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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Arctic soil patterns analogous to fluid instabilities

Significance Slow-moving arctic soils form patterns resembling those found in common fluids, such as paint and cake icing drips. Inspired by fluid instabilities, we develop a conceptual model for soil patterns and use mathematical analysis to predict their wavelength. In particular, we propose that soil patterns arise due to competition between gravity and cohesion or the “stickiness” of soil grains. We compare our theoretical predictions with a dataset of soil features from Norway, finding that soil patterns are controlled by fluid-like properties as well as climate. Our work provides a physical explanation for a common pattern on both Earth and Mars, with implications for our understanding of landscapes and complex materials composed of both granular and fluid components.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Vegetation heterogeneity reflects soil thermal state and surface soil displacement in a thawing permafrost landscape

Thawing permafrost has the potential to dramatically alter the physical and ecological structure of northern landscapes. Warming of the Arctic and subsequent degradation of permafrost have created a need to assess the stability and movement of soils on hillslopes and the potential impacts on ecosystem structure. In this work, we explore the relationships among vegetation heterogeneity, soil temperature, and soil surface displacements observed from 2019 to 2022 in a watershed in the discontinuous permafrost region on the Seward Peninsula of Alaska. Vegetation heterogeneity was measured as the standard deviation (SD) of the normalized difference vegetation index (NDVI) from 3 m PlanetScope satellite imagery around each soil temperature and active layer thickness observation. Locations of observations were clustered into three soil thermal groups, warm, intermediate, and cold, based on soil temperature and active layer thickness. Average annual horizontal surface displacements were significantly lower for soils within the warm thermal group (median = 0.033 m yr −1 ) compared to soils within the cold thermal group (median = 0.090 m yr −1 ; p < 0.001). Conversely, vegetation heterogeneity was significantly higher in the warm (median = 0.014 SD NDVI; p = 0.002) and intermediate (median = 0.015 SD NDVI; p = 0.002) groups compared with the cold thermal group (median = 0.012 SD NDVI), suggesting a warming-induced shift in vegetation community complexity. Because of the observed associations of ground surface displacement rates and vegetation heterogeneity with soil thermal state, we hypothesize that warming soil conditions induce changes in the rates and patterns of hillslope erosion due to an increase in surface movement as near-surface permafrost thaws, followed by a decrease as the permafrost table deepens and excess ice content diminishes. The transition to warm soils promotes surface ecosystem transformation, shifting the dominant vegetation at the site, given the warming climatic conditions of the region. We integrated our observations of soil temperature, vegetation heterogeneity, and soil surface displacements into a conceptual model that describes the co-evolution of hillslopes and vegetation in warming permafrost environments, which is currently unrepresented in earth system models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

The microbial rare biosphere: current concepts, methods and ecological principles

ABSTRACT Our ability to describe the highly diverse pool of low abundance populations present in natural microbial communities is increasing at an unprecedented pace. Yet we currently lack an integrative view of the key taxa, functions and metabolic activity which make-up this communal pool, usually referred to as the ‘rare biosphere’, across the domains of life. In this context, this review examines the microbial rare biosphere in its broader sense, providing an historical perspective on representative studies which enabled to bridge the concept from macroecology to microbial ecology. It then addresses our current knowledge of the prokaryotic rare biosphere, and covers emerging insights into the ecology, taxonomy and evolution of low abundance microeukaryotic, viral and host-associated communities. We also review recent methodological advances and provide a synthetic overview on how the rare biosphere fits into different conceptual models used to explain microbial community assembly mechanisms, composition and function.

Pascoal, Francisco↗
DOE OSTI2020

Microbial macroecology: In search of mechanisms governing microbial biogeographic patterns

Abstract Introduction Rapidly advancing technologies and accumulating information about microbial communities across the globe allow the quantification of microbial properties and functions at a macro‐scale. These emerging microbial biogeographic patterns call for a practical macroecological approach to investigate their underlying mechanisms. Aims The primary aims of this paper are to review the advancements of microbial macroecology in seeking mechanisms governing microbial biogeographic patterns, and to further lay out a roadmap for microbial macroecology in 10 years. Methods We reviewed the progress of microbial macroecology and demonstrated the application of the microbial macroecological approach to microbial biogeographic patterns with three case studies. Results Microbial macroecology provides a platform for understanding microbial abundance, community structure, and functioning across space, time, and taxonomic hierarchy. It emphasizes the integral effects of environmental filtering, microbial responses, diversification, dispersal, and local extinction that drive the microbial biogeographic patterns. The microbial macroecological approach emphasizes the last two stages of the four‐stage scientific method applied to microbial ecology: (a) describing microbial traits across scales to reveal patterns, (b) mathematically representing these patterns, (c) developing and testing conceptual models to build a mechanistic understanding of these patterns from a macroecological perspective, (d) plugging the new knowledge into the theoretical advancements. Three case studies were used to demonstrate the microbial macroecological approach for understanding the global patterns of microbial biomass carbon, microbial composition (fungi : bacteria ratio), and microbial carbon use efficiency. Conclusions Microbial macroecology offers a platform for understanding the mechanisms that drive biogeographic patterns of microbial abundance, diversity and functions. It is likely that these patterns and mechanisms will be increasingly incorporated into predictive models that link climate, carbon dynamics, and biogeochemical processes. A roadmap is outlined for the growing microbial macroecology field; we expect significant progress will be made in five research directions over the next 10 years.

Xu, Xiaofeng↗
DOE OSTI2023

Desorption and Co–Dissolution of Uranium–Bearing Solids During Alkalinity–Enhanced Flushing of Contaminated Sediments

Elevated uranium concentrations in groundwater remain a persistent challenge at contaminated sites. Several sites rely on natural flushing of uranium as a remediation strategy. Uncertainties in conceptual models can cause remediation strategies to underestimate timeframes required to reach remediation goals. In this study, laboratory experiments were conducted to investigate uranium flushing of sediments from a site with persistent groundwater contamination. Six columns were used to simulate alkalinity-enhanced flushing of uranium from sediments, by switching influent alkalinity after ~12 pore volumes. About 20% to 31% of sediment uranium was consistently flushed from the sediments. K d values varied greatly (5.3 to 117 L/kg) but were consistently lower (20% to 50%) during influents with elevated alkalinity. The mass of uranium recovered from the columns also was consistently higher (5% to 80%) during alkalinity-enhanced flushing periods. However, column experiments with sequentially increasing alkalinity showed diminishing returns in uranium elution at higher carbonate concentrations. The loss of flushing efficiency is attributed to significant calcite precipitation at higher alkalinities. Furthermore, the results show that alkalinity-enhanced flushing of uranium could be employed as a viable remediation scheme if calcite precipitation could be minimized in a field application.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Mortality predispositions of conifers across Western USA

Conifer mortality rates are increasing in North America, but the physiological mechanisms underlying this trend are still not well understood. We examined tree-ring based growth rates, stable carbon and oxygen isotope ratios (d13C and d18O, respectively) of dying and surviving conifers at eight old-growth forest sites across a strong moisture gradient in the western USA to retrospectively investigate mortality predispositions. Compared to surviving trees, lower growth of dying trees was detected at least one decade prior to mortality at seven of the eight sites. Intrinsic water-use efficiency (iWUE) increased over time in both surviving and dying trees, with a weaker increase in dying trees at five of the eight sites. The relationship between iWUE and d18O was much stronger and steeper for surviving trees, suggesting an important hydraulic role in mortality. Carbon starvation was a strong correlate of conifer mortality based on a conceptual model incorporating growth, d13C, and d18O. Our results provide a direct link of mortality to growth constraints in western USA conifers.

Wang, Wenzhi↗
DOE OSTI2020

Genome-Resolved Metagenomics and Detailed Geochemical Speciation Analyses Yield New Insights into Microbial Mercury Cycling in Geothermal Springs

Geothermal systems emit substantial amounts of aqueous, gaseous, and methylated mercury, but little is known about microbial influences on mercury speciation. Here, we report results from genome-resolved metagenomics and mercury speciation analysis of acidic warm springs in the Ngawha Geothermal Field (< 55°C, pH < 4.5), Northland Region, Aotearoa New Zealand. Our aim was to identify the microorganisms genetically equipped for mercury methylation, demethylation, or Hg(II) reduction to volatile Hg(0) in these springs. Dissolved total and methylated mercury concentrations in two adjacent springs with different mercury speciation ranked among the highest reported from natural sources (250 to 16,000 ng liter -1 and 0.5 to 13.9 ng liter -1 , respectively). Total solid mercury concentrations in spring sediments ranged from 1,274 to 7,000 μg g -1 . In the context of such ultrahigh mercury levels, the geothermal microbiome was unexpectedly diverse and dominated by acidophilic and mesophilic sulfur- and iron-cycling bacteria, mercury- and arsenic-resistant bacteria, and thermophilic and acidophilic archaea. By integrating microbiome structure and metagenomic potential with geochemical constraints, we constructed a conceptual model for biogeochemical mercury cycling in geothermal springs. The model includes abiotic and biotic controls on mercury speciation and illustrates how geothermal mercury cycling may couple to microbial community dynamics and sulfur and iron biogeochemistry.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Genome-Resolved Metaproteomics Decodes the Microbial and Viral Contributions to Coupled Carbon and Nitrogen Cycling in River Sediments

Rivers have a significant role in global carbon and nitrogen cycles, serving as a nexus for nutrient transport between terrestrial and marine ecosystems. Although rivers have a small global surface area, they contribute substantially to worldwide greenhouse gas emissions through microbially mediated processes within the river hyporheic zone. Despite this importance, research linking microbial and viral communities to specific biogeochemical reactions is still nascent in these sediment environments. To survey the metabolic potential and gene expression underpinning carbon and nitrogen biogeochemical cycling in river sediments, we collected an integrated data set of 33 metagenomes, metaproteomes, and paired metabolomes. We reconstructed over 500 microbial metagenome-assembled genomes (MAGs), which we dereplicated into 55 unique, nearly complete medium- and high-quality MAGs spanning 12 bacterial and archaeal phyla. We also reconstructed 2,482 viral genomic contigs, which were dereplicated into 111 viral MAGs (vMAGs) of >10 kb in size. As a result of integrating gene expression data with geochemical and metabolite data, we created a conceptual model that uncovered new roles for microorganisms in organic matter decomposition, carbon sequestration, nitrogen mineralization, nitrification, and denitrification. We show how these metabolic pathways, integrated through shared resource pools of ammonium, carbon dioxide, and inorganic nitrogen, could ultimately contribute to carbon dioxide and nitrous oxide fluxes from hyporheic sediments. Further, by linking viral MAGs to these active microbial hosts, we provide some of the first insights into viral modulation of river sediment carbon and nitrogen cycling.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Hydrologic windows into the crystalline basement and their controls on groundwater flow patterns across the Paradox Basin, western USA

Conceptual models of sedimentary basin groundwater flow systems typically assume that the crystalline basement acts as an impermeable boundary and can be neglected. In this study, we use hydrologic models constrained by isotopic and geochemical datasets to argue that the La Sal Mountains, Utah, USA, act as a hydrologic window into the Paradox Basin’s lower aquifer system and underlying crystalline basement. We conducted a sensitivity study in which we varied crystalline basement/laccolith permeability as well as fault zone connectivity along a cross-sectional transect from the La Sal Mountains to Lisbon Valley. When the crystalline basement/laccolith units are set at relatively permeable levels (10–14 m 2 ), simulated tracers that include total dissolved solids, oxygen isotopic composition of pore fluids (δ 18 O), and groundwater residence times are in closest agreement with field measurements. Model results indicate that pore fluids in the basal aquifer system underlying the Paradox Formation confining unit are a mixture of relatively young meteoric fluids and older Paradox Formation brines. The presence of faults did not significantly modify fluid exchange between the upper and lower aquifer systems. This was due, in part, to underpressuring within the Paradox Formation. Our study concludes that the Paradox Basin represents a regional recharge area for the Colorado Plateau, with groundwater discharge occurring along the Colorado River within the Grand Canyon some 375 km away to the southwest. This is only possible with a permeable crystalline basement. Our findings help explain the genesis of Mississippi Valley-type ore deposits of the US Midcontinent, where the presence of a permeable basement may be useful in addressing issues related to solute mass and energy balance.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Thermal chains and entrainment in cumulus updrafts, Part 2: Analysis of idealized simulations

Research has suggested that the structure of deep convection often consists of a series of rising thermals, or “thermal chain”, which contrasts with existing conceptual models that are used to construct cumulus parameterizations. In this work, simplified theoretical expressions for updraft properties obtained in Part 1 of this study are used to develop a hypothesis explaining why this structure occurs. In this hypothesis, cumulus updraft structure is strongly influenced by organized entrainment below the updraft’s vertical velocity maximum. In a dry environment, this enhanced entrainment can locally reduce condensation rates and increase evaporation, thus eroding buoyancy. For moderate-to-large initial cloud radius R, this breaks up the updraft into a succession of discrete pulses of rising motion (i.e., a thermal chain). For small R, this leads to the structure of a single, isolated rising thermal. In contrast, moist environments are hypothesized to favor plume-like updrafts for moderate-to-large R. In a series of axisymmetric numerical cloud simulations, R and environmental relative humidity (RH) are systematically varied to test this hypothesis. Vertical profiles of fractional entrainment rate, passive tracer concentration, buoyancy, and vertical velocity from these runs agree well with vertical profiles calculated from the theoretical expressions in Part 1. Analysis of the simulations supports the hypothesized dependency of updraft structure on R and RH, that is, whether it consists of an isolated thermal, a thermal chain, or a plume, and the role of organized entrainment in driving this dependency. Additional 3-dimensional (3-D) turbulent cloud simulations are analyzed, and the behavior of these 3-D runs is qualitatively consistent with the theoretical expressions and axisymmetric simulations.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Multiple Environmental Influences on the Lightning of Cold-Based Continental Convection. Part II: Sensitivity Tests for Its Charge Structure and Land–Ocean Contrast

In Part I, an electrification scheme was described and a simulation of an observed cold-based storm from the U.S. Great Plains was validated with electrical observations. Most charge in the storm was separated by rebounding collisions of secondary ice originating from prior graupel–snow collisions. In this Part II, sensitivity tests are performed with the control simulation (Part I) and influences from environmental factors (aerosols, temperature, moisture, and shear) on lightning are elucidated. Environmental factors [e.g., convective available potential energy (CAPE)] controlling updraft speed are salient. When ascent is reduced by 30% and 70%, flashes become 70% fewer and disappear, respectively; faster ascent promotes positive cloud-to-ground (+CGs) flashes. Since cloud base is too cold (1°C) for coalescence, cloud condensation nucleus aerosol concentrations do not influence the lightning appreciably. The electrical response to varying concentrations of active ice nuclei is limited by most ice particles being secondary and less sensitive—a natural “buffer.” Imposing a maritime sounding suggests that the land–sea contrast in lightning for such storms is due to the vertical structure of environmental temperature and humidity. Weak CAPE, and both entrainment and condensate weight from a low cloud base, suppress ascent and charging. Maritime thermodynamic conditions reduce simulated flash rates by two orders of magnitude. Reducing aerosol loadings from continental to maritime only slightly reinforces this suppression. Last, a conceptual model is provided for how any simulated storm is either normal because graupel/hail is mostly positively charged or else is inverted/anomalous because graupel/hail is mostly negatively charged, with environmental factors controlling the charging. Impacts from microphysical processes, including three processes of secondary ice production, on lightning are analyzed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Satellite-Based Observations of Nonlinear Relationships between Vertical Wind Shear and Intensity Changes during the Life Cycle of Hurricane Joaquin (2015)

A CIMSS vertical wind shear (VWS-C) dataset based on reprocessed GOES-East atmospheric motion vectors (AMVs) at 15-min intervals has a −0.36 correlation with the CIMSS Satellite Consensus (SATCON) intensity changes at 30-min intervals over the life cycle of Hurricane Joaquin (2015). Correlations are then calculated for four intensity change events including two rapid intensifications (RIs) and two decays, and four intensity change segments immediately before or after these events. During the first RI, the peak intensity increase of 16 kt (6 h) −1 (1 kt ≈ 0.51 m s −1 ) follows a small VWS-C decrease to a moderate 8 m s −1 value (negative correlation). A 30-h period of continued RI following the first peak RI occurred under moderate magnitude VWS-C (negative correlation), but with a rotation of the VWS-C direction to become more aligned with the southwestward heading of Joaquin. During the second RI, the peak intensity increase of 15 kt (6 h) −1 leads the rapid VWS-C increase (positive correlation), which the horizontal plots of VWS-C vectors demonstrate is related to an upper-tropospheric cyclone to the northeast of Joaquin. A conceptual model of ocean cooling within the anticyclonic track loop is proposed to explain a counterintuitive decreasing intensity when the VWS-C was also decreasing (positive correlation) during the Joaquin track reversal. These alternating negative and positive correlations during the four events and four segments of intensity change demonstrate the nonlinear relationships between the VWS-C and intensity changes during the life cycle of Joaquin that must be understood, analyzed, and modeled to improve tropical cyclone intensity forecasts, and especially RI events.

Elsberry, Russell L.↗
DOE OSTI2022

Long-term nitrogen deposition enhances microbial capacities in soil carbon stabilization but reduces network complexity

Background: Anthropogenic activities have increased the inputs of atmospheric reactive nitrogen (N) into terrestrial ecosystems, affecting soil carbon stability and microbial communities. Previous studies have primarily examined the effects of nitrogen deposition on microbial taxonomy, enzymatic activities, and functional processes. Here, we examined various functional traits of soil microbial communities and how these traits are interrelated in a Mediterranean type grassland administrated with 14 years of 7 g m –2 year –1 of N amendment, based on estimated atmospheric N deposition in areas within California, USA, by the end of the twenty-first century. Results: Soil microbial communities were significantly altered by N deposition. Consistent with higher aboveground plant biomass and litter, fast-growing bacteria, assessed by abundance-weighted average rRNA operon copy number, were favored in N deposited soils. The relative abundances of genes associated with labile carbon (C) degradation (e.g., amyA and cda) were also increased. In contrast, the relative abundances of functional genes associated with the degradation of more recalcitrant C (e.g., mannanase and chitinase) were either unchanged or decreased. Compared with the ambient control, N deposition significantly reduced network complexity, such as average degree and connectedness. The network for N deposited samples contained only genes associated with C degradation, suggesting that C degradation genes became more intensely connected under N deposition. Conclusions: We propose a conceptual model to summarize the mechanisms of how changes in above- and belowground ecosystems by long-term N deposition collectively lead to more soil C accumulation.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Soil Desiccation Treatability Testing at BC Waste Disposal Cribs

During Hanford’s production period, low-level waste products generated from chemical processing of uranium fuel rods were discharged directly to the ground through a system of cribs and trenches located in the 200-BC-1 Operable Unit (OU). The site consists of 6 cribs and 20 trenches that received more than 117,000 m3 of radioactive liquid waste discharged to the soil. These unlined infiltration galleries held volumes of liquid waste while it seeped into the ground, with the understanding that the 100 m (330 ft) thick vadose zone in the area would effectively capture the effluent and prevent groundwater impacts. A conceptual model showing the operation of cribs and trenches is shown in Figure 1. Data show effluent from the 26 cribs and trenches containing about 410 curies of Technetium-99 (Tc-99) is primarily located between 30 m and 70 m (98 ft and 230 ft) depth (Corbin et al., 2005; Ward et al., 2004). Despite no evidence indicating that the contamination has reached the groundwater at BC cribs and trenches, the mobility of Tc-99 had been demonstrated in laboratory tests and was recognized as a threat to groundwater at the site. Using data from numerical models, laboratory analyses, field investigations, and information on historical discharges, the EPA and Ecology identified Tc-99 and U contamination of the vadose zone as a remediation priority. The U.S. DOE was notified by EPA and Ecology regarding risks associated with Tc-99 contamination in a letter requesting development of a strategy for improved methods to understand the nature and extent of vadose zone contamination, specifically Tc-99, and to develop remedial options for addressing such contamination. To develop the appropriate technology for characterizing, remediating, and monitoring the deep vadose zone Tc-99 contamination, the U.S. DOE worked with the EPA and Ecology to create a Treatability Test Plan under a Remedial Investigation/Feasibility Study (RI/FS) for the Hanford 200 Areas. Under this RI/FS, it was determined that a treatability test for soil desiccation should be carried out as it was identified as a promising in-situ treatment technology for mitigating risks posed by Tc-99 contamination to the groundwater table. The BC Cribs and Trenches site was identified as a representative site for Tc-99 and U contamination and selected for the soil desiccation treatability test. In this chapter, we summarize the overlying regulatory framework of RI/FS and treatability tests and illustrate how development and experimentation supported the evaluation of selected remedies. We briefly discuss the RI/FS for the 200 Areas of the Hanford Site and focus on the soil desiccation treatability testing performed at the BC cribs and trenches site under the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DVZ-TT). The DVZ-TT is one component of the remedial investigation/feasibility study for the Hanford 200 Areas and represents the underlying regulatory framework that drives site operations towards records of decision and site closure.

Mangel, Adam R.↗
DOE OSTI2024

Enhanced Attenuation of Uranium in the Subsurface

Over time, the focus for the Hanford Site has moved from production to decommissioning and site remediation. Several hundred metric tons of near-surface vadose zone sediment have been excavated from the 300 Area in an effort to remove the source of the uranium contamination (DOE/RL, 2011). Despite remediation efforts, uranium continues to be problematic with concentrations greater than the maximum contaminant level (MCL, which is 30 µg/L) for drinking water. Due to the close proximity of the Columbia River, the uranium continues to be a focus of investigation and remediation. After finding that the uranium concentrations were not decreasing as quickly as expected (based on the 1996 ROD) the Tri-Parties set new milestones, including an update of the conceptual model for the 300 Area uranium plume (Williams et al., 2007). In order to more accurately complete a feasibility study and identify how to remediate the uranium in the groundwater, the DOE authorized a remedial investigation/feasibility study (RI/FS). RI/FSs are designed to screen technologies to determine effectiveness, implementability, and cost (see Chapter 2b). These studies are designed to be conducted concurrently as part of the CERCLA process, so the data collected during site characterization (part of the RI) can inform the treatability studies and field tests conducted under the FS (EPA 1988). For the 300 Area, this study included laboratory, field, and modeling components as well as additional sediment and groundwater characterization to determine a suitable remediation strategy to reduce the uranium concentration in the groundwater plume within the expected time frame and cost.

300 area, uranium, polyphosphate, Hanford book pro↗
DOE OSTI2026

WHONDRS Surface Water and Sediment Geochemistry and Organic Matter Characterization Data from Streams across HJ Andrews Experimental Forest, Oregon (v2)

This dataset supports a broader study developing conceptual models for river corridor critical zone processes across spatial scales and was generated in collaboration with the HJ Andrews River Corridor Critical Zone Workshop in 2025. The dataset provides surface water geochemistry (dissolved organic carbon, total dissolved nitrogen) from 48 sites across the HJ Andrews Experimental Forest, Oregon (https://andrewsforest.oregonstate.edu). Some of the sites have been impacted by the Holiday Farm Fire and the Lookout Fire in 2020 and 2023, respectively. Related data were collected as part of the workshop and will be published separately in collaboration with other workshop attendees and available at http://www.hydroshare.org/resource/b274c4a234bf4b12b7cb8a54a696c629. Related genomic data can be found on the National Center for Biotechnology Information (NCBI) under BioProject PRJNA1503030 (see critical details section below for more information). Additional related data collected in 2016 from a similar effort can be found at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3377027 and http://www.hydroshare.org/resource/ea6c0832885a46c3939e7bb22e48e754 and are described within https://doi.org/10.5194/essd-11-1-2019 (Ward et al., 2019). This data package was originally published in March 2026. It was updated in August 2026 (v2; new and modified files). See the change history section in the readme for more details. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of field photos, (2) a folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data, (3) a data checks report, (4) a folder of sample data, (5) file-level metadata, (6) data dictionary, (7) field metadata, (8) readme, (9) international generic sample number (IGSN) mapping file; and (10) field protocol. The sample data subfolder contains surface water and sediment (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages, (2) total dissolved nitrogen data and averages, (3) methods codes, (4) FTICR-MS methods; and (5) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains the CoreMS processed data and seven subfolders, thee containing .xml files for each sample type (sediment, surface water and blank samples), three containing the sediment CoreMS output files for each sample type (sediment, surface water and blank samples), and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .Rmd, .py, .cal, .json, .jpg, or .jpeg.

Biogeochemistry↗
DOE OSTI2025

Basin-Scale Structural Features Database

The Basin-Scale Structural Features database provides spatial datasets of faults, fractures, folds, and earthquakes compiled from public, authoritative sources (e.g., U.S. Geological Survey and State Geological Surveys) and aggregated into derivative forms to support subsurface assessments. Recognizing that characterizing basin-scale structural features requires interpreting data that are often ambiguous or lack key information, the source data were evaluated using a knowledge-data framework and geospatial fuzzy logic method (Justman et al., 2020) to represent both measured (observed) and predicted (inferred or potential) structural features as derivative datasets. This workflow employs conceptual models for known structural features and predicted structural features, incorporating geospatial data to estimate potential, even with limited data. The aim is to aid and support an understanding of basin-scale features and identify potential gaps in data and knowledge. As of 4/30/2025, the database includes resources for nine sedimentary basins: Appalachian, Denver, U.S. Gulf Coast, Illinois, Michigan, Permian, Sacramento, San Joquin and Williston. The database is organized by basin and then data category: 1) Faults, fractures, folds, 2) Earthquakes, 3) Topographic, 4) Structural contours and isopachs, 5) Geophysical, and 6) Structural feature density assessment maps.

basin scale↗
DOE OSTI2024

Impact of Pressure-Dependent Interfacial Tension and Contact Angle on Capillary Heterogeneity Trapping of CO2 in Storage Aquifers

Summary Carbon dioxide (CO2) capillary trapping increases the total amount of CO2 that can be effectively immobilized in storage aquifers. This trapping, manifesting itself as accumulated CO2 columns at a continuum scale, is because of capillary threshold effects that occur below low-permeability barriers. Considering that capillary pressure is dictated by heterogeneous pore throat size, the trapped CO2 column height and associated CO2 saturation will vary spatially within a storage aquifer. This variation will be influenced by two pressure-dependent interfacial parameters—CO2/brine interfacial tension (IFT) and CO2/brine/rock contact angle. Our objective is to understand how the pressure dependence of these two parameters affects the heterogeneity of capillary trapped CO2 at a continuum scale. Our conceptual model is a 1D two-zone system with the upper zone being a flow barrier (low permeability) and the lower zone being a flow path (high permeability). The inputs to this model include microfacies-dependent capillary pressure vs. saturation curves and permeability values. The input capillary pressure curves were collected in the literature that represents carbonate microfacies (e.g., dolograinstone) in a prevalent formation in the Permian Basin. We then used the Leverett j-function to scale the capillary pressure curve for the two zones that are assigned with the same or different microfacies. During scaling, we considered the influence of pressure on both the IFT and contact angle of CO2/brine/dolomite systems. We varied the zone permeability contrast ratio from 2 to 50. We then assumed capillary gravity equilibriums and calculated the CO2 saturation buildup corresponding to various trapped CO2 column heights. The CO2 saturation buildup is defined as the CO2 saturation in the lower layer minus that in the upper one. We found that the saturation buildup can be doubled when varying pressure in a storage aquifer, after considering pressure-dependent IFT and contact angles. Thus, assuming these two parameters to be constant across such aquifers would cause large errors in the quantification of capillary trapping of CO2. The whole study demonstrates the importance of considering pressure-dependent interfacial properties in predicting the vertical distribution of capillary trapped CO2. It has important implications in developing a better understanding of leakage risks and consequent storage safety.

Engineering↗