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162 records · Page 9

Investigating the Effects of Gamma Radiation on Selected Chemicals for Use in Biosignature Detection Instruments on the Surface of Jupiter's Moon Europa

Jupiter's moon Europa is a prime target for the search for potential signs of life in the solar system. The Europa Lander Science Definition Team Report outlined investigations and measurement requirements on a future Europa Lander and has led us to consider application of powerful techniques such as pyrolysis and derivatization gas chromatography mass spectrometry (GC-MS) and laser desorption mass spectrometry (LD-MS) to elucidate the organic composition of near-surface ice and minerals. Definitive identification of chemical biosignatures using such techniques is strongly enabled by the use of various chemicals, such as perfluorotributylamine (PFTBA) for the MS calibration, α-cyano-hydroxycinnamic acid (CHCA) for matrix-assisted laser desorption and ionization (MALDI) and N,N-dimethylformamide dimethyl acetal (DMF-DMA), N-tert-butyldimethylsilyl-N-methyltrifluoroacetamide (MTBSTFA) and tetramethylammonium hydroxide (TMAH) for wet chemistry GC-MS protocols. The jovian radiation environment is known to represent a uniquely challenging risk to mission performance and lifetime, principally due to high radiation levels. To assess the potential ionizing radiation damage to these important chemicals, we tested their effectiveness following gamma radiation exposure doses up to the anticipated Europa Lander rating requirement of 300 krad(Si). The chemicals were sealed in glass ampules under vacuum (<10 mTorr), to reduce trapped oxygen gas, as the oxidation by O2 may be enhanced in the presence of radiation. We report that all five chemicals exposed to total ionizing doses of 0, 150 and 300 krad(Si) maintained their full effectiveness, and no significant degradation was observed.

Radiation↗

MOVPE of GaSb/InGaAsSb Multilayers and Fabrication of Dual Band Photodetectors

Metalorganic vapor phase epitaxy (MOVPE) of GaSb/InGaAsSb multilayer thin films and fabrication of bias-selectable dual band photodetectors are reported. For the dual band photodetectors the short wavelength detector, or the upper p- GaSb/n-GaSb junction photodiode, is placed optically ahead of the long wavelength one, or the lower photodiode. The latter is based on latticed-matched In0.13Ga0.87As0.11Sb0.89 with bandgap near 0.6 eV. Specifically, high quality multilayer thin films are grown sequentially from top to bottom as p+-GaSb/p-GaSb/n-GaSb/n-InGaAsSb/p-InGaAsSb/p-GaSb on undoped p-type GaSb substrate, and as n-GaSb/p-GaSb/p-InGaAsSb/n-InGaAsSb/n-GaSb on Te-doped n-type GaSb substrate respectively. The multilayer thin films are characterized by optical microscope, atomic force microscope (AFM), electron microprobe analyses etc. The photodiode mesa steps are patterned by photolithography with wet chemical etching and the front metallization is carried out by e-beam evaporation with Pd/Ge/Au/Ti/Au to give ohmic contact on both n- and p-type Sb based layer surfaces. Dark I-V measurements show typical diode behavior for both the upper and lower photodiodes. The photoresponsivity measurements indicate that both the upper and lower photodiodes can sense the infrared illumination corresponding to their cutoff wavelengths respectively, comparable with the simulation results. More work is underway to bring the long wavelength band to the medium infrared wavelength region near 4 micrometers.

Xiao, Ye-Gao↗

Interface Conductance Under a Real Electronics Box

Electronics Boxes with high heat dissipations use a thermal interface material to increase heat transfer to the radiator in a vacuum/space environment. There are lots of materials to choose from, but for Spacecraft applications, there are more than high heat transfer metrics which must be met. Contamination (both particle generation and outgassing), ease of cutting, and removal are just as important metrics in material selection. However, vendor data of material thermal conductance is usually based on a 1" X 1" piece of material under high uniform pressures. Large Electronics boxes almost never have optimal pressures, as they are bolted along the perimeter and leave gaps in the center regions. In order to characterize the relative thermal conductance for large Electronics boxes, an 8" X 8" plate was fabricated to simulate an electronics box bottom and bolted around the perimeter to a cold plate. Various thermal interface materials were inserted between the box and cold plate, and overall thermal conductance's were calculated. A table was generated which compares the full gamut of thermal interface materials for large boxes, from a dry joint to a wet joint. Materials were placed in order of high to low conductance's, so an engineer can compare the benefit of each material in a real-world scenario.

Thermal Interface Conductance↗

Deep space communications, weather effects, and error control

Deep space telemetry is and will remain signal-to-noise limited and vulnerable to interference. A need exists to increase received signal power and decrease noise. This includes going to Ka-band in the mid-1990's to increase directivity. The effects of a wet atmosphere can increase the noise temperature by a factor of 5 or more, even at X-band, but the order of magnitude increase in average data rate obtainable at Ka-band relative to X-band makes the increased uncertainty a good trade. Lowbit error probabilities required by data compression are available both theoretically and practically with coding, at an infinitesimal power penalty rather than the 10 to 15 dB more power required to reduce error probabilities without coding. Advances are coming rapidly in coding, as with the new constraint-length 15 rate 1/4 convolutional code concatenated with the already existing Reed-Solomon code to be demonstrated on Galileo. In addition, high density spacecraft data storage will allow selective retransmissions, even from the edge of the Solar System, to overcome weather effects. In general, deep space communication was able to operate, and will continue to operate, closer to theoretical limits than any other form of communication. These include limits in antenna area and directivity, system noise temperature, coding efficiency, and everything else. The deep space communication links of the mid-90's and beyond will be compatible with new instruments and compression algorithms and represent a sensible investment in an overall end-to-end information system design.

Posner, Edward C.↗

NASA’s Space Launch System Stands Ready on Doorstep of Maiden Voyage Launch and Progress Made to Future Missions

NASA and its partners made significant progress towards the Artemis I launch in 2022. The integrated Space Launch System (SLS)vehicleand Orion spacecraft were first rolled out of the Vehicle Assembly Building (VAB) at NASA’s Kennedy Space Center (KSC) in March. SLS is a super heavy-lift vehicle to send large, strategic payloads to the Moon, Mars, and beyond. It isthebackbone of the Artemis human lunar exploration program. Rollout transported the vehicle to Launch Pad 39B for a series of tests, including the wet dress rehearsal (WDR). Multiple attempts were required to complete WDR, each building on the one before. Following the WDR campaign, NASA teams refined hardware and launch procedures, and the vehicle was prepared for its first launch attempt scheduled for August 29. Challenges with the weather and hardware resulted in a scrub on the 29th, and the second attempt was set for Sept. 3. A hydrogen leak on the tail service mast umbilical forced a scrub. NASA teams completed repairs and testing on the vehicle on Launch Pad 39B to preserve a launch attempt at the end of September. Managers chose to return the vehicle to the VAB to protect it fromthe threat of Hurricane Ian. Within the VAB, NASA further inspected and prepared SLS for selected November windows. In addition to progress to the Artemis I mission, significant progress was made on the Artemis II and Artemis III rockets. Progress was also made towards on the Block 1B and Block 2 variants, beginning on the fourth and ninth flight, respectively. Both variants will provide significant improvements in both launch mass and mission flexibility to multiple destinations. This paper will discuss Artemis I vehicle integration, testing, and available results from the launch campaign to date.

Bruce Askins↗

Study of liquid and vapor flow into a Centaur capillary device

The following areas of liquid and vapor flow were analyzed and experimentally evaluated; 1) the refilling of capillary devices with settled liquid, and 2) vapor flow across wetted screens. These investigations resulted in: 1) the development of a versatile computer program that was successfully correlated with test data and used to predict Centaur D-1S LO2 and LH2 start basket refilling; 2) the development of a semi-empirical model that was only partially correlated with data due to difficulties in obtaining repeatable test results. Also, a comparison was made to determine the best propellant management system for the Centaur D-1S vehicle. The comparison identified the basline Centaur D-1S system (using pressurization, boost pumps and propellant settling) as the best candidate based on payload weight penalty. However, other comparison criteria and advanced mission condition were identified where pressure fed systems, thermally subcooled boost pumps and capillary devices would be selected as attractive alternatives.

Blatt, M. H.↗

Elevated Temperature, Notched Compression Performance of Out of Autoclave Processed Composites

Curved honeycomb sandwich panels composed of carbon fiber reinforced toughened-epoxy polymer facesheets are being evaluated for potential use as payload fairing components on the NASA heavy-lift space launch system (HL-SLS). These proposed composite sandwich panels provide the most efficient aerospace launch structures, and offer mass and thermal advantages when compared with existing metallic payload fairing structures. NASA and industry are investigating recently developed carbon fiber epoxy prepreg systems which can be fabricated using out-of autoclave (OOA) processes. Specifically, OOA processes using vacuum pressure in an oven and thereby significantly reducing the cost associated with manufacturing large (up to 10 m diameter) composite structures when compared with autoclave. One of these OOA composite material systems, CYCOM(R) 5320-1, was selected for manufacture of a 1/16th scale barrel portion of the payload fairing; such that, the system could be compared with the well-characterized prepreg system, CYCOM(R) 977-3, typically processed in an autoclave. Notched compression coupons for each material were obtained from the minimum-gauge flat laminate [60/-60/0]S witness panels produced in this manufacturing study. The coupons were also conditioned to an effective moisture equilibrium point and tested according to ASTM D6484M-09 at temperatures ranging from 25 C up to 177 C. The results of this elevated temperature mechanical characterization study demonstrate that, for thin coupons, the OHC strength of the OOA laminate was equivalent to the flight certified autoclave processed composite laminates; the limitations on the elevated temperature range are hot-wet conditions up to 163 C and are only within the margins of testing error. At 25 C, both the wet and dry OOA material coupons demonstrated greater OHC failure strengths than the autoclave processed material laminates. These results indicate a substantial improvement in OOA material development and processing since previous studies have consistently reported OOA material strengths on par or below those of autoclave processed composite laminates.

Grimsley, Brian W.↗

Dimethylsilanediol (DMSD) Source Assessment and Mitigation on ISS: Estimated Contributions from Personal Hygiene Products Containing Volatile Methyl Siloxanes (VMS)

Dimethylsilanediol (DMSD) is a small organosilicon compound present in humidity condensate on the International Space Station. Aqueous DMSD originates from volatile methyl siloxane (VMS) compounds in the ISS cabin atmosphere. DMSD is not effectively removed by the WPA (Water Processor Assembly), requiring removal and replacement of both WPA Multifiltration (MF) Beds for an estimated resupply penalty of approximately 70 kg/year. Analyses indicate that WPA can handle DMSD if the concentration in the condensate can by reduced by fifty percent. Personal Hygiene Products (PHPs) used by crew are suspected to be a significant source of VMS. Source removal of VMS will be required to achieve a measurable impact to the DMSD concentration in the condensate. The inventory of total crew provisions for ISS was analyzed to identify silicon containing materials and products used for personal hygiene that emit VMS. Accounting for the wide range in mass of hygiene product applied to skin or hair, the frequency of application, the product selection, the number of crew using a given product, the range in silicon mass fraction of different products, and the potential vaporization of the product, the potential total VMS emissions from personal hygiene products for a crew of six on ISS were estimated. The total daily VMS emissions from PHPs estimate ranges from 261 to 1145 mg-Si per day, compared to total estimated VMS generation rates on ISS of 800 to 1500 mg-Si per day. The main sources of VMS were determined to be antiperspirants (173 to 696 mg-Si per day), skin lotions (63 to 248 mg-Si per day), wipes (25 to 124 mg-Si per day) and hair conditioner (0 to 69 mg-Si per day). Several siloxanes-free options are available for deodorants, wet wipes, lotions, and leave-in conditioners. These products are now being assessed for crew member use in future increments.

Muirhead, Dean L.↗

Early Results from a Broad Compatibility Study of Various Materials with Ionic Silver Biocide

Ionic silver is baselined for microbial control in spacecraft potable water systems forfuture exploration missions, but materials compatibility analysis is required to evaluate thepassive depletion of ionic silver concentration onto wetted material surfaces over time.Various articles concerning such testing have been published that examine interactions withwater containing ionic silver biocide, but most tests have focused on only a couple ofmaterials each and comparing results of different evaluations to one another has provedchallenging.This paper reports the first results from static exposure testing of a large arrayof material coupons to a 400 parts per billion (ppb) aqueous silver fluoride (AgF) solution,using a surface to volume ratio of approximately 2 cm-1. The test is designed in two mainstages. Stage 1 is a one-week screening to evaluate silver uptake. Materials that performmodestly to well after that week are promoted to Stage 2, which is a longer test with periodicsampling to examine the silver uptake rates over time; these samples are evaluated for otherwater quality parameters in addition to the remaining silver concentration. In a tangentialinvestigation, select materials that take up some silver in Stage 1 may be “aged” by repeatingthe Stage 1 test to determine whether repeated exposure reduces silver uptake rate, andsuccessfully aged materials may then continue to Stage 2 testing. The materials under testinclude metallic and polymeric materials with various surface finishes, treatments, andcoatings, as well as select other materials historically used in spacecraft water systems. Thistest began in August 2019, and thus only includes early results; future follow-on papers willinclude additional results as the test progresses. The ultimate goal builds a broad, easilycomparable data set that can be used to guide material selections for silver biocide-compatible spacecraft water system design.

Silver Biocide↗

Structures Self-Assembled Through Directional Solidification

Nanotechnology has created a demand for new fabrication methods with an emphasis on simple, low-cost techniques. Directional solidification of eutectics (DSE) is an unconventional approach in comparison to low-temperature biomimetic approaches. A technical challenge for DSE is producing microstructural architectures on the nanometer scale. In both processes, the driving force is the minimization of Gibb's free energy. Selfassembly by biomimetic approaches depends on weak interaction forces between organic molecules to define the architectural structure. The architectural structure for solidification depends on strong chemical bonding between atoms. Constituents partition into atomic-level arrangements at the liquid-solid interface to form polyphase structures, and this atomic-level arrangement at the liquid-solid interface is controlled by atomic diffusion and total undercooling due to composition (diffusion), kinetics, and curvature of the boundary phases. Judicious selection of the materials system and control of the total undercooling are the keys to producing structures on the nanometer scale. The silicon-titanium silicide (Si-TiSi2) eutectic forms a rod structure under isothermal cooling conditions. At the NASA Glenn Research Center, directional solidification was employed along with a thermal gradient to promote uniform rods oriented with the thermal gradient. The preceding photomicrograph shows the typical transverse microstructure of a solidified Si-TiSi2 eutectic composition. The dark and light gray regions are Si and TiSi2, respectively. Preferred rod orientation along the thermal gradient was poor. The ordered TiSi2 rods have a narrow distribution in diameter of 2 to 3 m, as shown. The rod diameter showed a weak dependence on process conditions. Anisotropic etch behavior between different phases provides the opportunity to fabricate structures with high aspect ratios. The photomicrographs show the resulting microstructure after a wet chemical etch and a dry plasma etch. The wet chemical etches the silicon away, exposing the TiSi2 rods, whereas plasma etching preferentially etches the Si-TiSi2 interface to form a crater. The porous architectures are applicable to fabricating microdevices or creating templates for part fabrication. The porous rod structure can serve as a platform for fabricating microplasma devices for propulsion or microheat exchangers and for fabricating microfilters for miniatured chemical reactors. Although more work is required, self-assembly from DSE can have a role in microdevice fabrication.

Dynys, Frederick W.↗

Biomass Burning and Water Balance Dynamics in the Lake Chad Basin in Africa

The present study investigates the effect of biomass burning on the water cycle using a case study of the Chari-Logone Catchment of Lake Chad Basin. The Chari-Logone catchment was selected since it supplies over 90% of the water input to the Lake, which is the largest basin in the NSSA. Two water balance simulations, one considering burning and one without, were compared from the years 2003 to 2011. For a more comprehensive assessment of the effects of burning, albedo change, which has been shown to have a significant impact on a number of environmental factors, was used as a model input for calculating potential evapotranspiration. Analysis of the burning scenario show that burning grassland, which composes almost 75% of Chari-Logone total land cover, causes increased ET and runoff during winter months. Recent studies have demonstrated the increasing trend in LCB of converting shrubland, grassland, and wetlands to cropland. This change from grassland to cropland has the potential of decreasing water available to water bodies during the winter. All vegetative classes in a burning scenario showed a decrease in ET during the wet season, supporting the idea that, with increased burning, there would be a severe decrease of precipitation.

africa↗

Interaction of the terrestrial and atmospheric hydrological cycles in the context of the North American southwest summer monsoon

Work under this grant has used information on precipitation and water vapor fluxes in the area of the Mexican Monsoon to analyze the regional precipitation climatology, to understand the nature of water vapor transport during the monsoon using model and observational data, and to analyze the ability of the TRMM remote sensing algorithm to characterize precipitation. An algorithm for estimating daily surface rain volumes from hourly GOES infrared images was developed and compared to radar data. Estimates were usually within a factor of two, but different linear relations between satellite reflectances and rainfall rate were obtained for each day, storm type and storm development stage. This result suggests that using TRMM sensors to calibrate other satellite IR will need to be a complex process taking into account all three of the above factors. Another study, this one of the space-time variability of the Mexican Monsoon, indicate that TRMM will have a difficult time, over the course of its expected three year lifetime, identifying the diurnal cycle of precipitation over monsoon region. Even when considering monthly rainfalls, projected satellite estimates of August rainfall show a root mean square error of 38 percent. A related examination of spatial variability of mean monthly rainfall using a novel method for removing the effects of elevation from gridded gauge data, show wide variation from a satellite-based rainfall estimates for the same time and space resolution. One issue addressed by our research, relating to the basic character of the monsoon circulation, is the determination of the source region for moisture. The monthly maps produced from our study of monsoon variability show the presence of two rainfall maxima in the analysis normalized to sea level, one in south-central Arizona associated with the Mexican monsoon maximum and one in southeastern New Mexico associated with the Gulf of Mexico. From the point of view of vertically-integrated fluxes and flux divergence of water vapor from ECMWF data, most moisture at upper levels arrives from the Gulf of Mexico, while low level moisture comes from the northern Gulf of California. Composites of ECMWF analyses for wet and dry periods (classified by rain gauge data) show that both regimes show low level moisture arriving from northern and central Gulf of California. Above 700 MB, moisture comes from both source regions and the Sierra Madre Occidental. During wet periods a longer fetch through the moist air mass above western Mexico results in a greater moisture flux into the Sonoran Desert region, while there is less moisture from the Gulf of Mexico both above and below 700 mb. Work on the grant subcontract at the University of Colorado concentrated on the development of a technique useful to TRMM combining visible, infrared and passive microwave data for measuring precipitation. Two established techniques using either visible or infrared data applied over the US Southwest correlated with gauges at the 0.58 to 0.70 level. The application of some established passive microwave techniques were less successful for a variety of reason, including problems in both the gauge and satellite data quality, sampling problems and weaknesses inherent in the algorithms themselves. A more promising solution for accurate rainfall estimation was explored using visible and infrared data to perform a cloud classification, which when combined with information about the background (e.g. Iand/ocean), was used to select the most appropriate microwave algorithm from a suite of possibilities.

Dickinson, Robert E.↗

Performance of Two Cloud-Radiation Parameterization Schemes in the Finite Volume General Circulation Model for Anomalously Wet May and June 2003 Over the Continental United States and Amazonia

An objective assessment of the impact of a new cloud scheme, called Microphysics of Clouds with Relaxed Arakawa-Schubert Scheme (McRAS) (together with its radiation modules), on the finite volume general circulation model (fvGCM) was made with a set of ensemble forecasts that invoke performance evaluation over both weather and climate timescales. The performance of McRAS (and its radiation modules) was compared with that of the National Center for Atmospheric Research Community Climate Model (NCAR CCM3) cloud scheme (with its NCAR physics radiation). We specifically chose the boreal summer months of May and June 2003, which were characterized by an anomalously wet eastern half of the continental United States as well as northern regions of Amazonia. The evaluation employed an ensemble of 70 daily 10-day forecasts covering the 61 days of the study period. Each forecast was started from the analyzed initial state of the atmosphere and spun-up soil moisture from the first-day forecasts with the model. Monthly statistics of these forecasts with up to 10-day lead time provided a robust estimate of the behavior of the simulated monthly rainfall anomalies. Patterns of simulated versus observed rainfall, 500-hPa heights, and top-of-the-atmosphere net radiation were recast into regional anomaly correlations. The correlations were compared among the simulations with each of the schemes. The results show that fvGCM with McRAS and its radiation package performed discernibly better than the original fvGCM with CCM3 cloud physics plus its radiation package. The McRAS cloud scheme also showed a reasonably positive response to the observed sea surface temperature on mean monthly rainfall fields at different time leads. This analysis represents a method for helpful systematic evaluation prior to selection of a new scheme in a global model.

Sud, Y. C.↗

Characterization of microbial and chemical composition of shuttle wet waste with permanent gas and volatile organic compound analyses

Solid-waste treatment in space for Advanced Life Support, ALS, applications requires that the material can be safely processed and stored in a confined environment. Many solid-wastes are not stable because they are wet (40-90% moisture) and contain levels of soluble organic compounds that can contribute to the growth of undesirable microorganisms with concomitant production of noxious odors. In the absence of integrated Advanced Life Support systems on orbit, permanent gas, trace volatile organic and microbiological analyses were performed on crew refuse returned from the volume F "wet" trash of three consecutive Shuttle missions (STS-105, 109, and 110). These analyses were designed to characterize the short-term biological stability of the material and assess potential crew risks resulting from microbial decay processes during storage. Waste samples were collected post-orbiter landing and sorted into packaging material, food waste, toilet waste, and bulk liquid fractions deposited during flight in the volume F container. Aerobic and anaerobic microbial loads were determined in each fraction by cultivation on R2A and by acridine orange direct count (AODC). Dry and ash weights were performed to determine both water and organic content of the materials. Experiments to determine the aerobic and anaerobic biostability of refuse stored for varying periods of time were performed by on-line monitoring of CO2 and laboratory analysis for production of hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA Method TO15 by USEPA et al. [EPA Method TO15, The Determination of Volatile Organic Compounds (VOCs) in Ambient Air using SUMMA, Passivated Canister Sampling and Gas Chromatographic Analysis,1999] with gas chromatography/mass spectrometry and by gas chromatography with selective detectors. These baseline measures of waste stream content, labile organics, and microbial load in the volume F Shuttle trash provide data for waste subsystem analysis and atmospheric management within the ALS Project. Published by Elsevier Ltd on behalf of COSPAR.

NASA Center KSC↗

Isothermal Microcalorimetric Evaluation of Compatibility of Proposed Injector Materials with High-Test Hydrogen Peroxide Propellant

High-test hydrogen peroxide (HTP) is receiving renewed interest as a monopropellant and as the oxidizer for bipropellant systems. HTP is hydrogen peroxide in concentrations ranging from 70 to 98%. All surfaces wetted by HTP must be evaluated for compatibility with the fluid. In the case of tanks, lines and valves compatibility is required to preserve the HTP oxygen and energy content and to avoid overpressurization due to decomposition. With injectors and regenerative cooling passages shorter exposure time reduces these concerns. However, phase changes from fluid to gas impact heat transfer and become the dominant compatibility concern. Isothermal microcalorimetry (IMC) provides a convenient and reproducible means to observe the decomposition of HTP when exposed to structural materials and therefore the compatibility of those materials'. The instrument provides heat flow values in terms of watts that may be converted to a reaction rate given the heat of reaction for the decomposition of hydrogen peroxide. These values are then converted to percent active oxygen loss per week (%AOL/wk) to preserve an earlier convention for quantifying HTP compatibility. Additionally, qualitative designations of compatibility have been assigned to these values. This scheme consists of four classes with Class 1 being the most compatible. While historical compatibility data is available its current applicability is in question due to subtle changes in the compositions of both HTP and structural materials. Trace levels of molecules can have significant influence on compatibility. Therefore representative samples of materials must be evaluated with current HTP formulations. In this work seven materials were selected for their strength characteristics at high temperature as expected in a HTP injector. The materials were then evaluated by IMC for HTP compatibility.

Gostowski, Rudy↗

High-Energy-Density Capacitors

Capacitors capable of storing energy at high densities are being developed for use in pulse-power circuits in such diverse systems as defibrillators, particle- beam accelerators, microwave sources, and weapons. Like typical previously developed energy-storage capacitors, these capacitors are made from pairs of metal/solid-dielectric laminated sheets that are wound and pressed into compact shapes to fit into cans, which are then filled with dielectric fluids. Indeed, these capacitors can be fabricated largely by conventional fabrication techniques. The main features that distinguish these capacitors from previously developed ones are improvements in (1) the selection of laminate materials, (2) the fabrication of the laminated sheets from these materials, and (3) the selection of dielectric fluids. In simplest terms, a high-performance laminated sheet of the type used in these capacitors is made by casting a dielectric polymer onto a sheet of aluminized kraft paper. The dielectric polymer is a siloxane polymer that has been modified with polar pendant groups to increase its permittivity and dielectric strength. Potentially, this polymer is capable of withstanding an energy density of 7.5 J/cm3, which is four times that of the previous state-of-the-art-capacitor dielectric film material. However, the full potential of this polymer cannot be realized at present because (1) at thicknesses needed for optimum performance (.8.0 m), the mechanical strength of a film of this polymer is insufficient for incorporation into a wound capacitor and (2) at greater thickness, the achievable energy density decreases because of a logarithmic decrease in dielectric strength with increasing thickness. The aluminized kraft paper provides the mechanical strength needed for processing of the laminate and fabrication of the capacitor, and the aluminum film serves as an electrode layer. Because part of the thickness of the dielectric is not occupied by the modified siloxane polymer, the achievable energy density must be somewhat less than the maximum value. The laminate is produced by a continuous film-casting process, using the machinery depicted schematically in the figure. The designs of the process and machinery are dictated partly by the fact that during the processing step prior to casting the polymer, the aluminized kraft paper becomes wet with water. Because the polymer resin to be cast is hydrophobic, the paper must be dried to make it possible to coat the paper uniformly, leaving no pinholes. Accordingly, an infrared heater is placed next to the paper feed roll to dry the paper prior to casting.

Slenes, Kirk↗

Projections of Declining Surface-Water Availability for the Southwestern United States

16 of the CMIP5 models had all the data needed for this work for at least one simulation that was continuous from 1950 to 2040. Details of the models analyzed here are provided in Table S1. The model data analyzed here are available at http://strega.ldeo.columbia.edu:81/expert/home/.naomi/.AR5/.v2/.historical:rcp85/.mmm16/ a. Assessing the climatology of the models Despite increases in horizontal resolution of many models compared to their CMIP3 counterparts none of these models can adequately resolve the topography of the south west United States, such as the Sierra Nevada and Rocky Mountains and the associated orographic precipitation. This requires that caution be used when interpreting the results presented here. To assess the ability of the models to simulate the current hydroclimate, in Figure S1 we show the observed (from the Global Precipitation Climatology Centre gridded rain gauge data, (1)) monthly climatology of precipitation and the same for all the models and the multimodel mean for the California-Nevada, Colorado headwaters and Texas regions. The GPCC data uses rain gauges only and interpolates to regular grids of which we used the 1◦ by 1◦ one. Details of the data set can be found in (2). While the models apparently overestimate precipitation in California and Nevada the seasonal cycle with wet winters and dry summers is very well represented. It is also possible that the rain gauge observations are biased low by inadequately sampling the higher mountain regions. How ever the models might also be expected to underestimate orographic precipitation due to inadequate horizontal resolution. The 25 models are also too wet in the Colorado headwaters region but correctly represent the quite even distribution though the year. The bimodal distribution of precipitation in Texas, with peaks in May and September, and the absolute amounts, are well modeled but with the September peak too weak. The positive precipitation bias translates into a positive runoff bias for the Colorado headwaters as also shown in Figure S1. Here the observed runoff values are taken from simulations of the Variable Infiltration Capacity (VIC) land surface-hydrology model (3) forced by observed meteorology (5) that were conducted as part of the North American Land Data Assimilation System project phase 2 ( (NLDAS-2), http://www.emc.ncep.noaa.gov/mmb/nldas/. Runoff for California-Nevada is better simulated but there is a positive bias over Texas despite no strong precipitation bias. To check whether regional climate models better simulate P and runoff in these regions we analyzed the historical simulation with the Regional Climate Model version 3 driven by the National Centers for Environmental Prediction-Department of Energy Reanalysis 2 available from the North American Regional Climate Change Assessment Program (http://www.narccap.ucar.edu). This model configuration retained these biases in P and runoff although they were reduced in amplitude. Given these varying biases we plot P and P − E changes in actual values but apply the simplest bias correction possible to the runoff and soil moisture values and show the modeled changes in terms of percentages of the 20th Century model climatologies. A thorough assessment of the simulation of North American climate in CMIP5 models is conducted in Sheffield at al. (North American Climate in CMIP5 Experiments. Part I: Evaluation of 20th Century Continental and Regional Climatology, manuscript submit ted to J. Climate, available at http://www.climate.noaa.gov/index.jsp?pg=./cpo pa/ mapp/cmip5 publications.html). Sheffield et al. analyze the climatology of precipitation, surface air temperature, low level winds, moisture fluxes, runoff etc. and conclude that the main features of the hydrological cycle, including characteristics of the atmospheric moisture balance and its seasonality, are captured in the CMP5 models subject to biases in total precipitation amounts. We chose to use all available models instead of selecting some and rejecting others based on an assessment of model realism. This is in accord with the suggestions of Mote et al. for CMIP3 (4) but future work needs to revisit this matter for the case of the CMIP5 ensemble.

Seager, Richard↗

Proposed Mars Surveyor Landing Sites in Northern Meridiani Sinus, Southern Elysium Planitia, and Argyre Planitia

Our objective is to propose two landing sites that the Mars Surveyor 2001 Lander and Athena Rover could go to on Mars that should meet the safety requirements of the spacecraft landing system and optimize surface operations (chiefly driven by power and communications requirements). An additional site within Argyre Planitia, initially proposed by Parker to the Mars Surveyor Landing Site program, is also proposed for potential consideration for post-2001 missions to Mars, as it is well outside the current latitude limits for the Athena Rover. All three sites are designed to be situated as close to a diversity of geologic units within a few kilometers of the landing site so that diversity can be placed in a geologic context. This objective is very different from the Mars Pathfinder requirement to land at a site with a maximum chance for containing a diversity of rocks within a few tens of meters of the lander. That requirement was driven by the Sojourner mobility limit of a few tens of meters. It can be argued that the Athena project, with its much larger mobility capability, might actually want to avoid such a site, because placing collected samples in geologic context would be difficult. While it has been argued, both before and after the Mars Pathfinder landing, that the provenance for local blocks may be determined by orbiter spectra, primarily from the MGS TES instrument, our ability to do so has yet to be demonstrated. Indeed, several months after conclusion of the Pathfinder mission, we have yet to reach a consensus on the composition of local materials. Our primary data set for selecting a landing site within the latitude and elevation constraints of the 2001 mission is the Viking Orbiter image archive. The site must be selected to place the landing ellipse so as to avoid obvious hazards, such as steep slopes, large or numerous craters, or abundant large knobs. For this purpose, we chose a resolution limit of better than 50 m/pixel. This necessarily excludes from the present study images from current and future orbiter spacecraft, until such data does become readily available. Within each proposed region, it may be possible to identify additional sites once these data become available. Second, the fine-component thermal inertia data, should be greater than about 5 or 6 cgs Units (10(exp -3) cal/sq cm s(exp -0.5)/K). Low thermal inertias imply dusty environments, which could pose a mobility hazard. Similarly, the albedo of the site should not be particularly high, which would also suggest dusty surfaces. Low albedos are preferred, as they often coincide with low Viking red:violet ratios and indicate less dusty surfaces. Next, the Modeled Block Abundance should also not be too high or too low. Based on the Viking Lander and Mars Pathfinder experiences, percentages of blocks should be on the order of 5-25%. Too many blocks could pose a hazard to the landing and mobility. Too few blocks could also indicate a dusty surface. Primary Landing Site: Northern Meridiani Sinus (Proposed by T. J. Parker and K., S. Edgett) Vital Statistics: (1) Latitude, Longitude: 0-3 N, 350-2 W. *Elevation (Viking): about0.5-1.5 Ian. (2) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbits 709A and 410B). Possible stereo coverage in region where two orbits overlap (probably small parallax angle, as these orbits are not listed in NASA Contractor Report 3501) (3) Albedo: about .18 -.26 (4) Block Abundance: 5-26% (5)Fine-Component Thermal Inertia: 5-9 cgs units This region consists of bright deposits similar to those described by Edgett et al, that also lie within a prominent dark albedo region. These deposits are flat-lying, to such a degree that they ramp against topography rather than draping over it. This led Edgett and Parker to suggest that they may be subaqueous sediments, possibly lacustrine or marine evaporites, laid down sometime from the late Noachian to middle Hesperian (age determination pending crater counts). A contact between this material and elevated, dissected highlands to the south was identified , and is described by Edgett et al. Our desire in proposing this landing site is to sample the edge of this deposit where it has been exposed through etching, presumably eolian deflation (the deposit, though in the highlands, is itself only lightly to moderately cratered). This should enable access to in situ stratigraphy. The actual landing site will be selected where slopes are not expected to be steep, such that the rover itself should be able to traverse them and sample layered materials on the way, either up or down the slope. Perhaps due to uncertainties at this time as to the friability or meter-scale roughness of the deposit, it might make sense to place the landing ellipse on the exhumed highland surface adjacent to the deflated margin of the deposit and plan on driving to the deposit rather than landing on it and driving downslope. This should also enable imaging the margin for evidence of layering should it prove too difficult to climb. A target ellipse on the highland surface should also allow Athena access to ancient Noachian highland materials, particularly if placed near crater ejecta or an inlier of knobby material. Secondary Landing Site: Southern Elysium Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 1.5-3.5 S, 195-198 W. (2) Elevation (Viking): -1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbit 725). Possible stereo coverage between images from beginning and end of orbit that overlap (probably small parallax angle) (4) Albedo: about .27-.28 (5) Block Abundance: 4-7% (6) Fine-Component Thermal Inertia: about 3 cgs units This region consists of eroded knobby material, probably of Noachian age, though much of the crater population has been destroyed, that is onlapped at a sharp contact by an extensive plains unit in southern Elysium Planitia that is Amazonian in age. The plains materials have been attributed to unusually low-viscosity flood lavas from fissures south of the Elysium volcanic rise, or to lacustrine materials associated with a large, Amazonian lake at the source of Marte Vallis. Parker and Schenk presented evidence in support of the latter interpretation, though they attributed the putative shore morphology to an embayment of a northern plains ocean into the southern Elysium region. Detailed examination of the margin of the deposit, showing erosion, not simply burial, of small crater rims and fluidized ejecta blankets, also points to lacustrine or marine sedimentation rather than volcanic plains burial. The plains surface exhibits a "crusty" appearance that many researchers have attributed to pressure ridges in lava flows. In a lacustrine context, they also resemble pressure ridges in desiccated evaporite deposits and salt-rimmed pools (now dry) similar in scale and morphology to spectacular, hundred meter-scale pool rims in alkaline Lake Natron, East African Rift. The eroded highland margin surface adjacent to these plains appears to be fairly smooth, even at 15 m/pixel. Isolated knob inliers are scattered from a few kilometers to several tens of "kilometers apart. Heights of the knobs have not been measured yet but, based on experience with similar features in the Pathfinder landing ellipse, are probably typically on the order of several tens of meters high and smaller, though some of the largest knobs in the region are probably up to a few hundred meters high. Two craters larger than a kilometer in diameter, with fluidized deposits, lie nearby the proposed landing site. Very high-resolution images from MOC should help to determine whether a landing site navigable by the Athena rover could be placed in this region. The space between knobs and craters is large enough to enable placement of a target landing ellipse between them but still provide access to one or more of them and to the margin of the Elysium plains material. Post-2001 Mars Surveyor Landing Site: Argyre Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 55-56 S, 41-43 W. (2) Elevation (Viking): 1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 40 m/pixel images (orbits 567B, 568B, and 569B). Excellent stereo coverage with large parallax angles over the entire landing site region, and much of central and southern Argyre. (4) Albedo: about .23-.24 (5) Block Abundance: No data (6) Fine-Component Thermal Inertia: No data The floors of both the Argyre and Hellas basins contain etched layered materials that are probably thick accumulations of channel or lacustrine sediments. The deposits in Hellas are much more eroded than those in Argyre, and Hellas lacks a channel outlet. Argyre is unique in that Uzboi Vallis flowed out of the basin, requiring overflow of a standing body of water within Argyre. This makes it the largest impact basin on Mars with channels both draining into it and flowing out from it. Hellas' channels may be catastrophic flood channels, whereas Argyre was fed by modest-scale valley networks, though the outlet at Uzboi Vallis was a catastrophic flood Highland craters and basins of this kind should be high-priority landing targets for missions intended to focus on the search for either prebiotic organic materials or even simple fossil microorganisms. Basins with internally-draining valley networks should be preferred over flood channels, as they could have provided the long-term influx of water favorable to the origin of life. (Catastrophic floods are not conducive to fossil preservation, due to their very short durations and high transportation energies). They also afford an opportunity to study the evolution of the planet's climate and volatiles during the period of time between the late Noachian and early Hesperian, when a drastic change from a proposed early warm, wet climate to one more closely resembling the modern environment is thought to have occurred. Large basin

Parker, T. J.↗