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At least 163 records · Page 9

Venus, Earth and Mars: Present bounds on similarities and differences in bulk composition

The bulk compositions of the terrestrial planets are constrained in part by rigorous bounds derivable from geophysical data and from chemical data obtained in situ or by remote sensing. In large part, however, the bulk compositions are constrained only by the inferred plausibility of assumptions made about the processes responsible for producing planets. Present data are consistent with Venus, Earth and Mars all having solar ratios of the major, non-volatile elements. The mantle of Mars has a higher FeO content than the Earth's present upper mantle. The FeO content of the Venus mantle is poorly constrained. Abundances of minor elements are virtually unconstrained by geophysical data and only weakly constrained by existing chemical data. Inferences drawn from SNC meteorites suggest that Mars may be enriched in most volatiles relative to the Earth. Simple models in which volatiles are added in a single component probably do not accurately predict bulk volatile inventories of the planets.

Goettel, K. A.↗

Workshop on Water on Mars

The opening session of the Workshop focused on one of the most debated areas of Mars volatiles research-the size of the planet's past and present bulk water content. Current estimates of the inventory of H2O on Mars range from an equivalent layer of liquid 10-1000 meters deep averaged over the planet's surface. The most recent of these estimates, presented at the Workshop, is based on the now popular belief that the SNC class of meteorites represent actual samples of the Martian crust. From a model of planetary accretion and degassing founded on this assumption, it was determined that the present inventory of H2O on Mars is equivalent to a global layer no more than 50 meters deep. During the discussion generated by this estimate, several investigators expressed reservations about an H2O inventory as small as a few tens of meters, for it appears to directly contradict the seemingly abundant morphologic evidence that Mars is (or has been) water rich. Others, however, argued that the interpretation of much of this morphologic evidence is at best equivocal and that the case for a wet Mars is far from established. Atmospheric water vapor measurements, compiled by Earth based telescopes and the Viking Orbiter Mars Atmospheric Water Detectors (MAWD), now span a period of over six Martian years. Analysis of this data suggests that the seasonal cycle is governed by both the sublimation and condensation of H2O at the poles and by its adsorption/desorption within the regolith. So far, efforts to simulate the seasonal vapor cycle have failed to reproduce the observed behavior.

Clifford, S.↗

Redetermination of parameters for semi-empirical model for spallogenic He and Ne in chondrites

A semi-empirical model described previously satisfactorily reproduced a number of shielding-dependent variations in the relative production rates of spallogenic He and Ne in chondrites. However, data for cores of the Keyes and St. Severin meteorites showed a subsurface build-up in He-3 which was not predicted with the original model parameters and the model was not pursued. Renewed interest in the preatmospheric size of meteorites, spurred in part by the desirability of understanding the exposure history of the SNC meteorites, justifies redetermination of model parameters.

Nyquist, L. E.↗

Formation ages and evolution of Shergotty and its parent planet from U-Th-Pb systematics

The isotopic composition of Pb from Shergotty, Zagami, and EETA 79001 meteorites was determined for different phases. Using phases with low U-238/Pb-204 ratio, the initial leads of these meteorites were defined. Samples from all three meteorites were shown to have distinct initial leads, and, thus to have evolved from different reservoirs over most of solar system history in a low U-238/Pb-204 environment. It follows that the parent planet of the shergottites has a high Pb-204 concentration relative to U and must also be high in other volatiles. The possibility of the Martian origin of the SNC-type meteorites is discussed.

Chen, J. H.↗

A discussion of isotopic systematics and mineral zoning in the shergottites - Evidence for a 180 m.y. igneous crystallization age

The chronologies of the Shergotty, Zagami, ALHA 77005, and EETA 79001 meteorites were reexamined on the basis of shergottites' petrography and mineral chemistry data. Among the various isochrons, the concordant Rb-Sr (about 180 Myr) and U-Th-Pb (about 190 Myr) internal isochrons are interpreted as representing the time of igneous crystallization, while the Rb-Sr, Sm-Nd, and Pb-Pb whole-rock isochrons are interpreted as mixing lines, and are reasonably attributed to igneous processes such as wall-rock assimilation and magma mixing. If the approximated age of less than 200 Myr is correct, the shergottites represent the youngest known extraterrestrial basalts. This conclusion supports the hypothesis that the SNC meteorites are samples of Mars.

Jones, J. H.↗

Core formation in the earth and shergottite parent body (SPB) - Chemical evidence from basalts

Abundances of siderophile and chalcophile elements in the shergottite parental body (SPB) have been compared with those of the earth. To this end, new INAA and RNAA analyses of non-Antarctic meteorites have been performed, and the composition of the shergottite SPB mantle has been inferred from the compositions of the SNC meteorites. The composition of the earth's mantle has been inferred from the compositions of terrestrial basalt. Finally, the effects of volatile depletion, core formation, and mineral/melt fractionation on the abundances of siderophile and chalcophile elements in the SPB and the earth have been taken into consideration. Compared to the earth, the SPB mantle is richer in moderately siderophile elements and more depleted with respect to chalcophile elements. The observed relative abundances of siderophile and chalcophile elements in the SPB and the earth mantles indicate that the SPB underwent accretion and/or differentiation processes which differ from those in the earth.

Treiman, A. H.↗

Beryllium-10 contents of shergottites, nakhlites, and Chassigny

Accelerator mass spectrometry gives the following Be-10 contents (dpm/kg) for the SNC meteorites: Shergotty, 13.0 + or - 1.5 and 17.3 + or - 2.7; Zagami, 18.6 + or - 2.5 and 20.0 + or - 3.2; ALHA 77005, 15 + or - 3; EETA 79001A, 7.8 + or - 1.1 and 6.3 + or - 0.5; EETA 79001B, 8.5 + or - 1.1; Nakhla, 19.7 + or - 3.3; Lafayette, 18.1 + or - 2.5; Governador Valadares, 25.6 + or - 3.6; Chassigny, 20.5 + or - 3.1. The Be-10 contents of the NC meteorites indicate that significant accumulation of cosmogenic nuclides occurred in decimeter rather than planetary-size bodies. The agreement of the He-3, Ne-21, and Be-10 exposure ages of the shergottites also supports small-body irradiation. A long terrestrial age for EETA 79001 appears unlikely.

Pal, D. K.↗

MEVTV Workshop on Nature and Composition of Surface Units on Mars

Topics addressed include: SNC meteorites and their potential for providing information about the geochemical evolution of Mars; remote sensing; photogeological inferences of Martian surface compositions; and interactions of the surface with volatiles in either the surface or the atmosphere.

Zimbelman, J. R.↗

Elemental composition of the Martian surface

The Viking landers carried X-ray fluorescence spectrometers (XRFS) to the surface of Mars for direct in-situ measurements of the elemental composition of samples that could be acquired by the surface sampler scoops. A total of 21 samples at two landing sites were acquired and analyzed. In this review, the constraints imposed on the design and operation of the XRFS; the accuracy and precision limitations of XRF; and the interpretation of the results are discussed. The latter includes relevance of the investigation to Martian geological processes, SNC meteorites, the formation and history of Mars, and future mission objectives/capabilities.

Clark, Benton C.↗

Aqueous alteration in S-N-C meteorites and implications for weathering products on Mars

Is shergottite, nakhlite, and chassignite (SNC) meteorites are rocks propelled to earth by large meteoroid impacts on Mars, then it is possible to deduce much about Martian igneous petrology and geochemistry. Because SNCs are igneous rocks, however, it was not obvious that they could reveal much about sedimentary and soil petrology and low-temperature geochemistry of Mars. It is important, though, that at least four of eight SNCs carry evidence for low-temperature, extraterrestrial weathering product phases. Evidence is reviewed for Martian weathering and alteration products in SNCs and possible inferences for volatile/regolith interactions, regolith mineralogy, and sinks for the putative hidden volatiles on Mars are outlined.

Gooding, J. L.↗

Water on Mars

It is reported that the SNC meteorites are a factor of 2 richer in moderately volatile elements (Na, K, P, etc.) and some volatile elements (Cl, Br, I, S) compared to the Earth and Mars. It is proposed that Mars accreted homogeneously, with the result that all the water except trace amounts (on reaction with metallic Fe) was converted to H(sub 2) and escaped. This model predicts a total Mars H(sub 2)O inventory of 18 ppm (equivalent to an ocean 80 m deep on the planet), and a value for Earth of 300 ppm, close to the actual abundance.

Waenke, H.↗

Martian regolith geochemistry and sampling techniques

Laboratory study of samples of the intermediate and fine-grained regolith, including duricrust peds, is a fundamental prerequisite for understanding the types of physical and chemical weathering processes on Mars. The extraordinary importance of such samples is their relevance to understanding past changes in climate, availability (and possible physical state) of water, eolian forces, the thermal and chemical influences of volcanic and impact processes, and the inventory and fates of Martian volatiles. Fortunately, this regolith material appears to be ubiquitous over the Martian surface, and should be available at many different landing sites. Viking data has been interpreted to indicate a smectite-rich regolith material, implying extensive weathering involving aqueous activity and geochemical alteration. An all-igneous source of the Martian fines has also been proposed. The X-ray fluorescence measurement data set can now be fully explained in terms of a simple two-component model. The first component is silicate, having strong geochemical similarities with Shergottites, but not other SNC meteorites. The second component is salt. Variations in these components could produce silicate and salt-rich beds, the latter being of high potential importance for microenvironments in which liquid water (brines) could exist. It therefore would be desirable to scan the surface of the regolith for such prospects.

Clark, B. C.↗

Earth rocks on Mars: Must planetary quarantine be rethought

Recent geochemical, isotopic, and rare gas studies suggest that eight SNC meteorites originated on the planet Mars. Since Martian rocks are found on Earth, consideration is being given to finding Earth rocks on Mars. Detailed consideration of the mechanism by which these meteorites were lofted into space strongly suggest that the process of stress-wave spallation near a large impact with, perhaps, an assist from vapor plume expansion, is the fundamental process by which lightly-shocked rock debris is ejected into interplanetary space. The theory of spall ejection was used to examine the mass and velocity of material ejected from the near vicinity of an impact. It seems likely that the half-dozen largest impact events on Earth would have ejected considerable masses of near surface rocks into interplanetary space. No computations were performed to indicate how long Earth ejecta would take to reach Mars.

Melosh, H. J.↗

Mars soil - A sterile regolith or a medium for plant growth?

The mineralogical composition and the physical, chemical and mechanical properties of the Mars soil have been the subject of a number of studies. Though definitive mineralogical measurements are lacking, elemental-chemical analyses and simulation experiments have indicated that clays are major components of the soil and that iron is present as adsorbed ion and as amorphous mineral coating the clay particles (Banin, 1986). Whether this soil can support plant growth or food production, utilizing conventional or advanced cultivational technologies, is a question that has not been thoroughly analyzed, but may be of importance and usefulness for the future exploration of Mars. Assuming that the proposed model of Mars soil components is valid, and drawing additional information from the analyses of the SNC meteorites believed to be ejected Mars rocks - the present contribution analyzes and evaluates the suitability of the soil as a medium for plant growth, attempting to identify the most critical limiting factors for such an undertaking and the possible remedies.

Banin, Amos↗

Elephant Moraine 87521 - The first lunar meteorite composed of predominantly mare material

This paper presents the results of trace-element analyses and detailed petrography obtained for the Elephant Moraine 87521 meteorite (EET87521) found recently in Antarctica. Its high values found for the Fe/Mn ratio and the bulk-Co content indicate that the EET87521 is not, as was originally classified, a eucrite. Moreover, its low Ga/Al and Na/Ca ratios exclude the possibility that it is an SNC meteorite. These and other characteristics (e.g., a very low Ti content) of the EET87521 suggest its affinity with very-low-Ti high-alumina varieties of lunar mare basalt.

Warren, Paul H.↗

Evolution of sulfide mineralization on Mars

It has been previously suggested, on the basis of compositional and petrographic similarities noted between komatites, SNC meteorites, and the silicate portion of the Martian regolith fines, that iron-sulfide ore deposites may exist on Mars. This paper examines the possible locations of Archean-type sulfide and related ore deposits on Mars, their evolution, and the emplacement mechanisms for the ore deposit. The clues to these questions are deduced by applying to Mars the temporal patterns of ore distribution on earth and the experimental observations on sulfur solubility in basaltic melts.

Burns, Roger G.↗

Iron-sulfur mineralogy of Mars - Magmatic evolution and chemical weathering products

Models are developed for the magmatic evolution and the oxidative weathering of sulfide minerals on Mars, based on petrogenetic associations among komatiitic rock types, Viking geochemical data, SNC meteorites, and terrestrial Fi-Ni deposits. The weathering model was tested by exposing komatiitic pyrrhotites and olivines to sulfuric acid solutions, with or without dissolved ferric iron, and identifying the reaction products by Moessbauer spectroscopy. The results suggest that, on Mars, acidic groundwater has induced oxidative weathering of pyrrhotite, yielding FeS2 and then FeOOH.

Burns, Roger G.↗

Proceedings of the MEVTV Workshop on The Evolution of Magma Bodies on Mars

The workshop focused on many of the diverse approaches related to the evolution of magma bodies on Mars that have been pursued during the course of the Mars Evolution of Volcanism, Tectonism, and Volatiles (MEVTV) Program. Approximately 35 scientists from the Mars volcanology, petrology, geochemistry, and modeling communities attended. Segments of the meeting concentrated of laboratory analyses and investigations of SNC meteorites, the interpretation of Viking Orbiter and Lander datasets, and the interpretation of computer codes that model volcanic and tectonic processes on Mars. Abstracts of these reports are presented.

Mouginis-Mark, P.↗