashes, as indicated also by HF spectroscopy of red giant stars.

Ziurys, L. M.↗

Comparison of the NASCAP/GEO, POLAR, SEE Charging Handbook, and NASCAP-2K.1 Spacecraft Charging Codes

The NASA Charging Analyzer Program (NASCAP) spacecraft charging software developed by Maxwell Technologies has been widely used for the past fifteen to twenty years in satellite design and investigation of spacecraft charging related anomalies. Individual versions of the NASCAP software are available for use in low inclination, low Earth orbit environments (NASCAP[LEO) and geostationary orbit environments (NASCAP/GEO). In addition, the Potentials of Large objects in the Auroral Region (POLAR) code is available for use in LEO polar orbit environments. NASCAP/GEO and POLAR were both written in the 1980's using algorithms appropriate for the computers of the time. They solve the Poisson-Vlasov system for currents and densities assuming limited speed and memory of computer systems standard for the day. In addition, use of the charging models requires individual input files that are not readily transported into the various codes to facilitate comparison of results by the user.

Neergaard, Linda E.↗

A search for HCCN in molecular clouds

We have conducted a deep search for HCCN towards the dark cloud TMC-l and several GMC's via its N(J) = 1(2)-->0(1) transition. HCCN was not detected in any of these sources. Towards TMC-l, assuming optically thin emission, the total column density upper limit is NHCCN < or = 2 x 10(12) cm-2, which corresponds to a fractional abundance upper limit with respect to molecular hydrogen of fHCCN < or = 2 x 10(-10). We find the abundance ratio of HCN:HCCN:HCCCN in TMC-l to be l : <0.01 : 0.3, which suggests that carbon-chain growth by the addition of single carbon atoms may not be efficient under dark cloud conditions. The HCCN abundance limit also places constraints on the branching ratio for the products of the dissociative electron recombination H3C2N+ + e.

Non-NASA Center↗

Prominence and Cool Loop Energetics Measured in the UV, EUV, and H-alpha

We investigate the thermal and dynamic properties of moving features in a prominence jet, a approx. 10(exp 5)K loop near a prominence channel, and an erupting prominence. In order to make measurements of the quickly moving features seen in prominences in the UV we use the SOHO/SUMER spectrograph to take a time series of exposures from a single pointing position, providing a measurement of spectral line properties as a function of time and position along the slit. The lines observed cover a broad range of temperatures from 80,000 - 1.6 million K. These measurements are combined with TRACE movies in transition region and coronal temperature bands and with ground based H-alpha data to obtain more complete information concerning prominence structure and motions. The resulting observations allow us perform DEM analysis and to calculate limits on densities, pressures, and the thermal and kinetic energies of the moving sources.

Kucera, Therese A.↗

Use of Ionic Liquids in Rod-Coil Block Copolyimides for Improved Lithium Ion Conduction

Solvent-free, solid polymer electrolytes (SPE) have the potential to improve safety, increase design flexibility and enhance performance of rechargeable lithium batteries. Solution based electrolytes are flammable and typically incompatible with lithium metal anodes, limiting energy density. We have previously demonstrated use of polyimide rod coil block copolymers doped with lithium salts as electrolytes for lithium polymer batteries. The polyimide rod blocks provide dimensional stability while the polyethylene oxide (PEO) coil portions conduct ions. Phase separation of the rods and coils in these highly branched polymers provide channels with an order of magnitude improvement in lithium conduction over polyethylene oxide itself at room temperature. In addition, the polymers have been demonstrated in coin cells to be compatible with lithium metal. For practical use at room temperature and below, however, at least an order of magnitude improvement in ion conduction is still required. The addition of nonvolatile, room temperature ionic liquids has been shown to improve the ionic conductivity of high molecular weight PEO. Herein we describe use of these molten salts to improve ionic conductivity in the rod-coil block copolymers.

Meador, Mary Ann B.↗

Low-temperature thermionic emitter

An improved photodelineatable cathode material is disclosed comprising a combination of triple carbonate (TC) and a hydrocarbon polymeric photoresist PR. A mixture of TC powder and PR is applied to a cathode by spraying, spinning or dipping and is then subjected to activation at a temperature from about 800.degree. C up to the melting temperature. The cathodes can be activated at a temperature as low as 800.degree. C and still deliver a 0-field, temperature-limited current density of 750 milliamperes per sq. centimeter at 600.degree. C. If a pattern is desired, the coating is exposed through a suitable mask to actinic light to harden the photoresist in the desired areas. Following exposure, the exposed image areas are developed and the unexposed portions of the coating are removed with solvent. When dry, the cathode is ready for activation.

Remington, Richard W.↗