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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

High pressure polymorphs and amorphization of upconversion host material NaY(WO 4 ) 2

The pressure effect on the structural change of upconversion host material NaY(WO 4 ) 2 was studied in this paper by using in-situ synchrotron X-ray diffraction. A transition from the initial scheelite phase to the M-fergusonite phase occurs near 10 GPa, and another phase transition is found near 27.5 GPa, which could be an isostructural transition without symmetry change. The sample becomes amorphous when the pressure is fully released from high pressure. Finally, this work demonstrates the possibility of synthesizing various polymorph structures for non-linear optical applications with a high pressure, chemical doping, or strained thin-film nanostructure process.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Structural transitions in Pb(In 1/2 Nb 1/2 )O 3 under pressure

Here, Raman scattering, x-ray diffraction, and first-principles calculations were employed to investigate the behavior of disordered Pb(In 1/2 Nb 1/2 )O 3 (PIN) under pressure up to 50 GPa. The experiments were performed at room temperature while ab-initio calculations were carried out at 0 K. Raman spectra for disordered PIN show broad bands but a peak near the 380 cm -1 increases its intensity with pressure. The linewidth of the band at 550 cm -1 also increases with pressure, while two of the Raman peaks merge above 6 GPa. Above 16 GPa, we observe additional splitting of the band at 50 cm -1 . The pressure evolution of the diffraction patterns for PIN shows obvious splitting for Bragg peaks above 16 GPa; the results indicate a possible lowering symmetry transition. We identified that the transition at 0.5 GPa is from pseudo-cubic to orthorhombic (Pbam), the transitions at 16 GPa are isostructure transitions due to changes in linear compressibility and octahedral titling, and the transition at 30 GPa is from orthorhombic to monoclinic. First-principles calculations results indicated that ground state is Pbam with antiferrodisdortion consistent with experiment.

36 MATERIALS SCIENCE↗
NASA NTRS1997

Interaction of central venous pressure, intramuscular pressure, and carotid baroreflex function

Seven healthy volunteer men participated in an experiment involving lower body positive pressure (LBPP) of 30 Torr and acute volume expansions of 5-6% (VE-I) and 9-10% (VE-II) of their total blood volume (TBV) to differentiate the effect of increased intramuscular pressure and central venous pressure (CVP) on the maximal gain (Gmax) of the carotid baroreflex. During each experimental condition, the heart rate (HR), mean arterial pressure (MAP; intraradial artery or Finapres), and CVP (at the 3rd-4th intercostal space) were monitored continuously. Gmax was derived from the logistic modeling of the HR and MAP responses to ramped changes in carotid sinus transmural pressure using a protocol of pulsatile changes in neck chamber pressure from +40 to -65 Torr. The increase in CVP during +30-Torr LBPP was 1.5 mmHg (P < 0.05) and was similar to that observed during VE-I (1.7 mmHg, P > 0.05). The Gmax of the carotid baroreflex of HR and MAP was significantly decreased during LBPP by -0.145 +/- 0.039 beats x min(-1) x mmHg(-1) (38%) and -0.071 +/- 0.013 mmHg/mmHg (25%), respectively; however, VE-I did not affect Gmax. During VE-II, CVP was significantly greater than that elicited by LBPP, and the Gmax of the carotid baroreflex of the HR and MAP responses was significantly reduced. We conclude that carotid baroreflex responsiveness was selectively inhibited by increasing intramuscular pressure, possibly resulting in an activation of the intramuscular mechanoreceptors during LBPP. Furthermore, it would appear that the inhibition of the carotid baroreflex, via cardiopulmonary baroreceptor loading (increased CVP), occurred when a threshold pressure (CVP) was achieved.

NASA Discipline Cardiopulmonary↗
DOE OSTI2014

Pressurized subsampling system for pressured gas-hydrate-bearing sediment: Microscale imaging using X-ray computed tomography

A pressurized subsampling system was developed for pressured gas hydrate (GH)-bearing sediments, which have been stored under pressure. The system subsamples small amounts of GH sediments from cores (approximately 50 mm in diameter and 300 mm in height) without pressure release to atmospheric conditions. The maximum size of the subsamples is 12.5 mm in diameter and 20 mm in height. Moreover, our system transfers the subsample into a pressure vessel, and seals the pressure vessel by screwing in a plug under hydraulic pressure conditions. In this study, we demonstrated pressurized subsampling from artificial xenon-hydrate sediments and nondestructive microscale imaging of the subsample, using a microfocus X-ray computed tomography (CT) system. In addition, we estimated porosity and hydrate saturation from two-dimensional X-ray CT images of the subsamples.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Developments in time-resolved high pressure x-ray diffraction using rapid compression and decompression

Complementary advances in high pressure research apparatus and techniques make it possible to carry out time-resolved high pressure research using what would customarily be considered static high pressure apparatus. This work specifically explores time-resolved high pressure x-ray diffraction with rapid compression and/or decompression of a sample in a diamond anvil cell. Key aspects of the synchrotron beamline and ancillary equipment are presented here, including source considerations, rapid (de)compression apparatus, high frequency imaging detectors, and software suitable for processing large volumes of data. A number of examples are presented, including fast equation of state measurements, compression rate dependent synthesis of metastable states in silicon and germanium, and ultrahigh compression rates using a piezoelectric driven diamond anvil cell.

47 OTHER INSTRUMENTATION↗
DOE OSTI2016

High-pressure high-temperature phase diagram of gadolinium studied using a boron-doped heater anvil

A boron-doped designer heater anvil is used in conjunction with powder x-ray diffraction to collect structural information on a sample of quasi-hydrostatically loaded gadolinium metal up to pressures above 8 GPa and 600 K. The heater anvil consists of a natural diamond anvil that has been surface modified with a homoepitaxially grown chemical-vapor-deposited layer of conducting boron-doped diamond, and is used as a DC heating element. Internally insulating both diamond anvils with sapphire support seats allows for heating and cooling of the high-pressure area on the order of a few tens of seconds. This device is then used to scan the phase diagram of the sample by oscillating the temperature while continuously increasing the externally applied pressure and collecting in situ time-resolved powder diffraction images. In the pressure-temperature range covered in this experiment, the gadolinium sample is observed in its hcp, αSm, and dhcp phases. Under this temperature cycling, the hcp → αSm transition proceeds in discontinuous steps at points along the expected phase boundary. From these measurements (representing only one hour of synchrotron x-ray collection time), a single-experiment equation of state and phase diagram of each phase of gadolinium is presented for the range of 0–10 GPa and 300–650 K.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Pressure-induced Td to 1T′ structural phase transition in WTe{sub 2}

WTe{sub 2} is provoking immense interest owing to its extraordinary properties, such as large positive magnetoresistance, pressure-driven superconductivity and possible type-II Weyl semimetal state. Here we report results of high-pressure synchrotron X-ray diffraction (XRD), Raman and electrical transport measurements on WTe{sub 2}. Both the XRD and Raman results reveal a structural transition upon compression, starting at 6.0 GPa and completing above 15.5 GPa. We have determined that the high-pressure lattice symmetry is monoclinic 1T′ with space group of P2{sub 1}/m. This transition is related to a lateral sliding of adjacent Te-W-Te layers and results in a collapse of the unit cell volume by ∼20.5%. The structural transition also casts a pressure range with the broadened superconducting transition, where the zero resistance disappears.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Pressure induced Ag{sub 2}Te polymorphs in conjunction with topological non trivial to metal transition

Silver telluride (Ag{sub 2}Te) is well known as superionic conductor and topological insulator with polymorphs. Pressure induced three phase transitions in Ag{sub 2}Te have been reported in previous. Here, we experimentally identified high pressure phase above 13 GPa of Ag{sub 2}Te by using high pressure synchrotron x ray diffraction method in combination with evolutionary crystal structure prediction, showing it crystallizes into a monoclinic structure of space group C2/m with lattice parameters a = 6.081Å, b = 5.744Å, c = 6.797 Å, β = 105.53°. The electronic properties measurements of Ag{sub 2}Te reveal that the topologically non-trivial semiconducting phase I and semimetallic phase II previously predicated by theory transformed into bulk metals for high pressure phases in consistent with the first principles calculations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Pressure-induced fcc to hcp phase transition in Ni-based high entropy solid solution alloys

A pressure-induced phase transition from the fcc to a hexagonal close-packed (hcp) structure was found in NiCoCrFe solid solution alloy starting at 13.5 GPa. The phase transition is very sluggish and the transition did not complete at ~40 GPa. The hcp structure is quenchable to ambient pressure. Only a very small amount (<5%) of hcp phase was found in the isostructural NiCoCr ternary alloy up to the pressure of 45 GPa and no obvious hcp phase was found in NiCoCrFePd system till to 74 GPa. Ab initio Gibbs free energy calculations indicated the energy differences between the fcc and the hcp phases for the three alloys are very small, but they are sensitive to temperature. The critical transition pressure in NiCoCrFe varies from ~1 GPa at room temperature to ~6 GPa at 500 K.

36 MATERIALS SCIENCE↗
DOE OSTI2020

High-Pressure Apparatus for Monitoring Solid–Liquid Phase Transitions

This work presents a new technique for observing the solid–liquid phase transformations in complex diesel fuel blends and diesel surrogates under high-pressure conditions intended to simulate those occurring in vehicle fuel injectors. A high-pressure apparatus based on a visual identification of freezing and thawing has been designed and built to monitor phase behavior and determine the crystallization temperature of complex fuels to predict wax precipitation. The proposed methodology was validated using pure substances—n-hexadecane (C16H34), cyclohexane (C6H12), and a binary cyclohexane/n-hexadecane mixture—all of which have been well-characterized previously. The crystallization temperatures of these compounds were measured from atmospheric pressure to 400 MPa for temperatures varying from 290 to 363 K and compared to those reported in the literature. The standard error of the estimated temperatures, based on a given pressure, between the experimental data obtained in this work was compared to data in the literature from Domanska et al. This methodology is being extended to investigate the properties of more complex fuel mixtures.

High-Pressure, phase change, diesel, solidificatio↗
DOE OSTI2026

Ambient-pressure 151-K superconductivity in HgBa 2 Ca 2 Cu 3 O 8+δ via pressure quench

Superconductivity has been a vigorously researched topic since its discovery in 1911. Raising the superconducting transition temperature (T c ) has been the main driving force behind such long-sustained efforts due to its potential for impacting humanity and the fundamental knowledge gained from understanding this macroscopic coherent quantum state at high temperatures. The successful development of high-T c superconductivity will make possible extraordinarily efficient generation, delivery, and utilization of energy and could also enable the development of controlled fusion while impacting other burgeoning fields like quantum computation and quantum electronics. However, progress has been hindered by a longstanding plateau in the record ambient-pressure T c , unchanged since 1993. Subsequent significant advancements in T c have been achieved only under high pressures, preventing the realization of superconductivity’s full potential. To directly address this challenge, we developed a pressure-quench protocol (PQP) to stabilize pressure-induced/-enhanced superconducting states at ambient pressure. Here, we achieve a record ambient-pressure T c of 151 K in the cuprate HgBa 2 Ca 2 Cu 3 O 8+δ via PQP. The experimental results are further supported by synchrotron X-ray diffraction measurements and phonon and electronic structure calculations. This breakthrough opens avenues for stabilizing and exploring ambient-pressure high-T c superconducting states and other quantum states that have been previously only accessible under pressure, paving the way for deeper understanding and practical applications of high-T c superconductivity and beyond.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

High-pressure polymorphism of Pb F 2 to 75 GPa

Lead fluoride, PbF 2 , was investigated experimentally in the laser-heated diamond anvil cell by x-ray diffraction to pressures of 75 GPa at room temperature and to 64.5 GPa and 2430 K, as well as through first-principles density functional theory calculations up to 70 GPa. During room temperature compression, no discontinuous changes in the x-ray diffraction pattern or volume were observed, but the lattice parameters displayed highly anomalous trends between 10-22 GPa with enhanced compressibility along the a direction and reduced or even negative compressibility along b and c. Theoretical calculations of valence electron densities at 22 GPa showed that α-PbF 2 underwent a pressure-induced isosymmetric phase transition to a postcotunnite Co 2 Si structure and also revealed the detailed atomic rearrangements associated with the development of an extra Pb-F bond in the high-pressure phase. Our x-ray results and theoretical calculations are consistent with an isosymmetric phase transition smoothly occurring over 10-22 GPa rather than abruptly as previously suggested. The characteristic values for the cell constants a/c and (a+c)/b, which are used to distinguish among cotunnite-, Co 2 Si-, and Ni 2 In-type phases, require modification based on our results. An equation of state fit yields a bulk modulus, K 0 , of 72(3) GPa for the cotunnite-type, and an ambient-pressure volume, V 0 , of 182(2)Å 3 , and K 0 =81(4)GPa for the Co 2 Si-type phase when fixing the pressure derivative of the bulk modulus, K 0 '=4. Upon heating above 1200 K at pressures at or above 25.9 GPa, PbF 2 partially transformed to the hexagonal Ni 2 In-type phase but wholly or partially reverted back to Co 2 Si-type phase upon temperature quench. From 43-65 GPa, nearly complete transformation to the Ni 2 In-type PbF 2 was observed at high temperature, but the material partially transformed back to the orthorhombic phase upon temperature quench. Our results show that high-pressure behavior of PbF 2 is distinct from that of the alkaline earth fluorides with similar ionic radii. These results also have relevance to understanding the behavior of lanthanide and actinide dioxides, which have been predicted theoretically to exhibit similar isosymmetric transitions at Mbar pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Pressure Dependence of Coherence-Incoherence Crossover Behavior in KFe 2 As 2 Observed by Resistivity and 75 As-NMR/NQR.

We present the results of 75 As nuclear magnetic resonance (NMR), nuclear quadrupole resonance (NQR), and resistivity measurements in KFe 2 As 2 under pressure (p). The temperature dependence of the NMR shift, nuclear spin-lattice relaxation time (T1), and resistivity show a crossover between a high-temperature incoherent, local-moment behavior and a low-temperature coherent behavior at a crossover temperature (T *). T * is found to increase monotonically with pressure, consistent with increasing hybridization between localized 3d orbitalderived bands with the itinerant electron bands. No anomaly in T * is seen at the critical pressure pc = 1.8 GPa where a change of slope of the superconducting (SC) transition temperature Tc(p) has been observed. In contrast, Tc(p) seems to correlate with antiferromagnetic spin fluctuations in the normal state as measured by the NQR 1/T1 data, although such a correlation cannot be seen in the replacement effects of A in the KFe 2 As 2 (A = K, Rb, Cs) family. In the superconducting state, two T1 components are observed at low temperatures, suggesting the existence of two distinct local electronic environments. The temperature dependence of the short T1s indicates a nearly gapless state below Tc. On the other hand, the temperature dependence of the long component 1/T1L implies a large reduction in the density of states at the Fermi level due to the SC gap formation. These results suggest a real-space modulation of the local SC gap structure in KFe 2 As 2 under pressure.

Wiecki, P.↗
NASA NTRSDate not supplied

Spectral Analysis of Integrated Pressures on Patches with Unsteady Pressure-Sensitive Paint Measurements

The technique of Pressure-Sensitive Paint (PSP) is commonly used in the aerospace industry to measure surface pressures on the model of launch vehicles and airplanes in the wind tunnel test. Recent research has demonstrated that Unsteady Pressure-Sensitive Paint (uPSP) can be an essential tool for the assessment of the unsteady, aerodynamic phenomena. The work described in this paper is a part of NASA’s development of a new state-of-the-art uPSP capability in production wind tunnels. This paper describes the spectral analysis of integrated pressures on patches of the scale model of the Space Launch System (SLS) Block 1 cargo vehicle with the uPSP measurements, which were collected in the Ascent Transient Aerodynamics Test (ATAT) with the Unitary Plan Wind Tunnel 11-by-11-foot Transonic Wind Tunnel in September 2019 at NASA Ames Research Center. The patches are defined with x station values, indicating the position along length of the SLS vehicle, and azimuth angles of the scale model. For each patch, the polygons are determined from the surface cells of the grid of the model, clipped with the edges of the patch, and each of the polygons is divided into triangles. The integrated pressure of the patch is determined as the ratio of the sum of the forces on the triangles over the sum of the areas of the triangles. For each run of the test, the Cross Power Spectral Density (CPSD) and magnitude squared coherence are computed from the time series of the integrated pressures on the patches. The pressure integration is coded in C++ and the spectral analysis is coded in MATLAB. The results were generated with the execution of the compiled C++ and MATLAB codes in parallel on the NASA Pleiades supercomputer. The results of pressure integration and spectral analysis are presented in this paper, and the data consistency of the test is also demonstrated. Funding for this research was provided by the NASA Aerosciences Evaluation and Test Capabilities Project.

Pressure-Sensitive Paint↗
NASA NTRSDate not supplied

Evaluating the Utility of Pressure Scanners for Unsteady Pressure Measurements in Wind Tunnel Characterization of the Space Launch System

In many aerodynamic measurement applications, the ability to make time-accurate measurements with pressure scanners provides practical advantages over making the same measurements directly using flush-mounted transducers. The pneumatic distortion due to the tubing between the sensing module and surface port limits the usefulness of such measurements to averaged, steady data only. This issue has restricted the application of pressure scanners for unsteady pressure measurements in wind tunnel and flight-testing applications. The Wiener-filtered inverse system response model has been proven to be effective in reconstructing complex unsteady pressure signals acquired remotely using pressure scanners. In this work, the feasibility of using pressure scanning systems for time-resolved pressure measurements in the NASA Langley 14- by 22-Foot Subsonic Wind Tunnel was evaluated. Results demonstrated good agreement between the reference transducers and reconstructed pressure scanner measurements up to frequencies of approximately 500 Hz.

Unsteady pressure↗
NASA NTRSDate not supplied

Characterization of Photodegredation in Unsteady Pressure-Sensitive Paint Under Varying Pressures

The lifetime and intensity techniques are two distinct methods used to measure the surface pressure of wind tunnel models with pressure-sensitive paint (PSP). When exposed to 405 nm light for extended periods, both the luminescence and the lifetime ratio were observed to decrease, affecting perceived pressure values. To help further the implementation of the unsteady pressure-sensitive paint (uPSP), this paper describes the efforts to characterize how photo degradation affects the intensity of the paint signal and its lifetime ratio, as well as the intensity calibration's response and how these changes vary with different pressure environments. It was found that the paint photo degrades at different rates depending on the partial pressure of oxygen during excitation. It was also found that the calibration curves exhibit greater changes when exposed to excitation light in higher pressure environments, both indicating photo degradation due to photo decomposition and photo-oxidation processes. These effects are observed on models in a subsonic 14” × 14” wind tunnel as well as a large-scale 11’ x 11’ transonic wind tunnel. The work provides analysis into the photo degradation behavior of PSP and uPSP, paving the way to reduce the error in pressure measurements obtained through these techniques.

Pressure-Sensitive Paint↗
NASA NTRSDate not supplied

Nodal Modeling of Helium Pressurization and Autogenous Pressurization and Draining using a Multi-Node-Ullage Approach

Pressurized expulsion tests of liquid methane were modeled by a nodal code using a multinode ullage approach. Generalized Fluid System Simulation Program (GFSSP), a finite volume based nodal code was used to model the expulsion of liquid methane from a 1.52-meter (5 ft) diameter spherical tank by pressurizing with helium and gaseous methane. The purpose of the model was to estimate the amount of pressurant required and amount of condensation and evaporation of methane during the operation. The ullage was discretized into multiple nodes and each fluid node was connected to solid nodes. Both the fluid and solid nodes grow as the tank drains. The heat and mass transfer between fluid and solid node in the tank ullage was computed. The heat and mass transfer between the bottom ullage node and the liquid methane was also computed. The model predictions were compared with data from twelve test cases. The predicted pressurant consumption for helium pressurization compares with test data with a Mean Absolute Percent Error (MAPE) of 3%. For autogenous pressurization, where gaseous methane was used to pressurize liquid methane, the predicted pressurant consumption compares with a MAPE of 6%.

Nodal Model↗