Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “TCO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Critical Interface: Poly-Silicon to Tunneling SiO2 for Passivated Contact Performance

Environmental exposure of our thin tunneling SiO2 layer on nCz wafer samples prior to poly-Silicon (poly-Si) deposition critically impacts the resulting contact passivation. We present ToF-SIMS evidence of SiO2 oxide storage-induced degradation, presumably by surface contaminants such as carbon, in symmetric and device poly-Si/SiO2 lifetime samples as well as in finished cells. We also present methods to resurrect a contaminated SiO2 layer, including UV-O3 treatment prior to passivated contact formation to produce >21% TCO-free solar cells.

14 SOLAR ENERGY↗
DOE OSTI2020

Observation of interacting polaronic gas behavior in Ta-doped TiO 2 thin films via terahertz time-domain spectroscopy

Transparent conductive oxides (TCOs)—materials that have the twin desirable features of high optical transmission and electrical conductivity—play an increasingly significant role in the fields of photovoltaics and information technology. As an excellent TCO, Ta-doped anatase TiO 2 shows great promise for a wide range of applications. Here, terahertz time-domain spectroscopy is used to study the complex optical conductivity $\tilde{σ}$ (ω) of the TCO—heavily Ta-doped TiO 2 thin films with different Ta-doping concentrations, in the frequency range of 0.3–2.7 THz and the temperature range of 10–300 K. Fitting the complex optical conductivity to a Drude-like behavior allows us to extract the temperature dependence of the effective mass, which suggests the existence of many-body large polarons. Moreover, the carrier scattering rate of Ta-doped TiO 2 with different carrier concentrations agrees with the interacting polaron gas theory. Our results suggest that with increasing electron density in TiO 2 , the interaction between polarons is larger and electron–phonon coupling is smaller, which is beneficial for achieving high mobility and conductivity in TiO 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2015

Low-temperature high-mobility amorphous IZO for silicon heterojunction solar cells

Parasitic absorption in the transparent conductive oxide (TCO) front electrode is one of the limitations of silicon heterojunction (SHJ) solar cells efficiency. To avoid such absorption while retaining high conductivity, TCOs with high electron mobility are preferred over those with high carrier density. Here, we demonstrate improved SHJ solar cell efficiencies by applying high-mobility amorphous indium zinc oxide (a-IZO) as the front TCO. We sputtered a-IZO at low substrate temperature and low power density and investigated the optical and electrical properties, as well as subband tail formation-quantified by the Urbach energy (E U )-as a function of the sputtering oxygen partial pressure. We obtain an E U as low as 128 meV for films with the highest Hall mobility of 60 cm 2 /Vs. When comparing the performance of a-IZO films with indium tin oxide (ITO) and hydrogenated indium oxide (IO:H), we find that IO:H (115 cm 2 /Vs) exhibits a similar E U of 130 meV, while ITO (25 cm 2 /Vs) presents a much larger E U of up to 270 meV. The high film quality, indicated by the low E U , the high mobility, and low free carrier absorption of the developed a-IZO electrodes, result in a significant current improvement, achieving conversion efficiencies over 21.5%, outperforming those with standard ITO.

14 SOLAR ENERGY↗
DOE OSTI2015

An autotrophic H 2 -oxidizing, nitrate-respiring, Tc(VII)-reducing A cidovorax sp. isolated from a subsurface oxic-anoxic transition zone: H 2 -oxidizing, Tc-reducing Acidovorax spp.

Increasing concentrations of H 2 with depth were observed across a geologic unconformity and associated redox transition zone in the subsurface at the Hanford Site in south-central Washington, USA. An opposing gradient characterized by decreasing O 2 and nitrate concentrations was consistent with microbial-catalyzed biogeochemical processes. Sterile sand was incubated in situ within a multi-level sampler placed across the redox transition zone to evaluate the potential for Tc(VII) reduction and for enrichment of H 2 -oxidizing denitrifiers capable of reducing Tc(VII). H 2 -driven TcO 4- reduction was detected in sand incubated at all depths but was strongest in material from a depth of 17.1 m. Acidovorax spp. were isolated from H 2 -nitrate enrichments from colonized sand from 15.1 m, with one representative, strain JHL-9, subsequently characterized. JHL-9 grew on acetate with either O 2 or nitrate as electron acceptor (data not shown) and on medium with bicarbonate, H 2 and nitrate. JHL-9 also reduced pertechnetate (TcO 4- ) under denitrifying conditions with H 2 as the electron donor. H 2 -oxidizing Acidovorax spp. in the subsurface at Hanford and other locations may contribute to the maintenance of subsurface redox gradients and offer the potential for Tc(VII) reduction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Thermodynamic parameters for the complexation of technetium(IV) with EDTA

Technetium-99 is a high yield (~6% fission yield) fission product and long-lived (2.13×10 5 year half-life) component of nuclear waste that will be disposed of in a geological repository. Some 99 Tc has been released into the environment due to nuclear fuel and weapon production activities at sites such as Hanford, WA. Strongly complexing ligands such as ethylenediamine- N , N , N ', N '-tetraacetic acid (EDTA) are known to increase Tc(IV) solubility and mobility in environmental systems and an accurate quantification of the complexation of Tc(IV) with EDTA is important for predicting its behavior in a geological repository. A liquid–liquid extraction system utilizing 0.2 M TOPO in dodecane was used to measure the stability constants of Tc(IV)-EDTA in 0.50 m NaNO 3 at variable temperatures (14.0±0.1, 25.0±0.1, and 32.0±0.1°C). The acid dependence of the apparent stability constants in the p C H range of 2.00–2.70 indicated the formation of TcO(EDTA) 2- (log β 101 =17.9±0.3, 25.0±0.1°C) and a protonated complex TcO(H)(EDTA) - (log β 111 =20.5±0.1, 25.0±0.1°C). The associated thermodynamic parameters Δ r G 101 =-101.7±0.4 kJ·mol -1 , Δ r H 101 =-47±9 kJ·mol -1 , Δ r S 101 =179±36 J·mol -1 ·K -1 , Δ r G 111 =-117.2±0.3 kJ·mol -1 , Δ r H 111 =-23±5 kJ·mol -1 , and Δ r S 111 =315±63 J·mol -1 ·K -1 (0.50 m NaNO 3 , 25.0±0.1°C) were determined by van’t Hoff analysis. The formation of each Tc(IV)–EDTA complex is exothermic and present favorable entropy terms.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

Materials Science of Electrodes and Interfaces for High-Performance Organic Photovoltaics

The science of organic photovoltaic (OPV) cells has made dramatic advances over the past three years with power conversion efficiencies (PCEs) now reaching ~12%. The upper PCE limit of light-to-electrical power conversion for single-junction OPVs as predicted by theory is ~23%. With further basic research, the vision of such devices, composed of non-toxic, earth-abundant, readily easily processed materials replacing/supplementing current-generation inorganic solar cells may become a reality. Organic cells offer potentially low-cost, roll-to-roll manufacturable, and durable solar power for diverse in-door and out-door applications. Importantly, further gains in efficiency and durability, to that competitive with inorganic PVs, will require fundamental, understanding-based advances in transparent electrode and interfacial materials science and engineering. This team-science research effort brought together an experienced and highly collaborative interdisciplinary group with expertise in hard and soft matter materials chemistry, materials electronic structure theory, solar cell fabrication and characterization, microstructure characterization, and low temperature materials processing. We addressed in unconventional ways critical electrode-interfacial issues underlying OPV performance -- controlling band offsets between transparent electrodes and organic active-materials, addressing current loss/leakage phenomena at interfaces, and new techniques in cost-effective low temperature and large area cell fabrication. The research foci were: 1) Theory-guided design and synthesis of advanced crystalline and amorphous transparent conducting oxide (TCO) layers which test our basic understanding of TCO structure-transport property relationships, and have high conductivity, transparency, and tunable work functions but without (or minimizing) the dependence on indium. 2) Development of theory-based understanding of optimum configurations for the interfaces between oxide electrodes/interfacial layers and OPV active layer organic molecules/polymers. 3) Exploration and perfection of new processing strategies and cell architectures for the next-generation, large-area flexible OPVs. The goal has been to develop for the solar energy community the fundamental scientific understanding needed to design, fabricate, prototype, and ultimately test high-efficiency cells incorporating these new concepts. We achieved success in all of these directions.

14 SOLAR ENERGY↗
DOE OSTI2017

Characterization of Non-pertechnetate Species Relevant to the Hanford Tank Waste

Among radioactive constituents present in the tank waste stored at the U.S. DOE Hanford Site, technetium-99 (Tc), which is generated from the fission of 235 U and 239 Pu in high yields, presents a unique challenge in that it has a long half-life ( = 292 keV; T1/2 = 2.11105 y) and exists predominately in soluble forms in the liquid supernatant and salt cake fractions of the waste. In the strongly alkaline environments prevalent in most of the tank waste, its dominant chemical form is pertechnetate (TcO 4 - , oxidation state +7). However, attempts to remove Tc from the Hanford tank waste using ion-exchange processes specific to TcO 4 - only met with limited success, particularly when processing tank waste samples containing elevated concentrations of organic complexants. This suggests that a significant fraction of the soluble Tc can be present as low-valent Tc (oxidation state < +7) (non-pertechnetate). The chemical identities of these non-pertechnetate species are poorly understood. Previous analysis of the SY-101 and SY-103 tank waste samples provided strong evidence that non-pertechnetate can be comprised of [fac-Tc(CO) 3 ] + complexes containing Tc in oxidation state +1 (Lukens et al. 2004). During the last three years, our team has expanded this work and demonstrated that high-ionic-strength solutions typifying tank waste supernatants promote oxidative stability of the [fac-Tc(CO) 3 ] + species (Rapko et al. 2013a; 2013b; Levitskaia et al. 2014; Chatterjee et al. 2015). Obtained results also suggest possible stabilization of Tc(VI) and potentially Tc(IV) oxidation states in the high-ionic-strength alkaline matrices particularly in the presence of organic chelators, so that Tc(IV, VI) can serve as important redox intermediates facilitating the reduction of Tc(VII) to Tc(I). Designing strategies for effective Tc management, including separation and immobilization, necessitates understanding the molecular structure of the non-pertechnetate species and their identification in the actual tank waste samples, which would facilitate development of new treatment technologies effective for dissimilar Tc species. The key FY 2016 results are summarized below.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Quarternary amine-based sodalite sorbent for selective removal of Tc-99 and I-129

Technetium-99 and Iodine-129 are risk-driven contaminants of high priority to DOE-EM office. Both radionuclides are prevalent at DOE nuclear waste sites. Because these radionuclides greatly affect the catalytic redox extraction process of uranium and plutonium in the fuel cycle, their removal from spent nuclear solution is highly desirable for efficient recovery of uranium and plutonium, and mitigation of potential releases of these radionuclides to the environment. The goals of this project were to develop advance sorbents for simultaneous capture of Tc-99 and I-129 from contaminated groundwater and nuclear waste streams. This research examined modification of porous commercial and synthesized aluminosilicate minerals (zeolite) for enhanced retention of radionuclides. Herein we report the development of a sorbent that: (1) binds pertechnetate ($TcO_4^-$) with a sorption efficiency (Kd) greater than any other sorbent materials previously reported in literature, (2) exhibits fast sorption kinetics and (3) uptakes $TcO_4^-$ under acidic and oxidizing conditions where Tc-99 retention is problematic. Thus, the use of quaternary-amine modified mesoporous zeolite as an amendment and/or permeable reactive barrier would be a robust strategy for Tc-99 remediation. Moreover, further modification of the evaluated zeolite materials with silver is envisioned to promote effective retention of both Tc-99 and I-129 and this study was slated for fiscal year 2019.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Review of Experimental Decontamination Factors (DF) of Iodine in the Pilot-Scale Law Melter Off-Gas Systems

The Low Activity Waste (LAW) melters at the Hanford Tank Waste Treatment and Immobilization Plant (WTP) will convert low-activity tank wastes containing high concentrations of sodium salts into glass for onsite disposal. Much of the airborne particulates during the calcination/fusion of the feed solids will be removed by condensation and scrubbing of the melter exhaust in the Submerged Bed Scrubber (SBS) and Wet Electrostatic Precipitator (WESP)of the primary off-gas treatment system. The gases exiting the WESP enter a secondary off-gas treatment system, which includes a High-Efficiency Particulate Air (HEPA) filter, an activated carbon absorber, a Thermal Catalytic Oxidizer (TCO), a Selective Catalytic Reduction (SCR) unit, a caustic scrubber, and an exhauster. Much of the volatile organics and NOx will be removed in the TCO and SCR, respectively. Under WTP Direct Feed LAW (DFLAW) configuration, the liquid effluents from the SBS and WESP will be collected and evaporated under vacuum with the evaporator concentrate recycled back to the LAW melter, while the evaporator condensate will be merged with the caustic scrubber solution and sent to the Effluent Treatment Facility (ETF).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Intermediate Temperature Proton‐Conducting Solid Oxide Electrolysis Cells with Improved Performance and Durability

Technical understanding: A high-performance and stable intermediate temperature proton-conducting solid oxide electrolysis cell (PCEC) will add significantly to the hydrogen roadmap of EERE. However, the low electrocatalytic activity of the air electrode and the instability of the electrolyte are technical barriers. In this research, we utilized computational fluid dynamic modeling and materials/microstructure engineering to investigate the complex reaction chain and to improve the performance and reliability of the protonic ceramic electrochemical cells. An active and stable Pr 1.8 Ba 0.2 NiO 4+δ -BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3-δ (BZCYYb) scaffold conformal coating electrode was rationally designed where the robust Pr 1.8 Ba 0.2 NiO 4+δ functions both as a catalytic active and a protective layer. The PCECs with porosity-optimized scaffold conformal coating electrodes demonstrate 1.46 Acm -2 under 1.3 V at 600°C, which is among the highest in recent years. The final optimization by computational fluid dynamic modeling and conformal coating technique was applied to evolve the PCEC air electrode from Pr 2 NiO 4+δ to Pr 1.8 Ba 0.2 NiO 4+δ -BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3-δ scaffold conformal coating. The electrolysis current was boosted from 0.445A/cm 2 to 1.46A/cm 2 at 600°C and 1.3V. A superior low degradation rate of 1mV/kh was achieved in a 5000-hour of operation. Technical effectiveness and economic feasibility: The effectiveness of this TCO conformal coating on electrolyte backbone as air electrode has been proven by long-term demonstration. Based on the highly conductive BZCYYb electrolyte and the TCO steam electrode PNO, this project rationally took advantage of the existent materials to structure a PCEC device with high TRL and low risk. The solution infiltration method used to structure the conformal coating is a standard method used by the solid oxide cell community. Very minimal adoption is needed in the current SOC fabrication process. It is a cost-effective, scalable method for manufacturing, and brings up remarkable impact on the current technical status of PCEC. Benefit to the public: The findings in the research showed the industry that the severe challenge in PCEC can be overcome in a practical way. A various energy-hydrogen ecosystem is not beyond reach. The success of this technology provides sustainable and affordable H 2 to society. It will stimulate investment from the governmental and private sectors in response to the device manufacture and deployment, and the related infrastructure construction. It will generate high-pay domestic jobs and environmental benefits to the general public in the United States.

08 HYDROGEN↗
DOE OSTI2022

Performance and Total Cost of Ownership of a Fuel Cell Hybrid Mining Truck

The main objective of this work was to investigate the potential of hydrogen and fuel cells replacing diesel and internal combustion engines in the ultraclass haul trucks deployed in the mining sector. Performance, range, durability, and cost are the main criteria considered for comparing the two fuels and engine options. Fuel cell system (FCS) performance is characterized in terms of heat rejection, efficiency, and fuel consumption for a hybrid platform equivalent to a 3500 hp diesel engine operating on a representative open pit mining duty cycle. A hybrid platform was chosen because the heat rejection, with a constrained radiator frontal area, limits the maximum fuel cell-rated power by about 50% compared to that of the diesel truck. The hybrid powertrain was 81–88% more efficient than the diesel powertrain on the truck duty cycle. A liquid hydrogen storage system is required for an equal range or time between refilling, but the packaging remains a challenge. Fuel cell and battery durability were evaluated for their performance degradation and lifetime. Achieving a fuel cell lifetime comparable to the time between major overhauls for diesel trucks necessitates the oversizing of the membrane-active area, catalyst overloading, and voltage clipping. For an equal lifetime, the battery must be oversized to control its depth of discharge and charge/discharge rates. A total cost of ownership (TCO) analysis considering the initial capital expenditures, as well as the lifetime cost of fuel, operation, and maintenance, indicates that fuel cells and hydrogen can compete with diesel. A breakeven fuel cost for TCO parity is obtained if H2 is available at USD 5.79–6.85/kg vs. diesel at USD 3.25/gal and the FCS-specific cost is USD 323/kW e relative to USD 250/kW for a diesel genset. Volume manufacturing is required for FCS cost reduction. High volume is possible through the standardization, modularity, and proliferation of class 8 long-haul truck systems across different heavy-duty applications.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Understanding Subsidies to Achieve Diesel Powertrain Financial Parity for Heavy-Duty Fuel Cell Electric Vehicles

The development of a long-term sustainable hydrogen energy economy for commercial vehicle transportation will need to overcome key critical technical and logistics considerations in the near term. As compared to zero-emission powertrains, fossil-fuel-based powertrains provide mission flexibility and high uptime at a comparatively low total cost of ownership (TCO). While the incumbent carbon-intensive powertrains suffer from poor efficiency and are not sustainable to support global climate change initiatives in transportation decarbonization, techno-economic challenges continue to create complex barriers to the large-scale displacement of these with highly electrified powertrains architectures. Here, this article specifically addresses opportunities that well-targeted subsidies would afford in achieving fuel cell electric powertrain financial parity with diesel powertrains in heavy-duty trucks (HDTs). It shows that a rigorous assessment of system TCO factors will be critical in designing a viable subsidy strategy. Based on powertrain component and fuel price points, subsidy variations (for both capital expenses and operating fuel expenses) are assessed and quantified to determine where and how much subsidies should be leveraged to accelerate achieving diesel system financial parity. It shows that subsidies on hydrogen fuel expenses (and associated constituents) will play an important role in achieving this goal while subsidies on capital expenses (the more typical subsidy formulation) may not always be the preferred subsidy strategy. The results provide subsidy agencies with clear guidance and a database approach to characterize and implement viable HDT hydrogen powertrain system subsidy strategies. The approach may be readily tailored for other applications and system architectures.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2025

Refining Control, Charging, and Battery Chemistry for CO 2 e Savings in Heavy-Duty Off-Road Plug-In Series Hybrid

With current and future regulations continuing to drive reductions in carbon dioxide equivalent (CO 2 e) emissions in the on-road industry, the off-road industry is also likely to be regulated for fuel and CO 2 e savings. This work focuses on converting a heavy-duty off-road material handler from a conventional diesel powertrain to a plug-in series hybrid, achieving a 49% fuel reduction and 29% CO 2 e reduction via simulation. Control strategies were refined for energy savings, including a regenerative braking strategy to increase regenerative braking and a load-following hydraulic strategy to decrease electrical energy consumption. The load-following hydraulic control shuts off the hydraulic electric machine when it is not needed—an approach not previously seen in a load-sensing, pressure-compensated system. Furthermore, these strategies achieved a 24.1% fuel savings, resulting in total savings of 61% in fuel and 41% in CO 2 e in the plug-in series compared to the conventional machine. Beyond control strategies, this study evaluated battery chemistry and charging strategy refinements for total cost of ownership (TCO) and lifetime CO 2 e. LFP batteries emerged as the most cost-effective and least emitting due to their longer lifespan, which reduced replacement frequency. Charging comparisons showed that Level 2 charging (L2C) typically resulted in lower TCO but higher lifetime CO 2 e than DC fast charging (DCFC). DCFC costs were heavily influenced by local demand charges, and DCFC emissions were heavily influenced by local grid emissions.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2022

Achieving Diesel Powertrain Ownership Parity in Battery Electric Heavy Duty Commercial Vehicles Using a Rapid Recurrent Recharging Architecture

Battery electric vehicles (BEV) in heavy duty (HD) commercial freight transport face challenging technoeconomic barriers to adoption. Specifically, beyond safety and compliance, fleet and operational logistics require both high up-time and parity with diesel system productivity/Total Cost of Ownership (TCO) to enable strong adoption of electrified powertrains. At present, relatively high energy storage prices coupled with the increased weight of BEV systems limit the practicality of HD commercial freight transport to shorter range applications, where smaller batteries will suffice for the mission energy requirements (single operational shift). This paper presents an approach to extend the feasibility of BEV HD trucking for a broad range of applications. The concept is based on the leveraging rapid and recurrent recharging of a BEV HD truck that may either already make frequent stops due to shipment drop-offs/reloading or be required to make frequent stops along with longer missions for recharging. While the challenges of the latter are well appreciated, the concept proposed explores making minimal impact to overall mission time by targeting high C-rate charging while optimizing the frequency (miles) through which these events must occur. The concept optimizes battery size and chemistry, such that the expected life (years and total energy throughput) is balanced with the depth of discharge between recharging events, thus making complete use of the energy available through the life of the battery system. The solution is constrained to minimize the impact on payload capacity. The paper analyzes critical levers in achieving diesel price parity (based on a simplified vehicle TCO), achieved through different purchase options (including lease versus buy) and operational models (half-life swap out). Finally, the paper identifies the application design domain where these solutions are viable with limited impact on fleet operations.

Sujan, Vivek↗
NASA NTRS2003

A Gold Medal Finish

During the summer of 1999, Darryl Mitchell of Goddard Space Flight Center's Technology Commercialization Office (TCO) met with the U.S. Olympic Committee at the official training facility in Colorado Springs, Colorado, to offer assistance in transferring NASA technologies applicable to Olympic sports. Following the meeting with the Olympic committee, Mitchell was approached by U.S. Speedskating Long Track Program Director Finn Halvorsen, who eagerly voiced his interest in working with NASA to identify a means of improving performance for his team. According to Halvorsen, 'If (NASA) can put a man on the moon, surely they can help our skaters.' Mitchell and Halvorsen went to work uncovering NASA technologies that could boost the U.S. team's skating capabilities. Mitchell received a crash course in speedskating, and as a result, generated a lengthy list of promising NASA developments that could benefit the sport. From this list, he and his Goddard TCO partner, Joe Famiglietti, deliberated over whether a NASA mirror-polishing technique could possibly be adapted to the athletes speedskates. The polishing technique, developed by Jim Lyons, a 16-year optical engineering veteran of Goddard, was derived from the same principles used to create the optics for NASA's science observatories, such as the Hubble Space Telescope (highly polished optics are required by NASA to obtain sharp, clear images in space).

Source record↗
NASA NTRS2019

Trends in Global Tropospheric Ozone Inferred from a Composite Record of TOMS/OMI/MLS/OMPS Satellite Measurements and the MERRA-2 GMI Simulation

Past studies have suggested that ozone in the troposphere has increased globally throughout much of the 20th century due to increases in anthropogenic emissions and transport. We show, by combining satellite measurements with a chemical transport model, that during the last four decades tropospheric ozone does indeed indicate increases that are global in nature, yet still highly regional. Satellite ozone measurements from Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) are merged with ozone measurements from the Aura Ozone Monitoring Instrument/Microwave Limb Sounder (OMI/MLS) to determine trends in tropospheric ozone for 1979–2016. Both TOMS (1979–2005) and OMI/MLS (2005–2016) depict large increases in tropospheric ozone from the Near East to India and East Asia and further eastward over the Pacific Ocean. The 38-year merged satellite record shows total net change over this region of about +6 to +7 Dobson units (DU) (i.e., ∼15 %–20 % of average background ozone), with the largest increase (∼4 DU) occurring during the 2005–2016 Aura period. The Global Modeling Initiative (GMI) chemical transport model with time-varying emissions is used to aid in the interpretation of tropospheric ozone trends for 1980–2016. The GMI simulation for the combined record also depicts the greatest increases of +6 to +7 DU over India and East Asia, very similar to the satellite measurements. In regions of significant increases in tropospheric column ozone (TCO) the trends are a factor of 2–2.5 larger for the Aura record when compared to the earlier TOMS record; for India and East Asia the trends in TCO for both GMI and satellite measurements are ∼+3 DU decade(exp −1) or greater during 2005–2016 compared to about +1.2 to +1.4 DU decade(exp −1) for 1979–2005. The GMI simulation and satellite data also reveal a tropospheric ozone increases in ∼+4 to +5 DU for the 38-year record over central Africa and the tropical Atlantic Ocean. Both the GMI simulation and satellite-measured tropospheric ozone during the latter Aura time period show increases of ∼+3 DU decade−1 over the N Atlantic and NE Pacific.

Ziemke, Jerald R.↗
NASA NTRS2020

Using Networked Pandora Observations to Capture Spatiotemporal Changes in Total Column Ozone Associated with Stratosphere-to-Troposphere Transport

Accurately capturing the evolution of episodic stratosphere-to-troposphere transport is critical due to the potential impacts on both climate and air quality. Until now, investigating associated spatiotemporal gradients in total column ozone (TCO) has primarily been the task of observations from polar-orbiting satellites as well as high-resolution models. We explore how a network of five ground-based Pandora spectrometer systems can be utilized in a similar fashion. The passage of a strong mid-latitude cyclone in March 2018 and its associated stratospheric intrusion is used as a case demonstrating the ability of networked Pandora observations to contextualize these regions of transport across space and time. Results show that the high temporal resolution of Pandora observations and the networked approach were able to resolve increases in TCO associated with stratosphere-to-troposphere transport and to capture the spatial context of the chosen episode. The use of networked Pandora observations shows promise for additional transport studies and for supporting future geostationary atmospheric composition satellite missions and modeling efforts.

J. Robinson↗
NASA NTRSDate not supplied

Observation of Stratospheric Intrusions and Ozone Transport using CrIS SiFSAP Products

The Single Field of View (SFOV) ozone (O3) profiles derived from the Cross-track Infrared Sounder (CrIS) onboard Suomi National Polar-Orbiting Partnership (SNPP), with a high horizontal resolution of approximately 14 km at nadir and good sensitivity to O3 in the upper troposphere and lower stratosphere (UTLS), provide a prominent opportunity to examine stratosphere to troposphere (STT) transport. A process-oriented analysis was performed to examine the fine-scale features of a stratospheric intrusion (SI) event on June 11-13, 2017 in the southwestern US using the CrIS SFOV products together with wind and potential velocity (PV) from models. It was found that the location and strength of O3 enhancement correlate well with the PV contours, and the intrusion depth can be characterized using the vertical cross-sections of O3 and relative humidity (RH). In addition, the capability to use total column ozone (TCO) to identify SI events was confirmed through analysis of TCO from CrIS SFOV and other satellite and reanalysis products. The ozone/PV ratio was derived using SFOV O3 and model PV, and the values, ranging from 23.2 to 35.8 ppbv PVU-1 (1 PV unit (PVU) = 10-6 km2 kg-1 s-1), are in the lower end of previous estimations. These results demonstrate the advantages of the SFOV products in monitoring the fine-scale ozone transport and thermodynamic structure of SI events, as well as their potential value for weather and climate study.

Xiaozhen Xiong↗