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At least 163 records · Page 9

SULI Report - Development of a Molten Salt Circulation Loop for in-situ Spectroscopy

This project supports the development of real time optical monitoring capabilities for molten salt reactor (MSR) environments by designing, testing, and refining a molten salt circulation loop suitable for combined laser induced breakdown spectroscopy (LIBS) and ultraviolet visible (UV Vis) absorption measurements. Online spectroscopic monitoring is increasingly important for nuclear safeguards, corrosion tracking, and material accountancy, yet MSR process fluids present substantial challenges due to their chemical complexity and hazards such as high temperatures and radiation. To address these needs, this work focuses on Phase I, the development of a room temperature aqueous circulation loop that serves as a surrogate platform for evaluating flow behavior, optical access, and component performance prior to high temperature salt operation. Initial testing identified several practical issues—including leaks, obstructions, and two-phase flow through the absorption cell—that were systematically resolved through hardware replacement, flow path redesign, and venturi pressure optimization. Relocating the flow cell upstream of the primary venturi enabled periods of stable single-phase flow, demonstrating the feasibility of integrating optical diagnostics into a circulation system. The results of Phase I provide essential design insight for Phase II, which will incorporate furnace compatible materials and LiCl KCl eutectic salt. Completion of the molten salt system will deliver a reusable testbed for evaluating multimodal spectroscopic techniques, advancing nondestructive, real time monitoring tools for future MSR and nuclear fuel cycle applications.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

Intracore Natural Circulation Study in the High Temperature Test Facility

The development of the Modular High-Temperature Gas-Cooled Reactor is a significant milestone in advanced nuclear reactor technology. One of the concerns for the reactor’s safe operation is the effects of a loss-of-flow accident (LOFA) where the coolant circulators are tripped, and forced coolant flow through the core is lost. Depending on the steam generator placement, loop or intracore natural circulation develops to help transfer heat from the core to the reactor cavity, cooling system. This paper investigates the fundamental physical phenomena associated with intracore coolant natural circulation flow in a one-sixth Computational Fluid Dynamics (CFD) model of the Oregon State University High Temperature Test Facility (OSU HTTF) following a loss-of-flow accident transient. This study employs conjugate heat transfer and steady-state flow along with an SST k-ω turbulence model to characterize the phenomenon of core channel-to-channel natural convection. Previous studies have revealed the importance of complex flow distribution in the inlet and outlet plenums with the potential to generate hot coolant jets. For this reason, complete upper and lower plenum volumes are included in the analyzed computational domain. CFD results also include parametric studies performed for a mesh sensitivity analysis, generated using the STAR-CCM+ software. The resulting channel axial velocities and flow directions support the test facility scaling analysis and similarity group distortions calculation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Encoders for block-circulant LDPC codes

In this paper, we present two encoding methods for block-circulant LDPC codes. The first is an iterative encoding method based on the erasure decoding algorithm, and the computations required are well organized due to the block-circulant structure of the parity check matrix. The second method uses block-circulant generator matrices, and the encoders are very similar to those for recursive convolutional codes. Some encoders of the second type have been implemented in a small Field Programmable Gate Array (FPGA) and operate at 100 Msymbols/second.

encoders↗

The Brewer–Dobson Circulation in CMIP6

The Brewer–Dobson circulation (BDC) is a key feature of the stratosphere that models need to accurately represent in order to simulate surface climate variability and change adequately. For the first time, the Climate Model Intercomparison Project includes in its phase 6 (CMIP6) a set of diagnostics that allow for careful evaluation of the BDC. Here, the BDC is evaluated against observations and reanalyses using historical simulations. CMIP6 results confirm the well-known inconsistency in the sign of BDC trends between observations and models in the middle and upper stratosphere. Nevertheless, the large uncertainty in the observational trend estimates opens the door to compatibility. In particular, when accounting for the limited sampling of the observations, model and observational trend error bars overlap in 40 % of the simulations with available output. The increasing CO2 simulations feature an acceleration of the BDC but reveal a large spread in the middle-to-upper stratospheric trends, possibly related to the parameterized gravity wave forcing. The very close connection between the shallow branch of the residual circulation and surface temperature is highlighted, which is absent in the deep branch. The trends in mean age of air are shown to be more robust throughout the stratosphere than those in the residual circulation.

Brewer–Dobson circulation↗

Unraveling the Mechanisms and Implications of a Stronger Mid-Pliocene Atlantic Meridional Overturning Circulation (AMOC) in PlioMIP2

The mid-Pliocene warm period (3.264–3.025 Ma) is the most recent geological period in which the atmospheric CO2 concentration was approximately equal to the concentration we measure today (ca. 400 ppm). Sea surface temperature (SST) proxies indicate above-average warming over the North Atlantic in the mid-Pliocene with respect to the pre-industrial period, which may be linked to an intensified Atlantic Meridional Overturning Circulation (AMOC). Earlier results from the Pliocene Model Intercomparison Project Phase 2 (PlioMIP2) show that the ensemble simulates a stronger AMOC in the mid-Pliocene than in the pre-industrial. However, no consistent relationship between the stronger mid-Pliocene AMOC and either the Atlantic northward ocean heat transport (OHT) or average North Atlantic SSTs has been found. In this study, we look further into the drivers and consequences of a stronger AMOC in mid-Pliocene compared to pre-industrial simulations in PlioMIP2. We find that all model simulations with a closed Bering Strait and Canadian Archipelago show reduced freshwater transport from the Arctic Ocean into the North Atlantic. This contributes to an increase in salinity in the subpolar North Atlantic and Labrador Sea that can be linked to the stronger AMOC in the mid-Pliocene. To investigate the dynamics behind the ensemble's variable response of the total Atlantic OHT to the stronger AMOC, we separate the Atlantic OHT into two components associated with either the overturning circulation or the wind-driven gyre circulation. While the ensemble mean of the overturning component is increased significantly in magnitude in the mid-Pliocene, it is partly compensated by a reduction in the gyre component in the northern subtropical gyre region. This indicates that the lack of relationship between the total OHT and AMOC is due to changes in OHT by the subtropical gyre. The overturning and gyre components should therefore be considered separately to gain a more complete understanding of the OHT response to a stronger mid-Pliocene AMOC. In addition, we show that the AMOC exerts a stronger influence on North Atlantic SSTs in the mid-Pliocene than in the pre-industrial, providing a possible explanation for the improved agreement of the PlioMIP2 ensemble mean SSTs with reconstructions in the North Atlantic.

AMOC↗

Utah FORGE: Wells 16A(78)-32 and 16B(78)-32 Stimulation Pressure and Circulation Data April, 2024

This dataset consists of all of the pressure pumping data for Utah FORGE Well16A78-32 fracturing stages, Well 16B78-32 fracturing stages, and a 9-hour circulation test which took place after all of the frac plugs were drilled out. Fracturing in the wells took place in stages from April 3rd to April 17th, while the circulation test occurred on April 27th, 2024. Data is in excel files, with ReadMe files for each of the .zip folders that detail what data is available. Also attached here is wellhead pressure data from Pason that is referred to in the ReadMe files.

15 GEOTHERMAL ENERGY↗

Corrosion of 316 L stainless steel under the natural circulation of molten NaCl-MgCl 2 salt

The corrosion behavior of 316 L stainless steel (SS) was studied via the natural circulation of molten eutectic NaCl-MgCl 2 salt through a microloop. The post-corrosion tested 316 L SS microloop sections were characterized with microscopy techniques to determine the microstructural and microchemical changes that occurred at the alloy/salt interface. It was found that 316 L SS showed heterogeneous dissolution at the hot-leg, whereas deposition of corrosion products occurred at the cold-leg. For the first time, experimentally obtained molten salt flow-induced corrosion of 316 L SS results were combined with computational thermodynamic-kinetic models to validate the dissolution and deposition in terms of elemental compositional changes at the alloy/salt interface. The thermodynamic-kinetic modeling predicted that the heterogeneous dissolution of Cr and Fe from the hot-leg section of 316 L SS persisted throughout the salt circulation. The model also estimated that, despite Cr deposition starting earlier than Fe, the total redeposition of Fe is expected to be significantly greater than that of Cr over the circulation of salt. Furthermore, the modeling accurately predicted the subsurface enrichment of Mo which is attributed to the reduced Cr activity and the relatively higher diffusion rate of Mo within the alloy matrix. Here, the agreement between modeling and experimental results confirms that Fe chlorides dissolve at the hot-leg and subsequently deposit at the cold-leg due to activity changes driven by the thermal gradient. By contrast, Cr was not detected in the cold-leg deposits, which is attributed to its weaker temperature dependence on activity, limiting its redeposition under these conditions.

36 - MATERIALS SCIENCE↗

An Antibody Cocktail-Based Immunoaffinity-LC-MS Method Enabled Ultra-Sensitive and Robust Quantification of Circulating Proinsulin Proteoforms and C-Peptide

Accurately measuring circulating proinsulin proteoforms is crucial for clinical investigation of diabetes, but was previously not feasible owing to limited assay specificity/sensitivity. Here, in this study, we devised a highly sensitive LC-MS-based strategy to quantify intact proinsulin, des-31,32 and des-64,65 proinsulin, and C-peptide in circulation. The method involves: (i) quantitative, robust affinity capture using an optimized antibody cocktail, eliminating the severe quantitative bias across multiple proteoforms typically introduced when using a single antibody; (ii) Lys-C digestion producing unique signature peptides for each proteoform, and (iii) trapping-nano-LC coupled with FAIMS/dCV-MS for an ultrasensitive analysis. The selective trapping/delivery ensured sensitive/selective analysis of the targets while achieving excellent analytical robustness that is critical for clinical assays, and the FAIMS/dCV substantially reduces baseline noise/interferences, further enhancing S/N. The assay achieved exceptional sensitivity, with serum LOQs of 1.7, 2.3, and 3.6 pg/mL respectively for intact-proinsulin, des-31,32 and des-64,65, representing the first assay capable of sensitively quantifying these major circulating proinsulin proteoforms. We applied this assay to 78 subjects, including autoantibody positive (n = 20) and new-onset type 1 diabetes (T1D, n = 19) with respective age/sex/BMI-matched controls, enabling the first accurate profiling of proinsulin proteoforms in clinical groups. The assay results demonstrated a clear separation of control and new-onset T1D groups that a parallel total-proinsulin ELISA assay fails to capture. Furthermore, distinct expression patterns in relative abundance ratios among proteoforms were observed across clinical groups. This assay may provide valuable insights into the β-cell functions and the onset/progression of diabetes and other associated conditions. Moreover, the strategy is broadly applicable to targeted measurement of other biomarker proteoforms.

Shen, Qingqing [University at Buffalo, NY (United ↗

Radiative, Hydrologic, and Circulation Responses to Warming in Cess‐Potter Simulations Using the Global 3.25‐km SCREAM

Using the global 3.25-km Simple Cloud Resolving E3SM Atmosphere Model (SCREAM 3 km), a pair of 13-month Cess-Potter simulations are performed to quantify the radiative feedbacks and the hydrologic and circulation responses to warming. Large-scale aspects of SCREAM 3 km's top-of-atmosphere radiative fluxes, precipitation rates, and circulations are in good agreement with observations and reanalysis, with notable differences, including a drier lower free-troposphere in the Tropics, reduced precipitation and humidity over the Tropical West Pacific, and poleward shifted Southern Hemisphere midlatitude jet. In response to warming, SCREAM 3 km predicts a total radiative feedback within the top 15% of the CMIP5 and CMIP6 models, which puts it substantially higher than the feedback reported by other kilometer-scale models. SCREAM 3 km's high radiative feedback stems from a strongly positive shortwave cloud feedback, most prominent over the mid- and high-latitudes. SCREAM 3 km's high precipitation response also puts it among the highest of CMIP models, whereas its circulation response is within the spread of CMIP models. An ensemble of five perturbed initial condition Cess-Potter simulations with a 12 km version of SCREAM (SCREAM 12 km) is performed to characterize uncertainty and resolution sensitivity. It suggests that the uncertainty from analyzing a pair of 1-year simulations is small compared to the inter-model spread in feedbacks and precipitation response. SCREAM 12 km also produces a strong precipitation response to warming but a much lower cloud feedback and total radiative feedback. The results from these experiments suggest that the spread in climate feedbacks will likely persist in the next generation of kilometer-scale models.

54 ENVIRONMENTAL SCIENCES↗

The Role of Deep Convection and Large-scale Circulation in Driving Model Spread in Low Cloud Feedback and Equilibrium Climate Sensitivity

This project aims to advance the understanding of the processes that drive the large uncertainties in climate change projections, use observations to constrain model physics and reduce the inter-model spread in equilibrium climate sensitivity (ECS). There are three major goals: 1) Characterize the representation of the physical pathways that link deep convection, large-scale circulation and low cloud feedback in CMIP6 model simulations and determine the relative contribution of each pathway to the CMIP6 model spread in low cloud feedback and ECS; 2) Use process-oriented diagnostics and multiple observations to evaluate CMIP6 model performance in capturing the observed cloud-circulation relation and deep convection characteristics including convective transition statistics and the bulk properties of mesoscale convective systems (MCSs). Error decomposition in CMIP6 models will be performed. 3) Conduct E3SM short-range hindcasts following the DOE Cloud-Associated Parameterizations Testbed (CAPT) protocol to pinpoint specific model parameters/processes that are crucial to the representation of deep convection, circulation, clouds and the pathways that connect them. We will modify convective parameters in E3SM and analyze the perturbed physics experiments (PPEs) to isolate model parameters that are critical to the uncertainty of ECS.

54 ENVIRONMENTAL SCIENCES↗

Circulation of Prince William Sound

The author has identified the following significant results. Visual examination of the available ERTS-1 and NASA NP-3 aircraft imagery has suggested that sediment-laden plumes from rivers may be useful in tracking surface circulation over the regions where these plumes retain their visible identities. Plumes of ice derived from tidewater glaciers are highly visible on the ERTS-1 imagery, but are generally of too small an areal extent to be useful in tracing surface circulation. Shore-fast ice is also highly visible on the ERTS-1 data. Practical scientific results include a corroboration of the westward flow just offshore in the Gulf of Alaska with inflow through Hinchinbrook Entrance into Prince William Sound. The tracer in this case was the Copper River Plume, which originates at the mouth of the Copper River east of Prince William Sound. A single partial image of Port Valdez, in northeastern Prince William Sound, suggests by the visible suspended sediment distribution that surface circulation there was cyclonic, as deduced previously from oceanographic baseline data. Surf along the shoreline of the Gulf of Alaska is highly visible on ERTS-1 imagery.

Muench, R. D.↗

The influence of surface waves on water circulation in a mid-Atlantic continental shelf region

The importance of wave-induced currents in different weather conditions and water depths (18.3 m and 36.6 m) is assessed in a mid-Atlantic continental-shelf region. A review of general circulation conditions is conducted. Factors which perturb the general circulation are examined using analytic techniques and limited experimental data. Actual wind and wave statistics for the region are examined. Relative magnitudes of the various currents are compared on a frequency of annual occurrence basis. Results indicated that wave-induced currents are often the same order of magnitude as other currents in the region and become more important at higher wind and wave conditions. Wind-wave and ocean-swell characteristics are among those parameters which must be monitored for the analytical computation of continental-shelf circulation.

Whitlock, C. H.↗

Dynamics, winds, circulation and turbulence in the atmosphere of Venus

With the possible exception of the lowest one or two scale heights, the dominant mode of circulation of Venus' atmosphere is a rapid, zonal, retrograde motion. Global albedo variations in the ultraviolet may reflect planetary scale waves propagating relative to the zonal winds. Other special phenomena such as cellular convection in the subsolar region and internal gravity waves generated in the interaction of the zonal circulation with the subsolar disturbance may also be revealed in ultraviolet imagery of the atmosphere. We discuss the contributions of experiments on the Orbiter and Entry Probes of Pioneer Venus toward unravelling the mystery of the planet's global circulation and the role played by waves, instabilities and convection therein

Schubert, G.↗

The zonally averaged circulation of the middle atmosphere

The steady-state, zonally averaged circulation of the middle atmosphere (15-125 km) is studied with a quasigeostrophic, numerical model that explicitly includes a self-consistent calculation of solar radiative heating due to O2 and O3 absorption, Newtonian cooling, Rayleigh friction, tropopause boundary conditions based on climatological averages, and the effects of vertically propagating planetary waves. It is found that the direct, radiatively driven pole-to-pole circulation at solstice is sufficient to account for the cold summer mesopause and warm isothermal winter mesosphere with associated zonal jets of realistic magnitude. The climatological heat and momentum fluxes associated with planetary wavenumber 2 have a negligible effect on the mean circulation. With planetary wavenumber 1, no steady-state solution could be obtained due to the formation of easterlies and hence critical layers in the winter mesosphere. The radiative heating associated with secondary peaks in the O3 density at the mesopause could render the polar mesopause region convectively unstable.

Schoeberl, M. R.↗

Numerical simulation of ozone production, transport and distribution with a global atmospheric general circulation model

The production, transport, and distribution of ozone are simulated for a January with a global atmospheric general circulation model. In this model, the ozone influences the radiational heating and the photochemical ozone production and destruction, the radiational heating influences the atmospheric circulation, and the circulation redistributes the ozone. The model has simulated the synoptic and time-averaged observed large-scale fields of temperature, mass, and velocity in the troposphere and stratosphere, although with deficiencies which are seen in the time-averaged O3 distribution. Transport of ozone in the summer and winter hemispheres, in different seasons, and in various latitudes is discussed, and it is concluded that the divergence of the ozone transport maintains it below its photochemical equilibrium concentration in the tropics and subtropics, and the convergence of the ozone transport maintains it above its photochemical equilibrium concentration in the middle and high latitudes of both hemispheres. Thus, both the atmospheric motions and the O3 photochemistry determine the O3 sources and sinks.

Schlesinger, M. E.↗

Computer-aided design of stripline ferrite junction circulators

A general design procedure is presented for stripline Y-junction circulators employing solid dielectric between ground planes. The resonator design and impedance matching are derived in a form suitable for computer evaluation. The procedure is applicable to cases where either the circulator bandwidth or the ground plane spacing is specified. An experimental S-band switching circulator design illustrates the technique.

Uzdy, Z.↗

On the dynamics of droughts in northeast Brazil - Observations, theory and numerical experiments with a general circulation model

The establishment of a thermally direct local circulation which has its ascending branch at about 10 deg N and its descending branch over northeast Brazil and the adjoining oceanic region is proposed as a possible mechanism for the occurrence of severe droughts over this Brazilian region. The driving for this anomalous circulation is provided by enhanced moist convection due to the effect of warmer sea surface anomalies over the northern tropical Atlantic and cooling associated with colder sea surface temperature anomalies in the southern tropical Atlantic. A simple primitive equation model is used to calculate the frictionally-controlled and thermally-driven circulation due to a prescribed heating function in a resting atmosphere, and a series of numerical experiments are carried out to test the sensitivity of the Goddard Laboratory's model to prescribed sea surface temperature anomalies over the tropical Atlantic.

Moura, A. D.↗

Zonal mean circulation at the cloud level on Venus - Spring and fall 1979 OCPP observations

Independent observations are presented of the zonal mean circulation deduced from the Pioneer Venus Orbiter images which substantiate the somewhat different circulation in the Venus atmosphere at the time of Pioneer observations. The most reassuring result from the present investigation is that measurements made by different individuals on the same set of images yield virtually the same zonal mean statistics for the cloud top circulation of Venus. The mean zonal component is about -95 m/sec at the equator, corresponding to a rotational period of about 4.8 days. The period of rotation increases to about 4.2 days for latitude regions 35-45 deg south and 25-40 deg north. The mean meridional motion is toward the northern pole north of 5 deg south latitude and toward the southern pole south of this latitude.

Limaye, S. S.↗