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At least 163 records · Page 9

Oxidation states of copper in preservative treated wood as studied by X-ray absorption near edge spectroscopy (XANES)

Copper is a common component in wood preservatives and is used to protect the wood against fungal degradation. Previous research has shown that the Cu ++ oxidation state provides the best wood protection, and Cu ++ is widely believed to be the oxidation state of most copper within treated wood. A recent study using X-ray absorption near edge spectroscopy (XANES) reported high amounts of Cu + in wood that had been in contact with corroded fasteners. This study uses XANES to examine the copper oxidation states in wood treated with several different wood preservatives as a function of time after treatment. In contrast with previous literature which focused on the fixation reaction in the first few hours after treatment, this paper examines the oxidation state of Cu in treated wood at longer times (up to 1-year) after treatment. The results showed in nearly all cases, Cu was in the Cu ++ oxidation state to within the measurement uncertainty. Cu XANES patterns taken approximately 1-year after treatment showed no discernable differences between preservative systems, indicating that regardless of the starting treatment the final Cu speciation is the same within one year. The results confirm previously held beliefs about the Cu oxidation states in wood and give further insights into the corrosion mechanism of metals embedded in treated wood.

59 BASIC BIOLOGICAL SCIENCES↗

AmeriFlux FLUXNET-1F US-xDS NEON Disney Wilderness Preserve (DSNY)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-xDS NEON Disney Wilderness Preserve (DSNY). This is the FLUXNET version of the carbon flux data for the site US-xDS NEON Disney Wilderness Preserve (DSNY) produced by applying the standard ONEFlux (1F) software. Site Description - The 12,000-acre Disney Wilderness Preserve straddles the headwaters of the Everglades ecosystem in south-central Florida. This site is seasonally wet and flooded. The Disney site was heavily logged and used as ranchland for decades. However, vegetation and site conditions have been restored to closely represent site condition records, documented by the area’s first Spanish missionaries. The large-scale wetland and upland restoration at Disney included the removal of non-native, invasive plants and grasses and the removal of agricultural ditches. The primary management activity is controlled burns.

Network), NEON (National Ecological Observatory↗

Theory and measurements of emittance preservation in plasma wakefield acceleration

In this dissertation, we examine the preservation and measurement of emittance in the plasma wakefield acceleration blowout regime. Plasma wakefield acceleration (PWFA) is a revolutionary approach to accelerating charged particles that has been demonstrated to have the potential for gradients orders of magnitude greater than traditional approaches. The application of PWFA to the design of a linear collider will make new high energy physics research possible, but the design parameters must first be shown to be competitive with traditional methods. Emittance preservation is necessary in the design of a linear collider in order to maximize luminosity. We examine the conditions necessary for circular symmetry in the PWFA blowout regime, and demonstrate that current proposals meet these bounds. We also present an application of beam lamentation which describes the process of beam parameter and emittance matching. We show that the emittance growth saturates as a consequence of energy spread in the beam. The initial beam parameters determine the amount of emittance growth, while the contribution of energy spread is negligible. We also present a model for ion motion in the presence of a beam that is much more dense than the plasma. By combining the model of ion motion and emittance growth, we find the emittance growth due to ion motion is minimal in the case of marginal ion motion. In addition, we present a simulation that validates the ion motion model, which is under further development to examine emittance growth of both marginal and pronounced ion motion. Finally, we present a proof-of-concept of an emittance measurement which may enable the analysis of emittance preservation in future PWFA experiments.

43 PARTICLE ACCELERATORS↗

Bound-Preserving Discontinuous Galerkin Methods for Conservative Phase Space Advection in Curvilinear Coordinates

We extend the positivity-preserving method of Zhang & Shu [49] to simulate the advection of neutral particles in phase space using curvilinear coordinates. The ability to utilize these coordinates is important for non-equilibrium transport problems in general relativity and also in science and engineering applications with specific geometries. The method achieves high-order accuracy using Discontinuous Galerkin (DG) discretization of phase space and strong stabilitypreserving, Runge-Kutta (SSP-RK) time integration. Special care in taken to ensure that the method preserves strict bounds for the phase space distribution function f; i.e., f ϵ [0, 1]. The combination of suitable CFL conditions and the use of the high-order limiter proposed in [49] is su cient to ensure positivity of the distribution function. However, to ensure that the distribution function satisfies the upper bound, the discretization must, in addition, preserve the divergencefree property of the phase space ow. Proofs that highlight the necessary conditions are presented for general curvilinear coordinates, and the details of these conditions are worked out for some commonly used coordinate systems (i.e., spherical polar spatial coordinates in spherical symmetry and cylindrical spatial coordinates in axial symmetry, both with spherical momentum coordinates). Results from numerical experiments - including one example in spherical symmetry adopting the Schwarzschild metric - demonstrate that the method achieves high-order accuracy and that the distribution function satisfies the maximum principle.

97 MATHEMATICS AND COMPUTING↗

Historic Buildings Report: Five-Year Preservation Planning for Manhattan Project National Historical Park Sites

This report offers a preservation maintenance plan for the next five years for buildings and structures included in or eligible for inclusion in the Manhattan Project National Historical Park at Los Alamos National Laboratory. There are twenty-three buildings, structures, and ruins of previously standing buildings covered within this report. Many of the preservation maintenance issues addressed here concern problems with health and live safety of staff and visitors alike, and also structural concerns that affect the long-term preservation of these important buildings.

42 ENGINEERING↗

PHYSICAL-CONSTRAINT-PRESERVING CENTRAL DISCONTINUOUS GALERKIN METHODS FOR SPECIAL RELATIVISTIC HYDRODYNAMICS WITH A GENERAL EQUATION OF STATE

The ideal gas equation of state (EOS) with a constant adiabatic index is a poor approximation for most relativistic astrophysical flows, although it is commonly used in relativistic hydrodynamics (RHD). This paper develops high-order accurate, physical-constraints-preserving (PCP), central, discontinuous Galerkin (DG) methods for the one- and two-dimensional special RHD equations with a general EOS. It is built on our theoretical analysis of the admissible states for RHD and the PCP limiting procedure that enforce the admissibility of central DG solutions. The convexity, scaling invariance, orthogonal invariance, and Lax–Friedrichs splitting property of the admissible state set are first proved with the aid of its equivalent form. Then, the high-order central DG methods with the PCP limiting procedure and strong stability-preserving time discretization are proved, to preserve the positivity of the density, pressure, specific internal energy, and the bound of the fluid velocity, maintain high-order accuracy, and be L {sup 1}-stable. The accuracy, robustness, and effectiveness of the proposed methods are demonstrated by several 1D and 2D numerical examples involving large Lorentz factor, strong discontinuities, or low density/pressure, etc.

79 ASTRONOMY AND ASTROPHYSICS↗

Status Report of the DPHEP Collaboration: A Global Effort for Sustainable Data Preservation in High Energy Physics

Data from High Energy Physics (HEP) experiments are collected with significant financial and human effort and are mostly unique. An inter-experimental study group on HEP data preservation and long-term analysis was convened as a panel of the International Committee for Future Accelerators (ICFA). The group was formed by large collider-based experiments and investigated the technical and organizational aspects of HEP data preservation. An intermediate report was released in November 2009 addressing the general issues of data preservation in HEP and an extended blueprint paper was published in 2012. In July 2014 the DPHEP collaboration was formed as a result of the signature of the Collaboration Agreement by seven large funding agencies (others have since joined or are in the process of acquisition) and in June 2015 the first DPHEP Collaboration Workshop and Collaboration Board meeting took place. This status report of the DPHEP collaboration details the progress during the period from 2013 to 2015 inclusive.

Amerio, Silvia↗

Preservation of lunar core samples - Preparation and interpretation of three-dimensional stratigraphic sections

Preservation and analysis of core samples collected from the lunar regolith are discussed. The objectives of core sampling are described together with the core-sampling equipment used in the Apollo program. The effects of disaggregation in core samples are summarized, and ways to preserve the stratigraphy in these samples are reviewed, particularly partial impregnation of samples with polybutyl methacrylate. It is shown that stratigraphic sections preserved in this way reveal individual fragments of the regolith in their original positions, primary and secondary depositional structures related to lunar processes, and the nature and extent of deformations caused by sampling equipment. It is concluded that since the core sedimentary structures indicate complex three-dimensional variations in the regolith, quantitative models of regolith evolution must allow for distinctive local histories as well as irregular reworking and deposition events due to impact processes.

Fryxell, R.↗

Changes in vegetation spectra with deterioration of leaves under two methods of preservation

An experiment to measure changes in leaf spectra under different methods of preservation over time was conducted. The spectral measurements were made by a three band hand held radiometer which simulated three Thematic Mapper (TM) bands: TM3, TM4, and TM5. Daily spectral measurements of white oak leaves under three preservation treatments were made. The spectral readings over three treatments (fresh, bottled, and bagged vegetation) were indistinguishable in bands TM3 and TM5 for up to 4 days after collection. After that time bagged and bottled samples showed significant increases in reflected energy caused by loss of chlorophyll from and dehydration of the vegetation. No significant variation in the reflectance values from TM4 over preservation type for the experimental period was observed.

Labovitz, M. L.↗

Alternative Food Preservation Techniques, New Technology in Food Preparation and Appropriateness of Food Supply for the Permanently Manned Space Station

Alternative food preservation techniques are defined as unique processes and combinations of currently used processes for food preservation. Food preservation is the extension of the useful shelf-life of normally perishable foods (from harvest to final consumption) by controlling micro-organisms, enzymes, chemical changes, changes in sensory characteristics and the prevention of subsequent recontamination. The resulting products must comply with all applicable food manufacturing practice regulations and be safe. Most of the foods currently used in both space and military feeding are stabilized either by dehydration or the use of a terminal sterilization process. Other available options would be formulation to reduce water activity, the refrigeration and freezing of perishable foods, chemical addition, and physical treatment (ionizing or nonionizing radiation or mechanical action). These alternatives are considered and proposals made.

Richard H. Whelan↗

The energy decay in self-preserving isotropic turbulence revisited

The assumption of self-preservation allows for an analytical determination of the energy decay in isotropic turbulence. Here, the self-preserving isotropic decay problem is analyzed, yielding a more complete picture of self-serving isotropic turbulence. It is proven rigorously that complete self-serving isotropic turbulence admits two general types of asymptotic solutions: one where the turbulent kinetic energy K approximately t (exp -1) and one where K approximately t (sup alpha) with an exponent alpha greater than 1 that is determined explicitly by the initial conditions. By a fixed point analysis and numerical integration of the exact one-point equations, it is demonstrated that the K approximately t (exp -1) and where K approximately t (sup -alpha) with an exponent alpha greater than 1 that is determined explicitly by the initial conditions. By a fixed point analysis and numerical integration of the exact one-point equations, it is demonstrated that the K approximately t (exp -1) power law decay is the asymptotically consistent high Reynolds number solution; the K approximately 1 (sup -alpha) decay law is only achieved in the limit as t yields infinity and the turbulence Reynolds number vanishes. Arguments are provided which indicate that a K approximately t (exp -1) power law decay is the asymptotic state toward which a complete self-preserving isotropic turbulence is driven at high Reynolds numbers in order to resolve the imbalance between vortex stretching and viscous diffusion.

Speziale, Charles G.↗

A dual-eigenstate polarization preserving fiberoptic sensor

A dual-eigenstate polarization preserving fiberoptic sensor is tested, in which each eigenstate in a polarization preserving fiber forms an interferometer which could measure the temperature and the strain simultaneously. The temperature and strain coefficients for different polarization fibers are measured at the room temperature, indicating that there exist differences in temperature coefficients between two eigenstates in a polarization preserving fiber. The different temperature effects from those eigenstates make it possible to perform the temperature measurement and/or temperature compensation.

Yu, Dong X.↗

On positivity preserving finite volume schemes for compressible Euler equations

Positivity preserving property of first and higher order finite volume schemes for one and two dimensional compressible Euler equations of gas dynamics is considered. A general framework is established which shows the positivity of density and pressure whenever the underlying one dimensional first order building block based on exact or approximate Riemann solver and the reconstruction are both positivity preserving. Appropriate limitation to achieve high order positivity preserving reconstruction is described.

Perthame, Benoit↗

Institutional Memory Preservation at NASA Glenn Research Center

In this era of downsizing and deficit reduction, the preservation of institutional memory is a widespread concern for U.S. companies and governmental agencies. The National Aeronautical and Space Administration faces the pending retirement of many of the agency's long-term, senior engineers. NASA has a marvelous long-term history of success, but the agency faces a recurring problem caused by the loss of these engineers' unique knowledge and perspectives on NASA's role in aeronautics and space exploration. The current work describes a knowledge elicitation effort aimed at demonstrating the feasibility of preserving the more personal, heuristic knowledge accumulated over the years by NASA engineers, as contrasted with the "textbook" knowledge of launch vehicles. Work on this project was performed at NASA Glenn Research Center and elsewhere, and focused on launch vehicle systems integration. The initial effort was directed toward an historic view of the Centaur upper stage which is powered by two RL-10 engines. Various experts were consulted, employing a variety of knowledge elicitation techniques, regarding the Centaur and RL-10. Their knowledge is represented in searchable Web-based multimedia presentations. This paper discusses the various approaches to knowledge elicitation and knowledge representation employed, and assesses successes and challenges in trying to perform large-scale knowledge preservation of institutional memory. It is anticipated that strategies for knowledge elicitation and representation that have been developed in this grant will be utilized to elicit knowledge in a variety of domains including the complex heuristics that underly use of simulation software packages such as that being explored in the Expert System Architecture for Rocket Engine Numerical Simulators.

Coffey, J.↗

Preservation Methods Utilized for Space Food

Food for manned space flight has been provided by NASA-Johnson Space Center since 1962. The various mission scenarios and space craft designs dictated the type of food preservation methodologies required to meet mission objectives. The preservation techniques used in space flight include freeze-dehydration, thermostabilization, irradiation, freezing and moisture adjustment. Innovative packaging material and techniques enhanced the shelf-stability of the food items. Future space voyages may include extended duration exploration missions requiring new packaging materials and advanced preservation techniques to meet mission goals of up to 5-year shelf-life foods.

Vodovotz, Yael↗

Knowledge Preservation Techniques That Can Facilitate Intergroup Communications

We have developed tools, social methods and software, for (1) acquiring technical knowledge from engineers and scientists, (2) preserving that knowledge, (3) making the totality of our stored knowledge rapidly searchable. Our motivation has been, mainly, to preserve rare knowledge of senior engineers who are near retirement. Historical value of such knowledge, and also of our tools, has been pointed out to us by historians. We now propose the application these tools to enhancing communication among groups that are working jointly on a project. Of most value will be projects having groups among whom communication is rare and incomplete. We propose that discussions among members of a group be recorded in audio and that both the actual audio and transcriptions of that audio, and optional other pieces be combined into electronic, webpage-like "books". These books can then be searched rapidly by interested people in other groups. At points of particular interest, a searcher can zoom in on the text and even on the original recordings to pick up nuances (e.g. to distinguish a utterance said in seriousness from one in sarcasm). In this matter, not only can potentially valuable technical details be preserved for the future, but communication be enhanced during the life of a joint undertaking.

Moreman, Douglas↗

Sedimentary Parameters Controlling Occurrence and Preservation of Microbial Mats in Siliciclastic Depositional Systems

Shallow-marine, siliciclastic depositional systems are governed by physical sedimentary processes. Mineral precipitation or penecontemporaneous cementation play minor roles. Today, coastal siliciclastic environments may be colonized by a variety of epibenthic, mat-forming cyanobacteria. Studies on microbial mats showed that they are not randomly distributed in modern tidal environments. Distribution and abundancy is mainly function of a particular sedimentary facies. Fine-grained sands composed of "clear" (translucent) quartz particles constitute preferred substrates for cyanobacteria. Mat-builders also favor sites characterized by moderate hydrodynamic flow regimes, which permit biomass enrichment and construction of mat fabrics without lethal burial of mat populations by fine sediments. A comparable facies relationship can be observed in ancient siliciclastic shelf successions from the terminal Neoproterozoic Nama Group, Namibia. Wrinkle structures that record microbial mats are present but sparsely distributed in mid- to inner shelf sandstones of the Nudaus Formation. The sporadic distribution of these structures reflects both the narrow ecological window that governs mat development and the distinctive taphonomic conditions needed to preserve the structures. These observations caution that statements about changing mat abundance across the Proterozoic-Cambrian boundary must be firmly rooted in paleoenvironmental and taphonomic analysis. Understanding the factors that influence the formation and preservation of microbial structures in siliciclastic regimes can facilitate exploration for biological signatures in Earth's oldest rocks. Moreover, insofar as these structures can be preserved on bedding surfaces and are not easily mimicked by physical processes, they constitute a set of biological markers that can be searched for on Mars by remotely controlled rovers.

Noffke, Nora↗

Mars Hematite Site: Potential for Preservation of Microfossils

Defining locations where conditions may have been favorable for life is a key objective for the exploration of Mars. Of prime importance are sites where conditions may have been favorable for the preservation of evidence of pre-biotic or biotic processes. Areas displaying significant concentrations of the mineral hematite (alpha-Fe2O3) have been identified from orbit by thermal emission spectrometry. The largest such deposit, in Sinus Meridiani, is a strong candidate landing site for one of the twin Mars Exploration Rovers, scheduled to launch in 2003. The Martian hematite site may have significance in the search for evidence of extraterrestrial life. Since iron oxides can form as aqueous mineral precipitates, the potential exists for preserving microscopic evidence of life in ecosystems that deposit iron oxides. Terrestrial hematite deposits proposed as possible analogs for the hematite sites on Mars include massive (banded) iron formations, iron oxide hydrothermal deposits, iron-rich laterites and ferricrete soils, and rock varnish. We are engaged in a systematic effort to document the evidence of life preserved in iron oxide deposits from each of these environments.

Allen, Carlton C.↗