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At least 163 records · Page 9

Nuclear Power Plant Physical Protection Recommendation Document

This document is aimed at providing guidance to the National Nuclear Security Administration’s (NNSA) Office of International Nuclear Security’s (INS) country and regional teams for implementing effective physical protection systems (PPSs) for nuclear power plants (NPPs) to prevent the radiological consequences of sabotage. This recommendation document includes input from the Physical Protection Functional Team (PPFT), the Response Functional Team (RFT), and the Sabotage Functional Team (SFT) under INS. Specifically, this document provides insights into increasing and sustaining physical protection capabilities at INS partner countries’ NPP sites. Nuclear power plants should consider that the intent of this document is to provide a historical context as well as technologies and methodologies that may be applied to improve physical protection capabilities. It also refers to relevant guidance from the International Atomic Energy Agency (IAEA) and the U.S. Nuclear Regulatory Commission (NRC).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Reliable Protection for an Inverter-Based Resources Dominant Grid: Technology Development and Field Demonstration

The project aimed to address the challenges posed by the rapid growth of inverter-based resources (IBR) such as solar, wind, and battery storage, which have fundamentally changed fault behavior, system strength, and protection performance in bulk power systems. Traditional protection schemes, designed for synchronous generator-dominated grids, are inadequate under high IBR penetration. Overall, the project materially advances protection modeling and simulation capabilities needed to maintain reliable grid protection under high IBR penetration. The results build utility confidence in operating power systems safely and reliably across a wide range of generation mixes, supporting grid modernization goals.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Studying the Impact of Momentary Cessation of IBRs Compliant With IEEE Std. 2800-2022 on Transmission Line Protection Elements

This paper examines the impact of inverter-based resource (IBR) momentary cessation timing on transmission system protection relays. IEEE Std. 2800 mandates voltage ride-through, requiring IBRs to remain online during voltage disturbances. However, for severe voltage dips (|V| = 0.1 p.u.), the standard permits current blocking. In practice, vendors implement momentary cessation with varying delays, potentially affecting relay operation if IBRs cease too early. This article studies the impact of the time IBRs enter momentary cessation on transmission line protective relays. Using an electromagnetic transient (EMT) simulation, this study models IBR momentary cessation with tunable delays in a realistic transmission network. COMTRADE files generated from EMT simulations are analyzed in MATLAB using detailed protective relay models. Results indicate that IBRs must sustain operation for at least one cycle to ensure proper relay response; otherwise, relays may fail to oper- ate. These findings guide IBR vendors in optimizing momentary cessation settings to enhance transmission line protection.

24 POWER TRANSMISSION AND DISTRIBUTION↗

1.4.1.401 - Fish Protection Prize

The Fish Protection Prize sought new solutions, designs, and strategies to prevent fish from swimming into water infrastructure, such as water diversions and pipes and intakes at hydropower dams. Participants submitted innovative ideas to advance fish exclusion technology. WPTO collaborated with the U.S. Bureau of Reclamation on the Fish Protection Prize to inspire innovators to compete for $700,000 of combined cash prizes and voucher support to help protect fish from these threats. Five experts in fish passage and protection served as reviewers in the Pitch Contest, and represented a number of Federal and State agencies, including NOAA, USGS, ORNL, Washington Department of Fish and Wildlife, and AFS. Three finalists were selected as Grand Prize winners.

fish passage↗

Thermal protection barrier

A thermal protection barrier including a base layer having a high melting temperature granular media having free standing granules disposed within the base layer and a distributor grid layer having a plurality of spaced-apart distributors composed of a high melting temperature material disposed adjacent to the base layer. The spaced-apart distributors are dimensioned and configured to provide load bearing support to the thermal protection barrier prior to a breach of the thermal protection barrier and to divide and disperse a superheated flowing mass to the free standing granules of the base layer upon occurrence of a breach. In certain embodiments, the thermal protection barrier is positioned adjacent to a nuclear system such that, upon occurrence of a loss of containment accident, the distributor grid layer is positioned and configured to divide and disperse a superheated flowing nuclear mass to the free standing granules.

61 RADIATION PROTECTION AND DOSIMETRY↗

Attack-resilient algorithms and testbed federation for wide-area protection and control in smart grid

Today’s energy infrastructure is undergoing a massive transformation across all generation, transmission, and distribution systems to provide reliability, efficiency, and sustainability to the power system network. During the past 10 years, there has been a remarkable enhancement in developing close-loop wide-area protection and control (WAPAC) applications, such as automatic generation control (AGC), wide-area protection scheme (WAPS), synchrophasor-based wide-area voltage control system (WAVCS), etc., in the energy management system (EMS) to provide an adequate situational awareness to control center operators during physical disturbances and natural events. The rapid digitalization, unencrypted communication, and numerous data-sharing devices have increased digital access points that have exposed the grid network to countless cyberattacks pertinent to the WAPAC cybersecurity. Given the amount of complex grid network coupled with legacy infrastructures, it is untrustworthy to completely rely on information technology (IT)-based conventional security measures to defend against evolving cyberattacks. Hence, there is a compelling need to go beyond the traditional paradigm of ‘security by obscurity’ and ‘bolt-on’ security measures, and develop a suite of innovative security solutions at multiple layers to transform the current “fault-resilient” grid into “fault and attack-resilient” grid of the future. This dissertation specifically focuses on developing application-specific attack-resilient solutions for critical WAPAC applications in the smart grid. The first part of the study, Attack-Resilient Wide-Area Protection Scheme, presents a cyber-physical attack-resilient system (CPARS) for WAPS, where two anomaly detection methods are proposed to detect multi-level cyberattacks followed by the rules-based intrusion mitigation system (RIMS) to initiate effective mitigation strategies, tailored to these attacks, to restore the normal grid operation after disturbances. The first anomaly detection component, Machine learning-based Anomaly Detection for Centralized WAPS, discusses a novel architecture and methodology for developing a machine-learning-based anomaly detection system (ADS) for the centralized wide-area protection system (CWAPS) by applying the variational mode decomposition (VMD) technique and decision tree (DT) algorithms using cyber logs and synchrophasor measurements. The second component, Multi-Agent-based Anomaly Detection for Decentralized WAPS, presents a two-level hierarchical multi-agent-based decentralized WAPS against the system-aware stealthy cyber-attacks. Finally, for the RIMS, the state transition diagram-based mitigation measures are defined based on the grid operation states and experimental testing and evaluation are presented in a cyber-physical testbed environment. The second part of the study, Attack-Resilient Wide-Area Voltage Control System, addresses the existing vulnerabilities in the wide-area voltage control system (WAVCS), presents the methodology for performing an impact analysis during data integrity attacks, and proposes a data-driven attackresilient system (DARS) by incorporating machine learning-based ADS and rules-based anomaly mitigation system (RAMS) to detect these attacks and provide necessary mitigation actions to maintain the transient voltage stability after disturbances. Finally, the third part, Networked Federation Testbed (NEFTSec) for Smart Grid Cybersecurity, focuses on developing an interconnected federated testbed through a common network like the internet, describes its conceptual architectures, and also presents its design components for experimental testing, validation, and evaluation. Further, it presents the co-simulation interface algorithm (CIA) to facilitate the geographically-dispersed real-time distributed simulation (GD-RTDS) during the cyber-physical federation. In general, this dissertation presents innovative attack-resilient solutions for WAPAC applications that are experimentally tested and evaluated using the PowerCyber testbed and NEFTSec platform to accelerate the transition of state-of-the-art research works to the real-field deployments.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Decentralized Microgrid Protection Through Relative Fault Direction Classification: Preprint

Protection in inverter-based resources (IBRs) dominated microgrids generally face significant challenges due to the low fault current and inconsistent fault behaviors from IBRs. Recently, machine learning-based approaches have attracted considerable attention to address these challenges. This paper introduces a novel decentralized protection strategy for microgrids. The proposed method decomposes the protection challenge into several distributed learning tasks, enabling individual relays to autonomously determine the direction of faults using a binary classification framework based on support vector machine (SVM) algorithms. Following the distributed fault direction estimation, classifier outcomes are shared among neighboring relays, facilitating a local decision-making process to ascertain the presence of faults within the neighborhood. Finally, a tripping signal is generated based on the classifier results of each relay to operate the circuit breaker. To test and validate this approach, a 100% renewable microgrid model is simulated in MATLAB/Simulink. In the numerical analysis, the application of SVM classifiers in our approach yields impressive results: an average relay classification accuracy of 98%, and a 96% accuracy in circuit breaker control. These findings highlight the potential of machine-learning-based approaches in enhancing the efficiency and reliability of microgrid protection systems.

decentralized algorithm↗

Protection System Validation with Machine Learning Anomaly Classification

A poster for the Early Career Poster Session. Power system protection devices have transitioned over the past few decades from mechanical to analog devices, then to solid state and finally digital. Relays and their associated critical network of equipment have significantly increased in complexity. Even internally, relays have gained significant intricacy, with relatively simple overcurrent or differential functions now being assisted by a myriad of other functions. This is necessary as the grid becomes more complex, but it brings increased difficulty in monitoring and upkeep. Misoperation caused by improper relay settings or malicious actions is a constant challenge faced by all utilities. These improper settings can be difficult to identify and may require exhaustive post-mortem analysis, typically after a major outage event has already occurred. A mechanism is needed for monitoring the behavior of protection systems to validate that they act and perform as expected. This work presents a concept for a machine learning (ML) system capable of validating the performance of protection systems by classifying anomalous events and characterizing protection system responses based solely on available current and voltage measurements. As a first step in its development, an experimental dataset is generated, and a random forest model is implemented with high accuracy in distinguishing four power system scenarios.

24 - POWER TRANSMISSION AND DISTRIBUTION↗

Thiolate‐Protected Single‐Atom Alloy Nanoclusters: Correlation between Electronic Properties and Catalytic Activities

Abstract Due to their interesting chemical and optical properties, metal nanoclusters are used in various catalytic reactions and in energy conversion. By incorporating thiolate‐protecting ligands, their size and composition can be tuned. Doping these nanoclusters to form single‐atom alloy (SAA) nanoclusters is shown to further enhance these properties as a result from the synergy between the dopant and host atoms. In addition to their optical and chemical properties, SAA nanoclusters also have interesting electronic properties. However, these properties are often underdiscussed when studying SAA nanoclusters. This review provides an overview of representative studies done on the in‐depth understanding of the electronic properties and catalytic activities of Ag‐based and Au‐based thiolate‐protected SAA nanoclusters. The use of density functional theory (DFT), X‐ray absorption spectroscopy, and X‐ray photoelectron spectroscopy are employed to correlate the changes in charge states of thiolate‐protected SAA nanoclusters with their superior catalytic activity versus monometallic nanoclusters. DFT, UV–vis spectroscopy, and voltammetric methods link the changes in molecular energy levels of thiolate‐protected SAA nanoclusters to their enhanced catalytic performance over monometallic nanoclusters.

Walsh, Andrew G.↗

Deprotection of N ‐ tert ‐Butoxycarbonyl (Boc) Protected Functionalized Heteroarenes via Addition–Elimination with 3‐Methoxypropylamine

Continued pursuit of functionalized soft‐N‐donor complexant scaffolds with favorable solubility and kinetics profiles applicable for the separation of the trivalent minor actinides from the lanthanides has attracted significant interest over the last three decades. Recent work from this laboratory resulted in the production of various N ‐Boc protected [1,2,4]triazinyl‐pyridin‐2‐yl indole Lewis basic procomplexants which necessitated the removal of the indole N ‐Boc protecting group prior to evaluation of complexant efficacy in separations assays. Traditional deprotection strategies involving trifluoroacetic and other protic and Lewis acids proved unsuccessful in removal of the recalcitrant indole‐ N ‐Boc protecting group necessitating the development of a new strategy for deprotection of this complexant class. A serendipitous result facilitated utilization of 3‐methoxypropylamine as a mild deprotecting agent for various N ‐Boc protected heteroarenes via a proposed addition–elimination mechanism. Method development, application to various heteroarenes including indoles, 1,2‐indazoles, 1,2‐pyrazoles, and related derivatives, a ten‐fold scale‐up reaction, and experimental evaluation of a preliminary mechanistic hypothesis are reported herein.

Gulledge, Zachary Z.↗

Electron Microscopy Transfer System to Protect Atmosphere‐Sensitive Materials for Scanning Electron Microscopy Characterization

Atmosphere- and/or moisture-sensitive materials can be challenging to characterize using electron microscopy techniques due to sample preparation workflows that generally require exposure to ambient conditions. Here, we describe a novel preparation method that uses aluminum foil in combination with a commercial cryo-EM transfer system to circumvent undesired exposure to the atmosphere. First, hygroscopic MgCl 2 was used as a model material, and prepared samples (both protected and unprotected) were placed in a controlled-humidity environment (> 80% relative humidity) for various exposure lengths (circa seconds to hours). Following this, the effectiveness of the sample preparation method was determined by comparing qualitative photos and quantitative X-ray diffraction patterns between the two sample subsets. The combined results of these experiments suggest that the outlined preparation method effectively protects MgCl 2 from atmospheric contamination compared to MgCl 2 samples that had no protective measures taken. Finally, the preparation method was utilized to protect a highly hygroscopic crystalline BaO thin film for characterization via scanning electron microscopy, thereby demonstrating a functional application of the outlined preparation technique and an additional use for the commercial cryo-EM transfer system beyond its intended application.

atmosphere-sensitive materials↗

Food web dynamics drive variation in Smallmouth Bass Micropterus dolomieu mercury contamination in protected Southern Appalachian streams

Mercury is a global pollutant that threatens otherwise protected aquatic ecosystems. Mercury food web dynamics are not well understood in streams with no point sources of contamination but have the potential to concentrate this dangerous pollutant in upper trophic level consumers. A 2016 study revealed that mercury concentrations of Smallmouth Bass Micropterus dolomieu varied between three streams in Great Smoky Mountains National Park (GSMNP), Tennessee, USA. We tested the hypothesis that food web interactions drive spatial variation in mercury concentrations of the apex predator of protected stream ecosystems. We measured carbon and nitrogen stable isotope ratios, and mercury concentrations of eight food web components of GSMNP streams including basal resources, intermediate consumers, and Smallmouth Bass, the apex predator. Mean THg concentrations of basal resources did not differ between streams, but the spatial pattern of concentrations of intermediate consumers mirrored Smallmouth Bass. Relationships between organismal contaminant concentrations and trophic level were positive in all three streams, indicating biomagnification is occurring in the protected streams of GSMNP. Furthermore, our findings indicate that mercury dynamics in intermediate trophic levels, rather than differences in basal resource concentrations, may drive differences in mercury contamination of apex predators of the protected stream ecosystems of GSMNP.

Bioaccumulation↗

Native bee Pollination Ecosystem Services in Agricultural Wetlands and Riparian Protected Lands

Abstract Many freshwater wetlands and riparian systems are protected within agricultural landscapes. Yet, pollinator ecosystem services are seldom considered key ecosystem services provided by these conservation easements. The purpose of this study is to explore the extent of protected aquatic lands to provide pollination ecosystem services by assessing pollinator abundances, crop yield changes, and value estimations of increased soybean yields from a subset of common native solitary bees. We created a novel geodatabase of United States Department of Agriculture (USDA) conservation easements and used this database in the InVEST crop pollination model to model wild solitary bee pollination. We then estimated the monetary value of yield increases provided by pollinators. We found that wetland uplands provided the greatest potential for pollination services for ground nesting bees, followed by herbaceous and forested riparian respectively. Stem nesters preferred forested riparian, then upland habitats. In soybeans fields, we found wild pollinators can provide up to 5.5% yield response from current private aquatic conservation lands. The current landscape is not optimized to use wetlands and riparian conservation lands as pollinator habitat, but these results suggest protected aquatic lands can sustainably increase wild pollination services to agricultural crops if landscapes are managed, protected, and optimized with pollinator services as co-benefit.

Hinson, Audra L. (ORCID:0000000242314820)↗

On the mechanical behavior of a Nb 3 Sn superconducting coil during a quench: Two-dimensional finite element analysis of a quench heater protected magnet

New high-field accelerator magnets based on $Nb_3Sn$ superconductors are pushing the boundaries of magnet design and quench protection towards new limits. While their large stored energies and current densities result in a very challenging scenario for magnet protection, their great electromagnetic forces create also new requirements in terms of magnet design and stress management techniques. Furthermore, the strain sensitivity of $Nb_3Sn$ cables turns the electro-mechanical limits of the conductor into a parameter of the highest importance, where conductor degradation becomes a critical aspect in magnet operation. The coupling of all the above-mentioned considerations during quench is a case of special interest that adds further complexity to the design of $Nb_3Sn$ magnets. The objective of this paper is to provide a complete two-dimensional investigation of the coil and magnet structure mechanics during a quench event. Here, the analysis is performed using a combination of finite element codes that provide the necessary input for the mechanical study. The core of the modelling strategy relies on a thermal-electric model, whose results are directly used as loads in the mechanical simulation. In doing so, the stress evolution during and after a quench is obtained. We focus for this time in the analysis of a quench heater protected magnet, where dynamic effects are of less importance in contrast to other protection systems like CLIQ.

43 PARTICLE ACCELERATORS↗

PPARα agonist exerts protective effects in podocyte injury via inhibition of the ANGPTL3 pathway

Peroxisome proliferator-activated receptor α (PPARα) activation has been reported to exert protective effects on podocytes, whereas angiopoietin-like 3 (ANGPTL3) has been shown to exert significant pathogenic effects on these cells. This study aimed to investigate the link between the protective effects of PPARα activation and the pathogenic effects of ANGPTL3 in podocytes. Both PPARα and ANGPTL3 were expressed in cultured podocytes. PPARα mRNA and protein levels decreased whereas ANGPTL3 mRNA and protein levels increased in a time-dependent manner in podocytes treated with puromycin aminonucleoside (PAN). Gemfibrozil, a pharmacological agonist of PPARα, increased PPARα levels and activity in podocytes. The drug also decreased ANGPTL3 levels by potentially weakening ANGPTL3 promoter activity in both normal and PAN-treated podocytes. Furthermore, gemfibrozil significantly decreased PAN-induced apoptosis and F-actin rearrangement. Primary podocytes from Angptl3-knockout mice were cultured. There was no significant difference between Angptl3{sup −/−} podocytes treated with or without gemfibrozil in the lamellipodia numbers after PAN treatment. The results suggested that the protective effects of gemfibrozil on podocytes were not exerted following knockout of the Angptl3 gene. This study identified a novel mechanism of the PPARα agonist gemfibrozil that exerts its protective effects by inhibiting PAN-induced apoptosis and cytoskeleton rearrangements through inhibition of ANGPTL3 expression.

60 APPLIED LIFE SCIENCES↗

Protection against Chemical Warfare Agents and Biological Threats Using Metal–Organic Frameworks as Active Layers

The SARS-CoV-2 pandemic outbreak and the unfortunate misuse of toxic chemical warfare agents (CWAs) highlight the importance of developing functional materials to protect against these chemical and pathogen threats. Metal–organic frameworks (MOFs), which comprise a tunable class of crystalline porous materials built from inorganic nodes and organic linkers, have emerged as a class of heterogeneous catalysts capable of rapid detoxification of multiple classes of these harmful chemical or biological hazards. In particular, zirconium-based MOFs (Zr-MOFs) feature Lewis acidic nodes that serve as active sites for a wide range of catalytic reactions, including the hydrolysis of organophosphorus nerve agents within seconds in basic aqueous solutions. In addition, postsynthetic modification of Zr-MOFs enables the release of active species capable of reacting with and deactivating harmful pathogens. Despite this impressive performance, utilizing Zr- MOFs in powder form is not practical for application in masks or protective uniforms. To address this challenge, our team sought to develop MOF/fiber composite systems that could be adapted for use under realistic operating conditions to protect civilians, military personnel, and first responders from harmful pathogens and chemical warfare agents. Over the last several years, our group has designed and fabricated reactive and biocidal MOF/fiber composites that effectively capture and deactivate these toxic species. In this Account, we describe the evolution of these porous and reactive MOF/fiber composites and focus on key design challenges and considerations. First, we devised a scalable method for the integration of Zr-MOFs onto textile substrates using aqueous precursor solutions and without using pretreated textiles, highlighting the potential scalability of this method. Moving beyond standard textiles, we also developed a microbial synthesis strategy to prepare hierarchically porous MOF/bacterial cellulose nanofiber composite sponges that can both capture and detoxify nerve agents when exposed to contaminated gas flows. The mass loading of the MOF in the nanofibrous composite sponge is up to 90%, affording higher work capacities compared to those of textile-fiber-based composites with relatively lower MOF loadings. Next, we demonstrated that heterogeneous polymeric bases are suitable replacements for volatile liquid bases typically used in solution-phase reactions, and we showed that these composite systems are capable of effectively hydrolyzing nerve agents in the solid state by using only water that is present as humidity. Moreover, incorporating a reactive dye precursor into the composite affords a dual function sensing and detoxifying material that changes color from white to orange upon reaction with the byproduct following nerve agent hydrolysis, demonstrating the versatility of this platform for use in decontamination applications. We then created chlorine-loaded MOF/fiber composites that act as biocidal and reactive textiles that are capable of not only detoxifying sulfur-mustard-based chemical warfare agents and simulants but also deactivating both bacteria and the SARS-CoV-2 virus within minutes of exposure. Lastly, we synthesized a mixed-metal Ti/Zr-MOF coating on cotton fibers to afford a photoactive biocidal cloth that shows fast and broad-spectrum biocidal performance against viruses and Gram-positive and Gram-negative bacteria under visible light irradiation. Given the tunable, multifunctional nature of these MOF/fiber composites, we believe that this Account will offer new insights for the rational design and preparation of functional MOF/fiber composites and pave the way toward the development of next-generation reactive and protective textiles.

36 MATERIALS SCIENCE↗

Molecular insights into antibody-mediated protection against the prototypic simian immunodeficiency virus

SIVmac239 infection of macaques is a favored model of human HIV infection. However, the SIVmac239 envelope (Env) trimer structure, glycan occupancy, and the targets and ability of neutralizing antibodies (nAbs) to protect against SIVmac239 remain unknown. Here, we report the isolation of SIVmac239 nAbs that recognize a glycan hole and the V1/V4 loop. A high-resolution structure of a SIVmac239 Env trimer-nAb complex shows many similarities to HIV and SIVcpz Envs, but with distinct V4 features and an extended V1 loop. Moreover, SIVmac239 Env has a higher glycan shield density than HIV Env that may contribute to poor or delayed nAb responses in SIVmac239-infected macaques. Passive transfer of a nAb protects macaques from repeated intravenous SIVmac239 challenge at serum titers comparable to those described for protection of humans against HIV infection. Our results provide structural insights for vaccine design and shed light on antibody-mediated protection in the SIV model.

60 APPLIED LIFE SCIENCES↗