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At least 163 records · Page 9

Raw soil carbon dioxide, moisture, temperature and micrometeorological data in the East River Watershed, Colorado June 2021-June 2024. (DE-SC0021139)

This dataset contains raw data from four tripod stations along an elevation gradient on Snodgrass Mountain in the East River Watershed, CO, USA. Each station contains a datalogger connected to 3 soil Carbon Dioxide CO2 gas probes, 3 soil temperature/moisture sensors and a micrometeorological station. Sensors are scanned every minute, and the 30 minute average is reported. The file snodgrass_soil_ESS.csv contains raw data, a row of column descriptors, and units of measurements. some data processing and QA/QC was done to filter out data from sensors that went bad and extreme outliers. CO2 sensors that went bad were replaced with new sensors as soon as possible. This research was performed to investigate the ecohydrological linkages of belowground carbon processes in the East River watershed forested communities to better understand how these ecosystems will respond to a changing cold-season moisture input. This is the second version of this data set and was modified on 10/01/2024. The primary change in the data was the addition of data from the fall of 2022 to June of 2024. In addition, minor QA/QC was done to filter out data from sensors that went bad and extreme outliers. THe filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. This is now the third version of the data set, and was modified 03/25/2026. The primary change in the data was the addition of data from the June of 2024 to December 2025. Further r QA/QC was done with the new data to filter out bad data from faulty sensors and extreme outliers. The filtered data are now NA's in this data frame and primarily the CO2 sensors. Limited to no QA/QC has been done on the other environmental data. ##This additional data was funded under DE-SC0024218( Responses of Plant and Microbial Respiration Sources to Changing Cold Season Climate Drivers in the East River Watershed)

54 ENVIRONMENTAL SCIENCES↗

Soil moisture and temperature from 2019 to 2024 along northeast- and southwest-facing hillslopes at the Lower Montane site in the East River Watershed, Colorado

Soil moisture, temperature, and electrical conductivity have been monitored at multiple depths (between 10 and 50 cm) at 4 locations along a northeast-facing slope and 3 locations on the opposite southwest-facing slope at the Lower Montane site in the East River Watershed, Colorado, from Oct 2019 to Oct 2024. The purpose of this data is to inform hydro-biogeochemical analyses for the Watershed Function Scientific Focus Area (SFA). Two locations on the northeast-facing slope were reinstalled in 2020 due to damage from wildlife, and thus data for these sites are provided in two distinct files. Overall, the data are reported in 9 CSV files containing the measurements, and the locations are provided in the Sensor_Location.csv file. There is a total of 10 *.csv data files and 3 *.csv metadata files. Older datasets associated with the northeast-facing slope are provided in another archive (see reference). These data products are part of the Watershed Function Scientific Focus Area collection effort to further scientific understanding of biogeochemical dynamics from genome to watershed scales. Feel free to contact the author with any questions or collaboration interests.

54 ENVIRONMENTAL SCIENCES↗

Soil Temperature and Moisture within the Kougarok Fire Complex, Kougarok Road Mile Marker 86, Seward Peninsula, Alaska, 2019-2023

Daily averages of soil temperature and moisture measured once every hour at different heights located at Intensive Monitoring Stations within the Kougarok Fire Complex, Kougarok Road Mile Marker 86 site. Data were retrieved annually from 2019-2023. Package contains 21 *.CSV data files plus a file level metadata *.CSV, data dictionary *.CSV, data file inventory *.CSV, and sensor location site map *.JPG. Data files have header rows, NaN fields indicate invalid or missing data, and negative vertical offsets are above ground.The Kougarok tundra fire complex (KFC) is located north of Nome and the Kigluaik Mountains, near Quartz Creek and the Kougarok River. The site is accessed by foot from the end of the Nome-Taylor Highway (mile marker 86; also called the Kougarok or Beam Road). The KFC burned in six major fires in the decades since 1950 (Alaska Interagency Coordination Center, unpublished data). Lightning ignited five of these fires (1971, 1997, 2015, and 2019) and one was human caused (2002). The mosaic of overlapping fire scars allows for the study of repeat fires in the tundra which, until recently, was not a common phenomenon outside the boreal forest in Alaska. Our reference unburned tundra fire site is south of the KFC located at mile marker 80 of the Nome-Taylor Highway.The two most recent fires are the Mingvk Lake (2015; 21,698 acres burned from 7/27/2015 to 9/28/2015) and Garfield Creek (2019; 422 acres burned from 7/31/2019 to 8/20/19). The Mingvk Lake fire scar includes areas that burned 1-4x (1971, 1997, 2002), while the entirety of the Garfield Creek fire scar has burned 2x previously (1971, 2002).Previous research at the KFC focused on permafrost (Liljedahl et al. 2007; Narita et al. 2015; Iwahana et al. 2016; Tsuyuzaki, Iwahana, and Saito 2017) and vegetation (Narita et al. 2015; Hollingsworth et al. 2021) response to fire. The central Seward Peninsula is characterized by continuous permafrost with a thickness of 15 to 30 m and a mean active layer thickness of 56 cm (Hinzman et al. 2003). Sloping hills with mixed shrub–tussock tundra and tussock tundra vegetation in the uplands are characteristic of the region. Three micrometeorological towers near the Kougarok field site recorded a mean annual temperature of −2.4°C, mean January temperature of −23.1°C, mean July temperature of +11°C, and mean summer rainfall (June–August) of 94 mm from 2000 to 2006 (Liljedahl et al. 2007).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Carbon dioxide, water vapor and methane soil efflux (soil respiration) in a Pinus palustris root exclusion in Georgetown, SC

This dataset contains processed data from a combination of survey flux chambers and long-term automated flux chambers. Soil flux measurements were conducted from June 2023 through December 2025 in a mature longleaf pine forest in Georgetown, SC. Soil respiration measurements were conducted approximately biweekly for two and a half years, before and after a root exclusion that took place on May 5, 2024. Processed, QAQC’d data for the treatment (root exclusion) and control (roots intact) before and after the root exclusion can be found in the file: 1_DATA_ESS_DOE_HR_RS_HB2_QAQC_Survey_Data_20260223.csv. Two multiday deployments were also conducted prior to the root exclusion using long-term automated chambers to continuously monitor greenhouse gas soil efflux. Processed, QAQC’d data for both long-term deployments can be found in the file: 2_DATA_ESS_DOE_HR_RS_HB2_QAQC_Longterm_Data_20260209.csv. Raw and working data files (.json, .81x, & .82z format) from LI-COR equipment are included for reference and can be accessed using SoilFluxPro software. CSV metadata files describe the raw data and modifications made using SoilFluxPro v5 and Matlab R2024b, as well as formatting and units for processed CSVs. Matlab code is included for reading in the processed CSVs, with sample figures comparing treatment and control. This research was performed as part of the project: “Improving models of stand and watershed carbon and water fluxes with more accurate representations of soil-plant-water dynamics in southern pine ecosystems”, which examines in part the effects hydraulic redistribution on soil efflux of carbon dioxide, water vapor and methane, as well as soil moisture and temperature in a southern pine ecosystem with sandy soils and high water table.

CARBON DIOXIDE FLUX↗

Soil Characterizations of Five Urban Sites in Knoxville, Tennessee. 2024-2025

This dataset includes soil characterizations from five urban parks in Knoxville, Tennessee, USA: Cumberland Estates Park (CEP), Socially Equal Energy Efficient Development (SEED), West View Park (WVP), Victor Ashe Park (VAP), and West Hills Park (WHP). The dataset consists of seven CSV files reporting the data from the measurements of gravimetric moisture content, pH, total carbon and nitrogen, soil texture, dissolved organic carbon and nitrogen, and microbial biomass carbon and nitrogen derived from these soil cores. During five separate sampling events conducted in 2024 and 2025, five soil cores were collected at each site within 3 meters of the remote soil monitoring equipment. In 2025, an additional three soil cores were collected adjacent to the monitoring equipment at each site to assess soil bulk density. This dataset is part of a larger study investigating the effects of soil moisture and plant evapotranspiration on ambient temperature and relative humidity across multiple urban parks in Knoxville, Tennessee.

Mayes, Melanie A [ORNL] (ORCID:0000000163689210)↗

Soil Carbon Dynamics Following Land Use Changes and Conversion to Oil Palm Plantations in Tropical Lowlands Inferred From Radiocarbon

We measured the 14C and 13C isotopic values of soil organic carbon in mineral soil from lowland tropical forests to provide insight into how quickly carbon is turning over in the soil following conversion of primary forests to oil palm plantations. In addition to areas converted to oil palm plantations in Peru, Indonesia, and Cameroon, we examine pastures and secondary forests in Peru as a comparison to the carbon cycling processes operating in the oil palm plantations.This dataset includes radiocarbon (Δ14C) and stable carbon (δ13C) isotopes of soil organic carbon in mineral soils from natural lowland forests and oil palm plantations in Peru, Indonesia, and Cameroon. We additionally examine plots of secondary forests following agricultural use and pastures on cleared natural forest in Peru. In addition to isotopic data, this dataset includes soil carbon and nitrogen concentrations and stock, soil texture (percent sand, silt, and clay), pH, ECEC (effective cation exchange capacity), base saturation, and bulk density. Soils were sampled in 4 depth increments to 100 cm depth.This dataset supports the publication Finstad et al., 2020. Finstad, K., van Straaten, O., Veldkamp, E., & McFarlane, K. (2020). Soil carbon dynamics following land use changes and conversion to oil palm plantations in tropical lowlands inferred from radiocarbon. Global Biogeochemical Cycles, 34, e2019GB006461. https://doi.org/10.1029/2019GB006461

54 ENVIRONMENTAL SCIENCES↗

Radiocarbon of deep fine roots across four in lowland seasonal tropical forests in Panama

Objectives:Fine roots are key to ecosystem-scale nutrient, carbon (C), and water cycling, but our understanding of fine root traits variation within and among tropical forests, one of Earth’s most C-rich ecosystems, is limited. In 2022 and 2023, we aimed to explore differences in deep root characteristics among four lowland tropical forests in Panama, which vary in fertility and mean annual precipitation. We measured radiocarbon content (fraction modern [FM] and Δ14C) and δ13C of live fine roots at depths greater than 80 cm, up to 120 cm. The goal was to understand how deep root characteristics differ across these sites.Datasets included:The datasets provided include .csv and .xlsx files for radiocarbon content (fraction modern [FM] and Δ14C) and δ13C of live fine roots at depths greater than 80 cm, up to 120 cm collected from late 2017 to 2018 across four different forests. Additionally, a .kml file is provided with coordinates for all 32 plots included in the study across four forests (n = 8 plots per site). This dataset serves as baseline data before a throughfall exclusion experiment, Panama Rainforest Changes with Experimental Drying (PARCHED), was implemented. No special software is needed to open these files.

54 ENVIRONMENTAL SCIENCES↗

In Situ Soil Moisture and Thaw Depth Measurements Coincident with Airborne SAR Data Collections, Seward Peninsula, Alaska, 2022

The in-situ soil moisture and thaw depth measurements provided in this dataset were collected coincident with airborne overflights of L-band synthetic aperture radar (SAR) instruments at the Teller, Kougarok, and Council study sites on the Seward Peninsula, Alaska. Overflights occurred on August 19, 2022. Soil moisture data at Teller and Kougarok was collected on August 19, and at Council on August 20. Thaw depth, soil pits, and any additional measurements were recorded on August 20 and 21. Field measurements and flights were conducted during the summer of 2022 as a collaboration between the National Aeronautics and Space Administration (NASA) Arctic-Boreal Vulnerability Experiment (ABoVE) Project’s Airborne SAR Campaign and the Next-Generation Ecosystem Experiments (NGEE) Arctic Project. This dataset includes a data file (*.csv), a data dictionary (*_dd.csv) and a file-level metadata (*_flmd.csv). The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy’s Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy’s Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

EARTH SCIENCE > LAND SURFACE > FROZEN GROUND↗

Soil moisture, physical and chemical properties coincident with airborne SAR data collections for 2017 and 2019, Seward Peninsula, Alaska

Soil samples were collected coincident with in-situ soil moisture and thaw depth measurements at NGEE Arctic study sites on the Seward Peninsula, Alaska in August 2017 and 2019 Field measurements and flights were conducted during both summers as a collaboration between the NASA ABoVE Project's Airborne SAR Campaign and the NGEE Arctic Project. Airborne overflights of L-band SAR instruments occurred during the soil sampling periods. Laboratory measurements of soil properties include bulk density, volumetric and gravimetric water content, carbon and nitrogen content, and particle size of mineral components. Soil samples processed and reported in this dataset were collected coincident with in situ measurements of soil moisture and thaw depth and airborne P-band and L-band SAR measurements as a collaboration between NGEE Arctic and NASA ABoVE. To learn more about how ABoVE protocols were applied for sampling site selection and making in situ measurements, see the following datasets: (2017: https://doi.org/10.5440/1423892 and 2019: https://doi.org/10.5440/1856042). Contained in this dataset are four .csv data files (including data dictionaries) and one zipped folder of *.pdf files.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort (with some overlap with Covid-19 pandemic) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

In Situ Soil Moisture and Thaw Depth Measurements Coincident with Airborne SAR Data Collections, Seward Peninsula, Alaska, 2019

The in-situ soil moisture and thaw depth measurements provided in this dataset were collected coincident with airborne overflights of L- and P-band SAR instruments at the Teller and Kougarok NGEE Arctic study sites on the Seward Peninsula, Alaska. Field measurements and flights were conducted in August 2019 as a collaboration between the NASA ABoVE Project's Airborne SAR Campaign and the NGEE Arctic Project. ABoVE protocols for establishing field measurement plots were followed. NGEE Arctic plots for the ground-based measurements are located at existing study sites where SAR data would also add value to current monitoring and characterization efforts of the NGEE Team. The ground-based data will be used by ABoVE to analyze, calibrate and validate the remote sensing products. This dataset follows the format and collection guidelines of the collaboration effort in 2017. Contained in this dataset are *.csv (including data dictionaries), .zip, .kml, .jpgs, .py, and .pdf files.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort (with some overlap with Covid-19 pandemic) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

A globally sampled high-resolution hand-labeled validation dataset for evaluating surface water extent maps

Effective monitoring of global water resources is increasingly critical due to climate change and population growth. Advancements in remote sensing technology, specifically in spatial, spectral, and temporal resolutions, are revolutionizing water resource monitoring, leading to more frequent and high-quality surface water extent maps using various techniques such as traditional image processing and machine learning algorithms. However, satellite imagery datasets contain trade-offs that result in inconsistencies in performance, such as disparities in measurement principles between optical (e.g., Sentinel-2) and radar (e.g., Sentinel-1) sensors and differences in spatial and spectral resolutions among optical sensors. Therefore, developing accurate and robust surface water mapping solutions requires independent validations from multiple datasets to identify potential biases within the imagery and algorithms. However, high-quality validation datasets are expensive to build, and few contain information on water resources. For this purpose, we introduce a globally sampled, high-spatial-resolution dataset labeled using 3 m PlanetScope imagery. Our surface water extent dataset comprises 100 images, each with a size of 1024×1024 pixels, which were sampled using a stratified random sampling strategy covering all 14 biomes. We highlighted urban and rural regions, lakes, and rivers, including braided rivers and coastal regions. We evaluated two surface water extent mapping methods using our dataset – Dynamic World, based on Sentinel-2, and the NASA IMPACT model, based on Sentinel-1. Dynamic World achieved a mean intersection over union (IoU) of 72.16 % and F1 score of 79.70 %, while the NASA IMPACT model had a mean IoU of 57.61 % and F1 score of 65.79 %. Performance varied substantially across biomes, highlighting the importance of evaluating models on diverse landscapes to assess their generalizability and robustness. Our dataset can be used to analyze satellite products and methods, providing insights into their advantages and drawbacks. Our dataset offers a unique tool for analyzing satellite products, aiding the development of more accurate and robust surface water monitoring solutions. The dataset can be accessed via https://doi.org/10.25739/03nt-4f29.

54 ENVIRONMENTAL SCIENCES↗

Structure of the (110) Ln ScO 3 ( Ln =Gd,Tb,Dy) surfaces

The surface reconstruction on the (110) surface of LnScO 3 (Ln=Gd,Tb,Dy) has been investigated using x-ray photoelectron spectroscopy, atomic force microscopy, and transmission electron diffraction coupled with higher-level density-functional theory methods. The experimental techniques generate constraints on the surface chemistry and structure that are used to inform the theoretical comparison of a number of potential surface structures. The resulting structure is then compared to experimental aberration-corrected transmission electron microscopy results using multislice simulation. The surfaces of both single-crystalline substrates and hydrosauna synthesized nanoparticles exhibit a Sc-rich double layer with a Sc 3 O 4 termination.

36 MATERIALS SCIENCE↗

Oceanographic Conditions. 2007 - 2040. North Slope Alaska.

Complete representations of oceanographic conditions require spatial and temporal information about the significant wave height (Hs), peak wave period (Tp), wind speed, wind direction, wave direction, water level, salinity, and temperature. This data develops location-independent typologies to reduce the number of boundary conditions needed to assess nearshore oceanographic environments in both a Historical (2007-2019) and Future (2020-2040) timespan along the Alaskan North Slope. Wave information for both time spans were generated from WaveWatch III, Delft3D-FLOW, and Delft3D-WAVE simulations forced by wind conditions from reanalysis data (e.g., ASRv2 and ERA5) for the historical simulations while projected conditions were obtained from downscaled GFDL-CM3 forced under RCP8.5 conditions. Salinity was generated from GOFS 3.1 for the years between 2008-2015 and skin temperature of the ocean was obtained from ASRv2 reanalysis data for the years between 2007-2016. To identify generalized oceanographic typologies, K-means clustering was applied to the energy-weighted joint-probability distribution of Hs and Tp at six sites along the North Slope of Alaska. Distributions of wave and wind direction, wind speed, and water level associated with locaiton-indepndent centroids were assigned single values to describe a reduced order, typological rendition of offshore oceanographic conditions. These final typologies and their constituent data are provided here and can be used to evaluate the change in ocean energy over the next two decades in response to climate change and provide insight into expected consequences such as coastal erosion and flooding. A full assessment of the findings and techniques developed can be found in: Eymold, W.K., Flanary, C., Erikson, L., Nederhoff, K., Chartrand, C.C., Jones, C., Kasper, J., and Bull, D.L. Typological Representation of the Offshore Oceanographic Environment along the Alaskan North Slope. Continental Shelf Research (2022). 10.1016/j.csr.2022.104795

54 ENVIRONMENTAL SCIENCES↗

Interfacial charge transfer driven by surface termination-controlled Ti 2 C MXene for enhanced hydrogen storage in magnesium

Two-dimensional transition metal carbides and nitrides (MXenes) with layered structure and high conductivity have been effectively utilized in various energy materials, including as a catalytic support of MgH 2 for hydrogen storage. However, the terminal groups formed on the surface during the etching step tend to deactivate reactive Mg metal and add dead mass, thereby deteriorating the catalytic role of MXene in hydrogen sorption of Mg. For this work, we exploited a molten-salt derived MXene with easily modifiable –Cl terminations, compared to conventional –O, –OH and –F groups, and synthesized a composite of Mg and delaminated Ti 2 CCl x MXene to improve the hydrogen storage performance of Mg through charge transfer. This strategy enables the formation of an intimate interface between Mg and MXene, facilitating charge transfer and thereby boosting the catalytic effect. The resulting composite demonstrates significantly enhanced hydrogen sorption kinetics by modulating Mg–H bond strength. This novel approach of modifying surface terminations leverages the unique properties of MXene as a superior support for active materials, offering broader applications in energy materials.

2D material↗

Northern Hemisphere Winter Air Temperature Patterns and Their Associated Atmospheric and Ocean Conditions

The Northern Hemisphere (NH) has experienced winter Arctic warming and continental cooling in recent decades, but the dominant patterns in winter surface air temperature (SAT) are not well understood. Here, a self-organizing map (SOM) analysis is performed to identify the leading patterns in winter daily SAT fields from 1979 to 2018, and their associated atmospheric and ocean conditions are also examined. Three distinct winter SAT patterns with two phases of nearly opposite signs and a time scale of 7–12 days are found: one pattern exhibits concurrent SAT anomalies of the same sign over North America (NA) and northern Eurasia, while the other two patterns show SAT anomalies of opposite signs between, respectively, NA and the Bering Sea, and the Kara Sea and East Asia (EA). Winter SAT variations may arise from changes in the SOM frequencies. Specifically, the observed increasing trends of winter cold extremes over NA, central Eurasia, and EA during 1998–2013 can be understood as a result of the increasing occurrences of some specific SAT patterns. These SOMs are closely related to poleward advection of midlatitude warm air and equatorward movements of polar cold airmass. These meridional displacements of cold and warm airmasses cause concurrent anomalies over different regions not only in SAT but also in water vapor and surface downward longwave radiation. Anomalous sea surface temperatures in the tropical Pacific, midlatitude North Pacific, and North Atlantic and anomalous Arctic sea ice concentrations also concur to support and maintain the anomalous atmospheric circulation that causes the SAT anomalies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Calcium Sulfate and Calcium Carbonate Scaling of Thin-Film Composite Polyamide Reverse Osmosis Membranes with Surface-Tethered Polyacrylic Acid Chains

The gypsum and calcite scaling propensities of the thin-film composite polyamide (PA-TFC) reverse osmosis (RO) membrane, modified with a tethered surface layer of polyacrylic acid (PAA) chains, was evaluated and compared to the scaling of selected commercial RO membranes. The tethered PAA layer was synthesized onto a commercial polyamide membrane (i.e., base-PA) via atmospheric pressure plasma-induced graft polymerization (APPIGP). The PAA nano-structured (SNS) base-PA membrane (SNS-PAA-PA) was scaled to a lesser degree, as quantified by a lower permeate flux decline and surface imaging, relative to the tested commercial membranes (Dow SW30, Toray SWRO, and BWRO). The cleaning of gypsum-scaled membranes with D.I. water flushing achieved 100% water permeability recovery for both the SNS-PAA-PA and Dow SW30 membranes, relative to 92–98% permeability restoration for the Toray membranes. The calcium carbonate scaling of SNS-PAA-PA membranes was also lower relative to the commercial membranes, but permeability recovery after D.I. water cleaning was somewhat lower (94%) but consistent with the level of surface scale coverage. In contrast, the calcite and gypsum-scaled membrane areas of the commercial membranes post-cleaning were significantly higher than for the SNS-PAA-PA membrane but with 100% permeability recovery, suggesting the potential for membrane damage when mineral scaling is severe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

ESS-DIVE Unoccupied Aerial Systems (UAS) Reporting Format v1

Here we present documentation of the ESS-DIVE reporting format for Unoccupied Aerial System (UAS) data and metadata. This reporting format provides guidance to data contributors on how to store data to maximize their discoverability, facilitate their efficient reuse, and add value to individual datasets. For data users, the reporting format will better allow data repositories to optimize data search and extraction, and more readily integrate similar data into harmonized synthesis products. The reporting format provides templates and guidance for the reporting of metadata for UAS experimental campaigns, individual flights, platform and sensor description. To improve data access and discoverability, the reporting format proposes a data description scheme of Levels based on the degree of processing, where Level 0 includes raw data, through to Level 3 being derived data end products. A range of examples of data types for each Level are given, with suggested file naming schemes. The reporting format presented here is intended to form a foundation for future development that will accommodate new UAS technologies and approaches to data access and use in the future. The reporting format documentation is maintained and updated on the ESS-DIVE Community Space GitHub at https://github.com/ess-dive-community/essdive-uas. This data package is the first published version of this reporting format, and comprises a zip file of the complete content of https://github.com/ess-dive-community/essdive-uas v1.0. The zip contains the reporting format description, instructions and variable definitions in GitHub markdown language (*.md) and metadata templates in csv format. The reporting format is designed to be compatible with other ESS-DIVE formats, and it is specifically recommended that this reporting format be used in conjunction with the File-level metadata (FLMD) and comma separated values (csv) reporting formats for submission to the ESS-DIVE repository.

54 ENVIRONMENTAL SCIENCES↗

Aqueous Organic Matter from Kougarok Fire Complex, Alaska, 2023

Chemical analyses of aqueous organic matter extracted by filtration from a small set of organic layer samples collected from burned and unburned tussock tundra sites in the Kougarok Fire Complex, near Nome, Alaska. There are five files in *.csv format with one data file and four data description files including data dictionary, methods, terminology, and file-level metadata.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗