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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Electron Transfer Dissociation of All Ions at All Times, MS{sup ETD}, in a Quadrupole Time-of-Flight (Q-ToF) Mass Spectrometer

Data-independent mass spectral acquisition is particularly powerful when combined with ultra-performance liquid chromatography (LC) that provides excellent separation of most components present in a given sample. Data-independent analysis (DIA) consists of alternating full MS scans and scans with fragmentation of all ions within a selected m/z range, providing precursor masses and structure information, respectively. Fragmentation spectra are acquired either by sequential isolation and fragmentation of sliding m/z ranges or fragmenting all ions entering the MS instrument with no ion isolation, termed broadband DIA. Previously, broadband DIA has only been possible using collision induced dissociation (CID). Here, we report the use of electron transfer dissociation (ETD) as the fragmentation technique in broadband DIA instead of traditional collision induced dissociation (CID) during MS{sup E}. In this approach, which we refer to as MS{sup ETD}, we implement the inherent benefits provided by ETD, such as discrimination of leucine and isoleucine, in a DIA setup. The combination of DIA analysis and ETD fragmentation with supplemental CID energy provides a powerful platform to obtain information on all precursors and their sequence from a single experiment. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2017

TOF MS Investigation of Nickel Oxide CVD

NiO layers were deposited by metal-organic chemical vapor deposition using bis-(ethylcyclopentadienyl) nickel (EtCp){sub 2}Ni and oxygen or ozone. As a continuation of kinetic study of NiO MOCVD the gas-phase, transformations of (EtCp){sub 2}Ni were studied in the temperature range of 380–830 K. Time of reactions corresponding to the residence time of the gas stream in hot zone of the reactor was about 0.1 s under conditions studied. The interaction of (EtCp){sub 2}Ni with oxygen started at 450 K and its conversion rate reached the maximum at 700 K. The interaction of (EtCp){sub 2}Ni with ozone started at 400 K and its conversion rate reached the maximum at 600 K. Transformations of the gas phase with the temperature in the reaction zone were studied, the model reaction schemes illustrating (EtCp){sub 2}Ni transformations in the reaction systems containing oxygen and ozone have developed. In the reaction system (EtCp){sub 2}Ni–O{sub 2}–Ar the main gas-phase products at 380–500 K were CO, CO{sub 2}, HCO, C{sub 2}H{sub 5}OH, CpCOOH, and CpO. Formation of the C{sub 2}H{sub 2}O, C{sub 3}H{sub 4}O, and C{sub 5}H{sub 8}O was found at 630–830 K. The same gas-phase species, (C{sub 4}H{sub 3}O){sub 2}Ni and dialdehydes was formed in the reaction system (EtCp){sub 2}Ni–O{sub 3}–O{sub 2}–Ar. .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

ToF-SIMS Depth Profiling of Organic Delta Layers with Low-Energy Cesium Ions: Depth Resolution Assessment

The advent of cluster ion beams has paved the way to the routine 3D analysis of organic heterojunctions. Alternatively, organic thin layers have also been successfully depth profiled with a low-energy cesium ion beam (Cs{sup +}), to exploit the high chemical reactivity of cesium atoms, acting as free-radical scavengers. Despite of this, little is known about the depth resolution associated with low-energy Cs{sup +} sputtering on organic multilayers. In this work, amino acids multilayers, consisting of phenylalanine delta layers alternated with tyrosine spacers, were used as model systems to assess the depth resolution associated with 500 eV Cs{sup +} depth profiles. High yields were obtained for quasi-molecular ions from both amino acids, and no significant chemical alteration was noticed under the monoatomic bombardment. A depth resolution as low as 4 nm is demonstrated without sensible degradation on a rather long profile depth (300 nm). Limited depth resolution (> 10 nm) along with high molecular degradation was previously reported on similar systems by combining low-energy Cs{sup +} with Ga{sup +} analysis beam. The use of the Bi{sub 3}{sup +} analysis beam results in a dramatic improvement of both the characteristic molecular signal intensities and the depth resolution. Even though the analysis beam fluence is very low compared to the sputtering beam fluence, data suggest that further reducing the analysis Bi{sub 3}{sup +} fluence could improve the depth resolution by ~ 1 nm. .

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2019

MeV-SIMS TOF Imaging of Organic Tissue with Continuous Primary Beam

MeV-SIMS is an emerging mass spectrometry imaging method, which utilizes fast, heavy ions to desorb secondary molecules. High yields and low fragmentation rates of large molecules, associated with the electronic sputtering process, make it particularly useful in biomedical research, where insight into distribution of organic molecules is needed. Since the implementation of MeV-SIMS in to the micro-beam line at the tandem accelerator of Jožef Stefan Institute, MeV-SIMS provided some valuable observations on the distribution of biomolecules in plant tissue, as discussed by Jenčič et al. (Nucl. Inst. Methods Phys. Res. B. 371, 205–210, 2016; Nucl. Inst. Methods Phys. Res. B. 404, 140–145, 2017). However, limited focusing ability of the chlorine ion beam only allowed imaging at the tissue level. In order to surpass shortcomings of the existing method, we introduced a new approach, where we employ a continuous, low-current primary beam. In this mode, we bombard thin samples with a steady chlorine ion flux of approx. 5000 ions/s. After desorbing molecules, chlorine ions penetrate through the thinly cut sample and trigger the time-of-flight “start” signal on a continuous electron multiplier detector, positioned behind the sample. Such bombardment is more effective than previously used pulsing-beam mode, which demanded several orders of magnitude higher primary ion beam currents. Sub-micrometer focusing of low-current primary ion beam allows imaging of biological tissue on a subcellular scale. Simultaneously, new time-of-flight acquisition approach also improves mass resolution by a factor of 5. Within the article, we compare the performance of both methods and demonstrate the application of continuous mode on biological tissue. We also describe the thin sample preparation protocol, necessary for measurements with low primary ion currents. .

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2016

In-situ TOF neutron diffraction studies of cyclic softening in superelasticity of a NiFeGaCo shape memory alloy

Real-time in-situ neutron diffraction was conducted during uniaxial cycling compression of a Ni 49.3 Fe 18 Ga 27 Co 5.7 shape memory alloy to explore the mechanism on its superelasticity at room temperature, which was manifested by the almost recoverable large strains and the apparent cyclic softening. Based on the Rietveld refinements, the real-time evolution of volume fraction of martensite was in-situ monitored, indicating the incremental amount of residual martensite with increasing load cycles. Real-time changes in intensities and lattice strains of { hkl } reflections for individual phase were obtained through fitting individual peaks, which reveal the quantitative information on phase transformation kinetics as a function of grain orientation and stress/strain partitioning. Moreover, a large compressive residual stress was evidenced in the parent phase, which should be balanced by the residual martensite after the second unloading cycle. As a result, the large compressive residual stress found in the parent austenite phase may account for the cyclic effect on critical stress required for triggering the martensitic transformation in the subsequent loading.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Dynamic magnetic shield for the CLAS12 central TOF detector photomultiplier tubes

The Central Time-of-Flight detector for the Jefferson Laboratory 12-GeV upgrade is being designed with linear-focused photomultiplier tubes that require a robust magnetic shield against the CLAS12 main 5-T solenoid fringe fields of 100 mT (1 kG). Theoretical consideration of a ferromagnetic cylinder in an axial field has demonstrated that its shielding capability decreases with increasing length. This observation has been confirmed with finite element analysis using Poisson model software. Several shields composed of coaxial ferromagnetic cylinders have been studied. All difficulties caused by saturation effects were overcome with a novel dynamical shield, which utilizes a demagnetizing solenoid between the shielding cylinders. Basic dynamical shields for ordinary linear-focused 2-in. photomultiplier tubes were designed and tested both with models and experimental prototypes at different external field and demagnetizing current values. Our shield design reduces the 1 kG external axial field by a factor of 5000.

Source record↗
DOE OSTI2015

Stopping power measurements with the Time-of-Flight (ToF) technique

In our review of measurements of the stopping power of ions in matter is presented along with new measurements of the stopping powers of O, Si, Ti, and Au ions in self-supporting thin foils of SiO 2 , Nb 2 O 5 , and Ta 2 O 5 . Moreover, a Time-of-Flight system at the Ion Beam Materials Laboratory at the University of Tennessee, Knoxville, was used in transmission geometry in order to reduce experimental uncertainties. Finally, the resulting stopping powers show good precision and accuracy and corroborate previously quoted values in the literature. New stopping data are determined.

36 MATERIALS SCIENCE↗