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All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Development of a Technical Standard for Radiological Characterization of DAW - 18062

Throughout its 70+-year history, the U.S. Department of Energy (DOE) and its predecessor agencies have performed a wide mission involving nuclear materials and weapons development, production, testing, and modernization. While the initial mission components relied heavily upon reactor physics and chemistry, the environmental programs have increasingly relied upon development of more accurate and effective measurement methodologies to determine the radiological and chemical properties of the unique waste streams that were generated during the weapons production and testing mission. Over time, the DOE laboratories and former production sites have developed a wide range of site-specific processes and procedures for conducting radiological characterization of dry active waste (DAW) that is managed as low-level radioactive waste. This has resulted in a Complex-wide variability among sites with respect to the methodologies and instrumentation used to characterize individual waste streams. The DAW-type waste was selected for development of a characterization standard since it is a simple, voluminous, and repetitive waste stream with a substantial knowledge base, established experience history at multiple site locations, and the potential for realization of programmatic benefits though standardization. The Energy Facility Contractors Group (EFCOG) Waste Management Working Group (WMWG) has proposed the development of a new DOE Technical Standard for radiological characterization of DAW. The purpose of the proposed new standard is to provide a technical resource that integrates and enhances the utilization of current site-specific methodologies and processes. A Technical Basis Document (TBD) has been prepared to support the development and utilization of the new standard by providing detailed information for use by site personnel when implementing the guidance provided in the standard. It also provides the rationale for and details concerning the recommended technical approaches for radiological characterization of representative DAW-type waste streams. The TBD will be included as an appendix to the proposed standard. Adoption of a standardized approach to DAW characterization will take advantage of multiple applications for a technology that is both mature and stable. The DAW characterization process is repetitive and lends itself to implementation at a wide range of operating locations - resulting in economies of scale, compliance with regulatory requirements, and consistent implementation of procedures which support design, operations, maintenance, and management of facilities, activities and programs. The purpose of the proposed new Technical Standard for DAW Radiological Characterization is to integrate and improve the utilization of current site-specific methodologies and processes and will include a comprehensive evaluation and comparison of current radiological characterization methodologies to determine which ones are most reliable and effective in producing relevant and valid data. In view of the long history and participation by several agencies in the regulation of nuclear programs, existing Voluntary Consensus Standards have also been reviewed for relevancy and applicability to the new proposed standard. The proposed new Standard will be developed in concert with existing scientific and regulatory guidance to produce a document that incorporates the state of current knowledge and site practices with a graded approach to applying those methodologies that are applicable and effective for characterizing a wide range of DAW-type wastes - including, but not limited to, debris, low specific activity (LSA) material, and surface contaminated objects (SCO). Under the leadership of the National Laboratory Subgroup of the EFCOG/WMWG), an EFCOG team will develop the proposed technical standard. This process will incorporate the information gathered during preparation of the TBD, which will serve as a technical resource to support the technical approach for selection of DAW characterization methodologies. Preparation of the TBD included a detailed survey of historical site practices and examination of the characterization approaches and measurement methodologies currently being applied to DAW-type wastes. Future activities include the development and submittal of a Project Justification Statement that will be submitted to the DOE Technical Standards Program for review and comment. The EFCOG/WMWG Team will respond to reviewer comments, as required. Following final concurrence by affected organizations through the DOE Technical Standards Coordination process, the EFCOG/WMWG Team will prepare the draft technical standard and respond to comments generated during RevCom review and final format review by the DOE Technical Standards Management Program. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2015

Next Generation UAS Based Spectral Systems for Environmental Monitoring

This presentation provides information on the development of a small Unmanned Aerial System(UAS) with a low power, high performance Intelligent Payload Module (IPM) and a hyperspectral imager to enable intelligent gathering of science grade vegetation data over agricultural fields at about 150 ft. The IPM performs real time data processing over the image data and then enables the navigation system to move the UAS to locations where measurements are optimal for science. This is important because the small UAS typically has about 30 minutes of battery power and therefore over large agricultural fields, resource utilization efficiency is important. The key innovation is the shrinking of the IPM and the cross communication with the navigation software to allow the data processing to interact with desired way points while using Field Programmable Gate Arrays to enable high performance on large data volumes produced by the hyperspectral imager.

onboard processing↗
DOE OSTI2022

Smart connected worker edge platform for smart manufacturing: Part 1—Architecture and platform design

Abstract The challenge of sustainably producing goods and services for healthy living on a healthy planet requires simultaneous consideration of economic, societal, and environmental dimensions in manufacturing. Enabling technology for data driven manufacturing paradigms like Smart Manufacturing (a.k.a. Industry 4.0) serve as the technological backbone from which sustainable approaches to manufacturing can be implemented. Unfortunately, these technologies are typically associated with broader and deeper factory automation that is often too expensive and complex for the small and medium sized manufacturers (SMMs) that comprise the majority of manufacturing business in the USA and for whom their most valuable asset are the people whose jobs automation while replace. This paper describes an edge intelligent platform to integrate internet‐of‐things technologies with computing hardware, software, computational workflows for machine learning, and data ingestion, enabling SMMs to transition into smart manufacturing paradigms by leveraging the intelligence of their people. The platform leverages consumer grade electronics and sensors (affordable and portable), customized software with open source software packages (accessible), and existing communication network infrastructures (scalable). The software systems are implemented via Kubernetes orchestration of Docker containerization to ensure scalability and programmability. The platform is adaptive via computational workflow engines that produce information from data by processing with low‐cost edge computing devices while efficiently accessing resources of cloud servers as needed. The proposed edge platform connects workers to technological resources that provide computational intelligence (i.e., silicon‐based sensing and computation for data collection and contextualization) to enable decision making at the edge of advanced manufacturing.

Kim, Yoon G.↗
NASA NTRS2014

Using Lunar Sample Disks and Resources to Promote Scientific Inquiry

This poster presentation will illustrate the use of NASA Lunar Sample Disks and resources to promote scientific inquiry and address the Next Generation Science Standards. The poster will present information on the Lunar Sample Disks, housed and managed by the Astromaterials Research and Exploration Science (ARES) Directorate at the NASA Johnson Space Center. The poster will also present information on an inquiry‐based planetary sample and impact cratering unit designed to introduce students in grades 4‐10 to the significance of studying the rocks, soils, and surfaces of a planetary world. The unit, consisting of many hands‐on activities, provides context and background information to enhance the impact of the Lunar Sample Disks.

Graff, Paige↗
DOE OSTI2017

Techno-Economic Assessment for Integrating Biosorption into Rare Earth Recovery Process

The current uncertainty in the global supply of rare earth elements (REEs) necessitates the development of novel extraction technologies that utilize a variety of REE source materials. Herein, we examined the techno-economic performance of integrating a biosorption approach into a large-scale process for producing salable total rare earth oxides (TREOs) from various feedstocks. An airlift bioractor is proposed to carry out a biosorption process mediated by bioengineered rare earth-adsorbing bacteria. Techno-econmic asssements were compared for three distinctive categories of REE feedstocks requiring different pre-processing steps. Key parameters identified that affect profitability include REE concentration, composition of the feedstock, and costs of feedstock pretreatment and waste management. Among the 11 specific feedstocks investigated, coal ash from the Appalachian Basin was projected to be the most profitable, largely due to its high-value REE content. Its cost breakdown includes pre-processing (primarily leaching) (8077.71%), biosorption (1619.04%), and oxalic acid precipitation and TREO roasting (3.35%). Surprisingly, biosorption from the high-grade Bull Hill REE ore is less profitable due to high material cost and low production revenue. Overall, our results confirmed that the application of biosorption to low-grade feedstocks for REE recovery is economically viable.

15 GEOTHERMAL ENERGY↗
NASA NTRS1983

High-density Schottky barrier IRCCD sensors for remote sensing applications

It is pointed out that the ambitious goals envisaged for the next generation of space-borne sensors challenge the state-of-the-art in solid-state imaging technology. Studies are being conducted with the aim to provide focal plane array technology suitable for use in future Multispectral Linear Array (MLA) earth resource instruments. An important new technology for IR-image sensors involves the use of monolithic Schottky barrier infrared charge-coupled device arrays. This technology is suitable for earth sensing applications in which moderate quantum efficiency and intermediate operating temperatures are required. This IR sensor can be fabricated by using standard integrated circuit (IC) processing techniques, and it is possible to employ commercial IC grade silicon. For this reason, it is feasible to construct Schottky barrier area and line arrays with large numbers of elements and high-density designs. A Pd2Si Schottky barrier sensor for multispectral imaging in the 1 to 3.5 micron band is under development.

Elabd, H.↗
DOE OSTI2025

Primer to SWIFt 2.0 Technical Information Sheets

More than 16,000 publicly owned municipal wastewater treatment plants (WWTPs) in the U.S. treat a wide range of wastewater (WW) flows ranging from <0.5 to >200 MGD. Municipal WWTPs act as the last barrier before exposure to water-borne diseases and contaminants, thus serving as a critical infrastructure protecting human health and the environment. A recent survey by the American Society of Civil Engineers assigned the U.S.’s WW infrastructure a grade of D+ because of the number of improvements needed for end-of-life infrastructure with operating conditions being over or under design capacities. With increasing population growth and urbanization, the municipal WW sector needs to grow resiliently and sustainably to accommodate increasing sewer flows in the wake of new infrastructure needs and global priorities. In addition, this growth will be affected by rising concerns over constrained resources (e.g., electricity, energy, and water) and regulations. This necessitates molding the WW sector toward sustainability- and resiliency-related planning and innovations to address current and future needs while simultaneously producing profitable by-products.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Upgraded Coal and Coal Waste to Graphite for Lithium-Ion Battery Applications

Presentation to the Fortieth Annual International Pittsburgh Coal Conference, Istanbul, Turkiye, October 4–6, 2023. To assist in meeting the global graphite supply limitations, this study aims to investigate efficient ways to synthesize high-quality graphite from abundant coal and coal waste resources that exist in many areas around the world. A recently developed upgraded coal-to-products (UCP) process has shown great promise in the ability to reduce coal-borne impurities and produce a graphitizable product that yields good quality graphite for LIB applications. Preliminary results show that the quality of coal-derived graphite obtained by the UCP process is similar to that of commercial LIB-grade graphite. Available results are presented and discussed as well as maturation plans and flexibility of the UCP technology.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

Upgraded Coal to High-Quality Graphite for Lithium-Ion Battery Applications

Presentation for the World Conference on Carbon 2023, Cancun, Mexico, July 16–21, 2023. To assist in meeting the global graphite supply limitations, this study aims to investigate efficient ways to synthesize high-quality graphite from abundant coal resources that exist in many areas around the world. A recently developed upgraded coal-to-products (UCP) process has shown great promise in the ability to reduce coal-borne impurities and produce a graphitizable product that yields good-quality graphite for LIB applications. Preliminary results show that the quality of coal-derived graphite obtained by the UCP process is close to that of commercial LIB-grade graphite. Results are presented and discussed as well as maturation plans and flexibility of the UCP technology.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2021

Model America - data and models of every U.S. building

The 5-year goal of the 'Model America' concept was to generate a model of every building in the United States. This data repository delivers on that goal. Oak Ridge National Laboratory (ORNL) has developed the Automatic Building Energy Modeling (AutoBEM) software suite to process multiple types of data, extract building-specific descriptors, generate building energy models, and simulate them on High Performance Computing (HPC) resources. For more information, see AutoBEM-related publications (bit.ly/AutoBEM). There were 125,714,640 buildings detected in the United States and this dataset contains 122,930,327 (97.8%) buildings which resulted in a successful simulation. Future, annual updates have been proposed that may include additional buildings, data improvements, or other algorithmic enhancements. This dataset of 122.9 million buildings includes: Models (state_county.zip) - OpenStudio (v3.1.0) and EnergyPlus (v9.4) building energy models. Please note that the download requires the free Globus Connect Personal (https://www.globus.org/globus-connect-personal); Each model has approximately 3,000 building input descriptors that can be extracted. Please see the EnergyPlus(v9.4) 2,784-page Input/Output Reference Guide (https://energyplus.net/sites/all/modules/custom/nrel_custom/pdfs/pdfs_v9.4.0/InputOutputReference.pdf) for everything that can be retrieved or simulated from these models. These models were derived from the following metadata, which is not included in this dataset: 1. ID - unique building ID 2. County - county name 3. State - state name 4. CZ - ASHRAE Climate Zone designation 5. Clim_Zone - text label of climate zone 6. est_year - estimated year of construction 7. est_commercial - estimated building type (0=residential, 1=commercial) 8. Centroid - building center location in latitude/longitude (from Footprint2D) 9. Footprint2D - building polygon of 2D footprint (lat1/lon1_lat2/lon2_...) 10. Height - building height (meters) 11. Area2D - footprint area (ft2) 12. BuildingType - DOE prototype building designation (IECC=residential) as implemented by OpenStudio-standards 13. WWR_surfaces - percent of each facade (pair of points from Footprint2D) covered by fenestration/windows (average 14.5% for residential, 40% for commercial buildings) 14. NumFloors - number of floors (above-grade) 15. Area - estimate of total conditioned floor area (ft2) 16. Standard - building vintage. These models are made free and openly available in hopes of stimulating any simulation-informed use case. Data is provided as-is with no warranties, express or implied, regarding fitness for a particular purpose. We wish to thank our sponsors which include Oak Ridge National Laboratory (ORNL) Laboratory Directed Research and Development (LDRD), U.S. Dept. of Energy's (DOE) Building Technologies Office (BTO), Office of Electricity (OE), Biological and Environmental Research (BER), and National Nuclear Security Administration (NNSA). This research used resources of the Argonne Leadership Computing Facility, which is a DOE Office of Science User Facility supported under Contract DE-AC02-06CH11357. Please cite as: New, Joshua R., Adams, Mark, Bass, Brett, Berres, Anne, and Clinton, Nicholas (2021). 'Model America - data and models of every U.S. building. [Data set].' Constellation, doi.ccs.ornl.gov/ui/doi/339, April 14, 2021

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS2015

Designing an Exploration Atmosphere Prebreathe Protocol

Extravehicular activities (EVAs) at remote locations must maximize limited resources such as oxygen (O2) and also minimize the risk of decompression sickness (DCS). A proposed remote denitrogenation (prebreathe) protocol requires astronauts to live in a mildly hypoxic atmosphere at 8.2 psia while periodically performing EVAs at 4.3 psia. Empirical data are required to confirm that the protocol meets the current accept requirements: less than or equal to 15% incidence of Type I DCS, less than or equal to 20% incidence of Grade IV venous gas emboli (VGE), both at 95% statistical confidence, with no Type II DCS symptom during the validation trial. METHODS: A repeated measures statistical design is proposed in which groups of 6 subjects with physical characteristics similar to active-duty astronauts would first become equilibrated to an 8.2 psia atmosphere in a hypobaric chamber containing 34% O2 and 66% N2, over 48 h, and then perform 4 simulated EVAs at 4.3 psia over the next 9 days. In the equilibration phase, subjects undergo a 3-h 100% O2 mask prebreathe prior to and during a 5-min ascent to 8.2 psia to prevent significant tissue N2 supersaturation on reaching 8.2 psia. Masks would be removed once 34% O2 is established at 8.2 psia, and subjects would then equilibrate to this atmosphere for 48 h. The hypoxia is equivalent to breathing air at 1,220 meters (4,000 ft) altitude, just as was experienced in the shuttle 10.2 psia - 26.5% O2 staged denitrogenation protocol and the current ISS campout denitrogenation protocol. For simulated EVAs, each subject dons a mask and breathes 85% O2 and 15% N2 during a 3-min depressurization to 6.0 psia, holds for 15 min, and then completes a 3-min depressurization to 4.3 psia. The simulated EVA period starts when 6.0 psia is reached and continues for a total of 240 min (222 min at 4.3 psia). During this time, subjects will follow a prescribed repetitive activity against loads in the upper and lower body with mean metabolic rate approaching 1500 BTU/hr [378 kcal/hr (O2 consumption about 1.3 l(sub STPD)/min)] in ambulatory subjects. Noninvasive Doppler ultrasound bubble monitoring for VGE in the pulmonary artery will be performed on subjects by 2 Doppler Technicians at about 15 min intervals while at 4.3 psia. At the end of this period, a 15-min repressurization returns all subjects back to 8.2 psia and the cycle is repeated 3 additional times with a day of rest between simulated EVAs. RESULTS: With an assumed 1.5% probability of DCS [P(DCS)] and accounting for within-subject correlation, running the proposed study with 20 subjects has a 95% probability of meeting the accept criterion for DCS. But if the true probability of DCS is 3.0%, then 30 subjects would be needed to achieve about the same probability to meet our accept criterion. These results assume a standard deviation of 1.4 for the between-subjects random component of P(DCS) on a logit scale, which was estimated from a previous study.

Conkin, Johnny↗
NASA NTRSDate not supplied

Wastewater Brine Purification and Recovery through Electrodialysis Ion Exchange

Reutilizing resources onboard the International Space Station (ISS) and for future deep space missions are critical for mission longevity and sustainability. Wastewater brine produced from water recovery systems contain chemical species that could be processed into a potential fertilizer for future plant systems. This can be achieved through a process called electrodialysis ion exchange. Wastewater containing inorganic salt components are fed through a series of ion exchange membranes to produce fertilizer (a phosphate rich stream), electrolysis-grade water, and other useful commodities. Electrodialysis cells consisting of anion and cation exchange membranes, monovalent anion exchange membranes, and bipolar membranes were utilized to achieve selective ion exchange. The use of the electrodialysis cells were effective for both water extraction and ion separation. Ions successfully diffused across their respective membranes into the concentrate, acid, and base streams. This resulted in pure water, a phosphate rich stream, and a separate anion/hydrogen and cation/hydroxide stream. However, sulfate and some phosphate ions were able to diffuse through the monovalent anion exchange membrane into the acid stream. This resulted in predominantly phosphate ions remaining in the concentrate. Optimization of the process was accomplished by altering flowrates of each stream and initial volumes, adjusting the power input and resulting current through each cell, and varying the starting parameters by splitting the inorganic waste input into the diluate and the concentrate. As expected, increasing the flowrate and the power input to each cell reduced the overall time of the process. However, mission constraints may require a longer duration process in order to reduce the power consumption. Further analysis will be required to determine the power input necessary to achieve ion diffusion effectively and in a timely manner.

Ion Exchange Membranes↗
DOE OSTI2019

Efficient Modeling of HIL Multi-Grid System for Scalability & Concurrency in CPS Security Testbed

Cyber-event-triggered power grid blackout compels utility operators to intensify cyber-aware and physics-constrained recovery and restoration process. Recently, coordinated cyber attacks on the Ukrainian grid witnessed such a cyber-event-triggered power system blackout. Various cyber-physical system (CPS) testbeds have attempted with multitude designs to analyze such interdependent events and evaluate remedy measures. However, resource constraints and modular integration designs have been significant barriers while modeling large-scale grid models (scalability) and multi-grid isolated models (concurrency) under a single real-time execution environment for the hardware-in-the-loop (HIL) CPS security testbeds. This paper proposes a meticulous design and effective modeling for simulating large-scale grid models and multi-grid isolated models in a HIL realtime digital simulator environment integrated with industry-grade hardware and software systems. We have used our existing HIL CPS security testbed to demonstrate scalability by the realtime performance of a Texas-2000 bus US synthetic grid model and concurrency by the real-time performance of simultaneous ten IEEE-39 bus grid models and an IEEE-118 bus grid model. The experiments demonstrated significant results by 100% realtime performance with zero overruns, low latency while receiving and executing control signals from SEL Relays via IEC-61850 protocol and low latency while computing and transmitting grid data streams including stability measures via IEEE C37.118 synchrophasor data protocol to SEL Phasor Data Concentrators.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS1995

Looking at Earth from Space: Teacher's Guide with Activities for Earth and Space Science

The Maryland Pilot Earth Science and Technology Education Network (MAPS-NET) project was sponsored by the National Aeronautics and Space Administration (NASA) to enrich teacher preparation and classroom learning in the area of Earth system science. This publication includes a teacher's guide that replicates material taught during a graduate-level course of the project and activities developed by the teachers. The publication was developed to provide teachers with a comprehensive approach to using satellite imagery to enhance science education. The teacher's guide is divided into topical chapters and enables teachers to expand their knowledge of the atmosphere, common weather patterns, and remote sensing. Topics include: weather systems and satellite imagery including mid-latitude weather systems; wave motion and the general circulation; cyclonic disturbances and baroclinic instability; clouds; additional common weather patterns; satellite images and the internet; environmental satellites; orbits; and ground station set-up. Activities are listed by suggested grade level and include the following topics: using weather symbols; forecasting the weather; cloud families and identification; classification of cloud types through infrared Automatic Picture Transmission (APT) imagery; comparison of visible and infrared imagery; cold fronts; to ski or not to ski (imagery as a decision making tool), infrared and visible satellite images; thunderstorms; looping satellite images; hurricanes; intertropical convergence zone; and using weather satellite images to enhance a study of the Chesapeake Bay. A list of resources is also included.

Steele, Colleen↗
NASA NTRS2019

Waste Water Brine Purification through Electrodialysis Ion Exchange

Reutilizing resources onboard the International Space Station (ISS) and for future deep space missions are critical for mission longevity and sustainability. Waste water brine produced from water recovery systems contain chemical species that could be processed into a potential fertilizer for future plant systems.Fertilizer production can be achieved through a process called electrodialysis ion exchange. Waste water containing inorganic salt components are fed through a series of ion exchange membranes to produce fertilizer (a phosphate rich stream), electrolysis-grade water, and other useful commodities.A test bed was constructed to conduct controlled experiments and an experimental design procedure developed to determine the feasibility of the process. Conductivity and pH probes were utilized to determine the ion concentration in each of the product streams, along with ion chromatography (IC) to define the exact concentration of each ion in every stream throughout the experiment. This is crucial in order to convey the effectiveness of ion removal from the incoming waste water stream.The waste water and electrolyte streams were prepared in the lab prior to experimentation. Additionally, the ion exchange membrane configurations were developed and Opto 22 data analysis software incorporated to conduct measurements in real time.Ions successfully diffused across their respective membranes into the concentrate, acid, and base streams. This resulted in pure water, a phosphate rich stream, and a separate anion/hydrogen and cation/hydroxide stream.

Hancock, Matthew L.↗
DOE OSTI2020

Major element composition controls rare earth element solubility during leaching of coal fly ash and coal by-products

Coal combustion ash and pre-combustion coal refuse are currently under consideration as potential sources of rare earth elements. One of the early steps in recovering REEs from coal by-products is often acid leaching, which can result in low pH leachates with complex aqueous chemistry. The aim of this work was to understand the connection between REE solubility, pH, and major elemental components of leachates for coal by-products. To accomplish this, we investigated the effects of solids concentration (i.e., pulp density) and pH adjustment on REE solubility in acid leachates of coal fly ashes from the Powder River Basin (PRB) and Appalachian Basin in the United States, and a coal processing refuse from the Southwestern U.S. For PRB ashes, the concentrations of soluble REEs generally increased with increasing pulp density; however, at pulp density values above 80–100 g/L, the soluble REE concentrations in the leachates were markedly lower. Similarly, the soluble concentrations of other major solutes (Fe, Al, Si) that leached from PRB fly ashes were also non-linear with pulp density. These major elements tended to reach maximum concentration values at 60–70 g/L pulp density. In contrast, for the Appalachian fly ashes and the coal by-product, soluble concentrations of REE and major elements in leachates increased linearly with pulp density. Chemical equilibria calculations of mineral saturation indices indicated that trends in soluble REE concentrations could be explained by saturation conditions for Fe and Al-(hydr)oxides and possibly sulfate minerals, but not lanthanide hydroxides. Furthermore, pH adjustment of the acid leachates showed that REEs and many major solutes were removed from solution at pH values above 4.5, also consistent with Fe- and Al-(hydr)oxide precipitation. These results highlight the importance of understanding the chemical composition of leachates when designing REE recovery processes for low-grade geologic feedstocks and that precipitation of hydr(oxide) or sulfate minerals of major elements rather than discreet formation of REE mineral phases could be used for process optimization.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2022

Fragility Functions Resource Report: Documented Sources for Electricity and Water Resilience Valuation

Fragility curves provide the vulnerability between hazard intensity and an asset. Federal installations may include many different electricity and water infrastructure types (or assets) such as generators, wind turbines, solar PV, switch yards, substations and power lines as well as water distribution systems that could be affected by different hazards. The vulnerability of each asset is a function of its age, type of materials and maintenance. In addition, the vulnerability changes with the hazards intensity and has a probability distribution function associated with it. The fragility functions are used in conjunction with hazard probability and consequence valuations to determine the values at risk for examination of investment grade analyses of alternative mitigation strategies. This document provides examples of fragility functions and links to their sources for different electricity and water infrastructure assets by hazard type.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2017

Development and Implementation of an Automatic Continuous Online Monitoring and Control Platform for Polymerization Reactions to Sharply Boost Energy and Resource Efficiency in Polymer Manufacturing

The project goal was to create an energy saving paradigm shift in how polymers are manufactured in the 21st century. It used Automatic Continuous Online Monitoring of Polymerization reactions (ACOMP) integrated for the first time with automatic active control to create the innovative ‘ACOMP/Control Interface’, or ‘ACOMP/CI’. ACOMP/CI will begin the transformation from old, inefficient processes into highly evolved, energy and resource efficient ones. The ACOMP platform is broadly applicable to many types of reactions and processes throughout the vast polymer industry. The industry provides materials for sectors such as automotive, aerospace, oil recovery, agriculture, paints, resins, adhesives, pharmaceuticals and therapeutic proteins, optics, electronics, lightweight building materials, and many more. The U.S. chemical industry is one of the last major sectors in which the U.S. has top global stature. It consumes 24% of all U.S. manufacturing energy, produces over $800B of product annually, supports 25% of the U.S. GDP and employs over 6 million people. It is also a major source of GHG emissions. Polymers make up approximately 30% of this sector. It is estimated that annually 60 TBtu of energy could be saved and 3 million tons less of GHG emissions produced by optimizing production in the polyolefin manufacturing sector alone. The project scope included first time design and prototyping of an ACOMP/CI, creation of active reaction controllers, and demonstration of control capabilities on ideal, low concentration polymerization reactions. All these elements of the scope were met, including advances and findings not originally anticipated. Extensions to more complex reactions, beyond the reactor capabilities of the current project ACOMP/CI, such as polyolefins and other high pressure/high temperature reactions, are being proposed in Fall 2017 to CESMII, a DoE based NNMI. The initial proposal was for a three year funded project, but this was reduced to a two year project and budget due to funding constraints. Hence, some of the original plans, such as adaptation of the ACOMP/CI to more relevant industrial processes, such as emulsion and dispersion technologies, could not be carried out. A third year of funding was requested at the end of the project, but DoE did not have resources to grant this. The sub-contractor Fluence Analytics (previously Advanced Polymer Monitoring Technologies, Inc) designed, prototyped, and commissioned a working ACOMP/CI by June 2015. The reaction characteristics to be automatically controlled were i) conversion kinetics, ii) molecular weight, iii) copolymer composition, and iv) simultaneous molecular weight and composition. A two pronged control strategy was used. The Tulane/Fluence group took a basic principles approach that did not rely on kinetic models. The LSU group took a more complex, non-linear model-oriented approach involving complete kinetic descriptions of the reaction system Each of these approaches proved successful in their own way. By April 2016 fully automatic control of conversion and weight average molecular weight, Mw, trajectories was achieved using the Tulane/Fluence (TF) basic principles controller. Similar results were obtained by the LSU non-linear model controller by August 2016. The demonstration system was aqueous free radical polymerization of acrylamide, Am. The control variables were temperature and semi-batch feed to the reactor of Am monomer and initiator. A demonstration of active manual conversion control in an industrial process using high solids in inverse emulsion polymerization of Am was achieved. During Summer 2016 the TF controller was used in conjunction with a chain transfer agent, another control variable, to automatically produce multi-modal molecular weight distributions, MWD, in a single reactor. Industrially, multi-modal MWD are produced by mixing products made in separate reactors, requiring significant extra time, energy, and reactor resources. Recognizing the industrial potential a patent on automatic production of multi-modal polymers was filed, and DoE acknowledged. In Fall 2016 the TF team developed a basic principles controller for copolymer composition and demonstrated it on aqueous free radical copolymerization of comonomers Am and styrene sulfonate, SS. TF then fused the Mw and composition controllers to achieve simultaneous control of both Mw and copolymer composition trajectories. Numerous simultaneous trajectories were demonstrated, including a trimodal composition distribution with constant Mw. Meanwhile, the LSU group developed a Kalman filter to improve the results of their automatic Mw and conversion controller and successful tests were made. During the project the TF team developed a means of computing full MWD during polymer synthesis without need for any chromatographic separation, based on model distributions. This means the polymer product is ‘born characterized’ and this can eliminate post-manufacture analytical laboratory quality control. TF filed a joint patent application on this new approach to chromatography-free determination of MWD with acknowledgment to DoE. The Tulane group obtained a 60MHz NMR during the project and recently completed the first work on separating three comonomers, Am, SS, and Na-acrylate, with a first demonstration of terpolymer composition control with the TF basic principles controller. Widespread dissemination of ACOMP/CI in the polymer manufacturing sector will bolster DoE goals of energy efficiency and reduced GHG emissions: The ability to monitor and actively control polymerization reactions will lead to more efficient use of energy and non-renewable resources, plant and labor time, increase the safety of manufacturing personnel, and will enhance product quality and lead to feasibility of manufacturing of polymers currently too complex for industrial scale production, while leading to less GHG emissions per kilo of product, and allowing for increased U.S. competitiveness in this enormous manufacturing sector. When ACOMP/CI is expanded to the polyolefin industry it is estimated that 60 TeraBTU/year of energy can be saved. Much of this saving is anticipated to come from optimized control of grade changeovers in steady state reactors and maintenance of steady states. Conclusions: ACOMP’s ability to provide continuous realtime data streams of measured polymer and reaction characteristics made it possible, for the first time, to directly and automatically control free radical polymerization reactions. An industrial client of Fluence Analytics has requisitioned the first ACOMP/CI which uses the TF basic principles controller. This sets the stage for FA to add control features to the ACOMP systems it has begun to install on the industrial scale beginning in 2014. Recommendations: This successful project was mainly limited to ideal polymerizations not of an industrial sort. The most energy intensive portion of polymer manufacturing is polyolefins. Adoption of ACOMP/CI to this enormous industrial sector faces the enormous challenges of high temperature, high pressure continuous sampling and high temperature sensor operation to obtain the continuous data needed for direct reaction control. The project team has a strategy for achieving this ambitious goal and will present it in Fall 2017 as a proposal to CESMII/DoE. It is recommended that this upcoming proposal be funded in order to make full use of the achievements of this just ended DoE project as the next step towards making polyolefin ACOMP/CI an energy saving reality. It is projected that ACOMP/CI can have its first polyolefin testbed demonstrations within two years of beginning the proposed project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗