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At least 163 records · Page 9

On the Nature of the Enigmatic Object IRAS 19312+1950: A Rare Phase of Massive Star Formation?

IRAS19312+1950 is a peculiar object that has eluded firm characterization since its discovery, with combined maser properties similar to an evolved star and a young stellar object (YSO). To help determine its true nature, we obtained infrared spectra of IRAS19312+1950 in the range 5-550 microns using the Herschel and Spitzer space observatories. The Herschel PACS maps exhibit a compact, slightly asymmetric continuum source at 170 microns, indicative of a large, dusty circumstellar envelope. The far-IR CO emission line spectrum reveals two gas temperature components: approx. = 0.22 Stellar Mass of material at 280+/-18 K, and ≈1.6 Me of material at 157+/-3 K. The OI 63 micron line is detected on-source but no significant emission from atomic ions was found. The HIFI observations display shocked, high-velocity gas with outflow speeds up to 90 km/s along the line of sight. From Spitzer spectroscopy, we identify ice absorption bands due to H2O at 5.8 microns and CO2 at 15 microns. The spectral energy distribution is consistent with a massive, luminous (approx. 2 × 10(exp 4) Stellar Luminosity) central source surrounded by a dense, warm circumstellar disk and envelope of total mass approx. 500-700 Stellar Mass with large bipolar outflow cavities. The combination of distinctive far-IR spectral features suggest that IRAS19312+1950 should be classified as an accreting, high-mass YSO rather than an evolved star. In light of this reclassification, IRAS19312+1950 becomes only the fifth high-mass protostar known to exhibit SiO maser activity, and demonstrates that 18 cm OH maser line ratios may not be reliable observational discriminators between evolved stars and YSOs.

ISM: molecules aEuro" masers aEuro" stars↗

Potential Multi-Component Structure of the Debris Disk Around HIP 17439 Revealed by Herschel DUNES

Context. The dust observed in debris disks is produced through collisions of larger bodies left over from the planet/planetesimal formation process. Spatially resolving these disks permits to constrain their architecture and thus that of the underlying planetary/planetesimal system. Aims. Our Herschel open time key program DUNES aims at detecting and characterizing debris disks around nearby, sun-like stars. In addition to the statistical analysis of the data, the detailed study of single objects through spatially resolving the disk and detailed modeling of the data is a main goal of the project. Methods. We obtained the first observations spatially resolving the debris disk around the sun-like star HIP 17439 (HD 23484) using the instruments PACS and SPIRE on board the Herschel Space Observatory. Simultaneous multi-wavelength modeling of these data together with ancillary data from the literature is presented. Results. A standard single component disk model fails to reproduce the major axis radial profiles at 70 μm, 100 μm, and 160 μm simultaneously. Moreover, the best-fit parameters derived from such a model suggest a very broad disk extending from few au up to few hundreds of au from the star with a nearly constant surface density which seems physically unlikely. However, the constraints from both the data and our limited theoretical investigation are not strong enough to completely rule out this model. An alternative, more plausible, and better fitting model of the system consists of two rings of dust at approx. 30 au and 90 au, respectively, while the constraints on the parameters of this model are weak due to its complexity and intrinsic degeneracies. Conclusions. The disk is probably composed of at least two components with different spatial locations (but not necessarily detached), while a single, broad disk is possible, but less likely. The two spatially well-separated rings of dust in our best-fit model suggest the presence of at least one high mass planet or several low-mass planets clearing the region between the two rings from planetesimals and dust.

sun-like stars↗

Eta Carinae & the Homunculus: Far Infrared Sub-millimeter Spectral Lines detected with the Herschel Space Observatory

The evolved massive binary star η Carinae underwent eruptive mass loss events that formed the complex bi-polar “Homunculus” nebula harboring tens of solar masses of unusually nitrogen-rich gas and dust. Despite expectations for the presence of a significant molecular component to the gas, detections have been observationally challenged by limited access to the far-infrared and the intense thermal continuum. A spectral survey of the atomic and rotational molecular transitions was carried out with theHerschel Space Observatory, revealing a rich spectrum of broad emission lines originating in the ejecta. Velocity profiles of selected PACS lines correlate well with known substructures: Hi in the central core; NH and weak [Cii] within the Homunculus; and [Nii] emissions in fast-moving structures external to the Homunculus.We have identified transitions from [Oi], Hi, and 18 separate light C- and O-bearing molecules including CO, CH, CH+, and OH, and a wide set of N-bearing molecules,NH, NH+, N2H+, NH2, NH3, HCN, HNC, CN, and N2H+. Half of these are new detections unprecedented for any early-type massive star environment. A very low ratio[12C/13C]≤4 is estimated from five molecules and their isotopologues. We demonstrate that non-LTE effects due to the strong continuum are significant. Abundance patterns are consistent with line formation in regions of carbon and oxygen depletions with nitrogen enhancements, reflecting an evolved state of the erupting star with efficient transport of CNO-processed material to the outer layers. The results offer many opportunities for further observational and theoretical investigations of the molecular chemistry under extreme physical and chemical conditions around massive stars in their final stages of evolution.

T. R. Gull↗

Exposure of Plant Seeds to the Space Environment outside the International Space Station

If crop seeds are to be stored on space vehicles for long-duration missions, the effects of the space environment on the seeds must be understood for developing mitigation strategies to prevent seed degradation. The MISSE-Seed project was designed to investigate the effects of space exposure on seed quality and storage. The project also tested the Materials International Space Station Experiment (MISSE) platform for exposing biological samples to the space environment and evaluated the capability of a newly designed passive sample containment vessel for the provision of acceptable storage conditions for seeds, or other biological samples, to be preserved upon exposure to the space environment outside the ISS. The experiment was launched to the ISS on NG-15and returned to Earth aboard SpX-24. The specimens consisted of eleven seed varieties (Lettuce, Scarlet Frills, Amara, Garnet Giant, Pac Choi, Radish, Mizuna, Tomato, Cauliflower, Pepper, and Arabidopsis). The exposure lasted eight months outside the ISS in the MISSE hardware at the Zenith position. Data-loggers and thermoluminescent dosimeters (TLDs) were included in each container to record the environmental data. Temperature profiles and radiation/UV exposure data were also provided by Aegis Aerospace, the MISSE Implementation Partner. In this presentation, the hardware and experimental design, the environmental profiles, and the results of post-flight germination tests will be presented.

Jeffrey T Richards↗

Exposure of Plant Seeds to the Space Environment Outside the International Space Station

If crop seeds are to be stored on space vehicles for long-duration missions, the effects of the space environment on the seeds must be understood for developing mitigation strategies to prevent seed degradation. The MISSE-Seed project was designed to investigate the effects of space exposure on seed quality and storage. The project also tested the Materials International Space Station Experiment (MISSE) platform for exposing biological samples to the space environment and evaluated the capability of a newly designed passive sample containment vessel for the provision of acceptable storage conditions for seeds, or other biological samples, to be preserved upon exposure to the space environment outside the ISS. The experiment was launched to the ISS on NG-15and returned to Earth aboard SpX-24. The specimens consisted of eleven seed varieties (Lettuce, Scarlet Frills, Amara, Garnet Giant, Pac Choi, Radish, Mizuna, Tomato, Cauliflower, Pepper, and Arabidopsis). The exposure lasted eight months outside the ISS in the MISSE hardware at the Zenith position. Data-loggers and thermoluminescent dosimeters (TLDs) were included in each container to record the environmental data. Temperature profiles and radiation/UV exposure data were also provided by Aegis Aerospace, the MISSE Implementation Partner. In this presentation, the hardware and experimental design, the environmental profiles, and the results of post-flight germination tests will be presented.

Jeffrey T Richards↗

Exposure of Plant Seeds to the Space Environment Outside the International Space Station

Crop seeds may prove to be a vital component of future long-term spaceflight missions, and the impacts of extended exposure on seed degradation is not well understood. The MISSE-Seed project was designed to investigate the effects of space exposure on seed quality and storage. The project also served as a test of biological materials aboard the Materials International Space Station Experiment (MISSE) platform, and evaluated the capability of a newly designed passive sample containment vessel for the provision of acceptable storage conditions for seed and other biological samples to be preserved upon exposure to the space environment outside the ISS. MISSE-Seed was launched to the ISS on NG-15 in July of 2021 and returned to Earth aboard SpX-24 after approximately 8 months of exposure to the space environment. The specimens consisted of eleven seed varieties (Lettuce, Scarlet Frills, Amara, Garnet Giant, Pac Choi, Radish, Mizuna, Tomato, Cauliflower, Pepper, and Arabidopsis). Data-loggers and thermoluminescent dosimeters (TLDs) were included in each container to record environmental data. Temperature profiles and radiation/UV exposure data were also provided by Aegis Aerospace, the MISSE Implementation Partner. Hardware and experimental design, environmental profiles, and post-flight germination and growth results will be presented.

Alexander D Meyers↗

Plasma-Coupled Flow Reactor Studies of Low-Temperature Plasma Assisted Kinetics of Methanol Blended with CO2

Ignition technologies based on low-temperature plasmas (LTP) have the potential to operate next generation engines at elevated pressures and increased dilution limits promoting higher efficiencies. From a practical standpoint, research on LTP igniters has shown to enhance combustion and ignition, improve flame stability, and extend the dilution limits of combustion. All of the aforementioned gains are complemented with higher ignition efficiencies. However, the biggest challenge with incorporating this technology into engines is the knowledge gap of how exactly plasma chemistry effects can enhance the basic combustion phenomena. This coupled with the lack of validated kinetic mechanisms for plasma-combustion chemistry is the biggest obstruction to recognize efficient ignition, especially for application relevant fuels and biofuels. In order to comprehensively evaluate the effects of LTP on an oxygenated fuel specific system, this present study examines the kinetics of methanol plasma-assisted pyrolysis and oxidation using a custom-built plasma flow reactor (PFR). Experimental regimes are also further extended to understand the effects of adding CO2 to the mixture and its consequence on reaction kinetics. The PFR is installed with a dielectric-barrier discharge (DBD) configuration to induce LTP into the fuel mixture. Non-equilibrium plasmas are generated by high-voltage pulses (nearing 20 KV) administered by a plasma pulser at high-pulse repetition rates (up to 10 kHz). In order to better understand and isolate plasma chemistry and its effect on neutral chemistry, the experiments were carried out by heavily diluting reactive mixtures in nitrogen at near isothermal conditions. This suppresses the effect of exothermic reactions on chemistry allowing stable intermediates and products to be detected and quantified using ex-situ GC/MS diagnostic methods. Experiments were carried out at 0.5 atm pressure and over a wide range of temperatures from 523 K to 1203 K. Experimental results depicted the enhancement in intermediates production as well as overall lower temperatures required for complete fuel consumption in the plasma specific cases as opposed to their pure thermal counterpart. Formation of oxygenated and nitrile compounds specific to plasma assisted pyrolysis cases illustrated the efficacy of LTP to introduce new reaction pathways accelerating fuel decomposition. Increase in reactivity at lower temperatures is sought to be an effect induced by plasma chemistry postulating the acceleration in intermediates production. The onset of thermal ignition in plasma assisted oxidation is seen 200 K earlier than thermal oxidation highlighting efficient fuel conversion to final byproducts. Enhanced collisional processes afforded by LTP is seen to perturb reaction pathways between oxygenated fuel radicals and N-atoms to alter overall chemical reactivity. New insights into kinetics are gained from this study highlighting governing plasma assisted combustion (PAC) pathways for oxygenated fuel reaction chemistry. The results from this study can be used to develop future mechanisms specific to plasma chemistry which can bridge the mechanistic knowledge gap for LTP ignition so that future engines can adopt LTPs in their design for efficient combustion.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Solvent–free Synthesis of Multi–Module Pore–Space–Partitioned Metal–Organic Frameworks for Gas Separation

Multi-module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property optimization. Few examples are known that use environmentally friendly and cost-effective solvent-free method to synthesize such materials. Here, we report the use of solvent-free method (also modulator-free) to synthesize a series of multi-module MOFs with high stability and separation property for C 2 H 2 /CO 2 . The synthesis only requires simple mixing of reactants and short reaction time (2 h). Highly porous and stable materials can be made without any post-synthetic activation. Here, the success of solvent-free synthesis of multi-module MOFs reflects the synergy between different modules, resulting in stable pore-partitioned materials, despite the fact that other competitive crystallization pathways with simpler framework compositions also exist.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Developing Water–Stable Pore–Partitioned Metal–Organic Frameworks with Multi–Level Symmetry for High–Performance Sorption Applications

Here a new perspective is proposed in the design of pore-space-partitioned MOFs that is focused on ligand symmetry properties sub-divided here into three hierarchical levels: 1) overall ligand, 2) ligand substructure such as backbone or core, and 3) the substituent groups. Different combinations of the above symmetry properties exist. Given the close correlation between nature of chemical moiety and its symmetry, such a unique perspective into ligand symmetry and sub-symmetry in MOF design translates into the influences on MOF properties. Five new MOFs have been prepared that exhibit excellent hydrothermal stability and high-performance adsorption properties with potential applications such as C 3 H 6 /C 2 H 4 and C 2 H 2 /CO 2 selective adsorption. The combination of high stability with high benzene/cyclohexane selectivity of ≈13.7 is also of particular interest.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Plasma-based global pathway analysis to understand the chemical kinetics of plasma-assisted combustion and fuel reforming

The Global Pathway Analysis (GPA) algorithm helps analyze the chemical kinetics of complex combustion systems by identifying important global reaction pathways connecting a source species to a sink species through various important intermediate species (i.e., hub species). Here, the present work aims to extend GPA algorithm to plasma-assisted combustion and fuel reforming systems to identify the dominant global pathways in such systems at various conditions. In addition, the present study extends the ability of GPA algorithm to identify reaction cycles involving the excitation of high-concentration species (e.g., O 2 , N 2 , and fuel) to their vibrational and electronic states and the subsequent de excitation to their ground state, based on their significance on the reactivity of plasma-assisted systems in terms of gas heating and radical production. Provisions are made in the GPA algorithm to evaluate the reactivity of identified re action pathways and cycles based on the element-flux transfer (i.e., dominance), heat release, and radical production rate. The newly developed Plasma-based Global Pathway Analysis (PGPA) algorithm is then used to analyze the plasma assisted combustion of ammonia and reforming of methane. The PGPA analyses elucidated the significance of vibrational-translational cycles on the reactivity of NH 3 /air mixtures. Further, analyses on the production of NO ascribed the early reforming of NH 3 to N 2 and H 2 in impeding the production of NO during plasma-assisted NH 3 ignition. Lastly, the enhanced reforming of CH 4 /N 2 mixtures using plasma has been attributed to electron impact dissociation of CH 4 when compared to thermal reforming. In contrast, conventional path-Flux analysis (PFA) was found to require significant manual effort and pre-analysis intuitions from expert knowledge, making it arduous to provide valuable in sights into plasma chemistry. The user-friendly and automated nature of PGPA thus provides a valuable tool for assessing the kinetics of plasma-assisted systems helpful in analyzing and, further, a foundation in reducing plasma-assisted chemistry, without the needs of expert knowledge.

33 ADVANCED PROPULSION SYSTEMS↗

The JSNS 2 detector

The JSNS 2 (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) experiment aims to search for oscillations involving a sterile neutrino in the eV 2 mass-splitting range. The experiment will search for the appearance of electron antineutrinos oscillated from muon antineutrinos. The electron antineutrinos are detected via the inverse beta decay process using a liquid scintillator detector. A 1 MW beam of 3 GeV protons incident on a spallation neutron target produces an intense and pulsed neutrino source from pion, muon, and kaon decay at rest. The JSNS detector is located 24 m away from the neutrino source and began operation from June 2020. The detector contains 17 tonnes of gadolinium (Gd) loaded liquid scintillator (LS) in an acrylic vessel, as a neutrino target. It is surrounded by 31 tonnes of unloaded LS in a stainless steel tank. Optical photons produced in LS are viewed by 120 R7081 Hamamatsu 10-inch Photomultiplier Tubes (PMTs). In this study, we describe the JSNS detector design, construction, and operation.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Evaluation of the performance of event reconstruction algorithms in the JSNS 2 experiment using a 252 Cf calibration source

JSNS 2 investigates short-baseline neutrino oscillations using a 24-meter baseline and a 17-tonne Gd-loaded liquid scintillator target. Accurate event-reconstruction algorithms are crucial for analyzing experimental data. The algorithms undergo meticulous validation through calibration with a 252 Cf source. This paper outlines the methodology and evaluates the reconstruction performance, focusing on neutrino interactions up to approximately 50 MeV for sterile neutrino searches. Both 252 Cf and Michel electron events are studied to evaluate reconstruction accuracy. The analysis concludes that the uncertainty of the fiducial volume, with an appropriate correction, is much less than the requirement of JSNS 2 requirement (10%). Furthermore, the energy resolution is measured to be 3.3 ± 0.1% for the Michel electron endpoint and 4.3 ± 0.1% for the n-Gd peak in the central region.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Performance of PMTs for the JSNS 2 experiment

The JSNS 2 (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) experiment aims to search for neutrino oscillations over a 24 m short baseline at J-PARC. The JSNS 2 inner detector is filled with 17 tons of gadolinium-loaded liquid scintillator (LS) and both the intermediate γ-catcher and the optically separated outer veto are filled with un-loaded LS. Optical photons from scintillation are observed by 120 Photomultiplier Tubes (PMTs). A total of 130 PMTs for the JSNS 2 experiment were both donated by other experiments and purchased from Hamamatsu. Donated PMTs were purchased around 10 years ago, therefore JSNS 2 did pre-calibration of the PMTs including the purchased PMTs. 123 PMTs demonstrated acceptable performance for the JSNS 2 experiment, and 120 PMTs were installed in the detector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The JSNS 2 data acquisition system

The JSNS 2 (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) experiment aims to search for neutrino oscillations over a 24 m short baseline at J-PARC. The JSNS 2 inner detector is filled with 17 tons of gadolinium(Gd)-loaded liquid scintillator (LS) with an additional 31 tons of unloaded LS in the intermediate γ-catcher and an optically separated outer veto volumes. A total of 120 10-inch photomultiplier tubes observe the scintillating optical photons and each analog waveform is stored with flash analog-to-digital converters. Here, we present details of the data acquisition, processing, and data quality monitoring system. We also present two different trigger logics which are developed for the beam and self-trigger.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The acrylic vessel for JSNS 2 -II neutrino target

The JSNS 2 (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) is an experiment designed for the search for sterile neutrinos. The experiment is currently at the stage of the second phase named JSNS 2 -II with two detectors at near and far locations from the neutrino source. One of the key components of the experiment is an acrylic vessel, that is used for the target volume for the detection of the anti-neutrinos. Here, the specifications, design, and measured properties of the acrylic vessel are described.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Muon tagging with flash ADC waveform baselines

Here, this manuscript describes an innovative method to tag muons using the baseline information of the Flash ADC (FADC) waveform of PMTs in the JSNS 2 (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) experiment. The experiment is designed to search for evidence of sterile neutrinos, and a reliable method for muon tagging is an essential component for background rejection because the detector is located above ground, on the 3rd floor of the J-PARC Material and Life Science Experimental Facility (MLF). Cosmogenic muons that stop within the detector volume and produce a Michel electron are a particularly important background that must be rejected for our sterile neutrino search. Utilizing this innovative method, more than 99.8 % of Michel electrons can be rejected even without using information from the detector’s veto region PMTs. This technique can be employed by any experiments which uses a similar detector configuration.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

PMT calibration for the JSNS^2-II far detector with an embedded LED system

The JSNS^2-II (the second phase of JSNS^2, J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) is an experiment aimed at searching for sterile neutrinos. Here, this experiment has entered its second phase, employing two liquid scintillator detectors located at near and far positions from the neutrino source. Recently, the far detector of the experiment has been completed and is currently in the calibration phase. The following properties of all functioning Photo-Multiplier-Tubes (PMTs) to detect the neutrino events in the far detector have been calibrated: PMT gain, its dependence of supplied High Voltage (HV), Peak-to-Valley (PV), and signal timing. This paper presents a detailed description of the calibration process utilizing the LED system. The LED system of the far detector uses two Ultra-Violet (UV) LEDs, which are effective in calibrating all of the PMTs at once. The UV light is converted into the visible light wavelengths inside liquid scintillator via the wavelength shifters, providing pseudo-isotropic light. To achieve a good energy resolution for physics events, a relative gain adjustment of up to 10% is required for all functioning PMTs. This will be achieved using the HV curves measured and the results of the LED calibration. The Peak-to-Valley (PV) ratio values, which distinguish the single photo-electron signal from the pedestal, are similar to those from the production company. Additionally, the precision of the PMT signal timing is measured to be 2.1 ns. This meets the event reconstruction requirement of 10 ns.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Slow control and monitoring system at the JSNS 2

The Sterile Neutrino Search at the J-PARC Spallation Neutron Source (JSNS$^2$) experiment aims to search for sterile neutrino oscillations using a neutrino beam from muon decays at rest. The JSNS$^2$ detector contains 17 tons of 0.1$\%$ gadolinium (Gd) loaded liquid scintillator (LS) as a neutrino target. Detector construction was completed in the spring of 2020. A slow control and monitoring system (SCMS) was implemented for reliable control and quick monitoring of the detector operational status and environmental conditions. It issues an alarm if any of the monitored parameters exceed a preset acceptable range. The SCMS monitors the high voltage of the photomultiplier tubes, the LS level in the detector, possible LS overflow and leakage, the temperature and air pressure in the detector, the humidity of the experimental hall, and the LS flow rate during filling and extraction. An initial 10 days of data-taking with a neutrino beam was done following a successful commissioning of the detector and SCMS in 2020 June. In this paper, we present a description of the assembly and installation of the SCMS and its performance.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗