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NASA NTRS1991

A mathematical model of the maximum power density attainable in an alkaline hydrogen/oxygen fuel cell

A mathematical model of a hydrogen/oxygen alkaline fuel cell is presented that can be used to predict the polarization behavior under various power loads. The major limitations to achieving high power densities are indicated and methods to increase the maximum attainable power density are suggested. The alkaline fuel cell model describes the phenomena occurring in the solid, liquid, and gaseous phases of the anode, separator, and cathode regions based on porous electrode theory applied to three phases. Fundamental equations of chemical engineering that describe conservation of mass and charge, species transport, and kinetic phenomena are used to develop the model by treating all phases as a homogeneous continuum.

Kimble, Michael C.↗

NASA NTRS1992

Designing Birefringent Filters For Solid-State Lasers

Mathematical model enables design of filter assembly of birefringent plates as integral part of resonator cavity of tunable solid-state laser. Proper design treats polarization eigenstate of entire resonator as function of wavelength. Program includes software modules for variety of optical elements including Pockels cell, laser rod, quarter- and half-wave plates, Faraday rotator, and polarizers.

Monosmith, Bryan↗

NASA NTRS1992

Calorimetric determination of the thermoneutral potential of Li/BCX and Li/SOCl2 cells

Results are presented of the calorimetric determination of the effective thermoneutral potential, Eetp, of Li/BCS and Li/SOCl2 cells in the temperature range 0-60 C through a continuous recording of the cell voltage, heat flow, and current. The average effective thermoneutral potential at 25 C was 4.0 and 3.84 V for BCX and Li/SOCl2 cells, respectively. Based on the classical approach, the reversible cell potential, Er, and temperature dependence of reversible cell potential, dEr/dT, for BCX cell were 3.74 V and -0.952 mV/K, respectively, and for Li/SOCl2, Er = 3.67 V and dEr/dT = 0.567 mV/K. The thermal polarization (Eetp-E1), where E1 is the load voltage, for both cells, showed that they are the most thermally efficient near 40 C. An overall reaction proposed for the BCX chemistry is supported by the calculated thermodynamic parameters.

Kalu, E. E.↗

NASA NTRS2002

Improved performance and safety of lithium ion cells with the use of fluorinated carbonate-based electrolytes

There has been increasing interest in developing lithium-ion electrolytes that possess enhanced safety characteristics, while still able to provide the desired stability and performance. Toward this end, our efforts have been focused on the development of lithium-ion electrolytes which contain partially and fully fluorinated carbonate solvents. The advantage of using such solvents is that they possess the requisite stability demonstrated by the hydrocarbon-based carbonates, while also possessing more desirable physical properties imparted by the presence of the fluorine substituents, such as lower melting points, increased stability toward oxidation, and favorable SEI film forming Characteristics on carbon. Specifically, we have demonstrated the beneficial effect of electrolytes which contain the following fluorinated carbonate-based solvents: methyl 2,2,2-trifluoroethyl carbonate (MTFEC), ethyl-2,2,2 trifluoroethyl carbonate (ETFEC), propyl 2,2,2-trifluoroethyl carbonate (PTFEC), methyl-2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (MHFPC), ethyl- 2,2,2,2',2',2' -hexafluoro-i-propyl carbonate (EHFPC), and di-2,2,2-trifluoroethyl carbonate (DTFEC). These solvents have been incorporated into multi-component ternary and quaternary carbonate-based electrolytes and evaluated in lithium-carbon and carbon-LiNio.8Coo.202 cells (equipped with lithium reference electrodes). In addition to determining the charge/discharge behavior of these cells, a number of electrochemical techniques were employed (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further characterize the performance of these electrolytes, including the SEI formation characteristics and lithium intercalatiodde-intercalation kinetics. In addition to their evaluation in experimental cells, cyclic voltammetry (CV) and conductivity measurements were performed on select electrolyte formulations to further our understanding of the trends in stability and ionic mobility imparted by different alkyl substituents in linear carbonates.

li-ion batteries fluorinated carbonate electrolyte↗

NASA NTRS1995

Passive measurement and interpretation of polarized microwave brightness temperatures

The goal of this project is to develop satellite-based observational techniques for measuring both oceanic and atmospheric variables using passive polarimetric radiometry. Polarimetric radiometry offers a potential alternative to radar scatterometry in observing global ocean surface wind direction from satellites. Polarimetric radiometry might also provide a means of detecting cell-top ice in convective storms by virtue of the polarizing properties of oriented ice particles, and thus facilitate estimation of the phase of the storm. The project focuses on the development of polarimetric microwave radiometers using digital cross-correlators for obtaining precise measurements of all four Stokes' parameters. As part of the project a unique four-band polarimetric imaging radiometer, the Polar Scanning Radiometer (PSR), is being designed for use on the NASA DC-8 aircraft. In addition to providing an aircraft-based demonstration of digital correlation technology the PSR will significantly enhance the microwave imaging capability of the existing suite of DC-8 instruments. During the first grant year excellent progress has been made in the following areas: (1) demonstrating digital correlation radiometry, (2) fabricating aircraft-qualified correlators for use in the PSR, and (3) modeling observed SSM/I brightness signatures of ocean wind direction.

Gasiewski, A. J.↗

NASA NTRS1986

Satellite accelerometer measurements of neutral density and winds during geomagnetic storms

A new thermospheric wind measurement technique is reported which is based on a Satellite Electrostatic Triaxial Accelerometer (SETA) system capable of accurately measuring accelerations in the satellite's in-track, cross-track and radial directions. Data obtained during two time periods are presented. The first data set describes cross-track winds measured between 170 and 210 km during a 5-day period (25 to 29 March 1979) of mostly high geomagnetic activity. In the second data set, cross-track winds and neutral densities from SETA and exospheric temperatures from the Millstone Hill incoherent scatter radar are examined during an isolated magnetic substorm occurring on 21 March 1979. A polar thermospheric wind circulation consisting of a two cell horizontal convection pattern is reflected in both sets of cross-track acceleration measurements. The density response is highly asymmetric with respect to its day/night behavior. Latitude structures of the density response at successive times following the substorm peak suggest the equatorward propagation of a disturbance with a phase speed between 300 and 600 m/s. A deep depression in the density at high latitudes (less than 70 deg) is evident in conjunction with this phenomenon. The more efficient propagation of the disturbance to lower latitudes during the night is probably due to the midnight surge effect.

Marcos, F. A.↗

NASA NTRS1995

The Earth's magnetosphere is 165 R(sub E) long: Self-consistent currents, convection, magnetospheric structure, and processes for northward interplanetary magnetic field

The subject of this paper is a self-consistent, magnetohydrodynamic numerical realization for the Earth's magnetosphere which is in a quasi-steady dynamic equilibrium for a due northward interplanetary magnetic field (IMF). Although a few hours of steady northward IMF are required for this asymptotic state to be set up, it should still be of considerable theoretical interest because it constitutes a 'ground state' for the solar wind-magnetosphere interaction. Moreover, particular features of this ground state magnetosphere should be observable even under less extreme solar wind conditions. Certain characteristics of this magnetosphere, namely, NBZ Birkeland currents, four-cell ionospheric convection, a relatively weak cross-polar potential, and a prominent flow boundary layer, are widely expected. Other characteristics, such as no open tail lobes, no Earth-connected magnetic flux beyond 155 R(sub E) downstream, magnetic merging in a closed topology at the cusps, and a 'tadpole' shaped magnetospheric boundary, might not be expected. In this paper, we will present the evidence for this unusual but interesting magnetospheric equilibrium. We will also discuss our present understanding of this singular state.

Fedder, J. A.↗

NASA NTRS2010

NASA Tech Briefs, July 2010

Topics covered include: Wirelessly Interrogated Wear or Temperature Sensors; Processing Nanostructured Sensors Using Microfabrication Techniques; Optical Pointing Sensor; Radio-Frequency Tank Eigenmode Sensor for Propellant Quantity Gauging; High-Temperature Optical Sensor; Integral Battery Power Limiting Circuit for Intrinsically Safe Applications; Configurable Multi-Purpose Processor; Squeezing Alters Frequency Tuning of WGM Optical Resonator; Automated Computer Access Request System; Range Safety for an Autonomous Flight Safety System; Fast and Easy Searching of Files in Unisys 2200 Computers; Parachute Drag Model; Evolutionary Scheduler for the Deep Space Network; Modular Habitats Comprising Rigid and Inflatable Modules; More About N2O-Based Propulsion and Breathable-Gas Systems; Ultrasonic/Sonic Rotary-Hammer Drills; Miniature Piezoelectric Shaker for Distribution of Unconsolidated Samples to Instrument Cells; Lunar Soil Particle Separator; Advanced Aerobots for Scientific Exploration; Miniature Bioreactor System for Long-Term Cell Culture; Electrochemical Detection of Multiple Bioprocess Analytes; Fabrication and Modification of Nanoporous Silicon Particles; High-Altitude Hydration System; Photon Counting Using Edge-Detection Algorithm; Holographic Vortex Coronagraph; Optical Structural Health Monitoring Device; Fuel-Cell Power Source Based on Onboard Rocket Propellants; Polar Lunar Regions: Exploiting Natural and Augmented Thermal Environments; Simultaneous Spectral Temporal Adaptive Raman Spectrometer - SSTARS; Improved Speed and Functionality of a 580-GHz Imaging Radar; Bolometric Device Based on Fluxoid Quantization; Algorithms for Learning Preferences for Sets of Objects; Model for Simulating a Spiral Software-Development Process; Algorithm That Synthesizes Other Algorithms for Hashing; Algorithms for High-Speed Noninvasive Eye-Tracking System; and Adapting ASPEN for Orbital Express.

Source record↗

NASA NTRS1986

Modeling for CO poisoning of a fuel cell anode

Poisoning losses in a half-cell in the 110-190 C temperature range have been measured in 100 wt pct H3PO4 for various mixtures of H2, CO, and CO2 gases in order to investigate the polarization loss due to poisoning by CO of a porous fuel cell Pt anode. At a fixed current density, the poisoning loss was found to vary linearly with ln of the CO/H2 concentration ratio, although deviations from linearity were noted at lower temperatures and higher current densities for high CO/H2 concentration ratios. The surface coverages of CO were also found to vary linearly with ln of the CO/H2 concentration ratio. A general adsorption relationship is derived. Standard free energies for CO adsorption were found to vary from -14.5 to -12.1 kcal/mol in the 130-190 C temperature range. The standard entropy for CO adsorption was found to be -39 cal/mol per deg K.

Dhar, H. P.↗

NASA NTRS2004

Cusp and LLBL as Sources of the Isolated Dayside Auroral Feature During Northward IMF

An intense dayside proton aurora was observed by IMAGE FUV for an extensive period of northward interplanetary magnetic field (IMF) on 17 and 18 September, 2000. This aurora partially coincided with the auroral oval and intruded farther poleward into the polar cap, and it showed longitudinal motions in response to IMF $B-y$ variation. Intense magnetosheath-like electron and ion precipitations have been simultaneously detected by DMSP above the poleward portion of the high-latitude dayside aurora. They resemble the typical plasmas observed in the low-altitude cusp. However, less intense electrons and more intense energetic ions were detected over the equatorward part of the aurora. These plasmas are closer to the low-latitude boundary layer (LLBL) plasmas. Under strongly northward IMF, global ionospheric convection derived from SuperDARN radar measurements showed a 4-cell pattern with sunward convection in the middle of the dayside polar cap and the dayside aurora corresponded to two different convection cells. This result further supports two source regions for the aurora. The cusp proton aurora is on open magnetic field lines convecting sunward whereas the LLBL proton aurora is on closed field lines convecting antisunward. These IMAGE, DMSP and SuperDARN observations reveal the structure and dynamics of the aurora and provide strong evidence for magnetic merging occurring at the high-latitude magnetopause poleward from the cusp. This merging process was very likely quasi-stationary.

Chang, S.↗

NASA NTRS2004

Cusp and LLBL as Sources of the Isolated Dayside Auroral Feature During Northward IMF

An intense dayside proton aurora was observed by Imager for Magnetopause-to- Aurora Global Exploration Far Ultra-Violet imager (IMAGE FUV) for an extensive period of northward interplanetary magnetic field (IMF) on 17 and 18 September 2000. This aurora partially coincided with the auroral oval and intruded farther poleward into the polar cap, and it showed longitudinal motions in response to IMF By variation. Intense magnetosheath-like electron and ion precipitations have been simultaneously detected by Defense Meteorological Satellite Program (DMSP) above the poleward portion of the high-latitude dayside aurora. They resemble the typical plasmas observed in the low-altitude cusp. However, less intense electrons and more energetic ions were detected over the equatonvard part of the aurora. These plasmas are closer to the low-latitude boundary layer (LLBL) plasmas. Under strongly northward IMF, global ionospheric convection derived from Super Dual Auroral Radar Network (SuperDARN) radar measurements showed a four-cell pattern with sunward convection in the middle of the dayside polar cap and the dayside aurora corresponded to two different convection cells. This result further supports two source regions for the aurora. The cusp proton aurora is on open magnetic field lines convecting sunward whereas the LLBL proton aurora is on closed field lines convecting antisunward. These IMAGE, DMSP, and SuperDARN observations reveal the structure and dynamics of the aurora and provide strong evidence for magnetic merging occurring at the high-latitude magnetopause poleward from the cusp. This merging process was very likely quasi-stationary.

Chang, S.-W.↗

NASA NTRS1997

Three-Dimensional Analysis of Nuclear Size, Shape and Displacement in Clover Root Cap Statocytes from Space and a Clinostat

Under normal (l-g) conditions the statocytes of root caps have a characteristic polarity with the nucleus in tight association with the proximal cell wall; but, in altered gravity environments including microgravity (mu-g) and the clinostat (c-g) movement of the nucleus away from the proximal cell wall is not uncommon. To further understand the cause of gravity-dependent nuclear displacement in statocytes, three-dimensional cell reconstruction techniques were used to precisely measure the volumes, shapes, and positions of nuclei in white clover (Trifolium repens) flown in space and rotated on a clinostat. Seeds were germinated and grown for 72 hours aboard the Space Shuttle (STS-63) in the Fluid Processing Apparatus (BioServe Space Technologies, Univ. of Colorado, Boulder). Clinorotation experiments were performed on a two-axis clinostat (BioServe). Computer reconstruction of selected groups of statocytes were made from serial sections (0.5 microns thick) using the ROSS (Reconstruction Of Serial Sections) software package (Biocomputation Center, NASA Ames Research Center). Nuclei were significantly displaced from the tops of cells in mu-g (4.2 +/- 1.0 microns) and c-g (4.9 +/- 1.4 microns) when compared to l-g controls (3.4 +/- 0.8 gm); but, nuclear volume (113 +/- 36 cu microns, 127 +/- 32 cu microns and 125 +/- 28 cu microns for l-g, mu-g and c-g respectively) and the ratio of nuclear volume to cell volume (4.310.7%, 4.211.0% and 4.911.4% respectively) were not significantly dependent on gravity treatment (ANOVA; alpha = 0.05). Three-dimensional analysis of nuclear shape and proximity to the cell wall, however, showed that nuclei from l-g controls appeared ellipsoidal while those from space and the clinostat were more spherically shaped. This change in nuclear shape may be responsible for its displacement under altered gravity conditions. Since the cytoskeleton is known to affect nuclear polarity in root cap statocytes, those same cytoskeletal elements could also control nuclear shape. This alteration in nuclear shape and position in mu-g and c-g when compared to l-g may lead to functional differences in the gravity signaling systems of plants subjected to altered gravity environments.

Smith, J.D.↗

NASA NTRS1992

Analysis of rotationally symmetric arrays of apertures on conducting spherical surfaces

Rotationally symmetric arrays of circular waveguide fed apertures on conducting spherical surfaces have been analyzed. Representation of the outside electromagnetic fields in terms of spherical transmission line modes permit the array analysis to be viewed as a spherical waveguide junction discontinuity problem. The apertures, in general, carry dual polarized circular waveguide TE11 modes. Two independent formulations - the unit cell method and the eigenexcitation method that take rotational symmetry into account - are developed and are checked against each other numerically for computational accuracy. These two formulations are analytically linked as discrete Fourier series pairs. It is seen that mutual coupling along the array decays more rapidly when the polarization of excitation is perpendicular to the array plane than when it is parallel to it. This analysis has been applied in the performance analysis of the Dome Lens phased array radar antenna.

Bondyopadhyay, Probir K.↗

NASA NTRS2010

Microfluidics microFACS for Life Detection

A prototype micro-scale Fluorescent Activated Cell Sorter (microFACS) for life detection has been built and is undergoing testing. A functional miniature microfluidics instrument with the ability to remotely distinguish live or dead bacterial cells from abiotic particulates in ice or permafrost of icy bodies of the solar system would be of fundamental value to NASA. The use of molecular probes to obtain the bio-signature of living or dead cells could answer the most fundamental question of Astrobiology: Does life exist beyond Earth? The live-dead fluorescent stains to be used in the microFACS instrument function only with biological cell walls. The detection of the cell membranes of living or dead bacteria (unlike PAH's and many other Biomarkers) would provide convincing evidence of present or past life. This miniature device rapidly examine large numbers of particulates from a polar ice or permafrost sample and distinguish living from dead bacteria cells and biological cells from mineral grains and abiotic particulates and sort the cells and particulates based on a staining system. Any sample found to exhibit fluorescence consistent with living cells could then be used in conjunction with a chiral labeled release experiment or video microscopy system to seek addition evidence for cellular metabolism or motility. Results of preliminary testing and calibration of the microFACS prototype instrument system with pure cultures and enrichment assemblages of microbial extremophiles will be reported.

Platt, Donald W.↗

NASA NTRS1982

Polar views of the earth's aurora with Dynamics Explorer

Preliminary examination of the first global auroral images gained with the vacuum-ultraviolet imaging photometer on board DE 1 reveals a remarkable spatial configuration of auroral luminosities. Frequently the northern auroral oval is bifurcated by a sun-aligned arc extending from the midday auroral zone to the nighttime sector of the oval. Simultaneous plasma measurements with the low-altitude DE-2 spacecraft are used to show that the character of plasmas above the polar arc is similar to those found over the poleward zones of the auroral oval. The spatial distribution of auroral luminosities is suggestive of a two-cell structure of current systems and convection electric fields over the earth's polar cap and a similar division of the corresponding lobe in the magnetotail.

Frank, L. A.↗

NASA NTRSDate not supplied

Goniometric and Polarized Imaging Spectroscopic Lab Measurements ofSpacecraft Materials

To better characterize the spectral response of common spacecraft materials, the following laboratory measurements are presented to support the Space Situational Awareness community in the analysis of remotely sensed observational data. Of interest is classifying material reflective properties using spectral bidirectional reflectance distribution function (BRDF) data and spatially resolved polarized imaging spectroscopy, allowing laboratory data to be applicable to ground-based optical telescope observations. The team acquired a typical CubeSat solar panel and a sample of multi-layer insulation commonly used on spacecraft for initial measurements. The data were collected at the Goniometer of the Rochester Institute of Technology (GRIT) laboratory with a field and laboratory goniometer housing two Analytical Spectral Device (ASD) spectrometers and a Headwall micro-Hyperspec E-Series imaging spectrometer with an adjustable linear polarizer. The goniometer provides spectral reflectance over a broad spectral range from 350-2500 nm at 1 nm spacing with 3 nm spectral resolution in the visible and near infrared and 8 nm in the shortwave infrared. The Headwall imager covers a spectral range from 400-1000 nm with 1.6 nm spectral resolution. We present the results from these initial measurements that show highly reflective regions at various locations in the angular domain for both materials. In addition, the solar cell spectra exhibited strong interference effects typically observed with thin films. Our team is pursuing a variety of typical solar cells to assess variations in product type. The spatially resolved polarization ratio maps show variability across the materials due to surface structure and varying material composition. Based on these results, we outline a plan for simulating spectral radiance light curves of the materials in various orbital configurations as they would be measured from ground- based telescopes for a clear observing sky during twilight. The paper will also present a plan for expanding ours of interest to determine if the results presented are unique to these samples and to categorize the spectral response for different material classes.

Chris H. Lee↗

NASA NTRS1984

The lipid composition and its alteration during the growth stage in pathogenic fungus, epidermophyton floccosum

Qualitative and quantitative changes of lipid components during the growth stages were studied in E. floccosum. The acyl group components of total lipids of Trichophyton rubrum and Microsporum cookei were also examined. The lipids of E. floccosum amounted to approximately 4% of the dry cell weight. Neutral lipids mainly consisted of triglycerides and sterols, and major polar lipids were phosphatidylcholine, phosphatidylethanolamine, and an unknown lipid X. The fatty acids in tryglycerides and phospholipids were palmitic, palmitoleic, stearic, oleic, and linoleic acids. The unknown polar lipid X which appeared between phosphatidylethanolamine and cardiolipin on thin layer chromatography plates contained no phosphorus. There was no significant change in the fatty acid components of E. floccosum and T. rubrum during the cell growth, whereas profound changes occurred in M. cookei. The sterol components of E. floccosum showed striking changes depending on the growth stage.

Yamada, T.↗

NASA NTRS1979

Polar clearing in the Venus clouds observed from the Pioneer Orbiter

High data rate, high resolution observations made by the Pioneer Venus 1 Orbiter of Venus clouds in the polar region are reported. Data obtained by the Pioneer IR radiometer reveal the presence of a localized, very warm (260 K) feature at about 80 deg N, 359 deg E, indicating a cloud height differential of about 15 km between the depressed, but not totally absent, cloud level indicated by the temperature peak and the surrounding cold zones. The observations are considered to constitute new evidence for the presence of strong atmospheric subsidence near the poles, fitting a model of vortex-type polar circulation. Implications of the observations for the single cell model of the Venus stratosphere are noted.

Taylor, F. W.↗