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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

The effect of rare earth (RE 3+ ) ionic radii on transparent lanthanide-tellurite glass-ceramics: correlation between ‘hole-formalism’ and crystallization

Rare earth (RE) doped transparent tellurite glass-ceramics (GCs) are widely explored for their application as advanced photonic materials. Specifically, the growth of RE based “anti-glass” crystalline phases in transparent GCs enhances their effective functionality. Enormous studies on the properties of GCs revealed that optimization of glass composition and heat-treatment schedule are the foremost factors that affect the transparency of the GCs. Nevertheless, the direct effect of RE 3+ ions on the crystallization mechanism of glass has hardly been reported. Therefore, a base glass of the composition La 2 O 3 –Gd 2 O 3 –TiO 2 –TeO 2 (LGTT) is doped with RE 3+ ions (Ce 3+ , Pr 3+ , Nd 3+ , Sm 3+ , Eu 3+ , Tb 3+ , and Dy 3+ ) with varied ionic radii. Rietveld refinement from XRD of GCs confirms that (La/Gd) 2 Te 6 O 15 phases are precipitated, where dopants Ce, Pr and Nd occupy La sites, while Sm, Eu, Tb, and Dy occupy Gd sites. The configurational heat-capacity (ΔC p ) from DSC is found to be lower for larger ionic radii REs (Ce, Pr, Nd) than smaller ionic radii REs (Sm, Eu, Tb, Dy) thereby exhibiting higher chemical ordering followed by faster crystal growth rate in the former. However, the transparency retention profile of different RE-doped GCs follows the trend Eu:Tb > Sm:Dy > Nd > Pr > Ce, confirming the ionic radii effect. In addition to the ionic radii effect, in this work, we propose a ‘Hole-Formalism’ concept to explain the observed trend. It is further corroborated with an identical neutron diffraction pattern and ΔC p values for these ion pairs Sm 3+ : Dy 3+ (4f 5 : 4f 9 ) and Eu 3+ : Tb 3+ (4f 6 : 4f 8 ) results in a similar crystallization mechanism, transmission profile and fine-scale microstructures of these RE-based tellurite GCs.

36 MATERIALS SCIENCE↗
NASA NTRS1987

RE-1000 free-piston Stirling engine hydraulic output system description

The NASA Lewis Research Center was involved in free-piston Stirling engine research since 1976. Most of the work performed in-house was related to characterization of the RE-1000 engine. The data collected from the RE-1000 tests were intended to provide a data base for the validation of Stirling cycle simulations. The RE-1000 was originally build with a dashpot load system which did not convert the output of the engine into useful power, but was merely used as a load for the engine to work against during testing. As part of the interagency program between NASA Lewis and the Oak Ridge National Laboratory, (ORNL), the RE-1000 was converted into a configuration that produces useable hydraulic power. A goal of the hydraulic output conversion effort was to retain the same thermodynamic cycle that existed with the dashpot loaded engine. It was required that the design must provide a hermetic seal between the hydraulic fluid and the working gas of the engine. The design was completed and the hardware was fabricated. The RE-1000 was modified in 1985 to the hydraulic output configuration. The early part of the RE-1000 hydraulic output program consisted of modifying hardware and software to allow the engine to run at steady-state conditions. A complete description of the engine is presented in sufficient detail so that the device can be simulated on a computer. Tables are presented showing the masses of the oscillating components and key dimensions needed for modeling purposes. Graphs are used to indicate the spring rate of the diaphragms used to separate the helium of the working and bounce space from the hydraulic fluid.

Schreiber, Jeffrey G.↗
NASA NTRS1991

Diffusion mechanisms in Ir-coated Re for high-temperature, radiation-cooled rocket thrusters

Materials used for radiation-cooled rocket thrusters must be capable of surviving under extreme conditions of high temperatures and oxidizing environments. Thruster chambers were developed using chemical-vapor-deposited (CVD) Re coated with CVD Ir on the inside surface which is exposed to hot combustion gases. Ir serves as an oxidation barrier protecting the Re which maintains structural integrity at high temperatures. In order to predict and extend the performance limits of these Ir-coated Re thrusters, the diffusion kinetics of CVD materials at temperature are studied. Thruster end ring sections were examined using electron microprobe analysis both before and after exposure to high temperature vacuum environments. The resulting elemental maps for Re, Ir, and Mo in the near-surface region allow identification of diffusion mechanisms operating at these temperatures. Line scans for Ir and Re were fit using a diffusion model to extract relevant diffusion constants. The fastest diffusion process is seen to be grain boundary diffusion with Re diffusing down grain boundaries in the Ir overlayer. The measured dependence of the diffusion rate on temperature will allow prediction of operating lifetimes for these thrusters.

Hamilton, J. C.↗
NASA NTRS1994

Problems with Re-Os isochron determinations

We have developed closed-system techniques for the equilibration of Os isotopes and for the calibration of Re and Os tracers using high-purity metals. The results show reproducibility of +/- 0.5% for calibrations of Os using different chunks of the same high-purity Os metal produced by vacuum arc melting. On a Re-Os evolution diagram the analyses of Negrillos and of Tocopilla are displaced along horizontal lines and are not consistent with a well-defined isochron. We conclude that is unclear whether whole-rock samples of irons of individual classes of iron meteorites (including the IIA class) define isochrons.In light of these observations, one must consider the evidence for phases in which Re and Os may become redistributed. We note that the IIA irons are composed of large or single kamacite crystals and do not contain taenite. This may hinder redistribution of Re and Os and may allow the IIA irons to define isochrons in preference to other magmatic iron classes. However, the IIA irons also include ubiquitous rhabdites, up to 20 mm in length, and troilite-daubreelite nodules. It has been observed that rhabdites are extremely rich in Pt-group elements. In addition to these considerations, Negrillos and Tocopilla were found in nitrate deposits and show evidence of corrosion. Therefore, it is possible that different samples of these meteorites have been differentially weathered, although our samples appeared fresh. We conclude that it is important to identify the phases in which Re and the PGEs are located and to address in detail the evidence for Re and Os remobilization.

Papanastassiou, D. A.↗
NASA NTRS2007

Coronas-F Orbit Monitoring and Re-Entry Prediction

Russian scientific satellite CORONAS-F was launched on July, 31, 2001. The object was inserted in near-circular orbit with the inclination 82.5deg and a mean altitude approx. 520 km. Due to the upper atmosphere drag CORONAS-F was permanently descended and as a result on December, 6, 2005 it has finished the earth-orbital flight, having lifetime in space approx. 4.5 years. The satellite structural features and its flight attitude control led to the significant variations of its ballistic coefficient during the flight. It was a cause of some specific difficulties in the fulfillment of the ballistic and navigation support of this space vehicle flight. Besides the main mission objective CORONAS-F also has been selected by the Inter-Agency Space Debris Coordination Committee (IADC) as a target object for the next regular international re-entry test campaign on a program of surveillance and re-entry prediction for the hazard space objects within their de-orbiting phases. Spacecraft (S/C) CORONAS-F kept its working state right up to the end of the flight - down to the atmosphere entry. This fact enabled to realization of the additional research experiments, concerning with an estimation of the atmospheric density within the low earth orbits (LEO) of the artificial satellites, and made possible to continue track the S/C during final phase of its flight by means of Russian regular command & tracking system, used for it control. Thus there appeared a unique possibility of using for tracking S/C at its de-orbiting phase not only passive radar facilities, belonging to the space surveillance systems and traditionally used for support of the IADC re-entry test campaigns, but also more precise active trajectory radio-tracking facilities from the ground control complex (GCC) applied for this object. Under the corresponding decision of the Russian side such capability of additional high-precise tracking control of the CORONAS-F flight in this period of time has been implemented. The organizing of the CORONAS-F ballistic and navigational support (BNS) and solving its main tasks (such as S/C orbit determination (OD) and its motion prediction and connected with them) both for regular mission stage and for additional flight program were realized by the group of specialists from the Mission Control Center (MCC). MCC was also assigned as a principal organization from the Russian side for participation in the 7th IADC re-entry test campaign on CORONAS-F. The CORONAS-F flight features and space environments circumstances during its flight as well as a methodology and technology of spacecraft ballistic and navigational support are given below. The BNS results for different phases of S/C flight, including the results of its re-entry predictions, obtained during the realization of the 7th IADC test campaign are submitted. The accuracy of space vehicle re-entry prediction and its dependence on various factors are analyzed in more details.

Ivanov, N. M.↗
NASA NTRS2015

Re-Computation of Numerical Results Contained in NACA Report No. 496

An extensive examination of NACA Report No. 496 (NACA 496), "General Theory of Aerodynamic Instability and the Mechanism of Flutter," by Theodore Theodorsen, is described. The examination included checking equations and solution methods and re‐computing interim quantities and all numerical examples in NACA 496. The checks revealed that NACA 496 contains computational shortcuts (time‐ and effort‐saving devices for engineers of the time) and clever artifices (employed in its solution methods), but, unfortunately, also contains numerous tripping points (aspects of NACA 496 that have the potential to cause confusion) and some errors. The re‐computations were performed employing the methods and procedures described in NACA 496, but using modern computational tools. With some exceptions, the magnitudes and trends of the original results were in fair‐to‐very‐good agreement with the re‐computed results. The exceptions included what are speculated to be computational errors in the original in some instances and transcription errors in the original in others. Independent flutter calculations were performed and, in all cases, including those where the original and re‐computed results differed significantly, were in excellent agreement with the re‐computed results. Appendix A contains NACA 496; Appendix B contains a Matlab(Reistered) program that performs the re‐computation of results; Appendix C presents three alternate solution methods, with examples, for the two‐degree‐of-freedom solution method of NACA 496; Appendix D contains the three‐degree‐of‐freedom solution method (outlined in NACA 496 but never implemented), with examples.

Perry, Boyd, III↗
DOE OSTI2024

The OSIRIS-REx Sample Return Capsule re-entry: A coordinated seismo-acoustic observational campaign for the study of meteor phenomena

Objects entering Earth’s atmosphere at hypersonic velocities may generate powerful acoustic waves. Depending on atmospheric conditions and acoustic propagation paths, they may be captured using ground or balloon-borne microbarometers and microphones. Impacts into the Earth’s atmosphere by asteroids in a meter-size range are sporadic and unannounced, and thus, well-documented scientific observations of asteroids are rare and generally happen by chance. Arriving from interplanetary space at hypervelocity, spacecraft are considered analogues for low velocity meteoroids and asteroids impacting the Earth’s atmosphere, and as such provide unprecedented and unique opportunity to carry out planned observational campaigns and perform detailed studies of meteor phenomena. However, since the end of the Apollo era, only four instances of a hypersonic re-entry of an artificial body from interplanetary space with an incident speed of 11-12 km/s have been observed and studied. These were the Sample Return Capsules (SRCs) that brought physical samples of extraterrestrial material back to Earth (Genesis, Stardust, Hayabusa 1, Hayabusa 2). These re-entries were also detected by infrasound and/or seismic sensors. The next opportunity to observe an artificial meteor will be on 24 September 2023 with the re-entry of NASA’s OSIRIS-REx SRC that will bring samples of the carbonaceous near-Earth asteroid Bennu. The re-entry consists of several flight phases, including hypersonic and supersonic, providing a unique opportunity to observe these by infrasound and seismic sensors. We will discuss observational campaign efforts aimed to capture geophysical signals generated by the OSIRIS-REx SRC re-entry. This campaign utilizes an unparalleled number of instruments, both ground and airborne, strategically positioned in the immediate and extended region around the projected re-entry trajectory to maximize the scientific output.

47 - OTHER INSTRUMENTATION↗
DOE OSTI2024

A model for trapping and re-solution regarding intra-granular bubbles in UO 2 , linked to atomic-scale simulations

In the literature, a clear definition of the irradiation re-solution frequency of gas from bubbles in the UO 2 fuel is absent. Moreover, for intra-granular bubbles, a detailed calculation of the cumulated displaced gas quantities in function of the distance from the radius of the bubble after a re-solution event has never been published. The assessment of these two elements is very useful if we want to increase the adherence of fission gas release codes to our present knowledge of the behavior of fission gases. Hence, we suggest to link the definition of the re-solution frequency to atomic-scale simulations. Furthermore, we present the cumulated displaced gas quantities obtained from Molecular Dynamics calculations, from which we have derived a re-solution profile that can be exploited to better consider the irradiation re-solution phenomenon inside Fission Gas Release codes. On top of that, we have built a new trapping/re-solution model for intra-granular bubbles linked to Molecular Dynamics simulations that can be easily incorporated into Fission Gas Release codes. In conclusion, we also check that the model is properly built through the comparison of the new model against a reference.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Spectroscopic characterization of a new Re(i) tricarbonyl complex with a thiosemicarbazone derivative: towards sensing and electrocatalytic applications

This work describes the preparation of a new thiosemicarbazone derivative, (Z)- N -ethyl-2-(6-oxo-1,10-phenanthrolin-5(6 H )-ylidene)hydrazinecarbothioamide (phet) and its respective Re( I ) tricarbonyl chloro complex, fac -[ReCl(CO) 3 (phet)]. The spectroscopic, photophysical and electrochemical properties of the new complex were fully investigated through steady state and time-resolved techniques along with computational calculations. In fac -[ReCl(CO) 3 (phet)], the new ligand is coordinated to the metal center through the pyridyl rings of the phenanthroline moiety. The unbound electron pairs in the S atom of the bending thiosemicarbazone group induce new low energy lying electronic transitions. Consequently, enhanced visible light absorption up to 550 nm is observed in acetonitrile due to the overlap between MLCT Re→phet and IL phet(n→π*) transitions. The absorption bands and emission quantum yields of fac -[ReCl(CO) 3 (phet)] are sensitive to proton concentration due to an acid-basic equilibrium in the N atoms of the thiosemicarbazone. Proton dissociation constants of 10.0 ± 0.1 and 11.4 ± 0.2 were determined respectively for the ground and excited states of the new complex. Spectral changes could also be observed in the presence of Zn 2+ cations which can be further explored for sensing applications. The electrochemical behavior of the new complex was studied in detail, revealing up to four one electron reduction processes in the range from 0 to -2.4 V vs. Fc + /Fc. With support of DFT calculations, the first three processes are ascribed to the reduction of the coordinated phet ligand followed by the Re I/0 reduction and consequent Cl - release. Furthermore, the new complex was able to act as an electrocatalyst for CO 2 reduction into CO ( E onset = -1.92 V vs. Fc + /Fc), with a turnover frequency of 2.81 s -1 and turnover number of 24 ± 1 in anhydrous acetonitrile, being the first Re( I ) tricarbonyl complex with a thiosemicarbazone derivative described for this goal. The detailed characterization carried out here can drive the development of new Re( I )-thiosemicarbazone derivatives for different applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Materials Data on Re by Materials Project

Re is Magnesium structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Re is bonded to twelve equivalent Re atoms to form a mixture of edge, face, and corner-sharing ReRe12 cuboctahedra. There are six shorter (2.76 Å) and six longer (2.78 Å) Re–Re bond lengths.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re by Materials Project

Re is Copper structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Re is bonded to twelve equivalent Re atoms to form a mixture of edge, face, and corner-sharing ReRe12 cuboctahedra. All Re–Re bond lengths are 2.78 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Robust Wheel Detection for Vehicle Re-Identification

Vehicle re-identification is a demanding and challenging task in automated surveillance systems. The goal of vehicle re-identification is to associate images of the same vehicle to identify re-occurrences of the same vehicle. Robust re-identification of individual vehicles requires reliable and discriminative features extracted from specific parts of the vehicle. In this work, we construct an efficient and robust wheel detector that precisely locates and selects vehicular wheels from vehicle images. The associated hubcap geometry can hence be utilized to extract fundamental signatures from vehicle images and exploit them for vehicle re-identification. Wheels pattern information can yield additional information about vehicles in questions. To that end, we utilized a vehicle imagery dataset that has thousands of side-view vehicle collected under different illumination conditions and elevation angles. The collected dataset was used for training and testing the wheel detector. Experiments show that our approach could detect vehicular wheels accurately for 99.41% of the vehicles in the dataset.

47 OTHER INSTRUMENTATION↗
DOE OSTI2018

Electrochemical Behavior Assessment of As-Cast Mg-Y-RE-Zr Alloy in Phosphate Buffer Solutions (X Na{sub 3}PO{sub 4} + Y Na{sub 2}HPO{sub 4}) Using Electrochemical Impedance Spectroscopy and Mott–Schottky Techniques

In the present study, electrochemical behavior of as-cast Mg-Y-RE-Zr alloy (RE: rare-earth alloying elements) was investigated using electrochemical tests in phosphate buffer solutions (X Na{sub 3}PO{sub 4} + Y Na{sub 2}HPO{sub 4}). X-ray diffraction techniques and Scanning electron microscopy equipped with energy dispersive x-ray spectroscopy were used to investigate the microstructure and phases of the experimental alloy. Different electrochemical tests such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS) and Mott–Schottky (M–S) analysis were carried out in order to study the electrochemical behavior of the experimental alloy in phosphate buffer solutions. The PDP curves and EIS measurements indicated that the passive behavior of the as-cast Mg-Y-RE-Zr alloy in phosphate buffer solutions was weakened by an increase in the pH, which is related to formation of an imperfect and less protective passive layer on the alloy surface. The presence of the insoluble zirconium particles along with high number of intermetallic phases of RE elements mainly Mg{sub 24}Y{sub 5} in the magnesium matrix can deteriorate the corrosion performance of the alloy by disrupting the protective passive layer that is formed at pH values over 11. These insoluble zirconium particles embedded in the matrix can detrimentally influence the passivation. The M–S analysis revealed that the formed passive layers on Mg-Y-RE-Zr alloy behaved as an n-type semiconductor. An increase in donor concentration accompanying solutions of higher alkalinity is thought to result in the formation of a less resistive passive layer.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Multi-modal characterization of the B2 phase in the Ta-Re binary system

The energy and transportation industries demand materials that retain their mechanical property at high temperatures. Refractory complex concentrated alloys (RCCAs) with a BCC + B2 microstructure offer a potential solution, where maintaining the high temperature mechanical properties can be achieved by precipitation strengthening. This depends on the B2 phase in RCCAs being thermodynamically stable with a high solvus temperature. Recently, we predicted the high temperature stability of the B2 structure in the Ta-Re binary system, using density functional theory. Here, in this study, we provide experimental evidence for the existence of this phase for the first time, using a Ta 65 Re 35 alloy. Despite Ta-Re binary phase diagrams predicting a single-phase BCC microstructure for Ta 65 Re 35 , we show that a high Z nanoscale secondary phase appears after heat treatment at 1550 °C and 1100 °C. Scanning transmission electron microscopy (STEM) revealed that this phase has a cubic structure and is equiatomic TaRe though B2 superlattice reflections were absent in fast Fourier transforms (FFT) and diffraction patterns (DPs). DP simulations indicate that the B2 TaRe superlattice reflections are up to two orders of magnitude weaker than their fundamental reflections, making their detection challenging via electron microscopy. Neutron diffraction confirmed the second phase had a B2 structure. This study identified a previously unobserved high temperature stable B2 phase in the Ta-Re system, enabling the development of new high temperature BCC + B2 RCCAs.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Effects of neutron irradiation on hydrogen isotope permeation on W-Re

Hydrogen and deuterium permeation behavior for neutron damaged W and W-3 %Re was evaluated using a Plasma Driven Permeation device. For neutron damaged W-3 %Re at 773 K and 1473 K, precipitation of Re and Os was observed by atom probe tomography. Neutron irradiation introduced defect damage throughout the sample and enhanced H and D diffusion toward downstream side. The existence of irradiation damage by neutron irradiation was found to increase hydrogen isotope permeation. Moreover, the existence of Re has suppressed the formation of irradiation defects for hydrogen isotope trapping sites. Further, the recovery of irradiation defects by increasing the irradiation temperature led to the structural changes due to the diffusion of Re and Os, which also affected the hydrogen isotope permeation behavior.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Diffusive shock re-acceleration

Here, we have performed two-dimensional hybrid simulations of non-relativistic collisionless shocks in the presence of pre-existing energetic particles (‘seeds’); such a study applies, for instance, to the re-acceleration of galactic cosmic rays (CRs) in supernova remnant (SNR) shocks and solar wind energetic particles in heliospheric shocks. Energetic particles can be effectively reflected and accelerated regardless of shock inclination via a process that we call diffusive shock re-acceleration. We determine that re-accelerated seeds can drive the streaming instability in the shock upstream and produce effective magnetic field amplification. This can later trigger the injection of thermal protons even at oblique shocks that ordinarily cannot inject thermal particles. We characterize the current in reflected seeds, finding that it tends to a universal value $J\simeq en_{\text{CR}}v_{\text{sh}}$ , where $en_{\text{CR}}$ is the seed charge density and $v_{\text{sh}}$ is the shock velocity. When applying our results to SNRs, we find that the re-acceleration of galactic CRs can excite the Bell instability to nonlinear levels in less than ${\sim}10~\text{yr}$ , thereby providing a minimum level of magnetic field amplification for any SNR shock. Finally, we discuss the relevance of diffusive shock re-acceleration also for other environments, such as heliospheric shocks, galactic superbubbles and clusters of galaxies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2019

Effect of Electronic Coupling on Electron Transfer Rates from Photoexcited Naphthalenediimide Radical Anion to Re(bpy)(CO) 3 X

The electron transfer rate between a donor and an acceptor depends on the free energy change for the reaction as well as differences in structure and electronic coupling between the initial and final states. Selective excitation of a naphthalenediimide radical anion (NDI•–) covalently linked at the 4-, 5-, or 6-positions of the bipyridine (bpy) in the Re(bpy)(CO) 3 X (X = Cl or pyridine) carbon dioxide reduction catalyst results in electron transfer from 2* NDI •– to Re(bpy)(CO) 3 X to form Re(bpy•–)(CO) 3 X, the first intermediate in the photocatalytic reduction of CO 2 . Femtosecond UV/vis, near-IR, and mid-IR spectroscopy on these constitutional isomers and a set of appropriate reference molecules show that systematically varying the electronic coupling as well as the reaction free energy increases the lifetime of Re(bpy•–)(CO) 3 X by an order of magnitude when the NDI chromophore is attached to the 6-position of bpy. NMR and X-ray structural studies along with computational modeling are used to identify the conformation of Re(6-NDI-bpy)(CO) 3 X responsible for these favorable changes. Extending the lifetime of the reduced complex in the covalent photosensitizer–catalyst assembly is a critical requirement for the photocatalytic CO 2 reduction and artificial photosynthesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

First measurement of S/XB values of Re I visible emission lines

A spectroscopic parameter, so called S/XB (the number of ionization events per photon or inverse photon efficiency), is experimentally determined for Re I visible emission lines (488.9, 527.1, and 527.6 nm) at an electron temperature range of ~2–8 eV in the PISCES-B linear plasma device. Our standard mass loss method was applied, where a pure Re sample was sputtered by Ar plasma. In addition, a new alloy method was developed, where a W-3.3 at% Re alloy sample was used. In the new method, the sputtered flux ratio of Re and W atoms is assumed to be the same as the elemental composition because of the very similar sputtering yields. In this work, good agreement in measured Re I S/XB values is obtained between the standard mass loss and new alloy methods.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗