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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

The influence of counterion structure identity on conductivity, dynamical correlations, and ion transport mechanisms in polymerized ionic liquids

We used equilibrium and non-equilibrium atomistic simulations to probe the influence of anion chemistry on the true conductivity, dynamical correlations, and ion transport mechanisms in polymeric ionic liquids. An inverse correlation was found between anion self-diffusivities, ionic mobilities, and the anion size for spherical anions. While some larger asymmetric anions had higher diffusivities than smaller spherical anions, their diffusivities and mobilities did not exhibit a direct correlation to the anion volumes. Here, the conductivity and anion dynamical correlations also followed the same trends as displayed by the diffusivity and mobility of anions. All the systems we examined displayed positively correlated motion among anions, suggesting a contribution that enhances the conductivity beyond the ideal Nernst–Einstein value. Analysis of ion transport mechanisms demonstrated very similar hopping characteristics among the spherical anions despite differences in their sizes.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Crystal structure of the Arabidopsis SPIRAL2 C-terminal domain reveals a p80-Katanin-like domain

Epidermal cells of dark-grown plant seedlings reorient their cortical microtubule arrays in response to blue light from a net lateral orientation to a net longitudinal orientation with respect to the long axis of cells. The molecular mechanism underlying this microtubule array reorientation involves katanin, a microtubule severing enzyme, and a plant-specific microtubule associated protein called SPIRAL2. Katanin preferentially severs longitudinal microtubules, generating seeds that amplify the longitudinal array. Upon severing, SPIRAL2 binds nascent microtubule minus ends and limits their dynamics, thereby stabilizing the longitudinal array while the lateral array undergoes net depolymerization. To date, no experimental structural information is available for SPIRAL2 to help inform its mechanism. To gain insight into SPIRAL2 structure and function, we determined a 1.8 Å resolution crystal structure of the Arabidopsis thaliana SPIRAL2 C-terminal domain. The domain is composed of seven core α-helices, arranged in an α-solenoid. Amino-acid sequence conservation maps primarily to one face of the domain involving helices α1, α3, α5, and an extended loop, the α6-α7 loop. The domain fold is similar to, yet structurally distinct from the C-terminal domain of Ge-1 (an mRNA decapping complex factor involved in P-body localization) and, surprisingly, the C-terminal domain of the katanin p80 regulatory subunit. The katanin p80 C-terminal domain heterodimerizes with the MIT domain of the katanin p60 catalytic subunit, and in metazoans, binds the microtubule minus-end factors CAMSAP3 and ASPM. Structural analysis predicts that SPIRAL2 does not engage katanin p60 in a mode homologous to katanin p80. The SPIRAL2 structure highlights an interesting evolutionary convergence of domain architecture and microtubule minus-end localization between SPIRAL2 and katanin complexes, and establishes a foundation upon which structure-function analysis can be conducted to elucidate the role of this domain in the regulation of plant microtubule arrays.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2015

Progress for the Industry Application External Hazard Analyses Early Demonstration

This report describes the current progress and status related to the Industry Application #2 focusing on External Hazards. For this industry application within the Light Water Reactor Sustainability (LWRS) Program Risk-Informed Safety Margin Characterization (RISMC) R&D Pathway, we will create the Risk-Informed Margin Management (RIMM) approach to represent meaningful (i.e., realistic facility representation) event scenarios and consequences by using an advanced 3D facility representation that will evaluate external hazards such as flooding and earthquakes in order to identify, model and analyze the appropriate physics that needs to be included to determine plant vulnerabilities related to external events; manage the communication and interactions between different physics modeling and analysis technologies; and develop the computational infrastructure through tools related to plant representation, scenario depiction, and physics prediction. One of the unique aspects of the RISMC approach is how it couples probabilistic approaches (the scenario) with mechanistic phenomena representation (the physics) through simulation. This simulation-based modeling allows decision makers to focus on a variety of safety, performance, or economic metrics. In this report, we describe the evaluation of various physics toolkits related to flooding representation. Ultimately, we will be coupling the flooding representation with other events such as earthquakes in order to provide coupled physics analysis for scenarios where interactions exist.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
NASA NTRS1986

Fault latency in the memory - An experimental study on VAX 11/780

Fault latency is the time between the physical occurrence of a fault and its corruption of data, causing an error. The measure of this time is difficult to obtain because the time of occurrence of a fault and the exact moment of generation of an error are not known. This paper describes an experiment to accurately study the fault latency in the memory subsystem. The experiment employs real memory data from a VAX 11/780 at the University of Illinois. Fault latency distributions are generated for s-a-0 and s-a-1 permanent fault models. Results show that the mean fault latency of a s-a-0 fault is nearly 5 times that of the s-a-1 fault. Large variations in fault latency are found for different regions in memory. An analysis of a variance model to quantify the relative influence of various workload measures on the evaluated latency is also given.

Chillarege, Ram↗
DOE OSTI2019

Analysis of the Effect of Vehicle Platooning on the Optimal Control of a Heavy Duty Engine Thermal System

One promising method for reducing fuel consumption and emissions, particularly in heavy duty trucks, is platooning. As the distance between vehicles decreases, the following vehicles will experience less aerodynamic drag on the front of the vehicle. However, reducing the velocity of the air contacting the front of the vehicle could have adverse effects on the temperature of the engine. To compensate for this effect, the energy consumption of the engine cooling system might increase, ultimately limiting the overall improvements obtained with platooning. Understanding the coupling between drag reduction and engine cooling load requirement is key for successfully implementing platooning strategies. Additionally, in a Connected and Automated Vehicle (CAV) environment, where information of the future engine load becomes available, the operation of the cooling system can be optimized in order to achieve the maximum fuel consumption reduction. In this paper, a control-oriented physics-based model for the engine cooling loop of a Volvo engine is developed and validated against road data. Starting from the validated model, an optimal control problem for the coolant system is formulated considering the tradeoff between the tracking of the engine temperature setpoint and the corresponding fuel consumption under different trailing distances. To compare the coolant system performance, Dynamic Programming (DP) is used to determine the global optimal solution for the coolant system actuator. The coupling between optimal cooling system operation and reduction in ram air are evaluated by comparing the results obtained from the DP under different platooning conditions against the unrestricted scenario. In addition, the paper analyzes the changes in the tradeoff between fuel consumption and setpoint tracking for different vehicle distances. This analysis will provide useful insight on the sensitivity of the coolant system controller calibration to the platoon distance.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1982

Application of digital image analysis techniques to antimisting fuel spray characterization

Pulsed ruby laser sheet illumination of the spray is used for the initial recording of data on very-high-resolution photographic film. The digitization of mosaic elements is effected with a vidicon and video digitizer whose output is stored in computer RAM memory for processing. Highly nonspherical elements and a broad range of drop diameters (8-2000 microns) resulting from the unusual rheological properties of the fuel-additive system are accommodated by the device configuration and algorithms. It is found that the generation of two-dimensional images by means of scattered light also eliminates errors resulting from variations in the index of refraction and from the submicron scattering sites that are often present within the modified fuel. No a priori information on the drop size distribution or on the system response to various drop sizes is required.

Fleeter, R.↗
NASA NTRS1993

Analysis of LDEF micrometeoroid/debris data and damage to composite materials

This report presented published LDEF micrometeoroid/debris impact data in a nomogram format useful for estimating the total number of hits that could be expected on a space structure as a function of time in orbit, angular location relative to ram, and exposed surface area. Correction factors accounting for different altitudes are given. These are normalized to the average LDEF altitude. Examples on how to use the nomograph are also included. In addition, impact data and damage areas observed on composite laminates (experiment AO 180) are discussed.

Tennyson, R. C.↗
NASA NTRS1992

Long Duration Space Materials Exposure (LDSE)

The Center on Materials for Space Structures (CMSS) at Case Western Reserve University is one of seventeen Commercial Centers for the Development of Space. It was founded to: (1) produce and evaluate materials for space structures; (2) develop passive and active facilities for materials exposure and analysis in space; and (3) develop improved material systems for space structures. A major active facility for materials exposure is proposed to be mounted on the exterior truss of the Space Station Freedom (SSF). This Long Duration Space Materials Exposure (LDSE) experiment will be an approximately 6 1/2 ft. x 4 ft. panel facing into the velocity vector (RAM) to provide long term exposure (up to 30 years) to atomic oxygen, UV, micro meteorites, and other low earth orbit effects. It can expose large or small active (instrumented) or passive samples. These samples may be mounted in a removable Materials Flight Experiment (MFLEX) carrier which may be periodically brought into the SSF for examination by CMSS's other SSF facility, the Space Materials Evaluation Facility (SMEF), which will contain a Scanning Electron Microscope, a Variable Angle & Scanning Ellipsometer, a Fourier Transform Infrared Spectrometer, and other analysis equipment. These facilities will allow commercial firms to test their materials in space and promptly obtain information on their materials survivability in the LEO environment.

Allen, David↗
DOE OSTI2022

LoTSS Jellyfish Galaxies. IV. Enhanced Star Formation on the Leading Half of Cluster Galaxies and Gas Compression in IC3949

With Mapping Nearby Galaxies at APO integral field spectroscopy, we present a resolved analysis of star formation for 29 jellyfish galaxies in nearby clusters, identified from radio continuum imaging taken by the Low Frequency Array. Simulations predict enhanced star formation on the "leading half" (LH) of galaxies undergoing ram pressure stripping, and in this work we report observational evidence for this elevated star formation. The dividing line (through the galaxy center) that maximizes this star formation enhancement is systematically tied to the observed direction of the ram-pressure-stripped tail, suggesting a physical connection between ram pressure and this star formation enhancement. We also present a case study on the distribution of molecular gas in one jellyfish galaxy from our sample, IC3949, using Atacama Large Millimeter/submillimeter Array CO J = 1 – 0, HCN J = 1 – 0, and HCO + J = 1 – 0 observations from the ALMA MaNGA Quenching and Star Formation Survey. The H2 depletion time (as traced by CO) in IC3949 ranges from ~1 Gyr in the outskirts of the molecular gas disk to ~11 Gyr near the galaxy center. IC3949 shows a clear region of enhanced star formation on the LH of the galaxy where the average depletion time is ~2.7 Gyr, in line with the median value for the galaxy on the whole. Dense gas tracers, HCN and HCO + , are only detected at the galaxy center and on the LH of IC3949. Our results favor a scenario in which ram pressure compresses the interstellar medium, promoting the formation of molecular gas that in turn fuels a localized increase of star formation.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2010

Materials International Space Station Experiment-6 (MISSE-6) Atomic Oxygen Fluence Monitor Experiment

An atomic oxygen fluence monitor was flown as part of the Materials International Space Station Experiment-6 (MISSE-6). The monitor was designed to measure the accumulation of atomic oxygen fluence with time as it impinged upon the ram surface of the MISSE 6B Passive Experiment Container (PEC). This was an active experiment for which data was to be stored on a battery-powered data logger for post-flight retrieval and analysis. The atomic oxygen fluence measurement was accomplished by allowing atomic oxygen to erode two opposing wedges of pyrolytic graphite that partially covered a photodiode. As the wedges of pyrolytic graphite erode, the area of the photodiode that is illuminated by the Sun increases. The short circuit current, which is proportional to the area of illumination, was to be measured and recorded as a function of time. The short circuit current from a different photodiode, which was oriented in the same direction and had an unobstructed view of the Sun, was also to be recorded as a reference current. The ratio of the two separate recorded currents should bear a linear relationship with the accumulated atomic oxygen fluence and be independent of the intensity of solar illumination. Ground hyperthermal atomic oxygen exposure facilities were used to evaluate the linearity of the ratio of short circuit current to the atomic oxygen fluence. In flight, the current measurement circuitry failed to operate properly, thus the overall atomic oxygen mission fluence could only be estimated based on the physical erosion of the pyrolytic graphite wedges. The atomic oxygen fluence was calculated based on the knowledge of the space atomic oxygen erosion yield of pyrolytic graphite measured from samples on the MISSE 2. The atomic oxygen fluence monitor, the expected result and comparison of mission atomic oxygen fluence based on the erosion of the pyrolytic graphite and Kapton H atomic oxygen fluence witness samples are presented in this paper.

Banks, Bruce A.↗
DOE OSTI2023

Microporous structure in silicone polymers with polylactic acid and polyethylene glycol microspheres: Synthesis and characterization

Porosity in polymer parts could improve mechanical properties while reducing weight and density. Individual pores must be small enough that bulk mechanical properties are retained but significant enough to reduce the density of the material. Filler materials can be incorporated into polymer matrices and removed to create voids. Here, this paper focuses on creating spherical pores in silicone matrices by inserting and removing core materials or fillers during post-cure. A method was developed to incorporate pore formers into an uncured polymer resin and remove the pore former materials from the matrix. Polyethylene glycol (PEG) and polylactic acid (PLA) microspheres were created and incorporated into silicone matrices as pore formers. Microspheres with controllable size distributions were formed via an emulsion formation. Microspheres are removed from the matrix by solvent extraction and calcination. Thermogravimetric Analysis (TGA), Dynamic Mechanical Analysis (DMA), and optical imaging characterize and determine the successful creation of micropores in the polymer matrices.

36 MATERIALS SCIENCE↗
NASA NTRS1950

Determination of aromatics and olefins in wide-boiling petroleum fractions

A chromatographic method is described herein for the analysis of aromatics and olefins in wide boiling petroleum fractions. The fuel is split into four fractions: nonaromatic, intermediate, pure aromatic, and wash. The analysis, which need be run only on the intermediate cut to determine aromatics in the fuel, is based on specific dispersion. With analysis times of less than 8 hours, accuracies of 1 percent were attained.

FUELS - TURBINE ENGINES, RAM JETS, AND PULSE JETS↗
NASA NTRS1995

Organic matrix composite protective coatings for space applications

Successful use of composites in low earth orbit (LEO) depends on their ability to survive long-term exposure to atomic oxygen (AO), ultraviolet radiation, charged particle radiation, thermal cycling, and micrometeoroid and space debris. The AO environment is especially severe for unprotected organic matrix composites surfaces in LEO. Ram facing unprotected graphite/epoxy flown on the 69-month Long Duration Exposure Facility (LDEF) mission lost up to one ply of thickness (5 mils) resulting in decreased mechanical properties. The expected AO fluence of the 30 year Space Station Alpha mission is approximately 20 times that seen on LDEF. This exposure would result in significant material loss of unprotected ram facing organic matrix composites. Several protective coatings for composites were flown on LDEF including anodized aluminum, vacuum deposited coatings, a variety of thermal control coatings, metalized Teflon, and leafing aluminum. Results from the testing and analysis of the coated and uncoated composite specimens flown on LDEF's leading and trailing edges provide the baseline for determining the effectiveness of protectively coated composites in LEO. In addition to LDEF results, results from shuttle flight experiments and ground based testing will be discussed.

Dursch, Harry W.↗
DOE OSTI2024

Current State, Challenges, and Opportunities in Genome-Scale Resource Allocation Models: A Mathematical Perspective

Stoichiometric genome-scale metabolic models (generally abbreviated GSM, GSMM, or GEM) have had many applications in exploring phenotypes and guiding metabolic engineering interventions. Nevertheless, these models and predictions thereof can become limited as they do not directly account for protein cost, enzyme kinetics, and cell surface or volume proteome limitations. Lack of such mechanistic detail could lead to overly optimistic predictions and engineered strains. Initial efforts to correct these deficiencies were by the application of precursor tools for GSMs, such as flux balance analysis with molecular crowding. In the past decade, several frameworks have been introduced to incorporate proteome-related limitations using a genome-scale stoichiometric model as the reconstruction basis, which herein are called resource allocation models (RAMs). This review provides a broad overview of representative or commonly used existing RAM frameworks. This review discusses increasingly complex models, beginning with stoichiometric models to precursor to RAM frameworks to existing RAM frameworks. RAM frameworks are broadly divided into two categories: coarse-grained and fine-grained, with different strengths and challenges. Discussion includes pinpointing their utility, data needs, highlighting framework strengths and limitations, and appropriateness to various research endeavors, largely through contrasting their mathematical frameworks. Finally, promising future applications of RAMs are discussed.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1983

Visible glow induced by spacecraft-environment interaction

Illumination was found recently in the ram direction of the Shuttle Orbiter arising from interaction with the ambient surrounding atmosphere. We have examined a similar optical glow by analyzing photometric data taken by the Visible Airglow Experiment on board the Atmosphere Explorer Satellites. Analysis at six different wavelengths from the ultraviolet to the near infrared suggests that the glow has a diffuse band or continuum spectrum which peaks in the red and probably in the infrared.

Yee, J. H.↗
NASA NTRS1992

Validation and applications of the POLAR code

The Potentials of Large Objects in the Auroral Region (POLAR) code was written to model the charging of large spacecraft by auroral electrons in low polar orbit. It has also proven to be a powerful tool for analysis of active and voltage-plasma interactions. POLAR combines 3-D object definition, direct solution to Poisson's equation, space charge transport, and surface charge computation. Physical effects treated by POLAR include the plasma wake and ram, the geomagnetic field, ionization, sheath and barrier formation, and photo and secondary electron generation and transport. Polar development is complete and it is now available to the aerospace community. The methodology of POLAR is reviewed but concentration is on the applications of POLAR to physical problems and observations with the intent of demonstrating both the code's capabilities, and its limitations. These applications include the Space Shuttle, the Defense Meteorological Satellite Program (DMSP) satellites, sounding rockets, plasma chamber experiments, and things not yet flown.

Cooke, David L.↗
NASA NTRS1992

Analysis of a space-exposed thermoplastic resin

The chemical characterization of a thermoplastic resin exposed to the low Earth orbit (LEO) environment for 10 months and for 5.8 years is reported. The resin, processed as a thick film and as a matrix for a graphite fiber reinforced composite, few exposed in the RAM direction on the NASA Long Duration Exposure Facility (LDEF). Differences attributable to environmental exposure were detected in infrared spectra and in various molecular weight parameters of film after 10 months in LEO. Those effects were not as apparent in composites after 5.8 years in LEO. Increased exposure to atomic oxygen toward the end of the LDEF mission probably scrubbed these effects from specimens exposed for 5.8 years. The intent of this study is to increase our fundamental understanding of space environmental effects on polymeric materials and to develop a benchmark for enhancing our methodology for and understanding of the ground-based simulation of space environmental effects.

Young, Philip R.↗