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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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158 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

High Efficiency Multijunction Devices: Solar Cells, Thermophotovoltaics, LEDs

High-efficiency III-V multijunction solar cells require multiple alloys with optimal bandgaps and excellent material quality. However, many useful alloys are lattice-mismatched to available substrates, and require strain-engineering tricks to enable efficient use. To this extent, we have developed low-dislocation density metamorphic material and optically-thick stress-balanced superlattices, enabling access to a wide variety of III-V alloys. Combined with transparent tunnel junctions, these components allow optimizing multijunction devices for a variety of applications. We have designed multijunction cells for the G173G-terrestrial and AM0-space spectra with record 39.5% and 34.2% efficiency, respectively, and also thermophotovoltaic cells for blackbody spectra that reach over 40% TPV-efficiency. Finally, using these PV components, we demonstrate a multijunction LED with high quantum efficiency.

high-efficiency↗
DOE OSTI2015

Criticality safety analysis of spent fuel storage or handling disposals using burnup credit - loading curve calculation - 14445

MILLENNIUM and REEL SAS Companies have shared their own experience to develop a neutron and criticality calculations chain in order to perform isotopic composition predictions of spent fuel after irradiation in a reactor and criticality analysis of fuel storages taking into account burnup credit. The whole calculation sequence is divided into three steps, all calling SCALE 6.1.2 modules. The first two steps are dedicated to the evaluation of isotopic compositions of burnt fuel. As transport and depletion calculations in three dimensions appears to be way too long for the whole core (about several months), dealing with each fuel assembly one by one is the alternative solution MILLENNIUM and REEL SAS commonly chose to study. Therefore, the first step aims at determining the axial burnup profile of a given fuel assembly using a 3-D model with infinite reflections on lateral axes. The T6-depl sequence of TRITON module coupling KENO-VI and ORIGEN-S was used in this step. Sensitivity studies confirmed that addition of the 8 closest neighbors of the studied fuel assembly in the model has an insignificant impact on the axial burnup profile. However, fuel assemblies in the peripheral zone of the core must be treated separately with a model including the nearest fuel assemblies and the effect of peripheral water. Then, the second phase evaluates the isotopic compositions of each fuel assemblies at the center of the active height with a 2-D model under conservative core conditions. The T-depl sequence of the TRITON module coupling NEWT to ORIGEN-S is called in this step. Each fuel assembly must be studied separately to consider loading pattern changes occurring at each cycle. An infinite model with reflections on lateral axes is used and the closest neighbors of the fuel assembly are limited to 2 pins - which is around the size of the neutrons mean free path in the core. This is an innovative physical trick aiming at compensating for a limited computing power. Finally, isotopic compositions calculated are combined with the axial burnup profile of the first step to extrapolate the concentrations along the whole active length. Data can then be added in any criticality model, such as a spent fuel pit or any disposal handling fuel assemblies. Criticality analyses of burnt fissile material using burnup credit can be managed within a reasonable amount of time, on condition that sufficient proofs of code qualification for the studied range of parameters are provided, especially on fission products isotopic compositions calculation. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Aqueous Carbon Capture Using Guanidinium-Functionalized Hollow Fiber Sorbent Contactors

As part of the growing suite of technologies aimed at combatting rising temperatures, negative emissions technologies have become a powerful tool in the global effort to minimize the consequences of human-induced climate change. Among these, carbon removal from aqueous sources, which contain much higher carbon concentrations than the atmosphere, remains largely unexplored. Indeed, developing robust and efficient carbon capture materials for usage in complex aqueous environments remains a significant challenge. Here, we explore the potential of functionalizing polyvinylidene fluoride (PVDF) hollow fiber contactors grafted with a guanidinium-derived polymer sorbent for carbon removal from aqueous sources, including saline waters. Computational screening against amine-based analogs is utilized to identify guanidinium as a promising motif for bicarbonate (HCO 3 – ) ions binding. To leverage this finding, synthesis of a guanidinium polymer and subsequent covalent grafting onto PVDF hollow fibers is employed to structured polymer–sorbent–grafted hollow fiber contactors. Our prototype achieves an initial HCO 3 – removal of 34% with an increase to 98% after four cycles. The functionalized fibers demonstrate aqueous stability over 13 adsorption/desorption cycles in model NaHCO 3 solutions where regeneration is facilitated by a mild pH swing. Importantly, the system maintains selective performance in the presence of competitive chloride ions over multiple cycles; carbon removal remained above 10% even at high (10:1) NaCl/NaHCO 3 ratios. These findings demonstrate the feasibility of sorbent-based aqueous carbon removal and highlight its potential as a promising approach for negative emissions.

carbon capture↗
DOE OSTI2022

Entanglement between two gravitating universes

Abstract We study two disjoint universes in an entangled pure state. When only one universe contains gravity, the path integral for the n th Rényi entropy includes a wormhole between the n copies of the gravitating universe, leading to a standard ‘island formula’ for entanglement entropy consistent with unitarity of quantum information. When both universes contain gravity, gravitational corrections to this configuration lead to a violation of unitarity. However, the path integral is now dominated by a novel wormhole with 2 n boundaries connecting replica copies of both universes. The analytic continuation of this contribution involves a quotient by Z n replica symmetry, giving a cylinder connecting the two universes. When entanglement is large, this configuration has an effective description as a ‘swap wormhole’, a geometry in which the boundaries of the two universes are glued together by a ‘swaperator’. This description allows precise computation of a generalized entropy-like formula for entanglement entropy. The quantum extremal surface computing the entropy lives on the Lorentzian continuation of the cylinder/swap wormhole, which has a connected Cauchy slice stretching between the universes—a realization of the ER = EPR idea. The new wormhole restores unitarity of quantum information.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Dynamical heating across the Milky Way disc using APOGEE and Gaia

Abstract The kinematics of the Milky Way disc as a function of age are well measured at the solar radius, but have not been studied over a wider range of Galactocentric radii. Here, we measure the kinematics of mono-age, mono-[Fe/H] populations in the low and high [α/Fe] discs between 4 ≲ R ≲ 13 kpc and |z| ≲ 2 kpc using 65 719 stars in common between APOGEE DR14 and Gaia DR2 for which we estimate ages using a Bayesian neural network model trained on asteroseismic ages. We determine the vertical and radial velocity dispersions, finding that the low and high [α/Fe] discs display markedly different age–velocity dispersion relations (AVRs) and shapes σz/σR. The high [α/Fe] disc has roughly flat AVRs and constant σz/σR = 0.64 ± 0.04, whereas the low [α/Fe] disc has large variations in this ratio that positively correlate with the mean orbital radius of the population at fixed age. The high [α/Fe] disc component’s flat AVRs and constant σz/σR clearly indicate an entirely different heating history. Outer disc populations also have flatter radial AVRs than those in the inner disc, likely due to the waning effect of spiral arms. Our detailed measurements of AVRs and σz/σR across the disc indicate that low [α/Fe], inner disc ($R \lesssim 10\, \mathrm{kpc}$) stellar populations are likely dynamically heated by both giant molecular clouds and spiral arms, while the observed trends for outer disc populations require a significant contribution from another heating mechanism such as satellite perturbations. We also find that outer disc populations have slightly positive mean vertical and radial velocities likely because they are part of the warped disc.

Mackereth, J. Ted↗
DOE OSTI2023

Bacterium-enabled transient gene activation by artificial transcription factors for resolving gene regulation in maize

Abstract Understanding gene regulatory networks is essential to elucidate developmental processes and environmental responses. Here, we studied regulation of a maize (Zea mays) transcription factor gene using designer transcription activator-like effectors (dTALes), which are synthetic Type III TALes of the bacterial genus Xanthomonas and serve as inducers of disease susceptibility gene transcription in host cells. The maize pathogen Xanthomonas vasicola pv. vasculorum was used to introduce 2 independent dTALes into maize cells to induced expression of the gene glossy3 (gl3), which encodes a MYB transcription factor involved in biosynthesis of cuticular wax. RNA-seq analysis of leaf samples identified, in addition to gl3, 146 genes altered in expression by the 2 dTALes. Nine of the 10 genes known to be involved in cuticular wax biosynthesis were upregulated by at least 1 of the 2 dTALes. A gene previously unknown to be associated with gl3, Zm00001d017418, which encodes aldehyde dehydrogenase, was also expressed in a dTALe-dependent manner. A chemically induced mutant and a CRISPR-Cas9 mutant of Zm00001d017418 both exhibited glossy leaf phenotypes, indicating that Zm00001d017418 is involved in biosynthesis of cuticular waxes. Bacterial protein delivery of dTALes proved to be a straightforward and practical approach for the analysis and discovery of pathway-specific genes in maize.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

W3 Is a New Wax Locus That Is Essential for Biosynthesis of β-Diketone, Development of Glaucousness, and Reduction of Cuticle Permeability in Common Wheat

The cuticle plays important roles in plant development, growth and defense against biotic and abiotic attacks. Crystallized epicuticular wax, the outermost layer of cuticle, is visible as white-bluish glaucousness. In crops like barley and wheat, glaucousness is trait of adaption to the dry and hot cultivation conditions, and hentriacontane-14,16-dione (β-diketone) and its hydroxy derivatives are the major and unique components of cuticular wax in the upper parts of adult plants. But their biosynthetic pathway and physiological role largely remain unknown. In the present research, we identified a novel wax mutant in wheat cultivar Bobwhite. The mutation is not allelic to the known wax production gene loci W1 and W2, and designated as W3 accordingly. Genetic analysis localized W3 on chromosome arm 2BS. The w3 mutation reduced 99% of β-diketones, which account for 63.3% of the total wax load of the wild-type. W3 is necessary for β-diketone synthesis, but has a different effect on β-diketone hydroxylation because the hydroxy-β-diketones to β-diketone ratio increased 11-fold in the w3 mutant. Loss of β-diketones caused failure to form glaucousness and significant increase of cuticle permeability in terms of water loss and chlorophyll efflux in the w3 mutant. Transcription of 23 cuticle genes from five functional groups was altered in the w3 mutant, 19 down-regulated and four up-regulated, suggesting a possibility that W3 encodes a transcription regulator coordinating expression of cuticle genes. Biosynthesis of β-diketones in wheat and their implications in glaucousness formation and drought and heat tolerance were discussed.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

A path integral ground state Monte Carlo algorithm for entanglement of lattice bosons

A ground state path integral quantum Monte Carlo algorithm is introduced that allows for the study of entanglement in lattice bosons at zero temperature. The Rényi entanglement entropy between spatial subregions is explored across the phase diagram of the one dimensional Bose-Hubbard model for systems consisting of up to L=256 L = 256 sites at unit-filling without any restrictions on site occupancy, far beyond the reach of exact diagonalization. The favorable scaling of the algorithm is demonstrated through a further measurement of the Rényi entanglement entropy at the two dimensional superfluid-insulator critical point for large system sizes, confirming the existence of the expected entanglement boundary law in the ground state. The Rényi estimator is extended to measure the symmetry resolved entanglement that is operationally accessible as a resource for experimentally relevant lattice gases with fixed total particle number.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

The Effects of Iron Complexing Ligands on the Long Term Ecosystem Response to Iron Enrichment of HNLC waters (Final Activity Report)

Substantial increases in the concentrations of the stronger of two Fe(III) complexing organic ligand classes measured during the mesoscale Fe enrichment studies IronEx II and SOIREE appeared to sharply curtailed Fe availability to diatoms and thus limited the efficiency of carbon sequestration to the deep. Detailed observations during IronEx II (equatorial Pacific Ocean) and SOIREE (Southern Ocean –Pacific sector) indicate that the diatoms began re-experiencing Fe stress even though dissolved Fe concentrations remained elevated in the patch. This surprising outcome likely is related to the observed increased concentrations of strong Fe(III)-complexing ligands in seawater. Preliminary findings from other studies indicate that diatoms may not readily obtain Fe from these chemical species whereas Fe bound by strong ligands appears to support growth of cyanobacteria and nanoflagellates. The difficulty in assessing the likelihood of these changes with in-situ mesoscale experiments is the extended monitoring period needed to capture the long-term trajectory of the carbon cycle. A more detailed understanding of Fe complexing ligand effects on long-term ecosystem structure and carbon cycling is essential to ascertain not only the effect of Fe enrichment on short-term carbon sequestration in the oceans, but also the potential effect of Fe enrichment in modifying ecosystem structure and trajectory.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Action-based dynamical modeling for the Milky Way disk

We present RoadMapping, a full-likelihood dynamical modeling machinery that aims to recover the Milky Way’s (MW) gravitational potential from large samples of stars in the Galactic disk. RoadMapping models the observed positions and velocities of stars with a parameterized, three-integral distribution function (DF) in a parameterized axisymmetric potential. We investigate through differential test cases with idealized mock data how the breakdown of model assumptions and data properties affect constraints on the potential and DF. Our key results are: (i) If the MW’s true potential is not included in the assumed model potential family, we can—in the axisymmetric case—still find a robust estimate for the potential, with only ≲10% difference in surface density within |z|⩽1.1 kpc inside the observed volume. (ii) Modest systematic differences between the true and model DF are inconsequential. E.g., when binning stars to define sub-populations with simple DFs, binning errors do not affect the modeling as long as the DF parameters of neighboring bins differ by <20%. In addition, RoadMapping ensures unbiased potential estimates for either (iii) small misjudgements of the spatial selection function (i.e., ≲15% at the survey volume’s edge), (iv) if distances are known to within 10%, or (v) if proper motion uncertainties are known within 10% or are smaller than δμ≲1 mas yr{sup −1}. Challenges are the rapidly increasing computational costs for large sample sizes. Overall, RoadMapping is well suited to making precise new measurements of the MW’s potential with data from the upcoming Gaia releases.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Action-based Dynamical Modeling for the Milky Way Disk: The Influence of Spiral Arms

RoadMapping is a dynamical modeling machinery developed to constrain the Milky Way’s (MW) gravitational potential by simultaneously fitting an axisymmetric parametrized potential and an action-based orbit distribution function (DF) to discrete 6D phase-space measurements of stars in the Galactic disk. In this work, we demonstrate RoadMapping's robustness in the presence of spiral arms by modeling data drawn from an N-body simulation snapshot of a disk-dominated galaxy of MW mass with strong spiral arms (but no bar), exploring survey volumes with radii 500 pc⩽r{sub max}⩽5 kpc. The potential constraints are very robust, even though we use a simple action-based DF, the quasi-isothermal DF. The best-fit RoadMapping model always recovers the correct gravitational forces where most of the stars that entered the analysis are located, even for small volumes. For data from large survey volumes, RoadMapping finds axisymmetric models that average well over the spiral arms. Unsurprisingly, the models are slightly biased by the excess of stars in the spiral arms. Gravitational potential models derived from survey volumes with at least r{sub max}=3 kpc can be reliably extrapolated to larger volumes. However, a large radial survey extent, r{sub max}∼5 kpc, is needed to correctly recover the halo scale length. In general, the recovery and extrapolability of potentials inferred from data sets that were drawn from inter-arm regions appear to be better than those of data sets drawn from spiral arms. Our analysis implies that building axisymmetric models for the Galaxy with upcoming Gaia data will lead to sensible and robust approximations of the MW’s potential.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1969

Networks

Network analysis program using computerized optimization for designing broadband matched systems

Mayeda, W.↗
NASA NTRSDate not supplied

Enabling Simulation Interoperability between International Standards in the Space Domain

Today, the design and development of space systems are conducted cooperatively by historical space agencies in this area such as NASA, ESA, Roscosmos, and JAXA together with their industrial partners. The space system lifecycle is characterized by high costs, uncertain conditions, and dangerous scenarios. To mitigate these issues, space agencies rely heavily on Modelling and Simulation as a key technology to support the analysis, design, and operation of space systems. To support large-scale distributed simulations, the scientific community has developed several standards to support the reuse and interoperability of simulation models such as IEEE 1516 High-Level Architecture (HLA), Real-time Platform Reference Federation Object Model (RPR FOM), Simulation Model Portability (SMP), and the novel Space Reference Federation Object Model (SpaceFOM). While the SpaceFOM standard has been specifically conceptualized for handling space systems, the other ones are more general-purpose and can be used to design and simulate generic complex systems. As a consequence, there is a lake of rules and guidelines to enable interoperability among these standards. The paper presents solutions and experiences for enabling interoperability and transferability of HLA, RPR FOM, and SMP simulation models with SpaceFOM.

Simulation↗