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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Model-Based Least Squares Reconstruction of Coded Source Neutron Radiographs: Integrating the ORNL HFIR CG1D Source Model

At the present, neutron sources cannot be fabricated small and powerful enough in order to achieve high resolution radiography while maintaining an adequate flux. One solution is to employ computational imaging techniques such as a Magnified Coded Source Imaging (CSI) system. A coded-mask is placed between the neutron source and the object. The system resolution is increased by reducing the size of the mask holes and the flux is increased by increasing the size of the coded-mask and/or the number of holes. One limitation of such system is that the resolution of current state-of-the-art scintillator-based detectors caps around 50um. To overcome this challenge, the coded-mask and object are magnified by making the distance from the coded-mask to the object much smaller than the distance from object to detector. In previous work, we have shown via synthetic experiments that our least squares method outperforms other methods in image quality and reconstruction precision because of the modeling of the CSI system components. However, the validation experiments were limited to simplistic neutron sources. In this work, we aim to model the flux distribution of a real neutron source and incorporate such a model in our least squares computational system. We provide a full description of the methodology used to characterize the neutron source and validate the method with synthetic experiments.

Coded Apertures↗

Exergy analysis and operational efficiency of a horizontal ground-source heat pump system operated in a low-energy test house simulated occupancy conditions

This paper presents detailed analysis of a water to water ground source heat pump (WW-GSHP) to provide all the hot water needs in a 345 m 2 house located in DOE climate zone 4 (mixed-humid). The protocol for hot water use is based on the Building America Research Benchmark Definition (Hendron 2008; Hendron and Engebrecht 2010) which aims to capture the living habits of the average American household and its impact on energy consumption. The entire house was operated under simulated occupancy conditions. Detailed energy and exergy analysis provides a complete set of information on system efficiency and sources of irreversibility, the main cause of wasted energy. The WW-GSHP was sized at 5.275 kW (1.5-ton) for this house and supplied hot water to a 303 L (80 gal) water storage tank. The WW-GSHP shared the same ground loop with a 7.56 kW (2.1-ton) water to air ground source heat pump (WA-GSHP) which provided space conditioning needs to the entire house. Data, analyses, and measures of performance for the WW-GSHP in this paper complements the results of the WA-GSHP published in this journal (Ally, Munk et al. 2012). Understanding the performance of GSHPs is vital if the ground is to be used as a viable renewable energy resource.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

MassIVE MSV000085948 - Utilization of syringyl lignin-derived compounds and production of 2-pyrone-4,6-dicarboxylic acid by Pseudomonas putida KT2440: Lignin is an abundant aromatic polymer formed in plants by coupling reactions of p-coumaryl, coniferyl, and sinapyl alcohols. Pseudomonas putida KT2440 (P. putida KT2440), a robust soil bacterium, naturally catabolizes many aromatic compounds derived from lignin as carbon and energy sources and has been extensively engineered to valorize guaiacyl (G) and p-hydroxyphenyl (H) lignin-derived aromatic species to valuable chemicals. However, only a few studies report the capacity of Pseudomonads to grow on syringyl (S) lignin-derived compounds. In this work, we demonstrate that P. putida KT2440 catabolizes syringate in the presence of an auxiliary energy source. Overexpression of vanAB, encoding a native Rieske non-heme iron monooxygenase, enabled catabolism of syringate and syringaldehyde without an additional carbon and energy source. In vitro biochemical characterization of VanAB confirmed that this enzyme O-demethylates syringate to 3-O-methylgallate and, subsequently, 3-O-methylgallate to gallate, albeit 4- and 55-fold less efficiently than vanillate, respectively. Transcriptomics and proteomics experiments demonstrate that the galADBC transcripts and enzymes required for gallate catabolism are induced when vanAB is overexpressed during cultivation in syringate. Further, we show that that the endogenous protocatechuate-3,4-dioxygenase PcaHG ring-opens gallate to produce 2-pyrone-4,6-dicarboxylic acid (PDC), a promising bio-based chemical. Constitutive overexpression of vanAB and pcaHG along with galA deletion enabled PDC production from SA at a 70% (mol/mol) yield. Furthermore, leveraging the LigAB dioxygenase from Sphingobium sp. SYK-6 and VanAB O-demethylase from Pseudomonas sp. HR199 enabled simultaneous conversion of monomers with S-, G-, and H-type functionality to PDC at 82% (mol/mol) yield. Overall, this study elucidates a native pathway for catabolism of syringyl lignin-derived compounds in P. putida KT2440 and demonstrates the potential of this robust host for biological funneling of substrates derived from all three canonical monolignols.

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Beckham, Gregg↗

The influence of tillage and fertilizer on the flux and source of nitrous oxide with reference to atmospheric variation using laser spectroscopy

Nitrous oxide (N 2 O) is the third most important long-lived greenhouse gas and agriculture is the largest source of N 2 O emissions. Curbing N 2 O emissions requires understanding influences on the flux and sources of N 2 O. We measured flux and evaluated microbial sources of N 2 O using site preference ( S P ; the intramolecular distribution of 15 N in N 2 O) in flux chambers from a grassland tilling and agricultural fertilization experiments and atmosphere. We identified values greater than that of the average atmosphere to reflect nitrification and/or fungal denitrification and those lower than atmosphere as increased denitrification. Our spectroscopic approach was based on an extensive calibration with 18 standards that yielded S P accuracy and reproducibility of 0.7 ‰ and 1.0 ‰, respectively, without preconcentration. Chamber samples from the tilling experiment taken ~ monthly over a year showed a wide range in N 2 O flux (0–1.9 g N 2 O-N ha -1 d -1 ) and S P (- 1.8 to 25.1 ‰). Flux and S P were not influenced by tilling but responded to sampling date. Large fluxes occurred in October and May in no-till when soils were warm and moist and during a spring thaw, an event likely representing release of N 2 O accumulated under snow cover. These high fluxes could not be ascribed to a single microbial process as S P differed among chambers. However, the year-long S P and flux data for no-till showed a slight direct relationship suggesting that nitrification increased with flux. The comparative data in till showed an inverse relationship indicating that high flux events are driven by denitrification. Corn ( Zea mays ) showed high fluxes and S P values indicative of nitrification ~ 4 wk after fertilization with subsequent declines in S P indicating denitrification. Although there was no effect of fertilizer treatment on flux or S P in switchgrass ( Panicum virgatum) , high fluxes occurred ~1 month after fertilization. In both treatments, S P was indicative of denitrification in many instances, but evidence of nitrification/fungal denitrification also prevailed. At 2 m atmospheric N 2 O S P had a range of 31.1 ‰ and 14.6 ‰ in the grassland tilling and agricultural fertilization experiments, respectively. These data suggest the influence of soil microbial processes on atmospheric N 2 O and argue against the use of the global average atmospheric S P in isotopic modeling approaches.

Environmental Sciences & Ecology↗

Search for low-energy neutrinos from astrophysical sources with Borexino

We report on searches for neutrinos and antineutrinos from astrophysical sources performed with the Borexino detector at the Laboratori Nazionali del Gran Sasso in Italy. Electron antineutrinos ( $\bar{ν}_e$ ) are detected in an organic liquid scintillator through the inverse β -decay reaction. In the present work we set model-independent upper limits in the energy range 1.8-16.8 MeV on neutrino fluxes from unknown sources that improve our previous results, on average, by a factor 2.5. Using the same data set, we first obtain experimental constraints on the diffuse supernova $\bar{ν}_e$ fluxes in the previously unexplored region below 8 MeV. A search for $\bar{ν}_e$ in the solar neutrino flux is also presented: the presence of $\bar{ν}_e$ would be a manifestation of a non-zero anomalous magnetic moment of the neutrino, making possible its conversion to antineutrinos in the strong magnetic field of the Sun. We obtain a limit for a solar $\bar{ν}_e$ flux of 384 cm -2 s -1 (90% C.L.), assuming an undistorted solar 8 B neutrinos energy spectrum, that corresponds to a transition probability pνe→$\bar{ν}_e$< 7.2 ×10-5 (90% C.L.) for E $\bar{ν}_e$ > 1.8 MeV.At lower energies, by investigating the spectral shape of elastic scattering events, we obtain a new limit on solar 7 Be- ν e conversion into $\bar{ν}_e$ of pνe→$\bar{ν}_e$< 0.14 (90% C.L.) at 0.862 MeV. Last, we investigate solar flares as possible neutrino sources and obtain the strongest up-to-date limits on the fluence of neutrinos of all flavor neutrino below 3–7 MeV. Assuming the neutrino flux to be proportional to the flare’s intensity, we exclude an intense solar flare as the cause of the observed excess of events in run 117 of the Cl-Ar Homestake experiment.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Mercury-Impacted Scrap Metal: Source and Nature of the Mercury

The reuse and recycling of industrial solid wastes such as scrap metal is supported and encouraged both internationally and domestically, especially when such wastes can be used as substitutes for raw material. However, scrap metal processing facilities, such as mini-mills, have been identified as a source of mercury (Hg) emissions in the United States. This research aims to better define some of the key issues related to the source and nature of mercury in the scrap metal waste stream. Overall, it is difficult to pinpoint the key mercury sources feeding into scrap metal recycling facilities, quantify their associated mercury concentrations, or determine which chemical forms are most significant. Potential sources of mercury in scrap metal include mercury switches from discarded vehicles, electronic-based scrap from household appliances and related industrial systems, and Hg-impacted scrap metal from the oil and gas industry. The form of mercury associated with scrap metal varies and depends on the source type. The specific amount of mercury that can be adsorbed and retained by steel appears to be a function of both metallurgical and environmental factors. In general, the longer the steel is in contact with a fluid or condensate that contains measurable concentrations of elemental mercury, the greater the potential for mercury accumulation in that steel. Most mercury compounds are thermally unstable at elevated temperatures (i.e., above 350°C). As such, the mercury associated with impacted scrap is expected to be volatilized out of the metal when it is heated during processing (e.g., shredding or torch cutting) or melted in a furnace. This release of fugitive gas (Hg vapor) and particulates, as well as Hg-impacted bag-house dust and control filters, could potentially pose an occupational exposure risk to workers at a scrap metal processing facility. Thus, identifying and characterizing the key sources of Hg-impacted scrap, and understanding the nature and extent of associated releases, represent a practical research need that is essential for improving the environmental management of Hg-impacted scrap and assessing measures to protect workers from potential health and safety hazards that might be posed by mercury and Hg-impacted scrap.

mercury↗

Bright x-ray stainless steel K-shell source development at the National Ignition Facility

High x-ray conversion efficiency (XRCE) K-shell sources are being developed for high energy density experiments for use as backlighters and for the testing of materials exposed to high x-ray fluxes and fluences. Recently, sources with high XRCE in the K-shell x-ray energy range of iron and nickel were investigated at the National Ignition Facility (NIF). The x-ray conversion efficiency in the 5–9 keV spectral range was determined to be 6.8% ± 0.3%. These targets were 4.1 mm diameter, 4 mm tall hollow epoxy tubes having a 50 μm thick wall supporting a tube of 3 to 3.5 μm thick stainless steel. The NIF laser deposited ∼460 kJ of 3ω light into the target in a 140 TW, 3.3 ns square pulse. The absolute x-ray emission of the source was measured by two calibrated Dante x-ray spectrometers. Time resolved images filtered for the Fe K-shell were recorded to follow the heating of the target. Time integrated high-resolution spectra were recorded in the K-shell range.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

THE SOLAR WIND AS A POSSIBLE SOURCE OF FAST TEMPORAL VARIATIONS OF THE HELIOSPHERIC RIBBON

We present a possible source of pickup ions (PUIs) the ribbon observed by the Interstellar Boundary EXplorer (IBEX). We suggest that a gyrating solar wind and PUIs in the ramp and in the near downstream region of the termination shock (TS) could provide a significant source of energetic neutral atoms (ENAs) in the ribbon. A fraction of the solar wind and PUIs are reflected and energized during the first contact with the TS. Some of the solar wind may be reflected propagating toward the Sun but most of the solar wind ions form a gyrating beam-like distribution that persists until it is fully thermalized further downstream. Depending on the strength of the shock, these gyrating distributions can exist for many gyration periods until they are scattered/thermalized due to wave-particle interactions at the TS and downstream in the heliosheath. During this time, ENAs can be produced by charge exchange of interstellar neutral atoms with the gyrating ions. In order to determine the flux of energetic ions, we estimate the solar wind flux at the TS using pressure estimates inferred from in situ measurements. Assuming an average path length in the radial direction of the order of a few AU before the distribution of gyrating ions is thermalized, one can explain a significant fraction of the intensity of ENAs in the ribbon observed by IBEX. With a localized source and such a short integration path, this model would also allow fast time variations of the ENA flux.

79 ASTRONOMY AND ASTROPHYSICS↗

Electron energy partition in the ‘above-the-looptop’ solar hard X-ray sources

The presentation begins by considering the non-thermal fraction of electron energies (R ε ) in 'above-the-looptop' (ALT). Several spectral models area considered: isothermal model, power-law, and the newly derived kappa distribution. Technically, all 3 non-thermal models can fit the data. In the discussion of flare scenario, energy partition, energization mechanism, and collisionality are considered. It is concluded that the kappa distribution works (R ε ≲ 50%), magnetic reconnection scenario works, and Coulomb collisions may reduce the non-thermal fraction of electron energies.

79 ASTRONOMY AND ASTROPHYSICS↗

Parkes radio searches of Fermi gamma-ray sources and millisecond pulsar discoveries

In a search with the Parkes radio telescope of 56 unidentified Fermi-Large Area Telescope (LAT) gamma-ray sources, we have detected 11 millisecond pulsars (MSPs), 10 of them discoveries, of which five were reported by Kerr et al. We did not detect radio pulsations from six other pulsars now known in these sources. We describe the completed survey, which included multiple observations of many targets conducted to minimize the impact of interstellar scintillation, acceleration effects in binary systems, and eclipses. We consider that 23 of the 39 remaining sources may still be viable pulsar candidates. We present timing solutions and polarimetry for five of the MSPs and gamma-ray pulsations for PSR J1903–7051 (pulsations for five others were reported in the second Fermi-LAT catalog of gamma-ray pulsars). Two of the new MSPs are isolated and five are in >1 day circular orbits with 0.2–0.3 M{sub ⊙} presumed white dwarf companions. PSR J0955–6150, in a 24 day orbit with a ≈0.25 M{sub ⊙} companion but eccentricity of 0.11, belongs to a recently identified class of eccentric MSPs. PSR J1036–8317 is in an 8 hr binary with a >0.14 M{sub ⊙} companion that is probably a white dwarf. PSR J1946–5403 is in a 3 hr orbit with a >0.02 M{sub ⊙} companion with no evidence of radio eclipses.

79 ASTRONOMY AND ASTROPHYSICS↗

OPTICAL-FAINT, FAR-INFRARED-BRIGHT HERSCHEL SOURCES IN THE CANDELS FIELDS: ULTRA-LUMINOUS INFRARED GALAXIES AT z > 1 AND THE EFFECT OF SOURCE BLENDING

The Herschel very wide field surveys have charted hundreds of square degrees in multiple far-IR (FIR) bands. While the Sloan Digital Sky Survey (SDSS) is currently the best resource for optical counterpart identifications over such wide areas, it does not detect a large number of Herschel FIR sources and leaves their nature undetermined. As a test case, we studied seven ''SDSS-invisible'', very bright 250 μm sources (S {sub 250} > 55 mJy) in the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey fields where we have a rich multi-wavelength data set. We took a new approach to decompose the FIR sources, using the near-IR or the optical images directly for position priors. This is an improvement over the previous decomposition efforts where the priors are from mid-IR data that still suffer from the problem of source blending. We found that in most cases the single Herschel sources are made of multiple components that are not necessarily at the same redshifts. Our decomposition succeeded in identifying and extracting their major contributors. We show that these are all ultra-luminous infrared galaxies at z ∼ 1-2 whose high L {sub IR} is mainly due to dust-obscured star formation. Most of them would not be selected as submillimeter galaxies. They all have complicated morphologies indicative of mergers or violent instability, and their stellar populations are heterogeneous in terms of stellar masses, ages, and formation histories. Their current ultra-luminous infrared galaxy phases are of various degrees of importance in their stellar mass assembly. Our practice provides a promising starting point for developing an automatic routine to reliably study bright Herschel sources.

79 ASTRONOMY AND ASTROPHYSICS↗

GMRT DISCOVERY OF PSR J1544+4937: AN ECLIPSING BLACK-WIDOW PULSAR IDENTIFIED WITH A FERMI-LAT SOURCE

Using the Giant Metrewave Radio Telescope, we performed deep observations to search for radio pulsations in the directions of unidentified Fermi-Large Area Telescope {gamma}-ray sources. We report the discovery of an eclipsing black-widow millisecond pulsar, PSR J1544+4937, identified with the uncataloged {gamma}-ray source FERMI J1544.2+4941. This 2.16 ms pulsar is in a 2.9 hr compact circular orbit with a very low mass companion (M{sub c} > 0.017M{sub Sun }). At 322 MHz this pulsar is found to be eclipsing for 13% of its orbit, whereas at 607 MHz the pulsar is detected throughout the low-frequency eclipse phase. Variations in the eclipse ingress phase are observed, indicating a clumpy and variable eclipsing medium. Moreover, additional short-duration absorption events are observed around the eclipse boundaries. Using the radio timing ephemeris we were able to detect {gamma}-ray pulsations from this pulsar, confirming it as the source powering the {gamma}-ray emission.

79 ASTRONOMY AND ASTROPHYSICS↗

Replacing fish oil and astaxanthin by microalgal sources produced different metabolic responses in juvenile rainbow trout fed 2 types of practical diets

Dietary fish oil supplementation provides n-3 long-chained polyunsaturated fatty acids for supporting fish growth and metabolism and enriching fillet with eicosapentaenoic acid (EPA; 20:5n-3) and docosahexaenoic acid (DHA; c22:6n-3). Two experiments were performed as a 3 × 2 factorial arrangement of dietary treatments for 16 wk to determine effects and mechanisms of replacing 0%, 50%, and 100% fish oil with DHA-rich microalgae in combination with synthetic vs. microalgal source of astaxanthin in plant protein meal (PM)- or fishmeal (FM)- based diets for juvenile rainbow trout (Oncorhynchus mykiss). Fish (22 ± 0.26 g) were stocked at 17/tank and 3 tanks/diet. The 100% fish oil replacement impaired (P < 0.0001) growth performance, dietary protein and energy utilization, body indices, and tissue accumulation of DHA and EPA in both diet series. Here, the impairments were associated (P < 0.05) with upregulation of hepatic gene expression related to growth (ghr1and igf1) and biosynthesis of DHA and EPA (fads6 and evol5) that was more dramatic in the FM than PM diet-fed fish, and more pronounced on tissue EPA than DHA concentrations. The source of astaxanthin exerted interaction effects with the fish oil replacement on several measures including muscle total cholesterol concentrations. In conclusion, replacing fish oil by the DHA-rich microalgae produced more negative metabolic responses than the substitution of synthetic astaxanthin by the microalgal source in juvenile rainbow trout fed 2 types of practical diets.

59 BASIC BIOLOGICAL SCIENCES↗