The sudden approximation applied to molecular problems. I - Non-reactive collisions
Sudden approximation for calculating transition probabilities for energy transfer during collisions between molecules and atoms
ATOMIC COLLISION↗
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Theory of atomic transitions
Transition probabilities of atomic collisions, elastic scattering of electrons, and excitation functions
ELECTRON COLLISION↗
Atomic spectroscopy with the shock tube
Spectroscopy of light atoms and ions and transition probability determinations using gas-driven shock tube
GAS SPECTROSCOPY↗
Sudden approximation applied to rotational excitation of molecules by atoms. ii- scat- tering of polar diatomics
Sudden approximation applied to computation of rotational transition probability and inelastic total cross sections for scattering of polar and nonpolar diatomic molecules by atoms
SCATTERING↗
Sudden approximation applied to rotational excitation of molecules by atoms. II - Scattering of polar diatomics.
Sudden approximation applied to rotational transition probabilities and inelastic total cross sections for scattering of homonuclear diatomic molecules by atoms
SCATTERING CROSS SECTION↗
Direct measurements of predissociation probabilities in CH and CD molecules.
CH and CD molecule predissociation probabilities measured directly and compared with radiative transition probability
Hesser, J. E.↗
Unidentified lines in molecular clouds and a search for C-14 in IRC +10216
Two spectral features have been detected toward the Kleinmann-Low infrared nebula in Orion that agree in frequency with the 7(25)-7(16) and 7(35)-7(26) rotational transitions of the ring-structured molecule ethylene oxide (CH2)2O. A feature agreeing in frequency with the 8(24)-8(45) transition probably also was detected; however, seven other transitions in (CH2)2O were not. Additional unidentified lines were detected in Ori A and Sgr B2. Searches for H(C-14)N and (C-14)O in the luminous carbon star IRC +10216 were unsuccessful. However, an unidentified line was found in IRC +10216 that was not detected in the KL nebula.
Kuiper, E. N. R.↗
Shuttle glow emissions due to radiative relaxation of highly vibrationally excited NO molecules produced by surface reflection
A new mechanism is proposed for the Space Shuttle glow, which is due to the radiative relaxation of ambient nitric-oxide molecules that are excited to very high vibrational levels by collisions with the Shuttle surface. Many of the particles colliding with the Shuttle surface at a very high speed (about 8 km/sec) would bounce off, exciting vibrational and rotational motions of molecules up to the level of vibrational quantum number v not greater than 35. Radiative transfer from these high levels should cause emissions in the spectrum range from infrared (IR) to visible red depending upon the transition paths. A perturbation method is used to calculate the transition probability and the emission intensity for the transitions of Delta-v not greater than 4. The result indicates that the Delta-v not greater than 4 transitions from high vibrational levels dominates the other transitions; the Delta-v = 4 transitions generally occur at the IR range.
Shimazaki, T.↗
Vibrational relaxation and dissociation in nitrogen
Calculations of the vibrational and dissociation transition probabilities are made for N2-N2 and N2-N collisions by means of a semiclassical N-state approximation. The flaws in previous techniques are reviewed, with special attention given to the prediction of overtones. The method presented ignores the effects of molecular rotation and employs a revised extended Rydberg intermolecular potential to describe diatom-diatom and diatom-atom collisions. The collision velocities investigated exhibit probabilities of less than unity by means of the N-state method. The continuum is quantized to treat dissociation, and the collision results demonstrate probability enhancements for V-V-T transitions in both bound-bound and bound-free transitions. The technique is of particular interest for the theoretical modeling of reentry flows such as those encountered in aerobraking maneuvers.
Varghese, Philip L.↗
Quantum Choreography of the Nucleus: Rotations, Vibrations, and Emergent Structure
Abstract Nuclei are complex many-body quantum systems where interactions of the neutrons and protons via the strong, the weak, and the electromagnetic forces lead to the emergence of simple patterns of energy states that have been described by various theoretical approaches. One of the goals of all the theoretical models is the development of a universal theory that can be applied across the entire chart of nuclides. Significant progress has been made by experiments as well as the increasing sophistication of models, but a universal theory has yet to be established. A recent review of nuclei in the Z = 50–82 region of the chart of nuclides has analyzed all the available compiled data from several decades of studies towards a clarification of the low-lying structure of nuclei. Other reviews have reported and explained the emergence of multiple different shapes in nuclei at somewhat higher excitation energies than the ground state. Some have challenged the interpretation of the first excited K π = 0 + band as a vibration of ground state. This work attempts to provide a guide to determining the nature of the first excited K π = 0 + band in nuclei by the combined use of nuclear lifetimes, energy level evolutions, dynamic moments of inertia, and intrinsic quadrupole moments extracted from transition probabilities. The result is that for a subset of the nuclei in this region, the K π = 0 + band is consistent with the traditional 𝛽-vibration description of an oscillation built on the ground state.
CHFB+5DCH↗
The oscillator strengths of the SO /A 3Pi/-/X 3Sigma-/ band systems.
The oscillator strengths for these SO transition band systems are calculated using RKR Franck-Condon factors and the radiative lifetime previously derived from electron-beam phase-shift measurements by Smith (1971). The SO transition concerned is of considerable astrophysical importance in the search for SO in the interstellar medium by means of space-based telescopes with monochromators since the transition probability is concentrated, as shown, in relatively few transitions from the ground state.
Smith, W. H.↗
Theoretical study of the spectroscopy of ZrO
The absorption bands of ZrO have been observed in stars, particularly S stars. Here, theoretical transition probabilities are presented for the dipole-allowed transitions between the six lowest singlet and triplet states of ZrO. The results should be sufficiently reliable to provide opacity data for use in modeling stellar atmospheres. The theoretical radiative lifetime for the e 3Pi state is less than the experimental value as measured by the decay of resonant fluorescence. However, the theoretical electronic transition moments for the gamma system and the B 1Pi - X 1Sigma(+) system are much smaller than those deduced from emission studies. The calculated lifetime for the C 1Sigma(+) state is in excellent agreement with the laser-induced fluorescence studies. The as yet unobserved E 1Phi - A 1Delta band system is found to be relatively strong.
Langhoff, Stephen R.↗
Choice of gauge in 2-photon 1s-2s transition in atomic hydrogen and pseudostate expansions
The problem of gauge choice in multiphoton transitions in connection with the proper choice of the unperturbed wave functions require to insure gauge invariance was considered. J. Bassani, J. J. Forney, and A. Quattropani considered the case of 2-photon 1s-2s transition rate for hydrogen, using gauges vector E x vector r and vector A x vector p. Exactly the same results were obtained for the two gauges, but the findings indicate that the vector E x vector r interaction tends to the final result with a small number of intermediate states and is therefore the one to be used in any approximate calculation. Whether the so-called pseudostate expansion method works equally well with either gauge was tested. To accomplish this task, in addition to researching the problem, the FORTRAN programming was learned and a FORTRAN program was constructed for the calculation of the dimensionless 2-photon transition probability amplitude D(v) for 1s-2s transition in Hydrogen as a function as a function of the incident photon frequency v in gauge vector E x vector p at certain values of v, using the pseudostate method. However, some puzzling unresolved difficulties were experienced in the calculation. Then should the pseudostate calculations prove successful for gauge vector E x vector r the method will be applied to gauge vector A x vector p. If successful, then the problem is complete.
Shabazz, Abdulalim A.↗
Oscillator Strengths of Allowed and Intercombination Transitions in Neutral Sulfur
We have calculated oscillator strengths and transition probabilities of electric-dipole allowed and intercombination transitions from fine-structure levels of the ground 3s(sup 2)3p(sup 4) configuration to the levels belonging to configurations 3s(sup 2)3p(sup 3)4s, 3s(sup 2) 3p(sup 3)5s, 3(sup 2)3p(sup 3)3d, 3s(sup 2)3p(sup 3)4d of neutral sulfur. Extensive configuration-interaction wave functions are used to represent these levels. The relativistic corrections have been included through the Breit-Pauli Hamiltonian. The results are compared with previous theoretical calculations and with measurements.
Tayal, S. S.↗
High energy particle production from proton synchrotron radiation in strong magnetic fields in relativistic quantum field theory
We investigate photon, pion, and 𝜌-meson production from proton synchrotron radiation in the presence of strong magnetic fields. The proton decay widths and the luminosities of the emitted particles are calculated within a relativistic quantum framework that incorporates Landau quantization. A scaling rule is derived for the transition probability between different Landau levels. This allows an evaluation of transitions for extremely high Landau numbers exceeding 10 15 . Furthermore, we calculate the momentum distribution of the emitted particles by properly including the proton recoil effect associated with particle emission. The results differ significantly from conventional semiclassical approaches.
Cosmic ray sources↗
Evaluation of atomic constants for optical radiation, volume 1
Atomic constants for optical radiation are discussed which include transition probabilities, line strengths, and oscillator strengths for both dipole and quadrupole transitions, as well as the associated matrix elements needed for line broadening calculations. Atomic constants were computed for a wide selection of elements and lines. An existing computer program was used, with modifications to include, in an approximate manner, the effect of equivalent electrons, and to enable reordering and restructuring of the output for publication. This program is suitable for fast, low cost computation of the optical constants, using the Coulomb approximation formalism for LS coupling.
Kylstra, C. D.↗
Optogalvanic spectrum of argon in the visible wavelength region 4150-6700 A
Optogalvanic spectrum of argon has been investigated in the visible wavelength region 4150-6700 A by axially irradiating a hollow cathodic discharge with an excimer pumped dye laser. About 180 transitions have been recorded and a majority of them have been identified using the Jl-coupling scheme. The optogalvanic spectrum in the regions 4300-5300 and 6010-6700 A is being reported in detail for the first time. The optogalvanic signal intensities are found to agree with atomic transition probabilities. A technique has been discussed to record a maximum number of transitions in optogalvanic effect.
Reddy, B. R.↗
Impact of the continuum on the γ decay of the lowest 2 + states in 14 C
The half-life, T 1/2 =14.6(33) fs, of the 7012-keV 2$^{+}_{1}$ state in 14 C was measured in an experiment employing the 9 Be( 6 Li,pγ) fusion-evaporation reaction and the GODDESS setup. The γ decay from the 2$^{+}_{2}$ near-threshold resonance, located 142 keV above the 8176-keV neutron-emission threshold, was also investigated. An upper limit of 4.0 × 10 –5 was established for the γ-decay branching ratio with respect to the neutron-decay channel. The B(E2) transition probabilities for these 2$^{+}_{1}$ and 2$^{+}_{2}$ states were compared to predictions from the Shell Model Embedded in the Continuum (SMEC). Significant modifications of these B(E2) probabilities, with respect to the standard shell model, are expected due to the coupling to the continuum. For calculations using the YSOX interaction, agreement was found for large negative values of V 0 , the coupling constant to the continuum. The central value V 0 = −645 MeV fm 3 results in a retardation by a factor ∼ 3.5 for the 2$^{+}_{1}$ → 0$^{+}_{1}$ transition, and an enhanced probability by a factor ∼ 2.5 for the γ-decay out of the 2$^{+}_{2}$ state. The latter factor reflects the effect of collectivization of the 2$^{+}_{2}$ excitation when the coupling to the continuum is taken into account.
14C↗