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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Raytracing the long trace profiler

The optical design of the Long Trace Profiler optical system is explored with a commercial raytrace program, Zemax OpticStudio™ (ZOS)1, with the intent of finding and correcting sources of systematic error. ZOS provides both geometric raytracing tools and physical optics Gaussian beam propagation and diffraction image calculation tools, and two design modes, sequential component (SC) and non-sequential component (NSC) that are optimized for different aspects of the design process. The original LTP-II system employs a singlet lens with a 1250 mm focal length. It is optimized to provide minimum distortion over a surface slope angle range of ±5 mrad. Using the ZOS tools, we are able to simulate ghost rays that produce distortion in the beam spot image and can minimize the distortion by deliberate misalignment of the beamsplitter (BS) components. Unfortunately, the reference beam is compromised because of the component tilts. The most recent LTP500 system design simplifies the optical system and makes the reference beam usable again, even with misalignment of the polarizing beamsplitter (PBS). Two lenses are designed for the LTP500 - a cemented doublet that has been fabricated, and a singlet with one aspheric surface. Both have focal distances of 500 mm with an expanded angular measurement range of ±10 mrad. The aspheric singlet provides superior performance. ZOS allows the import of wavefront measurement data produced by commercial interferometer software. We apply the wavefront error measurement from the cemented doublet to the model to show that the 19nm RMS wavefront error needs to be improved by at least a factor of ten in order to reduce the systematic error to a level that will allow the LTP to approach its design limit of a few tens of nanoradians.

Takacs, Peter Z.↗
NASA NTRS1989

Antennas for 20/30 GHz and beyond

Antennas of 20/30 GHz and higher frequency, due to the small wavelength, offer capabilities for many space applications. With the government-sponsored space programs (such as ACTS) in recent years, the industry has gone through the learning curve of designing and developing high-performance, multi-function antennas in this frequency range. Design and analysis tools (such as the computer modelling used in feedhorn design and reflector surface and thermal distortion analysis) are available. The components/devices (such as BFN's, weight modules, feedhorns and etc.) are space-qualified. The manufacturing procedures (such as reflector surface control) are refined to meet the stringent tolerance accompanying high frequencies. The integration and testing facilities (such as Near-Field range) also advance to facilitate precision assembling and performance verification. These capabilities, essential to the successful design and development of high-frequency spaceborne antennas, shall find more space applications (such as ESGP) than just communications.

Chen, C. Harry↗
DOE OSTI2020

Probing the angular and polarization reconstruction of the ARIANNA detector at the South Pole

The sources of ultra-high energy (UHE) cosmic rays, which can have energies up to 10 20 eV, remain a mystery. UHE neutrinos may provide important clues to understanding the nature of cosmic-ray sources. ARIANNA aims to detect UHE neutrinos via radio (Askaryan) emission from particle showers when a neutrino interacts with ice, which is an efficient method for neutrinos with energies between 10 16 eV and 10 20 eV. The ARIANNA radio detectors are located in Antarctic ice just beneath the surface. Neutrino observation requires that radio pulses propagate to the antennas at the surface with minimum distortion by the ice and firn medium. Using the residual hole from the South Pole Ice Core Project, radio pulses were emitted from a transmitter located up to 1.7 km below the snow surface. By measuring these signals with an ARIANNA surface station, the angular and polarization reconstruction abilities are quantified, which are required to measure the direction of the neutrino. After deconvolving the raw signals for the detector response and attenuation from propagation through the ice, the signal pulses show no significant distortion and agree with a reference measurement of the emitter made in an anechoic chamber. Furthermore, the signal pulses reveal no significant birefringence for our tested geometry of mostly vertical ice propagation. The origin of the transmitted radio pulse was measured with an angular resolution of 0.37° indicating that the neutrino direction can be determined with good precision if the polarization of the radio-pulse can be well determined. In this work, we obtained a resolution of the polarization vector of 2.7°. Neither measurement show a significant offset relative to expectation.

47 OTHER INSTRUMENTATION↗
NASA NTRS1982

Elastic Surface Wrinkling

Instability phenomena in elastic surfaces subject to compressive stresses are examined theoretically in new report. Theory is potentially applicable to such practical problems as aircraft panel flutter, nondestructive testing, piezoelectric transducer design, distortion of optical surfaces, and tolerance studies of very precise machine parts.

Zak, M.↗
NASA NTRS1975

A generalized hyperbolic marching method for chemically reacting 3-D supersonic flow using a splitting technique

A generalized hyperbolic marching method employing a nonorthogonal coordinate system and using a split differencing scheme for calculating steady supersonic flow over aerodynamic shapes is presented. It is a second-order-accurate mixed explicit-implicit procedure that solves the inviscid adiabatic and nondiffusive equations for chemically reacting flow in integral conservation-law form. The relationship between the integral and differential forms of the equations are examined and the relative merits of each discussed. The method admits initial Cauchy data situated on any arbitrary surface and integrates them forward along a general curvilinear coordinate, distorting and deforming the surface as it advances. The chemical kinetics term is split from the convective terms which are themselves dimensionally split, thereby freeing the fluid operators from the restricted step-size imposed by the chemical reactions and increasing the computational efficiency. The accuracy of this splitting technique is analyzed, a sufficient stability criterion is established, and comparisons are made with another method.

Rizzi, A. W.↗
NASA NTRS1988

The structure of sheared turbulence near a plane boundary

An analysis is presented of how a plane boundary affects the structure of turbulence in a sheared free stream. A uniform-shear boundary layer (USBL) is formulated with slip velocity condition at the surface, and inhomogeneous rapid distortion theory is applied. The effects of blocking by the surface on the turbulence structure in USBL is compared with those in the shear-free boundary layer (SFBL). Shear produces highly anisotropic eddies elongated in the flow direction. The vertical velocity variance is reduced with shear at all heights, roughly in proportion to the reduction in the homogeneous value, but the shape of the profile remains unchanged only near the surface. The streamwise integral scales increase with shear, indicating elongation of the streamwise extent of eddies.

Lee, Moon J.↗
NASA NTRS1976

Split Space-Marching Finite-Volume Method for Chemically Reacting Supersonic Flow

A space-marching finite-volume method employing a nonorthogonal coordinate system and using a split differencing scheme for calculating steady supersonic flow over aerodynamic shapes is presented. It is a second-order-accurate mixed explicit-implicit procedure that solves the inviscid adiabatic and nondiffusive equations for chemically reacting flow in integral conservation-law form. The relationship between the finite-volume and differential forms of the equations is examined and the relative merits of each discussed. The method admits initial Cauchy data situated on any arbitrary surface and integrates them forward along a general curvilinear coordinate, distorting and deforming the surface as it advances. The chemical kinetics term is split from the convective terms which are themselves dimensionally split, thereby freeing the fluid operators from the restricted step size imposed by the chemical reactions and increasing the computational efficiency. The accuracy of this splitting technique is analyzed, a sufficient stability criterion is established, a representative flow computation is discussed, and some comparisons are made with another method.

Rizzi, Arthur W.↗
DOE OSTI2021

Effect of Ligand Polarity on the Internal Dipoles and Ferroelectric Distortion in BaTiO 3 Nanocubes

Here, surface adsorbates and surrounding matrix species have been demonstrated to affect the properties of nanoscale ferroelectrics and nanoscale ferroelectric composites; potentially counteracting performance losses that can occur in small particle sizes. In this work, the effects of nonpolar oleic acid (OA) and polar tetrafluoroborate (BF 4 - ) ligand capping on the surface of various sizes of BaTiO 3 nanocubes have been investigated with combined neutron diffraction and neutron pair distribution function (PDF), density functional theory (DFT), and ab initio molecular dynamics (AIMD) methods. The low real space PDF region provides an unobstructed view of rhombohedral (split short and long) Ti-O distances in BaTiO 3 nanocubes, mimicking the well-established order-disorder local structure found in bulk BaTiO 3 . Interestingly, the intermediate-range order in nanocubes is found to be orthorhombic, rather than tetragonal. It is concluded that polar ligands adsorbed at BaTiO 3 surfaces stabilize the correlation length scale of local rhombohedral distortions in ferroelectric nanoparticles relative to nonpolar ligands.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Effect of Collective Dynamics and Anharmonicity on Entropy in Heterogenous Catalysis: Building the Case for Advanced Molecular Simulations

In this paper, we present a perspective on the computational determination of entropy and its effects and consequences on heterogeneous catalysis. Special attention is paid to the role of anharmonicity and the deviations from the standard harmonic oscillator approximations which can fail to provide a reliable assessment of entropy. To address these challenges, advanced methodologies are needed that can explicitly account for these thermodynamic drivers through the appropriate statistical sampling of reactive free energy surfaces. We discuss where anharmonicity should be expected, where it has been observed from a theoretical perspective, and the methods currently employed to address it. We concentrate on three types of systems where we have observed major, nonnegligible anharmonic effects: (1) supported nanoparticles, where the migration of metal atoms, complexes, and entire clusters exhibit anharmonic behavior in their dynamic motion; (2) porous solids where confinement effects distort potential energy surfaces and hinder molecular motions resulting in large entropic terms; and (3) solid/liquid interfaces, where interactions between solvent molecules and adsorbed species can result in large solvent organization free energy and unique reactivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2002

Effect of Variable Chord Length on Transonic Axial Rotor Performance Investigated

During the life of any gas turbine, blade erosion is present, especially for those units that are exposed to unfiltered air, such as aviation turbofan engines. The effect of this erosion is to reduce the blade chord progressively from the midspan to the tip region and to roughen and distort the blade surface. The effects of roughness on rotor performance have been documented by Suder et al. and Roberts. These papers indicate that the penalty for leading-edge roughness and erosion can be significant. Turbofan operators, therefore, restore chord length at routine maintenance intervals to regain performance before deterioration is too severe to salvage blades. As the rotor blades erode, the leading edge becomes rough - blunt and distorted from the nominal shape - and the aerodynamic performance suffers. Nominal performance can be recovered by recontouring the leading edges. This process, which inherently shortens the blade chord, can be used until the blade chord erodes to the stall limit. Below this chord length, which varies among engine-compressor types, a decrease of stall margin is likely. After compressor blade rework that includes leading edge recontouring, the blades have different chord lengths, ranging from blades that are near nominal chord length down to those near the stall chord limit. Furthermore, as blades erode below the stall limit, they must be replaced with new blades that have the full nominal chord length. Consequently, a set of compressor blades with varying chord lengths will be installed into each turbofan engine that goes through a complete maintenance cycle. The question arises, "Does fan or compressor performance depend on the order in which mixed-chord blades are installed into a fan or compressor disk?"

Suder, Kenneth L.↗
NASA NTRS1995

Advanced Communication Technology Satellite (ACTS) Multibeam Antenna On-Orbit Performance

The NASA Lewis Research Center's Advanced Communication Technology Satellite (ACTS) was launched in September 1993. ACTS introduced several new technologies, including a multibeam antenna (MBA) operating at extremely short wavelengths never before used in communications. This antenna, which has both fixed and rapidly reconfigurable high-energy spot beams (150 miles in diameter), serves users equipped with small antenna terminals. Extensive structural and thermal analyses have been performed for simulating the ACTS MBA on-orbit performance. The results show that the reflector surfaces (mainly the front subreflector), antenna support assembly, and metallic surfaces on the spacecraft body will be distorted because of the thermal effects of varying solar heating, which degrade the ACTS MBA performance. Since ACTS was launched, a number of evaluations have been performed to assess MBA performance in the space environment. For example, the on-orbit performance measurements found systematic environmental disturbances to the MBA beam pointing. These disturbances were found to be imposed by the attitude control system, antenna and spacecraft mechanical alignments, and on-orbit thermal effects. As a result, the MBA may not always exactly cover the intended service area. In addition, the on-orbit measurements showed that antenna pointing accuracy is the performance parameter most sensitive to thermal distortions on the front subreflector surface and antenna support assemblies. Several compensation approaches were tested and evaluated to restore on-orbit pointing stability. A combination of autotrack (75 percent of the time) and Earth sensor control (25 percent of the time) was found to be the best way to compensate for antenna pointing error during orbit. This approach greatly minimizes the effects of thermal distortions on antenna beam pointing.

Source record↗
DOE OSTI2025

Advancing 3D surface imaging: single-axis structured light illumination plenoptic camera with machine learning integration

Structured light illumination (SLI) is a configurable 3D surface imaging modality that can function largely independently of surface texture. At the same time, machine learning (ML) approaches are providing new ways to capture relevant information from SLI patterns, avoiding the need to develop advanced computer vision algorithms. By projecting an optical pattern onto a surface and measuring the apparent distortion of that pattern, one can determine surface topography from a single image. Common realizations of SLI 3D imaging use off-axis SLI to allow for parallax-based determination of depth; however, in constrained geometries, the ability to make single-axis measurements can be of major benefit. While plenoptic imaging (PI) cameras have long been developed for the purpose of single-axis 3D imaging, they are generally reliant on the surface texture of the measured object, thus making them unreliable in certain experimental conditions. Therefore, we present a single-axis 3D SLI plenoptic camera, which combines the single-axis benefits of PI technology while using coaxial SLI to maintain indifference to surface conditions. We also present a study of the camera capabilities paired with the development of several algorithms, including traditional feature tracking methods as well as ML methods, which are found to enhance resolution and range. We report depth sensitivity down to 0.2% $\frac{dz}{z_0}$. The single-axis SLI 3D plenoptic camera demonstrates potential applicability for in-situ topographical measurements under a wide range of conditions including, but not limited to, objects without trackable surface texture, high temperatures, and constrained geometry environments.

Imaging systems↗
NASA NTRS1979

Reduction of intensity variations on a photovoltaic array with compound parabolic concentrators

The reduction of nonuniformities in the intensity distribution of light focused on a photovoltaic array by a compound parabolic concentrator is investigated. The introduction of small distortions into the surfaces of the reflector in order to diffuse the incident collimated light to fill the angular acceptance of the concentrator is calculated by means of ray tracing to decrease the irradiance nonuniformity at the cost of a lowered effective concentration of the concentrator. Measurements of the intensity distribution on a scale test model in terrestrial sunlight with corrugated aluminized mylar reflectors are shown to be in good agreement with the ray tracing results. A two-stage concentrator consisting of a focusing primary and a nonimaging secondary is also shown to result in a fairly uniform intensity distribution except in the case of a 4-deg incidence angle, which may be corrected by the introduction of distortions into one or both concentration stages.

Greenman, P.↗
DOE OSTI2025

Impact of Halogen Groups on the Properties of PEA–Based 2D Pb–Sn Halide Perovskites

Tuning broad emission in 2D Pb–Sn halide perovskites (HPs) is essential for advancing optoelectronic applications, particularly for color-tunable and white-light-emitting devices. This broad emission is linked to structural factors, such as defects and phase segregation of the Pb component within the Pb–Sn system, which are strongly influenced by the molecular structure and chemical properties of spacer cations. Atomic tuning of the spacers via halogenation opens up a new way to fine-tune the molecular properties, enabling further augmentations of HP functionalities. Nevertheless, the distinct broad emission's sensitivity to spacer chemistry remains underexplored. Here, halogenation's influence is systematically investigated on 2D HP emission characteristics using a high-throughput workflow. These findings reveal that the F-containing phenethylammonium (4F-PEA) spacer narrows the broadband PL, whereas Cl broadens it. Through a correlative study, it is found that 4F-PEA reduces not only the local phase segregation but also the defect levels and microstrains in 2D HPs. This is likely attributed to the manifestation of less lattice distortion via stronger surface coordination of the dipole-augmented 4F-PEA. Furthermore, these results highlight halogenation as a key factor in modulating phase segregation and defect density in 2D Pb–Sn HPs, offering a promising pathway to tune the emission for enhanced optoelectronic performance.

2D Pb-Sn halide perovskites↗
DOE OSTI2022

Effect of iron substitution in cryptomelane on the heterogeneous reaction with isoprene

Biogenic isoprene is an important pollutant for regional air quality. Being ubiquitously distributed on the earth surface, manganese (hydr)oxides should play a vital role in the transformation of isoprene. Cryptomelane is a typical manganese oxide with isomorphous substitution of Fe for Mn, but less attention has been paid to its heterogeneous reaction with isoprene. When Fe 3+ replaces Mn 3+ , K + is depleted and Mn 3+ is oxidized to Mn 4+ . In contrast, oxygen vacancies are formed when Fe 3+ substitutes Mn 4+ . Fe substitution creates weak crystallites and abundant mesopores, resulting in the increase of isoprene adsorption. As found by theoretical calculations, the Mn 4+ –O 2- bonds at the cross sections of the tunnels is more active than that on the outer wall of the tunnels. After the adsorption of isoprene, bridging carboxylate species and hydrogen-bonding water are produced and the surface octahedra are distorted, i.e., Mn 4+ O 6 → Mn 3+ O 6-δ . As the heat facilitates the breakage of Mn 4+ –O 2- , the increase of environmental temperature enhances the oxidation of isoprene. Here the above findings shed light on the effect of Fe substitution in cryptomelane to enhance the oxidation of isoprene, and illustrates that heterogeneous reaction with isoprene impairs the transformation of other environmental substances on cryptomelane.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Intercalation induced quasi-freestanding layer in TiSe 2

Angle-resolved photoemission spectroscopy is employed to study the electronic structure of bulk TiSe 2 before and after doping with potassium impurities. A splitting in the conduction band into two branches is observed after room-temperature deposition. The splitting energy increases to approximately 130 meV when the sample is cooled to 40 K. One branch exhibits a nondispersive two-dimensional feature, while the other shows the characteristics of three-dimensional bulk band dispersion. Core-level spectroscopy suggests that the K impurities predominantly occupy the intercalated sites within the van der Waals gap. Furthermore, the results indicate the formation of a quasi-freestanding TiSe 2 layer. Additionally, doping completely suppresses the periodic lattice distortion in the surface region. These findings are further supported by density functional theory calculations, which compare the band structure of monolayer and bulk TiSe 2 with experimental data. Thus, the dimensional and intrinsic electronic properties of 1⁢𝑇−TiSe 2 can be controlled through the intercalation procedure used in this work.

36 MATERIALS SCIENCE↗
NASA NTRS1980

Reduction of intensity variations on the absorbers of ideal flux concentrators

Large nonuniformities occur in the instantaneous distribution of flux on the absorber of an ideal light concentrator when it is illuminated by a point source such as the sun. These nonuniformities may be reduced by texturing the reflecting surface with small distortions. Such distortions will also be effective if used in the primary reflector of a two-stage concentrator. Data on a model compound parabolic concentrator are presented. The suitability of such concentrators for use by spacecraft is mentioned.

Greenman, P.↗