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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Mariner 9 ultraviolet spectrometer experiment - Pressure-altitude measurements on Mars

Ultraviolet spectrometer measurements of the reflectance at 3050 A are modeled to give pressure-altitudes for Mars assuming a quiescent atmosphere. Ultraviolet light that is Rayleigh-scattered by the Mars molecular atmosphere, with allowance for uniform turbidity, is proportional to surface pressure independent of atmospheric temperature structure. All model constants except the over-all scaling factors are found by requiring ultraviolet spectrometer pressures of 47 locations on the planet to be the same when measured at different geometries. The overall scaling factor is found by intercomparison with Mariner 9 occultation pressures. Comparison with other Mars pressure-altitude measurements show deviations from the assumption of uniform turbidity to occur over the Hesperia plateau for ultraviolet measurements obtained during the 13-26 February 1972 time period.

Hord, C. W.↗
NASA NTRS2013

Miniaturized, High-Speed, Modulated X-Ray Source

A low-cost, miniature x-ray source has been developed that can be modulated in intensity from completely off to full intensity on nanosecond timescales. This modulated x-ray source (MXS) has no filaments and is extremely rugged. The energy level of the MXS is adjustable from 0 to more than 100 keV. It can be used as the core of many new devices, providing the first practical, arbitrarily time-variable source of x-rays. The high-speed switching capability and miniature size make possible many new technologies including x-ray-based communication, compact time-resolved x-ray diffraction, novel x-ray fluorescence instruments, and low- and precise-dose medical x-rays. To make x-rays, the usual method is to accelerate electrons into a target material held at a high potential. When the electrons stop in the target, x-rays are produced with a spectrum that is a function of the target material and the energy to which the electrons are accelerated. Most commonly, the electrons come from a hot filament. In the MXS, the electrons start off as optically driven photoelectrons. The modulation of the x-rays is then tied to the modulation of the light that drives the photoelectron source. Much of the recent development has consisted of creating a photoelectrically-driven electron source that is robust, low in cost, and offers high intensity. For robustness, metal photocathodes were adopted, including aluminum and magnesium. Ultraviolet light from 255- to 350-nm LEDs (light emitting diodes) stimulated the photoemissions from these photocathodes with an efficiency that is maximized at the low-wavelength end (255 nm) to a value of roughly 10(exp -4). The MXS units now have much higher brightness, are much smaller, and are made using a number of commercially available components, making them extremely inexpensive. In the latest MXS design, UV efficiency is addressed by using a high-gain electron multiplier. The photocathode is vapor-deposited onto the input cone of a Burle Magnum(TradeMark) multiplier. This system yields an extremely robust photon-driven electron source that can tolerate long, weeks or more, exposure to air with negligible degradation. The package is also small. When combined with the electron target, necessary vacuum fittings, and supporting components (but not including LED electronics or high-voltage sources), the entire modulated x-ray source weighs as little as 158 grams.

Gendreau, Keith↗
DOE OSTI2023

On-Demand Aligned DNA Hydrogel Via Light Scanning

DNA is an anisotropic, water-attracting, and biocompatible material, an ideal building block for hydrogel. The alignment of the anisotropic DNA chains is essential to maximize hydrogel properties, which has been little explored. Here, we present a method to fabricate the anisotropic DNA hydrogel that allows precise control for the polymerization process of photoreactive cationic monomers. Scanning ultraviolet light enables the uniaxial alignment of DNA chains through the polymerization-induced diffusive mass flow using a concentration gradient. In conclusion, while studying anisotropic mechanical properties and orientation recovery according to the DNA chain alignment direction, we demonstrate the potential of directionally controlled DNA hydrogels as smart materials.

36 MATERIALS SCIENCE↗
NASA NTRS1983

Electron Transport in Paracoccus Halodenitrificans and the Role of Ubiquinone

The membrane-bound NADH oxidase of Paracoccus halodenitrificans was inhibited by dicoumarol, 2-n-heptyl-4-hydroxyquinoline-N-oxide (HQNO), and exposure to ultraviolet light (at 366 nm). When the membranes were extracted with n-pentane, NADH oxidase activity was lost. Partial restoration was achieved by adding the ubiquinone fraction extracted from the membranes. Succinate oxidation was not inhibited by dicoumarol or HQNO but was affected by ultraviolet irradiation or n-pentane extraction. However, the addition of the ubiquinone fraction to the n-pentane-extracted membranes did not restore enzyme activity. These observations suggested the reducing equivalents from succinate entered the respiratory chain on the oxygen side of the HQNO-sensitive site and probably did not proceed through a quinone.

Hochstein, L. I.↗
NASA NTRS1984

Electron transport in Paracoccus halodenitrificans and the role of Ubiquinone

The membrane-bound NADH oxidase of Paracoccus halodenitrificans was inhibited by dicoumarol, 2-n-heptyl-4-hydroxyquinoline-N-oxide (HQNO), and exposure to ultraviolet light (at 366 nm). When the membranes were extracted with n-pentane, NADH oxidase activity was lost. Partial restoration was achieved by adding the ubiquinone fraction extracted from the membranes. Succinate oxidation was not inhibited by dicoumarol or HQNO but was affected by ultraviolet irradiation or n-pentane extraction. However, the addition of the ubiquinone fraction to the n-pentane-extracted membranes did not restore enzyme activity. These observations suggested the reducing equivalents from succinate entered the respiratory chain on the oxygen side of the HQNO-sensitive site and probably did not proceed through a quinone.

Hochstein, L. I.↗
NASA NTRS2014

Visible-Light-Responsive Catalysts Using Quantum Dot-Modified TiO2 for Air and Water Purification

Photocatalysis, the oxidation or reduction of contaminants by light-activated catalysts, utilizing titanium dioxide (TiO2) as the catalytic substrate has been widely studied for trace contaminant control in both air and water applications. The interest in this process is due primarily to its low energy consumption and capacity for catalyst regeneration. Titanium dioxide requires ultraviolet light for activation due to its relatively large band gap energy of 3.2 eV. Traditionally, Hg-vapor fluorescent light sources are used in PCO reactors; however, the use of mercury precludes the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure. The development of a visible-light responsive (VLR) TiO2-based catalyst would eliminate the concerns over mercury contamination. Further, VLR development would allow for the use of ambient visible solar radiation or highly efficient LEDs, both of which would make PCO approaches more efficient, flexible, economical, and safe. Though VLR catalyst development has been an active area of research for the past two decades, there are few commercially available VLR catalysts. Those VLR catalysts that are commercially available do not have adequate catalytic activity, in the visible region, to make them competitive with those operating under UV irradiation. This study was initiated to develop more effective VLR catalysts through a novel method in which quantum dots (QD) consisting of narrow band gap semiconductors (e.g., CdS, CdSe, PbS, ZnSe, etc.) are coupled to TiO2 via two preparation methods: 1) photodeposition and 2) mechanical alloying using a high-speed ball mill. A library of catalysts was developed and screened for gas and aqueous phase applications using ethanol and 4-chlorophenol as the target contaminants, respectively. Both target compounds are well studied in photocatalytic systems and served as model contaminants for this research. Synthesized catalysts were compared in terms of preparation method, nature of the quantum dots, and dosage of quantum dots.

visible light↗
NASA NTRS2014

Visible-Light Responsive Catalysts Using Quantum Dot-Modified TiO2 for Air and Water Purification

Photocatalysis, the oxidation or reduction of contaminants by light-activated catalysts, utilizing titanium dioxide (TiO2) as the catalytic substrate has been widely studied for trace contaminant control in both air and water applications. The interest in this process is due primarily to its low energy consumption and capacity for catalyst regeneration. Titanium dioxide requires ultraviolet light for activation due to its relatively large band gap energy of 3.2 eV. Traditionally, Hg-vapor fluorescent light sources are used in PCO reactors; however, the use of mercury precludes the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure.

visible light↗
NASA NTRS1995

The development of a tunable, single-frequency ultraviolet laser source for UV filtered Rayleigh scattering

We present the development of a flexible, high power, narrow line width, tunable ultraviolet source for diagnostic application. By frequency tripling the output of a pulsed titanium-sapphire laser, we achieve broadly tunable (227-360 nm) ultraviolet light with high quality spatial and spectral resolution. We also present the characterization of a mercury vapor cell which provides a narrow band, sharp edge absorption filter at 253.7 nm. These two components form the basis for the extension of the Filtered Rayleigh Scattering technique into the ultraviolet. The UV-FRS system is comprised of four pieces: a single frequency, cw tunable Ti:Sapphire seeding source; a high-powered pulsed Ti:Sapphire oscillator; a third harmonic generator system; and an atomic mercury vapor filter. In this paper we discuss the development and characterization of each of these elements.

Finkelstein, N.↗
NASA NTRS1973

Investigation of laser dynamics, modulation and control by means of intra-cavity time varying perturbation

Work continued on a number of projects aimed at the generation of tunable visible, infrared, and ultraviolet light; and on the control of this light by means of novel mode-locking and modulation techniques. Progress is summarized for the following projects: (1) the transient modelocking of the Nd:YAG laser and application of short optical pulses; (2) studies of the sodium-xenon excimer laser; (3) development of techniques for vacuum ultraviolet holography; and (4) studies of multiple photon pumped xenon and argon excimer lasers.

Harris, S. E.↗
NASA NTRS1992

Flouorescence measurements of the thermal control coatings on LDEF experiments S0069 and A0114

Strong fluorescence emissions were observed, during post flight ultraviolet light inspection of experiments S0069 and A0114, from some of the surfaces exposed to the space environment. Subsequent wavelength measurements of the fluorescence emission characteristics, indicated large changes occurred between controls and exposed materials. Black urethane based coatings, especially ones having a silicone atomic oxygen protective overcoat, appear bright yellow under ultraviolet exposure. Measurements showed that the urethane based coatings had their emission spectra shifted into the visible wavelength range. In contrast, zinc oxide pigment type coatings showed a different effect, which was a quenching or reduction of their fluorescence versus exposure time. Silver Teflon bonded to aluminum with acrylic adhesive also showed a slight measurable fluorescence, which was found to originate in the acrylic adhesive.

Zwiener, James M.↗
NASA NTRS1973

Time variation of Martian regional contrasts.

Observations of contrast changes in blue light on Mars in 1969 and 1971 are presented. Seasonal effects evidently can be evaluated from these data, although nonseasonal effects are also present. A diurnal variation is noted for certain features during both apparitions. This variation cannot be fully accounted for without considering meteorological effects. An example of a contrast reversal in ultraviolet light is presented. The suggestion is made that during the Martian season covered herein, variability of the bright areas controlled the apparent contrasts observed.

Thompson, D. T.↗
DOE OSTI2025

Topology-imprinting in nonlinear metasurfaces

Flat optical components, or metasurfaces, have transformed optical imaging, data storage, information processing, and biomedical applications by providing unprecedented control over light-matter interactions. These nano-engineered structures enable compact, multidimensional manipulation of light’s amplitude, phase, polarization, and wavefront, producing scalar and vector beams with unique properties such as orbital angular momentum and knotted topologies. This flexibility has potential applications in optical communication and imaging, particularly in complex environments such as atmospheric turbulence and undersea scattering. However, designing metasurfaces for shorter wavelengths, such as visible and ultraviolet light, remains challenging due to fabrication limitations and material absorption. Here, we introduce an innovative concept called topology imprinting using judiciously designed all-dielectric nonlinear optical metasurfaces to replicate desired waveforms at fundamental and harmonic frequencies, opening promising avenues for advanced photonic applications.

42 ENGINEERING↗
NASA NTRS2000

Description of the Sun as a Star: General Physical Characteristics

Numerical parameters characterizing the size and energy output of the sun are presented. These values are the standard yardstick by which other stars are measured. The large number of significant digits tabulated here serve mainly to illustrate the precision to which these parameters are known. Also listed are parameters characterizing the earth's orbit around the sun and the intensity of the sun's radiation at the mean orbital distance. The appearance of the sun depends critically on how it is observed. Each type of radiation observed carries specific information about the physical processes at work on the sun. Special types of instruments reveal aspects otherwise invisible. Coronagraphs reveal the dimmer outer regions of the sun's atmosphere otherwise visible only during total solar eclipses. Spectroscopy can reveal motions, magnetic field strengths, temperatures and densities. In situ measurements have revealed the characteristics of the solar wind and extended our knowledge of the solar magnetic field both near the earth and beyond the orbits of the planets. As an example, the sun's disk observed almost simultaneously in six different wavelengths of light is shown. In visible light we can see the white disk of the sun with the dark spots known as sunspots. By analyzing the spectral lines produced by the sun we can measure the strength of the sun's magnetic field at its surface, producing a magnetogram. This magnetogram reveals that the sunspots are regions of intense magnetic field. Further images of the sun reveal that the sunspot regions are just the bases of systems of hot loops which emit radio-waves, ultraviolet light and X-rays. The sun imaged in a spectral line of hydrogen known as "H alpha" is shown. In this line we also see the long dark "filaments". These filaments form in long channels between areas of opposing magnetic field. Such channels can be seen in the ultraviolet image. Data concerning the sun are obtained with many different kinds of instruments and from many different vantage points, both on the ground and in space. Techniques for observing the sun's various emissions throughout the electromagnetic spectrum are illustrated.

Kucera, Theresa↗
NASA NTRS1974

Investigation of laser dynamics, modulation and control by means of intra-cavity time varying perturbation

Projects aimed at the generation of tunable visible, infrared, and ultraviolet light, and on the control of this light by means of novel mode-locking and modulation techniques are discussed. During this period the following projects have been active: (1) studies of transient mode-locking of the Nd:YAG laser and the application of short optical pulses; (2) experimental investigations of the Na-Xe excimer laser system; (3) further development of techniques for vacuum ultraviolet holography; and (4) theoretical and initial experimental studies of a new device which should prove very useful for both infrared up-conversion and generation of tunable UV radiation - a two-photon resonantly pumped frequency converter.

Harris, S. E.↗
NASA NTRS1972

Venus - Atmospheric rotation.

Photographs of Venus taken in ultraviolet light from Sept. 29, 1963, to May 29, 1971, indicate a general planet-wide circulation in the upper atmosphere of that planet having velocities which varied with time from -87 to -127m/sec at the equator. Positional measurements on 67 pairs of photographs which show the recurrence of similar patterns after intervals of one to three rotations suggest an asymmetric bimodal distribution of these velocities. The ultraviolet markings appear to be randomly distributed and quite ephemeral in nature, rarely enduring in a recognizable pattern for more than 20 days and usually much less. Attention is directed to an apparent but fictitious mean sidereal rotation period of approximately 4.06 days derived from observations which are made at a single station and span many months or years. Under such conditions this fictitious value for the rotation period is produced by the commensurability of the one-day period of earth and the assumed four-day period of the atmosphere of Venus.

Scott, A. H.↗
DOE OSTI2023

Spatio-temporally shaped deep UV laser source for ultrabright photocathodes using novel upconversion techniques (Final Report)

The goal of this project was to take a VUV laser system designed by Kapteyn-Murnane Labs (KMLabs)—the Hyperion VUV, and increase its functionality, efficiency, and applicability by further probing the fundamental physics taking place in the system and optimizing the system performance. More specifically, DOE accelerator applications—particularly for XFELs that require low-emittance electron beams, require precisely controlled ultrashort pulses in the deep-UV at 250-260 nm to drive the photocathode electron source. This is conventionally done using an ultrafast infrared laser, with subsequent stages of nonlinear upconversion in solid-state nonlinear-optical crystal media (principally BBO, which is commonly used for UV upconversion). However, maintaining high spatial mode beam quality, as well as precisely controlled temporal profile, has proven a persistent challenge. As a possible alternative to this approach, KMLabs has demonstrated a system that generates vacuum ultraviolet light (VUV) by upconverting pulses from an infrared ultrafast laser in a gas-filled hollow waveguide, driving a process of highly cascaded harmonic generation (HCHG). Because HCHG upconversion is done in a gas, rather than a solid, at high intensity in a guided-wave geometry, it retains an excellent beam spatial profile as well as a large spectral bandwidth that allows for control over the temperal structure of the pulse. A challenge, however, is in energy scaling of this HCHG technique to the ~1-20 μJ pulses required for photocathode applications. To-date, the pulse energies used in published HCHG work are sub-10-nJ. This project proposed to explore ways to generate higher-energy pulses using HCHG, as well as to investigate spectral and temporal shaping of the deep UV pulses by pulse shaping the infrared laser used to seed the process. Although we showed that our approach works for generating light at 259 nm, the total pulse energy achieved seems limited to approximately the same value as past work. However, the techniques we investigated may well have benefits for extending this source to much shorter wavelength output.

43 PARTICLE ACCELERATORS↗
NASA NTRS1982

ANS spectrophotometry - The bright X-ray binaries Hercules X-1 /HZ Herculis/ and Cygnus X-1 /HDE 226868/

Complete ultraviolet light curves for HZ Her immediately after a well-defined X-ray turn-on in 1975 are obtained. The features of the curve are found to correspond well with features seen in the optical. The absolute level of emission at maximum light at 1550 A is in good agreement with the calculations of the X-ray reflection effect of Milgrom and Salpeter (1975). It is found that at 1550 A approximately 20% of the light at maximum comes from the accretion disk. Similar observations of Cyg X-1 make it possible to determine the degree of reddening, equivalent to E(B-V) = 0.95 + or - 0.07, from the strength of the 2200 A interstellar absorption feature. The distance inferred from this amount of reddening requires that the optical star be luminous and, therefore, massive. Observations obtained during the May 1975 X-ray transition show ultraviolet excess when compared with the data obtained six months later.

Wu, C.-C.↗
NASA NTRS1979

Qualitative and quantitative flow visualization technique using ozone

The paper describes a new flow-visualization technique based on the absorption of ultraviolet light by ozone. Ozone is an excellent tracer, because as a gas it has the same effective physical properties as air. Ozone strongly absorbs the principal line (253.7 nm) of a mercury lamp, so that when an ozone-traced flow passes between a mercury lamp and a fluorescent screen, a sharp, shadow-like image of the ozone tracer is cast on the screen. Quantitative photometry can be carried out by replacing the screen with ultraviolet detectors that yield the path-integrated column density of ozone in the flow. High-speed quantitative point monitoring (10 Hz at 10 ppb O3) is possible with capillary probes and chemiluminescent analysis.

Dickerson, R. R.↗